CN101525459A - Plasticine with rainbow colors and manufacture method thereof - Google Patents
Plasticine with rainbow colors and manufacture method thereof Download PDFInfo
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- CN101525459A CN101525459A CN200810218194A CN200810218194A CN101525459A CN 101525459 A CN101525459 A CN 101525459A CN 200810218194 A CN200810218194 A CN 200810218194A CN 200810218194 A CN200810218194 A CN 200810218194A CN 101525459 A CN101525459 A CN 101525459A
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- plasticine
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- polyvinyl alcohol
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/001—Toy-moulding appliances; Toy moulding
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Abstract
The invention discloses plasticine and a manufacture method thereof. The plasticine comprises the main raw materials of polyvinyl alcohol, Kathon, propanediol or propanetriol, xanthan gum, borax and glitter. The Plasticine with rainbow colors has crystal appearance, dazzlingly beautiful color, pliability, no easy crack and good plasticity, has better tenacity and very good shaping effect when being compared with the prior plasticine, has no toxicity, odor and pollution, is not easy to mildew and deteriorate, is suitable for being used as toys and teaching aids for infants and pupils and is also suitable for being used as the raw material of sculpture and arts and crafts design.
Description
Technical field
The present invention relates to a kind of child, pupil's toy, teaching aid, also be applicable to the mould raw material of sculpture, arts and crafts design, particularly a kind of plasticine (clay) and production method thereof.
Background technology
Plasticine (clay) is a kind of child of inspiration, pupil's culture space imagination and manipulative ability and toy, the teaching aid that increases intelligence, and traditional plasticine generally is with compositions such as stone powder or flour, grease or paraffin, Vaseline, pigment, essence.Used stone powder has lime carbonate, talcum powder or kaolin, and used essence is nontoxic mineral dye or pigment dyestuff.But water-retentivity and elasticity that this plasticine has are bad, and is dry easily, and color is also relatively more dull, so people have carried out prescription and technologic improvement to plasticine in recent years, for example:
1, Chinese patent: application number: 03111236.6, title: a kind of color mud and making method, open (bulletin) number: CN1441024, application (patent right) people: Zhang Fengwu, address: No. 85 first in ShenYang, Liaoning Province city Tiexi District brocade worker one street, summary: a kind of color mud and making method, raw material by following weight is made, paper mud 400-600 gram, potassium sorbate 5-15 gram, polyvinyl acetate emulsion 5-10 gram, poster paint 15-35 gram, it is even that above-mentioned each raw material than part is put into container for stirring, promptly forms finished product.
2, Chinese patent: application number: 00123233.9 title: a kind of making method of normal temperature plasticine, open (bulletin) number: CN1352217 applies for (patent right) people: Liu Yi; Wu Dechen, the address: one section Lu xun academy of fine arts sculpture for city studio, three good streets, peace zone, ShenYang, Liaoning Province city, summary: this invention relates to the improvement of carving material.Be according to a certain percentage, Microcrystalline Wax, white vaseline, rosin put into metal vessel heat, after reaching certain fusing point, pour powder filler into and stir evenly, after the cooling promptly.Advantage of the present invention is, the density height, and viscosity is good, good hand touch, moulding sure, hand is difficult for foundry loam, sticking look, and is not yielding under the normal temperature, aseptic nontoxic, do not pollute.Be not only applicable to sculpture, be applicable to Industrial Moulding Design, architectural design, industrial art, Mold Making, art education and toy for children etc. yet.
3, Chinese patent: application number: 92108317.3 applyings date: 1992.01.27 title: Atoxic plasticine composition and method for making thereof, open (bulletin) number: CN1063701, application (patent right) people: Pijiang Rubber Factory, Shanghai, address: No. 141 inventions in Pudong Dongning County road, Shanghai City (design) people: Hu Chunhua, summary: a kind of Atoxic plasticine composition and preparation method thereof, said composition comprises polyvinyl chloride (PVC) paste resin, dibutyl phthalate and/or dioctyl phthalate (DOP), Vaseline, and/or the optional auxiliary material of nothing: pigment, essence, talcum powder, silicone oil.
