CN107974015A - A kind of nontoxic colored ultralight clay and preparation method thereof - Google Patents
A kind of nontoxic colored ultralight clay and preparation method thereof Download PDFInfo
- Publication number
- CN107974015A CN107974015A CN201711402003.8A CN201711402003A CN107974015A CN 107974015 A CN107974015 A CN 107974015A CN 201711402003 A CN201711402003 A CN 201711402003A CN 107974015 A CN107974015 A CN 107974015A
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- parts
- ultralight
- water
- physics
- microballoon
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/034—Post-expanding of foam beads or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
- C08J2491/06—Waxes
Abstract
The invention discloses a kind of nontoxic colored ultralight clay and production method, belong to the production and processing production field of ultralight clay.It is made of the following raw material component：Ultralight 8 10 parts of physics microballoon, 18 20 parts of polyvinyl alcohol, water-soluble 35 parts of mill base, 0.5 1.5 parts of moisturizer, 0.5 1.5 parts of antifreezing agent, 2 2.5 parts of vaseline, 60 70 parts of water.The beneficial effect of product of the present invention is：Safe and non-toxic, tensile property is superpower, non-greasy during use, while hand can be kept to moisten；Formula is reasonable, and ingredient stability, simple production process, formed product is good, easy moulding, easily bonding, will not cracking, may be reused in the state of no drying, preserves works for a long time after can also being allowed to dry.
Description
Technical field
The present invention relates to the production and processing production field of ultralight clay, and in particular to a kind of nontoxic colored ultralight viscous
Soil.
Background technology
Since 1956 come out, substitute of the plasticine as mud, plasticine is just into deep enjoyed by children
Intelligence development type toy.The plasticine most started only has a kind of greyish white color, but in subsequent several years plasticine just have it is various
Color and fragrance.Including noctilucence, gold, silver color, shampoo taste, scrape Hu water taste etc..Develop into today, high-end plasticine
Material and technique are all there occurs very big change, unlike former, it is impossible to colour mixture, it is impossible to reuse, and relatively rough harden.But
It is that existing plasticine more extensive on the market is mainly using raw materials such as calcium carbonate as filler, using atoleine as oil components.
It is formulated with glycerine etc., the oily clay used for child and children etc..Sericite system clay, manufactured goods have been used in filler
Manufactured goods with similar ceramic blank soil are with similar use feeling.Plasticine is a kind of toy, is also applied for sculpture, industrial art
The fields such as design, for child, Xue Tongxue, practices and moulds artifacts, and the relevant personnel practice making ceramics.
The plasticity of plasticine is extremely strong, and children can give full play to its imagination, it is abundant more to show it by playing plasticine
Color inner world, this intellectual development to teenager's early stage are helpful.But since child age is small, curiosity is strong,
Easily occurs the phenomenon eaten by mistake during use.With the continuous improvement of people's health consciousness, especially youngsters and children is good for
The concern of health, whether educational toy for children class product is safe, whether can damage to the health of children is increasingly subject to
The attention of people.
Recently as the progress of product material, the appearance of ultralight physics microballoon, which instead of flour, becomes the rubber of a new generation
The characteristics of mud main raw material(s), new nonpoisonous and tasteless, beautiful in colour, the moulding effect of ultralight clay is good, and drawing force is strong, but now
Manufacturer technique it is all not mature enough, complex production process, production environment is seriously polluted, and the ultralight clay of production does not reach
Due quality requirement, and there is the shortcomings that cannot for a long time preserving, gluing hand.
The content of the invention
The purpose of the present invention is exactly to solve the problems of the prior art, proposes a kind of nontoxic ultralight clay and production method,
Formula is reasonable, and ingredient stability, beautiful in colour, moulding effect is good, and tack-free, drawing force is strong, easy to preserve for a long time, nontoxic no gas
Taste, environment friendly and pollution-free, plasticity is strong, and tack-free toughness is good, beautiful in colour.
To achieve the above object, the present invention proposes a kind of nontoxic colored ultralight clay and is made by the following raw material component：
Ultralight 8-10 parts of physics microballoon, 18-20 parts of polyvinyl alcohol, water-soluble mill base 3-5 parts, 0.5-1.5 parts of moisturizer, antifreezing agent 0.5-
1.5 parts, 2-2.5 parts of vaseline, 60-70 parts of water.
