CN101708977B - Pearl clay - Google Patents
Pearl clay Download PDFInfo
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- CN101708977B CN101708977B CN2009101106483A CN200910110648A CN101708977B CN 101708977 B CN101708977 B CN 101708977B CN 2009101106483 A CN2009101106483 A CN 2009101106483A CN 200910110648 A CN200910110648 A CN 200910110648A CN 101708977 B CN101708977 B CN 101708977B
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- clay
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- pearl
- pearl clay
- water
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- 239000004927 clay Substances 0.000 title claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229910021538 borax Inorganic materials 0.000 claims abstract description 11
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 11
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 22
- 239000004794 expanded polystyrene Substances 0.000 claims description 16
- 239000000945 filler Substances 0.000 claims description 16
- 229920006327 polystyrene foam Polymers 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- 239000000976 ink Substances 0.000 claims description 12
- 239000000080 wetting agent Substances 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 9
- 235000011613 Pinus brutia Nutrition 0.000 claims description 9
- 241000018646 Pinus brutia Species 0.000 claims description 9
- -1 polyoxyethylene Polymers 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 238000005054 agglomeration Methods 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 abstract description 2
- 229920001285 xanthan gum Polymers 0.000 abstract description 2
- 239000000230 xanthan gum Substances 0.000 abstract description 2
- 229940082509 xanthan gum Drugs 0.000 abstract description 2
- 235000010493 xanthan gum Nutrition 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract 1
- 238000005187 foaming Methods 0.000 abstract 1
- 239000003906 humectant Substances 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 9
- 229920002451 polyvinyl alcohol Polymers 0.000 description 9
- 239000000049 pigment Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 210000001835 viscera Anatomy 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 2
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- KPIQXPLWZCDIHI-ISLYRVAYSA-N 5-hydroxy-1-(4-sulfophenyl)-4-[(e)-(4-sulfophenyl)diazenyl]-1h-pyrazole-3-carboxylic acid Chemical compound OC(=O)C1=NN(C=2C=CC(=CC=2)S(O)(=O)=O)C(O)=C1\N=N\C1=CC=C(S(O)(=O)=O)C=C1 KPIQXPLWZCDIHI-ISLYRVAYSA-N 0.000 description 1
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 206010009866 Cold sweat Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000123069 Ocyurus chrysurus Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 241000589636 Xanthomonas campestris Species 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- AMPCGOAFZFKBGH-UHFFFAOYSA-O [4-[[4-(dimethylamino)phenyl]-[4-(methylamino)phenyl]methylidene]cyclohexa-2,5-dien-1-ylidene]-dimethylazanium Chemical compound C1=CC(NC)=CC=C1C(C=1C=CC(=CC=1)N(C)C)=C1C=CC(=[N+](C)C)C=C1 AMPCGOAFZFKBGH-UHFFFAOYSA-O 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 238000010564 aerobic fermentation Methods 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- AOADSHDCARXSGL-ZMIIQOOPSA-M alkali blue 4B Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N.[Na+] AOADSHDCARXSGL-ZMIIQOOPSA-M 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000001058 brown pigment Substances 0.000 description 1
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- HBHZKFOUIUMKHV-UHFFFAOYSA-N chembl1982121 Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HBHZKFOUIUMKHV-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000012407 engineering method Methods 0.000 description 1
- SEACYXSIPDVVMV-UHFFFAOYSA-L eosin Y Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 SEACYXSIPDVVMV-UHFFFAOYSA-L 0.000 description 1
- PLYDMIIYRWUYBP-UHFFFAOYSA-N ethyl 4-[[2-chloro-4-[3-chloro-4-[(3-ethoxycarbonyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]phenyl]phenyl]diazenyl]-5-oxo-1-phenyl-4h-pyrazole-3-carboxylate Chemical compound CCOC(=O)C1=NN(C=2C=CC=CC=2)C(=O)C1N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(=N1)C(=O)OCC)C(=O)N1C1=CC=CC=C1 PLYDMIIYRWUYBP-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- KQSBZNJFKWOQQK-UHFFFAOYSA-N hystazarin Natural products O=C1C2=CC=CC=C2C(=O)C2=C1C=C(O)C(O)=C2 KQSBZNJFKWOQQK-UHFFFAOYSA-N 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- 229910001000 nickel titanium Inorganic materials 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 235000012752 quinoline yellow Nutrition 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000004172 quinoline yellow Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 description 1