What the plasticine of above-mentioned open source literature report had can overcome water-retentivity and the bad problem of elasticity, but color is gorgeous not enough,
Summary of the invention
The purpose of this invention is to provide a kind of plasticine and production method thereof, it is glittering and translucent that this plasticine has outward appearance, bright-colored brilliant, has softness, is not easy effect dry and cracked, that plasticity-is good.
The composition and the mass fraction of the main raw material of plasticine of the present invention are:
Polyvinyl alcohol 8.0-20.0 part;
Block loose 0.05-0.1 part;
Propylene glycol or glycerol 1.0-20.0 part;
Xanthan gum 2.0-10.0 part;
Glitter powder 2.0-15.0 part;
Borax 1.0-8.0 part;
Water 20-80% part.
Above-described polyvinyl alcohol English name is: polyvinyl alcohol, and viny alcohol polymer, poval is called for short PVA, molecular formula: [C
2H
4O] n; Polyvinyl alcohol (being called for short PVA) outward appearance is a white powder; it is a kind of purposes high molecular weight water soluble polymer quite widely; performance is between plastics and rubber; has unique powerful cementability; the epithelium snappiness; smoothness; oil-proofness; solvent resistance; protective colloid; gas barrier performance; wear resistance and the water tolerance that has through special processing; therefore except making fibrous material; also be used to produce coating in a large number; tackiness agent; the paper product machining agent; emulsifying agent; dispersion agent; products such as film, range of application spreads all over weaving; food; medicine; building; wood working; papermaking; printing; agricultural; iron and steel; industries such as macromolecule chemical industry.The performance of polyvinyl alcohol resin series product: white solid, nonpoisonous and tasteless, pollution-free, can in 80--90 ℃ of water, dissolve.Its aqueous solution has good cementability and film-forming properties; Most of organic solvents such as ability oils, lubricant and hydro carbons; In plasticine, add polyvinyl alcohol and can guarantee plasticine cementability and good film-forming property, be not easy dry and cracked.
Above-described card pine both can be used as sanitas, and external trade name " KATHON CG " (Ka Song or triumphant pine) is the isothiazolinone compounds for its active part, for example: 5-Chloro-2-methyl-3 (2H)-isothiazolone; (5 chloro-2-methyl-3 (2H), isothiazolinone); 5-Chloro-2-methyl-Isothiazolone; (5-chloro-2-methylisothiazolinone); 5-Chloro-2-methyl-4-isothiazolin-3-one; (5-chloro-2-methyl-4-isothiazoline-3-ketone); 2-Methyl-2,3-dihydroisothiazol-3-one; (2-methyl-2,3-isothiazoline-3-ketone); 2-Methyl-3-isothiazolone; (2-methyl-3-isothiazolinone); 2-Methylisothiazol-3-one; (2-methyl isothiazoline-3-ketone); Methyl-3 (2H)-isothiazolone; (2-methyl-3 (2H)-isothiazolones); 2-Methyl-4-Isothiazolin-3-one; (2-methyl-4-isothiazoline-3-ketone) etc., the card pine can be used as anti-virus activities bactericide, can effectively suppress and go out except that mushroom and various microorganism, and efficient, nontoxic, restraining and sterilizing bacteria wide spectrum, long-lasting are long.Good with various colorants, starch intermiscibility, have excellent compatibility.And can not change the smell and the color of plasticine.
Described propylene glycol or glycerol (glycerine), it is the pleasantly sweet viscous liquid of no color or smell, can be synthetic by the propylene in the oil pyrolysis gas, glycerine is the soapmaking industry byproduct, propylene glycol or glycerol are important Organic Chemicals, can be used for the production various kinds of resin, also can be used as solvent, moisture adsorbent, frostproofer, sweeting agent, weaving with shrinkproof treatment agent, diffusant, permeate agent and lubricant etc., water-absorbent is very strong, in plasticine, add propylene glycol or glycerol can guarantee the plasticine softness, be not easy dry and cracked.