It is as follows as preferred feedstock component：Ultralight 8 parts of physics microballoon, 18 parts of polyvinyl alcohol, water-soluble 3 parts of mill base, glycerine
0.5 part, 0.5 part of antifreezing agent, 2 parts of vaseline, 60 parts of water.
It is as follows as preferred feedstock component：Ultralight 9 parts of physics microballoon, 19 parts of polyvinyl alcohol, water-soluble 4 parts of mill base, the third two
0.5 part of alcohol, 0.5 part of sorbierite, 1 part of antifreezing agent, 2.3 parts of vaseline, 65 parts of water.
It is as follows as preferred feedstock component：Ultralight 10 parts of physics microballoon, 20 parts of polyvinyl alcohol, water-soluble 5 parts of mill base, the third two
1.5 parts of alcohol, 1.5 parts of antifreezing agent, 2.5 parts of vaseline, 70 parts of water.
The moisturizer is glycerine, propane diols, the one of which of sorbierite or several mixing.
A kind of nontoxic colored ultralight clay of the present invention, comprises the following steps：
（1）Take out in parts by weight in polyvinyl alcohol input reaction kettle, then it is small to carry out constant temperature stirring 4 to 95 DEG C for heating stirring
When, ensure granule of polyvinyl alcohol melt completely, then ready-made poly-vinyl alcohol solution is put into container cool it is spare；
（2）Take step（1）In cool poly-vinyl alcohol solution half amount input kneader in, add the ultralight physics of parts by weight it is micro-
It is sufficiently stirred in ball input kneader, poly-vinyl alcohol solution is sufficiently mixed uniformly with ultralight physics microballoon；
（3）It is ultralight that the mixed liquor of the poly-vinyl alcohol solution mixed and ultralight physics microballoon is added to heating progress in extruder
The physical expansion reaction of physics microballoon；
（4）Take step（1）In cool poly-vinyl alcohol solution half amount input kneader in, add step（3）In carried out
The ultralight physics microballoon of physical expansion, adds parts by weight water-soluble mill base, water, moisturizer, antifreezing agent, vaseline, then carries out
Finished product is made after being sufficiently stirred 30 minutes.
Beneficial effects of the present invention：
1st, the raw material that this product uses are safe and non-toxic, and tensile property is superpower, non-greasy during use, while can keep hand
Moisten；
2nd, it is environment-protecting and non-poisonous using water-soluble mill base, do not fade, not colour contamination, beautiful in colour, two kinds of blend of colors can generate the third
Color makes works color more rich；
3rd, formula is reasonable, and ingredient stability, simple production process, production environment is pollution-free, and formed product is good, and easy moulding is easy to stick
Connect, will not cracking, may be reused in the state of no drying, preserve works for a long time after can also being allowed to dry.
Embodiment
With reference to specific embodiment, the present invention will be further described, but the present invention is not limited to this.
Embodiment 1
Formula：Ultralight 8 parts of physics microballoon, 18 parts of polyvinyl alcohol, water-soluble 3 parts of mill base, 0.5 part of glycerine, 0.5 part of antifreezing agent are all
2 parts of intellectual circle, 60 parts of water.
Production method, including comprise the following steps that：
（1）18 parts of polyvinyl alcohol are put into reaction kettle, heating stirring is to 95 DEG C, when then progress constant temperature stirring 4 is small, ensures poly-
Vinyl alcohol particle melts completely, then ready-made poly-vinyl alcohol solution is put into container cool it is spare；
（2）Take step（1）In in the amount input kneader of 9 parts of poly-vinyl alcohol solution that cools, add 8 parts of ultralight physics microballoons and throw
Enter in kneader and be sufficiently stirred, poly-vinyl alcohol solution is sufficiently mixed uniformly with ultralight physics microballoon；
（3）It is ultralight that the mixed liquor of the poly-vinyl alcohol solution mixed and ultralight physics microballoon is added to heating progress in extruder
The physical expansion reaction of physics microballoon；
（4）Take step（1）In cool 9 parts of poly-vinyl alcohol solution amount input kneader in, add step（3）In carried out thing
The ultralight physics microballoon of expansion is managed, adds 3 parts of water-soluble mill bases, 60 parts of water, 0.5 part of glycerine, 0.5 part of antifreezing agent, 2 parts of all scholars
Woods, then carries out making finished product after being sufficiently stirred 30 minutes.