- 229960000943 tartrazine Drugs 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- JEVGKYBUANQAKG-UHFFFAOYSA-N victoria blue R Chemical compound [Cl-].C12=CC=CC=C2C(=[NH+]CC)C=CC1=C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 JEVGKYBUANQAKG-UHFFFAOYSA-N 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses pearl clay. The pearl clay comprises the following components in percentage by weight: 8.0 to 20.0 percent of water-soluble resin, 26.9 to 85.75 percent of water, 0.05 to 0.1 percent of kathon, 1.0 to 20.0 percent of humectant, 2.0 to 10.0 percent of xanthan gum, 2.0 to 15.0 percent of foaming ball filling powder, 1.0 to 8.0 percent of borax and 0.2 to 1.5 percent of colorant. Compared with the prior art, the pearl clay has the advantages that the pearl clay has better hand feel than common clay, and has no greasiness, difficult mildewing, long shelf life, nontoxicity and no peculiar smell; the pearl clay is easy to be sculptured and has excellent stereoscopic feeling after surface forming; and the pearly clay has pearlescent effects and can fully inspire curiosity and imagination of children.
Description
Technical field
The present invention relates to handicraft sculpture, art painting pigment technology field, particularly a kind of nontoxic, ultralight and the pearl clay that can preserve for a long time.
Background technology
Traditional clay is that plasticine is material of main part with paraffin, rubber, PVC paste resin etc. generally, contains a large amount of softening agent simultaneously, like Witcizer 300 or DOP, Vaseline etc.This plasticine temperature difference bad adaptability (winter hard and pinch motionless, summer heat and be prone to send out stick with paste sticking hand), main is that its component can cause certain toxicity, contaminate environment is harmful to health.
In order to overcome the problems referred to above, present this plasticine is replaced by flours plasticine basically, also is " color mud " on the market.The staple of color mud is flour and water.The color mud of this type produce with use in, have advantages such as nontoxic, pollution-free, good hand touch, but the finished product of processing often shrinks because of the surface-moisture evaporation after placing for some time, even chaps, can't accomplish permanent preservation.
In order to overcome the shortcoming of color mud, at present, the fashionable market of a kind of lightweight resin clay is arranged more, it is good that it has a plasticity, lightweight, softness is difficult for be full of cracks, advantage such as can preserve for a long time, not only as the instrument of tap intellectual resources, even can be used to craft articles.
Above-mentioned lightweight resin clay all is to adopt polyvinyl alcohol resin (PVA) as adhesive substance now basically, and hollow microsphere is mixed and made into as main body filler and water.But use the PVA of incomplete alcoholysis merely, then cause product to be clamminess easily, catch and touch even can be stained with to hand.The product stability of making is poor, and quality is hard, and fast drying.
Adhesive resin uses a certain proportion of PVA+CMC in the patent 02801940.7, adds an amount of boric acid, the agent of borax isogel, can significantly improve the use processing property and the processability of clay.Patent 200610075786.9 has proved to have only Z 150PH and wetting Agent for Printing Inks, jelling agent mating reaction could obtain all excellent light clay composition of each item performance.U.S. Pat P5171766,5506280,5364892,6359057 also is to use PVA as adhesive substance, is used certain jelling agent again.
So above patent all adopts the PVA resin, the jelling agent of matched with proper carries out crosslinked, reaches to reduce PVA viscosity, and increases the purpose of its flexibility.But the addition of jelling agent is difficult with control, and promptly the gelationization degree to PVA is difficult to grasp.Simultaneously, because borax etc. is hot reversible to the gelationization of PVA, so the envrionment temperature height is also bigger to the influence of gel degree.And its form of above-mentioned clay is single, for the user, lacks novel sense, can't excite the youngster heavy curiosity and the imagination.
Summary of the invention
In order to solve the weak point that exists in the above-mentioned prior art, the pearl clay that the purpose of this invention is to provide a kind of nontoxic, ultralight and can preserve for a long time.