Described xanthan gum is by starch, sucrose or glucose microbial polysaccharide outside the born of the same parents that the Xanthomonas campestris fermentation produces.Because its macromole special construction and colloid property, contain a large amount of hydrophilic radicals in the molecule, and has multiple function, can be used as the tackiness agent of emulsifying agent, stablizer, gelling thickener, treating compound, film forming agent, suspending agent and pharmaceutical tablet etc., also the framework controlled release preparation be can prepare, toothpaste, shampoo, hair style setting and hair dye etc. are widely used in.Xanthan gum is a kind of pale yellow brown city or grey brown city powder, and it has the main chain of Mierocrystalline cellulose glucose, contains the side chain of trisaccharide, and therefore some side chain band pyruvic acid and acetic acid group have many excellent characteristic.Xanthan gum is soluble in water, and its aqueous solution is transparent glue.The xanthan chamber is dissolved in hot water or the cold water fully.Very low concentration has very high viscosity, and plasticity-is good, no hysteresis quality.Also promptly, shearing force input back viscosity is recovered initial value immediately, and xanthan gum solution has higher pseudo-plasticity, and viscosity is just very big when lower concentration; Can in the pH of broad and temperature range, keep stable; In alkalescence and high content of salt system. stability is also fine; The antibiont acid degradation; Have good emulsification, dispersing property.So the inventor is used as the main raw material of plasticine with xanthan gum.
Described glitter powder is by the high plastics plating aluminium color film of smart brightness, and for example plating aluminium color films such as PET, PE, PVC are made with extra care through deep processing and formed.Its material has PET, PVC, OPP, alumina etc., the glitter powder particle diameter from 0.004mm-1.0mm all can, its shape has quadrangle, sexangle, rectangle etc.The glitter powder color has gold, silver color, redness, yellow, blueness, green, black, light blue, rose-red, purple, grey violet, illusion-colour pink, rainbow orange, rainbow pink, pearly-lustre look, radium-shine etc.Each colour system can add the upper epidermis protective layer.Material is handled on top layer as a kind of effect uniqueness, and glitter powder is widely used in christmas crafts product, candle technology, makeup, silk screen printing industry (cloth, leather-like, shoemaking class-footwear material class, ew Year pictures series), finishing material (glass skill product, polycrystalline glass; Crystal ball), field such as paint decoratees, furniture sprays paint, its characteristics are to strengthen the visual effect of product, make that decorative parts is concavo-convex to have levels, and have more stereoscopic sensation.The characteristic that it highly glistens, make again simultaneously ornament dazzlingly beautiful, add brilliance doubly.So add the visual effect that glitter powder can strengthen product at plasticine.
Of the present invention seven color plasticine can also further add pigment, and then add glitter powder, so just can guarantee the homogeneity of color.Described pigment comprises mineral dye or pigment dyestuff, can select for use: carbon black, titanium dioxide (titanium white), phthalein viridescent, phthalocyanine blue, permanent bordeaux FGR, permanent yellow 5GX, Fast Yellow 10G, nontoxic environmental-friendly pigments such as green, the red iron oxide of solid orange, fluorescent red, lucifer yellow, fluorescent indigo plant, fluorescent, lithopone, iron oxide green, lemon yellow, Sunset yellow, famille rose, light blue, amaranth, tetraiodofluorescein, greyish purple, brilliant black, chocolate brown, light green, antholeucin, amaranth forever.Pigment approximately is 0.5-5 part at the mass fraction of plasticine, but in fact general according to the depth of required color, deep or light decision.
Of the present invention seven color plasticine can also further add luminous color, described luminous color can be ZnS, fluorite (Calcium Fluoride (Fluorspan)), contain raw material powder such as manganese cleavage stone, the ore that contains rare earth, barium nickel minerals, use luminescent powder separately, make the effect of noctilucence, this is that conventional plasticine is not accomplished.
Of the present invention seven color plasticine can also further add essence, and the essence of use is food flavour, when making child, pupil's toy, teaching aid, add the fruity food flavour, and the child is preferred.
The production method of seven color plasticine of the present invention is: earlier polyvinyl alcohol is used 80-95 ℃ of hot water dissolving, add card pine, propylene glycol or glycerol, xanthan gum, borax and glitter powder then, add pigment, luminescent powder as required, stir, can obtain seven color plasticine glittering and translucent, the golden light flicker.