Embodiment 2
Formula：Ultralight 9 parts of physics microballoon, 19 parts of polyvinyl alcohol, water-soluble 4 parts of mill base, 0.5 part of propane diols, 0.5 part of sorbierite,
1 part of antifreezing agent, 2.3 parts of vaseline, 65 parts of water.
Production method, including comprise the following steps that：
（1）19 parts of polyvinyl alcohol are put into reaction kettle, heating stirring is to 95 DEG C, when then progress constant temperature stirring 4 is small, ensures poly-
Vinyl alcohol particle melts completely, then ready-made poly-vinyl alcohol solution is put into container cool it is spare；
（2）Take step（1）In cool 9.5 parts of poly-vinyl alcohol solution amount input kneader in, add 9 parts of ultralight physics microballoons
It is sufficiently stirred in input kneader, poly-vinyl alcohol solution is sufficiently mixed uniformly with ultralight physics microballoon；
（3）It is ultralight that the mixed liquor of the poly-vinyl alcohol solution mixed and ultralight physics microballoon is added to heating progress in extruder
The physical expansion reaction of physics microballoon；
（4）Take step（1）In cool 9.5 parts of poly-vinyl alcohol solution amount input kneader in, add step（3）In carried out
The ultralight physics microballoon of physical expansion, add 4 parts of water-soluble mill bases, 65 parts of water, 0.5 part of propane diols, 0.5 part of sorbierite, 1 part it is anti-
Freeze agent, 2.3 parts of vaseline, then carry out making finished product after being sufficiently stirred 30 minutes.
Embodiment 3
Formula：Ultralight 10 parts of physics microballoon, 20 parts of polyvinyl alcohol, water-soluble 5 parts of mill base, 1.5 parts of propane diols, 1.5 parts of antifreezing agent,
2.5 parts of vaseline, 70 parts of water.
Production method, including comprise the following steps that：
（1）20 parts of polyvinyl alcohol are put into reaction kettle, heating stirring is to 95 DEG C, when then progress constant temperature stirring 4 is small, ensures poly-
Vinyl alcohol particle melts completely, then ready-made poly-vinyl alcohol solution is put into container cool it is spare；
（2）Take step（1）In cool 10 parts of poly-vinyl alcohol solution amount input kneader in, add 10 parts of ultralight physics microballoons
It is sufficiently stirred in input kneader, poly-vinyl alcohol solution is sufficiently mixed uniformly with ultralight physics microballoon；
（3）It is ultralight that the mixed liquor of the poly-vinyl alcohol solution mixed and ultralight physics microballoon is added to heating progress in extruder
The physical expansion reaction of physics microballoon；
（4）Take step（1）In cool 10 parts of poly-vinyl alcohol solution amount input kneader in, add step（3）In carried out
The ultralight physics microballoon of physical expansion, add 5 parts of water-soluble mill bases, 70 parts of water, 1.5 parts of propane diols, 1.5 parts of antifreezing agents, 2.5 parts
Vaseline, then carries out making finished product after being sufficiently stirred 30 minutes.
Claims (6)
1. a kind of nontoxic colored ultralight clay, it is characterised in that be made by the following raw material component：Ultralight 8-10 parts of physics microballoon,
18-20 parts of polyvinyl alcohol, water-soluble mill base 3-5 parts, 0.5-1.5 parts of moisturizer, 0.5-1.5 parts of antifreezing agent, vaseline 2-2.5
Part, 60-70 parts of water.
2. a kind of nontoxic colored ultralight clay as claimed in claim 1, it is characterised in that be made by the following raw material component：It is ultralight
8 parts of physics microballoon, 18 parts of polyvinyl alcohol, water-soluble 3 parts of mill base, 0.5 part of glycerine, 0.5 part of antifreezing agent, 2 parts of vaseline, water 60
Part.
3. a kind of nontoxic colored ultralight clay as claimed in claim 1, it is characterised in that be made by the following raw material component：It is ultralight
9 parts of physics microballoon, 19 parts of polyvinyl alcohol, water-soluble 4 parts of mill base, 0.5 part of propane diols, 0.5 part of sorbierite, 1 part of antifreezing agent, all scholars
2.3 parts of woods, 65 parts of water.