The object of the invention is realized through following technical proposals: a kind of pearl clay, it mainly is made up of water soluble resin, water, card pine, wetting Agent for Printing Inks, XG 550, foamed ball filler powder, borax, tinting material
The composition and the mass percent of the main raw material of pearl clay of the present invention are:
Water soluble resin 8.0-20.0%
Water 26.9-85.75%
Block loose 0.05-0.1%
Wetting Agent for Printing Inks 1.0-20.0%
XG 550 2.0-10.0%
Foamed ball filler powder 2.0-15.0%
Borax 1.0-8.0%
Tinting material 0.2-1.5%
Above-described water soluble resin is: Z 150PH.
Above-described wetting Agent for Printing Inks is: any one of USP Kosher, Ucar 35, glycerine, polyoxyethylene glycol, sorbyl alcohol, triglycerin, 3,4 one glycol ethers, vegetables oil, MO or two or more mixtures.
Described foamed ball filler powder is: treated expanded polystyrene foam, starch mix any one or the two or more mixtures that forms in the high de-agglomeration polymer composites foam with the bulk goods of POLYACTIC ACID.
The particle diameter of described foamed ball filler powder is 0.5-1mm or 3-4mm.
Described tinting material is: any one or two or more mixtures in organic toner or the fluorescence toner.
The present invention compared with prior art has following advantage: than conventional clay good hand touch, non-greasy; Be difficult for mouldy, long quality-guarantee period; Nontoxic, free from extraneous odour, this kind pearl clay are prone to sculpture and are shaped, and good stereoscopic sensation is arranged behind the surface forming; Pearlescent effect is arranged, can well excite youngster heavy curiosity and fancy.
Embodiment
Below in conjunction with embodiment the present invention is done to specify further, but embodiment is not limited to this.
The water soluble resin that the present invention adopted is: Z 150PH;
The chemical name of the card pine that the present invention adopted: 5-chloro-2 methyl-4 isothiazoline-3 ketone and 2-methyl-4-isothiazoline-3-ketone (RH-893 Isothiazolinones); Trade name: Ka Songkaisong English name: Kathon; CAS No.26172-55-4,2682-20-4; Molecular formula: C4H4ClNOS+C4H5NOS; Molecular weight: 149.56+115.06; Quality standard: Q/SH006-1998.
The physical and chemical performance of this kind card pine is: these article are the aqueous solution of said mixture, and outward appearance is the light amber transparent liquid, and smell is gentle; Specific density (20/4) 1.19 viscosity (23) 5.0mpa.s, zero pour-18-21.5, pH3.5-5.0; It is soluble in water, low-carbon alcohol and terepthaloyl moietie.The best pH value 4-8 that uses, pH＞8 o'clock stability decreases was stored 1 year under the room temperature, stored half a year in 50 o'clock, active decline seldom, high temperature storage is active to descend, it can with emulsifying agent, the protein compatibility of negatively charged ion, positively charged ion, nonionic and various ionics.
The wetting Agent for Printing Inks that the present invention adopted is: any one of USP Kosher, Ucar 35, glycerine, polyoxyethylene glycol, sorbyl alcohol, triglycerin, 3,4 one glycol ethers, vegetables oil, MO or two or more mixtures; The preferred USP Kosher that adopts.
The XG 550 that the present invention adopted, XG 550 are claimed yellow glue, xanthan gum again, are a kind of natural polysaccharide and important biopolymer, are main raw material with the glucide by the cabbage black rot xanthomonas campestris, produce through the aerobic fermentation biotechnology; Molecular formula: (C35H49O29) n; CAS number: 11138-66-26; Outward appearance: pale or light beige powder.The extraction making method of this kind XG 550 can be with reference to Chinese invention patent publication number " CN1394878 ", and open day " 2003.02.05 ", denomination of invention is " engineering method of XG 550 separation and Extraction " disclosed associated viscera.