Outstanding substantive distinguishing features of the present invention and obvious improvement are:
1, seven color plasticine products have softness, are not easy effect dry and cracked, that plasticity-is good, toughness compared with present plasticine is better, extraordinary molding effect is arranged, pull into rectangular, be difficult for breaking, can cover any surface, can be used for child, pupil's toy, teaching aid, also be applicable to the raw material of sculpture, arts and crafts design.
2, product appearance is glittering and translucent, and is bright-colored brilliant, honorable tempting, can strengthen the visual effect of product especially after plasticine adds glitter powder, luminescent powder.
2, seven color plasticine pigment product are that pigment making processes is simple, and are nonpoisonous and tasteless, pollution-free, are not easy moldy metamorphism, are a kind of safe child, pupil's toy, teaching aid product.
Embodiment
Embodiment 1
With 10 kilograms of 80-95 ℃ of hot water dissolvings of 8 kilograms of usefulness of polyvinyl alcohol, add 0.05 kilogram of card pine then, 2 kilograms of propylene glycol, 2 kilograms of xanthan gum earlier, 1 kilogram of borax, 2 kilograms of golden glitter powders, fluorescent red stirs for 0.5 kilogram, can obtain seven color plasticine of golden red.
Embodiment 2
With 18 kilograms of 80-95 ℃ of hot water dissolvings of 15 kilograms of usefulness of polyvinyl alcohol, add 0.05 kilogram of card pine then, 2 kilograms of propylene glycol, 2 kilograms of xanthan gum earlier, 1 kilogram of borax, 2 kilograms of yellow glitter powders, 0.5 kilogram of permanent yellow 5GX, stir, can obtain xanchromatic seven color plasticine.
Embodiment 3
With 20 kilograms of polyvinyl alcohol, add 0.08 kilogram of card pine then earlier, 10 kilograms of glycerol, 9 kilograms of xanthan gum, 5 kilograms of boraxs, 12 kilograms of light blue glitter powders, phthalocyanine blue stirs for 1 kilogram, can obtain seven blue color plasticine.
Embodiment 4
With 25 kilograms of 80-95 ℃ of hot water dissolvings of 15 kilograms of usefulness of polyvinyl alcohol, add 0.06 kilogram of card pine then, 8 kilograms of propylene glycol, 5 kilograms of xanthan gum earlier, 3 kilograms of boraxs, 2 kilograms of silver color glitter powders, titanium dioxide stirs for 5 kilograms, can obtain argenteous seven color plasticine.
Embodiment 5
Earlier with 20 kilograms of polyvinyl alcohol, 10 kilograms of light calcium carbonates, with 30 kilograms of 80-95 ℃ of hot water dissolving's polyvinyl alcohol, add 0.08 kilogram of card pine then, 7 kilograms of glycerol, 6 kilograms of xanthan gum, 4 kilograms of boraxs, 10 kilograms of rainbow orange glitter powders, amaranth stirs for 0.3 kilogram, can obtain seven red color plasticine.
Embodiment 6
With 18 kilograms of 80-95 ℃ of hot water dissolvings of 12 kilograms of usefulness of polyvinyl alcohol, add 0.07 kilogram of card pine then, 4 kilograms of glycerol, 4 kilograms of xanthan gum earlier, 1 kilogram of borax, 2 kilograms of purple glitter powders, 0.5 kilogram of greyish purple pigment, stir, can obtain seven greyish purple color plasticine.
Embodiment 7
With 20 kilograms of polyvinyl alcohol,, add 0.1 kilogram of card pine then earlier with 40 kilograms of 80-95 ℃ of hot water dissolvings, 6 kilograms of glycerol, 6 kilograms of xanthan gum, 3 kilograms of boraxs, 12 kilograms of green glitter powders, light green pigment stirs for 0.8 kilogram, can obtain seven green color plasticine.
Embodiment 8
Earlier with 20 kilograms of polyvinyl alcohol, with 60 kilograms of 80-95 ℃ of hot water dissolvings, add 0.1 kilogram of card pine then, 7 kilograms of glycerol, 6 kilograms of xanthan gum, 3 kilograms of boraxs, 12 kilograms of luminescent powders (Calcium Fluoride (Fluorspan)), the fluorescent material red stirs for 0.5 kilogram, can obtain peach noctilucence plasticine.
