CN108192249A - It is a kind of for toy-clays of children and preparation method thereof - Google Patents
It is a kind of for toy-clays of children and preparation method thereof Download PDFInfo
- Publication number
- CN108192249A CN108192249A CN201810108170.XA CN201810108170A CN108192249A CN 108192249 A CN108192249 A CN 108192249A CN 201810108170 A CN201810108170 A CN 201810108170A CN 108192249 A CN108192249 A CN 108192249A
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- China
- Prior art keywords
- toy
- clays
- parts
- children
- pigment
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/22—Expandable microspheres, e.g. Expancel®
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- Toys (AREA)
Abstract
The invention discloses a kind of for toy-clays of children and preparation method thereof, the toy-clays are made of following component：1.8 2.2 parts of hollow 9 11 parts of foam microspheres, 27 33 parts of polyvinyl alcohol, 43.2 52.8 parts of water, 9 11 parts of D-sorbite and pigment.The toy-clays that the present invention is made, have product environmentally-friendly sanitary, strong operability, can random moulding, it is safer, more soft, be easier preserve and other effects.
Description
Technical field
The present invention relates to belong to toy articles for use manufacture technology field, and in particular to a kind of toy-clays for children and its
Preparation method.
Background technology
With the raising of China's national income level, people also increasingly increase the attention of children education, and toy for children disappears
There is huge growth space in expense demand.Children are the consumer groups of toy, since children are in the key of body development
Period will greatly jeopardize their physical and mental health using dangerous or unqualified toy.Children are limited by its age lacks self
Protective awareness, the constitution of itself is weaker, while they are for things understanding in itself and dangerous insufficient, it is easy to by outer
The injury or damage of boundary's things.The consumer objects of toy are children, and the physical and mental health of toy safety and children are closely bound up.I
The preamble part of state's Toy Safety Standards (GB6675) is pointed out：" meet the requirement of this standard, be not meant to that parent can be released
Their responsibility is taken care of when children are using toy with educator ", this namely the randomness of child behavior and attract an object for appreciation
Has extremely important basic principle in safety standard.Therefore, work is instructed to can not be ignored using toy children, and uses and play
The problem of tool safety and correctness, should naturally also cause the concern of parent and education side.
Ultralight clay is the children's craft class plastotype being made using hollow foam microspheres, polyvinyl alcohol as primary raw material
Toy has the characteristics that ultralight (equal volume only has 1/4 weight) compared with plasticine, soft, bright in luster, easy plastotype, can air-dry,
Entering classrooms have just gradually been walked by the favorable comment of manual intelligent, art worker deeply since listing, become the indispensable material of children's handwork education
Material.
Ultralight clay quality at present on the market is irregular, the basic moisturizing for adding industry glycerol as ultralight clay
Agent, the application of industry glycerol can be to be easy to causeing injury during children's use, therefore develop and surpass specifically for what children used
Light clay, to protection, children will be significant.
Invention content
It is used in view of the above-mentioned deficiencies in the prior art, it is an object of the present invention on the one hand provide a kind of safer children that are directed to
Plastotype toy-toy-clays, also referred to as ultralight clay or paper clay；On the other hand a kind of above-mentioned plastotype toy is provided
Preparation method.
To achieve the above object, in a first aspect, the present invention provides a kind of toy-clays for children, the toy glues
Soil is made of following component：Hollow foam microspheres 9-11 parts, 27-33 parts of polyvinyl alcohol, 43.2-52.8 parts of water, D-sorbite 9-
11 parts and 1.8-2.2 parts of pigment.
Preferably, the toy-clays are made of following component：Hollow 10 parts of foam microspheres, 30 parts of polyvinyl alcohol, water 48
2 parts of part, 10 parts of D-sorbite and pigment.
Preferably, the water is the tap water by degerming and processing of removing sand.
Preferably, the pigment is environmentally friendly pigment.
Preferably, the toy-clays further include antiseptic.
Preferably, the toy-clays further include fluorescer.
Preferably, the toy-clays further include fragrance.
It is further preferred that the fragrance is natural perfume material.
Second aspect, the present invention provides a kind of sides for preparing a kind of toy-clays for children described in first aspect
Method, the toy-clays are mixed by component as described in relation to the first aspect.