The foamed ball filler powder that the present invention adopted is: treated expanded polystyrene foam, starch mix any one or the two or more mixtures that forms in the high de-agglomeration polymer composites foam with the bulk goods of POLYACTIC ACID. Preferably, treated expanded polystyrene foam; Foamed ball filler powder is made method can be with reference to Chinese invention patent publication number " CN101528825 "; Open day " 2009.09.09 "; Denomination of invention is " treated expanded polystyrene foam " disclosed associated viscera; Perhaps Chinese invention patent publication number " CN101440169 " discloses day " 2009.05.27 ", and denomination of invention is " method for making of environmental-protecting foam material " disclosed associated viscera; Also or the above-mentioned treated expanded polystyrene foam of other known making or powder mix with the bulk goods of POLYACTIC ACID and form high de-agglomeration polymer composites foamy method, repeat no more here.
In the preferred 2-3mm scope of the particle diameter of foamed ball filler of the present invention.
The tinting material that the present invention adopted is: any one or two or more mixtures in organic toner or the fluorescence toner; Adopt those skilled in the art easily to select suitable pigment to get final product in a word according to required clay.For example, can be carbon black, rubber black etc. as black pigment.As yellow ultramarine can be such as but not limited to organic yellow, permanent yellow, yellow oxide of iron, zinc yellow, nickel titanium yellow, Naples yellow, naphthol yellow S, hansa yellow G, organic yellow 10G, quinoline yellow, Tartrazol yellow etc.As orange pigments can be such as but not limited to molybdate orange, permanent orange etc.As red pigment can such as but not limited to: sun-proof is red, permanent bordeaux, red iron oxide, madder lake, crimson lake, lithol red, pyrazolone red, C lake red CAN'T D, eosine lake, rhodamine color lake B, alizarine lake etc.As brown pigments such as but not limited to umber, loess, burnt ochre, burnt sienna etc.As violet pigment can be such as but not limited to permanent violet, iron oxide purple, pyoktanin blue color lake etc.As blue pigments can be such as but not limited to: phthalocyanine blue, ultramarine, Prussian blue, cobalt blue, alkali blue lake, victoria blue color lake, indanthrene blue etc.As veridian can be such as but not limited to phthalocyanine green, pigment green B, Victoria Green WPB color lake, naphthol green etc.As white pigment can be such as but not limited to titanium oxide, zinc white, zinc sulfate etc.Above-mentioned pigment can use separately, also can two or more combinations use.
Embodiment 1
In the present embodiment, water soluble resin is a Z 150PH, and wetting Agent for Printing Inks is a USP Kosher, and foamed ball filler powder is treated expanded polystyrene foam, and tinting material is the permanent bordeaux toner.The composition and the mass percent of the main raw material of the red pearl clay of this kind are:
Z 150PH 10.0%
Water 70.45%
Card pine 0.05%
USP Kosher 10.0%
XG 550 2.0%
Expanded polystyrene foam 5.0%
Borax 2.0%
Permanent bordeaux toner 0.5%
Embodiment 2
In the present embodiment, water soluble resin is a Z 150PH, and wetting Agent for Printing Inks is a USP Kosher, and foamed ball filler powder is treated expanded polystyrene foam, and tinting material is the phthalocyanine blue toner.The composition and the mass percent of the main raw material of the Day-Glo blue pearl clay of this kind are:
Z 150PH 10.0%
Water 70.75%
Card pine 0.05%
USP Kosher 10.0%
XG 550 2.0%
Expanded polystyrene foam 5.0%
Borax 2.0%
Phthalocyanine blue toner 0.2%
Embodiment 3
In the present embodiment, water soluble resin is a Z 150PH, and wetting Agent for Printing Inks is a USP Kosher, and foamed ball filler powder is treated expanded polystyrene foam, and tinting material is the fluorescent yellow toner.The composition and the mass percent of the main raw material of this kind fluorescent yellow pearl clay are:
Z 150PH 20.0%
Water 46.45%
Card pine 0.05%
USP Kosher 20.0%
XG 550 2.0%
Expanded polystyrene foam 2.0%
Borax 8.0%
Fluorescent yellow toner 1.5%
Embodiment 4