Claims (6)
1, a kind of seven color plasticine is characterized in that: the composition and the mass fraction of its main raw material are:
Polyvinyl alcohol 8.0-20.0 part;
Block loose 0.05-0.1 part;
Propylene glycol or glycerol 1.0-20.0 part;
Xanthan gum 2.0-10.0 part;
Glitter powder 2.0-15.0 part;
Borax 1.0-8.0 part;
Water 20-80% part.
2, according to claim 1 seven color plasticine is characterized in that: described glitter powder is made with extra care through deep processing by the high plastics plating aluminium color film of the smart brightness of multiple color and is formed.
3, according to claim 1 seven color plasticine is characterized in that: described seven color plasticine can further add luminescent powder.
4, according to claim 1 seven color plasticine is characterized in that: described seven color plasticine can further add pigment, and described pigment comprises mineral dye or pigment dyestuff.
5, according to claim 1 seven color plasticine is characterized in that: described seven color plasticine can further add essence, and the essence of use is food flavour.
6, the production method of seven color plasticine as claimed in claim 1, it is characterized in that: earlier polyvinyl alcohol is used 80-95 ℃ of hot water dissolving, add card pine, propylene glycol or glycerol, xanthan gum, borax and glitter powder then, add pigment, luminescent powder or essence as required, stir, promptly get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810218194A CN101525459A (en) | 2008-12-12 | 2008-12-12 | Plasticine with rainbow colors and manufacture method thereof |
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| CN200810218194A CN101525459A (en) | 2008-12-12 | 2008-12-12 | Plasticine with rainbow colors and manufacture method thereof |
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| CN101525459A true CN101525459A (en) | 2009-09-09 |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102058986A (en) * | 2010-11-22 | 2011-05-18 | 王冠东 | Manufacture method of elastic plasticine |
| CN102220019A (en) * | 2011-04-29 | 2011-10-19 | 东莞市汇欣工贸有限公司 | Industrial greasy filth and preparation method thereof |
| CN102382405A (en) * | 2010-09-03 | 2012-03-21 | 北京市理化分析测试中心 | Hydrogel and use thereof for cleaning and dedusting |
| CN102442798A (en) * | 2010-10-12 | 2012-05-09 | 惠州海翔文教用品有限公司 | Bamboo clay and preparation method thereof |
| CN103044825A (en) * | 2012-12-14 | 2013-04-17 | 深圳云之彩美术工艺用品有限公司 | Noctilucent clay |
| CN104492094A (en) * | 2014-11-28 | 2015-04-08 | 龚䶮 | Non-toxic plasticine and preparation method thereof |
| CN104692716A (en) * | 2013-12-07 | 2015-06-10 | 招远鲁娃婴幼儿用品有限公司 | Toy clay |
| CN104710717A (en) * | 2013-12-12 | 2015-06-17 | 漯河市罗弗文具制造有限公司 | High molecular clay material |
| CN104877285A (en) * | 2014-02-28 | 2015-09-02 | 宁波宝林达进出口有限公司 | Cotton mud preparation process |
| CN104875542A (en) * | 2014-02-28 | 2015-09-02 | 冯志刚 | Color-adjustable kneading molding material micro-sculpture three-dimensional pixel picture and production method thereof |
| CN106237628A (en) * | 2016-08-04 | 2016-12-21 | 陈毅忠 | A kind of preparation method of green edible child's plasticine |
| CN107903447A (en) * | 2017-11-28 | 2018-04-13 | 魏国文 | A kind of pearl mud and its production technology |
| CN108786144A (en) * | 2018-06-15 | 2018-11-13 | 河北农业大学 | Vegetable protein plasticine and preparation method thereof |