D-sorbite has been widely used as food additives, according to China《Food additives use sanitary standard》
(GB2760-1996) it is provided in：D-sorbite (liquid) can be needed by production for ice cream, ice lolly, cake, beverage, biscuit, face
Packet, pickles, candy.The moisturizer that industry glycerol as ultralight clay are replaced by the use of D-sorbite is safer, and more suitable children use,
Therefore, the toy-clays that are made of the present invention, not only with product environmentally-friendly sanitary, strong operability, can random moulding effect,
Also there is safer, more soft, easily preservation and other effects.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
This part carries out general description to the material and test method that are arrived used in present invention experiment.Although it is
It is it is known in the art that still the present invention still uses up herein to realize many materials and operating method used in the object of the invention
It may detailed description.It will be apparent to those skilled in the art that within a context, if not specified, material therefor of the present invention and behaviour
It is well known in the art as method.
Embodiment 1
A kind of toy-clays for children, the toy-clays are made of following component：Hollow foam microspheres 9-11 parts,
1.8-2.2 parts of 27-33 parts of polyvinyl alcohol, 43.2-52.8 parts of water, 9-11 parts of D-sorbite and pigment.Preferably, the toy
Clay is made of following component：Hollow 10 parts of foam microspheres, 30 parts of polyvinyl alcohol, 48 parts of water, 10 parts of D-sorbite and pigment 2
Part.
In one example, it is cost-effective, the water is the tap water by degerming and processing of removing sand.
In one example, it is the more environmentally friendly health of the toy-clays of preparation, the pigment, preferably environmentally friendly pigment needs
, it is noted that can be as needed, select different pigmentary colours.
The toy-clays are mixed with by above component, the finished product being prepared into, and feel is fine and smooth, can be repeatedly
It utilizes, there is good plastotype, moulding can be pressed into mold, model is carved, stretch moulding.Due to replacing industry using sorbierite
Glycerine is safer as the moisturizer of ultralight clay, and more suitable children use, therefore, the toy-clays that the present invention is made,
There is safer, more soft, easily preservation and other effects.
Embodiment 2
Because of the immune force difference of children, the bacterium of toy of all kinds intersects transmission and the incorrect use to toy,
For example can all cause a series of loss of toy-clays and destruction and the growth of bacterium using the front and rear custom do not washed one's hands, as this
Further optimal technical scheme in embodiment, in order to enable the toy-clays prepared can make certain within the regular hour
The growth or breeding of microorganism (bacterium, fungi, virus etc.) are maintained at necessary below horizontal, have antibacterial and bactericidal effect, institute
It states and antiseptic is further included in the component of toy-clays, such as silver ion, zinc oxide, copper oxide, ammonium dihydrogen phosphate, lithium carbonate are inorganic
Antiseptic.Preferably natural antibacterial agent.
The toy-clays are mixed with by above component, the finished product being prepared into, and feel is fine and smooth, can be repeatedly
It utilizes, there is good plastotype, moulding can be pressed into mold, model is carved, stretch moulding.Due to increasing antiseptic,
The toy-clays that the present invention is made have safer, more soft, easily preservation and other effects, can be repeatedly used for a long.
Embodiment 3
As optimal technical scheme further in the present embodiment, in order to increase interesting, the toy-clays at night
Component in further include fluorescer.
The toy-clays are mixed with by above component, the finished product being prepared into, and feel is fine and smooth, can be repeatedly
It utilizes, there is good plastotype, moulding can be pressed into mold, model is carved, stretch moulding.Due to increasing fluorescer,
The toy-clays that the present invention is made not only have safer, more soft, easily preservation and other effects, also further increase
The interest of toy-clays.
Embodiment 4
As optimal technical scheme further in the present embodiment, in order to enable the different fragrance that clay has, described
Fragrance is further included in the component of toy-clays.
The more environmentally friendly health of toy-clays for preparation, the fragrance, preferably natural perfume material, it should be pointed out that can root
According to needs, the fragrance of different smells is selected.
The toy-clays are mixed with by above component, the finished product being prepared into, and feel is fine and smooth, can be repeatedly
It utilizes, there is good plastotype, moulding can be pressed into mold, model is carved, stretch moulding.Due to increasing fragrance, this
The toy-clays being made are invented, not only has safer, more soft, easily preservation and other effects, also further increases object for appreciation
Has the interest of clay.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention belong to the scope of protection of present invention.
Claims (9)
1. a kind of toy-clays for children, which is characterized in that the toy-clays are made of following component：
Hollow foam microspheres 9-11 parts, 27-33 parts of polyvinyl alcohol, 43.2-52.8 parts of water, 9-11 parts of D-sorbite and pigment 1.8-
2.2 part.