In the present embodiment, water soluble resin is a Z 150PH, and wetting Agent for Printing Inks is a USP Kosher, and foamed ball filler powder is treated expanded polystyrene foam, and tinting material is a fluorescence purple powder.The composition and the mass percent of the main raw material of this kind fluorescence purple pearl clay are:
Z 150PH 18.5%
Water 26.9%
Card pine 0.1%
USP Kosher 20.0%
XG 550 10.0%
Expanded polystyrene foam 15.0%
Borax 8.0%
Fluorescence purple powder 1.5%
Embodiment 5
Water soluble resin is a Z 150PH, and wetting Agent for Printing Inks is a USP Kosher, and foamed ball filler powder is treated expanded polystyrene foam, and tinting material is the red powder of fluorescent material.The composition and the mass percent of the main raw material of the red pearl clay of this kind fluorescent material are:
Z 150PH 8.0%
Water 85.75%
Card pine 0.05%
USP Kosher 1.0%
XG 550 2.0%
Expanded polystyrene foam 2.0%
Borax 1.0%
Fluorescent material red 0.2%
The above is merely the preferred embodiment of invention, not in order to restriction the present invention, all any modifications of within spirit of the present invention and principle, being done, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. a pearl clay is characterized in that, it mainly is made up of water soluble resin, water, card pine, wetting Agent for Printing Inks, XG 550, foamed ball filler powder, borax, tinting material,
The composition and the mass percent of the main raw material of pearl clay are:
Described water soluble resin is: Z 150PH;
Described foamed ball filler powder is: treated expanded polystyrene foam, starch mix any one or the two or more mixtures that forms in the high de-agglomeration polymer composites foam with the bulk goods of POLYACTIC ACID.
2. pearl clay according to claim 1; It is characterized in that: described wetting Agent for Printing Inks is: any one of USP Kosher, Ucar 35, polyoxyethylene glycol, sorbyl alcohol, triglycerin, 3,4 one glycol ethers, vegetables oil, MO or two or more mixtures.
3. pearl clay according to claim 1 is characterized in that: the particle diameter of described foamed ball filler powder is 0.5-1mm or 3-4mm.
4. pearl clay as claimed in claim 1 is characterized in that: described tinting material is: any one or two or more mixtures in organic toner or the fluorescence toner.
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| KR20180022339A (en) * | 2016-08-24 | 2018-03-06 | 이순동 | Manufacturing method of waterproof clay and waterproof clay thereof |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107903447A (en) * | 2017-11-28 | 2018-04-13 | 魏国文 | A kind of pearl mud and its production technology |
| CN108102266A (en) * | 2017-12-21 | 2018-06-01 | 深圳市学巧教育文化传播有限公司 | A kind of ultralight clay and preparation method thereof |
| CN108299776A (en) * | 2018-01-24 | 2018-07-20 | 佛山市长飞文具有限公司 | snowflake mud and preparation method thereof |
| CN108192249A (en) * | 2018-02-02 | 2018-06-22 | 浙江尚欢工贸有限公司 | It is a kind of for toy-clays of children and preparation method thereof |
| CN108641251A (en) * | 2018-04-10 | 2018-10-12 | 傅伟伟 | A kind of ingredient and preparation method thereof of crystal wire drawing plasticine |
| CN115819905B (en) * | 2021-12-30 | 2024-05-24 | 义乌聚邦玩具有限公司 | High-performance degradable decompression cement gum |
| CN115819906B (en) * | 2021-12-30 | 2024-05-24 | 义乌聚邦玩具有限公司 | Crispy clay composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1843545A (en) * | 2006-04-29 | 2006-10-11 | 盱眙澳图科技开发服务有限公司 | Multipurpose mineral toy wadding |
| CN101070232A (en) * | 2006-05-09 | 2007-11-14 | 北京京师奕阳教育科技有限公司 | Light clay composition and preparing method |
-
2009
- 2009-10-16 CN CN2009101106483A patent/CN101708977B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1843545A (en) * | 2006-04-29 | 2006-10-11 | 盱眙澳图科技开发服务有限公司 | Multipurpose mineral toy wadding |
| CN101070232A (en) * | 2006-05-09 | 2007-11-14 | 北京京师奕阳教育科技有限公司 | Light clay composition and preparing method |
Non-Patent Citations (1)
| Title |
|---|
| 胡海彦 等.《聚氯乙烯ö粘土纳米复合材料的制备及性能》.《高分子材料科学与工程》.2004,第20卷(第5期),162-165. * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20180022339A (en) * | 2016-08-24 | 2018-03-06 | 이순동 | Manufacturing method of waterproof clay and waterproof clay thereof |
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