| CN113340865A (en) * | 2021-06-09 | 2021-09-03 | 浦江县富盛塑胶新材料有限公司 | Method and material for detecting borax content in plasticine |
| EP3928847A1 (en) * | 2020-06-23 | 2021-12-29 | Canal Toys España Distribución S.L. | Antimicrobial flexible play composition |
| CN114269446A (en) * | 2019-08-16 | 2022-04-01 | 鲜于润 | Method for producing a toy in a liquid using a model frame and device for carrying out said method |
| CN116376117A (en) * | 2023-01-31 | 2023-07-04 | 博士爱玩具有限公司 | Child toy color mud and preparation method thereof |
-
2008
- 2008-12-12 CN CN200810218194A patent/CN101525459A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382405A (en) * | 2010-09-03 | 2012-03-21 | 北京市理化分析测试中心 | Hydrogel and use thereof for cleaning and dedusting |
| CN102382405B (en) * | 2010-09-03 | 2014-08-20 | 北京市理化分析测试中心 | Hydrogel and use thereof for cleaning and dedusting |
| CN102442798A (en) * | 2010-10-12 | 2012-05-09 | 惠州海翔文教用品有限公司 | Bamboo clay and preparation method thereof |
| CN102058986A (en) * | 2010-11-22 | 2011-05-18 | 王冠东 | Manufacture method of elastic plasticine |
| CN102058986B (en) * | 2010-11-22 | 2012-05-02 | 王冠东 | Manufacture method of elastic plasticine |
| CN102220019A (en) * | 2011-04-29 | 2011-10-19 | 东莞市汇欣工贸有限公司 | Industrial greasy filth and preparation method thereof |
| CN102220019B (en) * | 2011-04-29 | 2012-12-05 | 东莞市汇欣工贸有限公司 | Industrial greasy filth and preparation method thereof |
| CN103044825A (en) * | 2012-12-14 | 2013-04-17 | 深圳云之彩美术工艺用品有限公司 | Noctilucent clay |
| CN103044825B (en) * | 2012-12-14 | 2014-12-10 | 深圳云之彩美术工艺用品有限公司 | Noctilucent clay |
| CN104692716A (en) * | 2013-12-07 | 2015-06-10 | 招远鲁娃婴幼儿用品有限公司 | Toy clay |
| CN104710717B (en) * | 2013-12-12 | 2016-08-24 | 漯河市罗弗文具制造有限公司 | Macromolecule clay material |
| CN104710717A (en) * | 2013-12-12 | 2015-06-17 | 漯河市罗弗文具制造有限公司 | High molecular clay material |
| CN104877285A (en) * | 2014-02-28 | 2015-09-02 | 宁波宝林达进出口有限公司 | Cotton mud preparation process |
| CN104875542A (en) * | 2014-02-28 | 2015-09-02 | 冯志刚 | Color-adjustable kneading molding material micro-sculpture three-dimensional pixel picture and production method thereof |
| CN104492094A (en) * | 2014-11-28 | 2015-04-08 | 龚䶮 | Non-toxic plasticine and preparation method thereof |
| CN106237628A (en) * | 2016-08-04 | 2016-12-21 | 陈毅忠 | A kind of preparation method of green edible child's plasticine |
| CN106237628B (en) * | 2016-08-04 | 2019-02-22 | 长乐智高生物科技有限公司 | A kind of preparation method of the edible children's plasticine of green |
| CN107903447A (en) * | 2017-11-28 | 2018-04-13 | 魏国文 | A kind of pearl mud and its production technology |
| CN108786144A (en) * | 2018-06-15 | 2018-11-13 | 河北农业大学 | Vegetable protein plasticine and preparation method thereof |
| CN114269446A (en) * | 2019-08-16 | 2022-04-01 | 鲜于润 | Method for producing a toy in a liquid using a model frame and device for carrying out said method |
| EP3928847A1 (en) * | 2020-06-23 | 2021-12-29 | Canal Toys España Distribución S.L. | Antimicrobial flexible play composition |
| CN113340865A (en) * | 2021-06-09 | 2021-09-03 | 浦江县富盛塑胶新材料有限公司 | Method and material for detecting borax content in plasticine |
| CN113340865B (en) * | 2021-06-09 | 2024-04-26 | 佛山市奇妙岛科技有限公司 | Material for detecting borax content in plasticine, and preparation method and application thereof |
| CN116376117A (en) * | 2023-01-31 | 2023-07-04 | 博士爱玩具有限公司 | Child toy color mud and preparation method thereof |
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Open date: 20090909 |