2. toy-clays according to claim 1, which is characterized in that the toy-clays are made of following component：
2 parts of hollow 10 parts of foam microspheres, 30 parts of polyvinyl alcohol, 48 parts of water, 10 parts of D-sorbite and pigment.
3. toy-clays according to claim 1, which is characterized in that the water is by degerming and removes sand processing originally
Water.
4. toy-clays according to claim 1, which is characterized in that the pigment is environmentally friendly pigment.
5. toy-clays according to claim 1, which is characterized in that the toy-clays further include antiseptic.
6. toy-clays according to claim 1, which is characterized in that the toy-clays further include fluorescer.
7. toy-clays according to claim 1, which is characterized in that the toy-clays further include fragrance.
8. toy-clays according to claim 7, which is characterized in that the fragrance is natural perfume material.
A kind of 9. method for preparing a kind of toy-clays for children described in claim 1-8, which is characterized in that the object for appreciation
Tool clay is mixed as the component as described in claim 1-8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810108170.XA CN108192249A (en) | 2018-02-02 | 2018-02-02 | It is a kind of for toy-clays of children and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810108170.XA CN108192249A (en) | 2018-02-02 | 2018-02-02 | It is a kind of for toy-clays of children and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108192249A true CN108192249A (en) | 2018-06-22 |
Family
ID=62592334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810108170.XA Pending CN108192249A (en) | 2018-02-02 | 2018-02-02 | It is a kind of for toy-clays of children and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108192249A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110204841A (en) * | 2019-03-26 | 2019-09-06 | 周平 | Children's craft plasticine and preparation method thereof |
| CN110558754A (en) * | 2019-08-12 | 2019-12-13 | 温州医科大学 | End corner anti-collision protection assembly and application method thereof |
| CN112159574A (en) * | 2020-09-23 | 2021-01-01 | 漯河市罗弗文具制造有限公司 | Titanate chelating agent, environment-friendly boron-free high-molecular polyvinyl alcohol-based ultralight clay and preparation method thereof |
| CN112679894A (en) * | 2020-12-24 | 2021-04-20 | 快思瑞科技(上海)有限公司 | Boron-free and nontoxic toy ultralight clay and preparation method thereof |
| CN113583371A (en) * | 2021-09-08 | 2021-11-02 | 上海卡乐优儿童用品有限公司 | Clay for children playing and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101070232A (en) * | 2006-05-09 | 2007-11-14 | 北京京师奕阳教育科技有限公司 | Light clay composition and preparing method |
| CN101708977A (en) * | 2009-10-16 | 2010-05-19 | 深圳云之彩美术工艺用品有限公司 | Pearl clay |
| CN103044825A (en) * | 2012-12-14 | 2013-04-17 | 深圳云之彩美术工艺用品有限公司 | Noctilucent clay |
-
2018
- 2018-02-02 CN CN201810108170.XA patent/CN108192249A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101070232A (en) * | 2006-05-09 | 2007-11-14 | 北京京师奕阳教育科技有限公司 | Light clay composition and preparing method |
| CN101708977A (en) * | 2009-10-16 | 2010-05-19 | 深圳云之彩美术工艺用品有限公司 | Pearl clay |
| CN103044825A (en) * | 2012-12-14 | 2013-04-17 | 深圳云之彩美术工艺用品有限公司 | Noctilucent clay |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110204841A (en) * | 2019-03-26 | 2019-09-06 | 周平 | Children's craft plasticine and preparation method thereof |
| CN110558754A (en) * | 2019-08-12 | 2019-12-13 | 温州医科大学 | End corner anti-collision protection assembly and application method thereof |
| CN110558754B (en) * | 2019-08-12 | 2021-11-02 | 温州医科大学 | End corner anti-collision protection assembly and application method thereof |
| CN112159574A (en) * | 2020-09-23 | 2021-01-01 | 漯河市罗弗文具制造有限公司 | Titanate chelating agent, environment-friendly boron-free high-molecular polyvinyl alcohol-based ultralight clay and preparation method thereof |
| CN112679894A (en) * | 2020-12-24 | 2021-04-20 | 快思瑞科技(上海)有限公司 | Boron-free and nontoxic toy ultralight clay and preparation method thereof |
| CN113583371A (en) * | 2021-09-08 | 2021-11-02 | 上海卡乐优儿童用品有限公司 | Clay for children playing and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180622 |
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| RJ01 | Rejection of invention patent application after publication |