4. a kind of nontoxic colored ultralight clay as claimed in claim 1, it is characterised in that be made by the following raw material component：It is ultralight
10 parts of physics microballoon, 20 parts of polyvinyl alcohol, water-soluble 5 parts of mill base, 1.5 parts of propane diols, 1.5 parts of antifreezing agent, 2.5 parts of vaseline,
70 parts of water.
A kind of 5. nontoxic colored ultralight clay as claimed in claim 1, it is characterised in that：The moisturizer is glycerine, the third two
Alcohol, the one of which of sorbierite or several mixing.
6. a kind of nontoxic colored ultralight clay as claimed in claim 1, it is characterised in that comprise the following steps：
（1）Take out in parts by weight in polyvinyl alcohol input reaction kettle, then it is small to carry out constant temperature stirring 4 to 95 DEG C for heating stirring
When, ensure granule of polyvinyl alcohol melt completely, then ready-made poly-vinyl alcohol solution is put into container cool it is spare；
（2）Take step（1）In cool poly-vinyl alcohol solution half amount input kneader in, add the ultralight physics of parts by weight it is micro-
It is sufficiently stirred in ball input kneader, poly-vinyl alcohol solution is sufficiently mixed uniformly with ultralight physics microballoon；
（3）It is ultralight that the mixed liquor of the poly-vinyl alcohol solution mixed and ultralight physics microballoon is added to heating progress in extruder
The physical expansion reaction of physics microballoon；
（4）Take step（1）In cool poly-vinyl alcohol solution half amount input kneader in, add step（3）In carried out
The ultralight physics microballoon of physical expansion, adds parts by weight water-soluble mill base, water, moisturizer, antifreezing agent, vaseline, then carries out
Finished product is made after being sufficiently stirred 30 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711402003.8A CN107974015A (en) | 2017-12-22 | 2017-12-22 | A kind of nontoxic colored ultralight clay and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711402003.8A CN107974015A (en) | 2017-12-22 | 2017-12-22 | A kind of nontoxic colored ultralight clay and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN107974015A true CN107974015A (en) | 2018-05-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711402003.8A Pending CN107974015A (en) | 2017-12-22 | 2017-12-22 | A kind of nontoxic colored ultralight clay and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109011650A (en) * | 2018-08-16 | 2018-12-18 | 临沂市博士爱文具有限公司 | A kind of lightweight Noctilucent color daub |
| CN110272635A (en) * | 2019-07-09 | 2019-09-24 | 临沂市博士爱文具有限公司 | A kind of preparation method of the ultralight clay of ultralight macromolecule |
| CN110305494A (en) * | 2019-07-09 | 2019-10-08 | 临沂市博士爱文具有限公司 | A kind of preparation method of the nontoxic ultralight clay of colour |
| CN112159574A (en) * | 2020-09-23 | 2021-01-01 | 漯河市罗弗文具制造有限公司 | Titanate chelating agent, environment-friendly boron-free high-molecular polyvinyl alcohol-based ultralight clay and preparation method thereof |
| CN112679894A (en) * | 2020-12-24 | 2021-04-20 | 快思瑞科技(上海)有限公司 | Boron-free and nontoxic toy ultralight clay and preparation method thereof |
| CN112708231A (en) * | 2020-12-24 | 2021-04-27 | 快思瑞科技(上海)有限公司 | Environment-friendly nontoxic ultralight clay and preparation method thereof |
| CN114804728A (en) * | 2022-06-26 | 2022-07-29 | 重庆市女子职业高级中学 | Plastic pulp mud for artistic modeling and preparation method thereof |
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| CN102311596A (en) * | 2010-07-02 | 2012-01-11 | 真彩文具有限公司 | Non-toxic and light resin clay composition and preparation method thereof |
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2017
- 2017-12-22 CN CN201711402003.8A patent/CN107974015A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102311596A (en) * | 2010-07-02 | 2012-01-11 | 真彩文具有限公司 | Non-toxic and light resin clay composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李良: "《食品包装学》", 31 July 2017, 中国轻工业出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109011650A (en) * | 2018-08-16 | 2018-12-18 | 临沂市博士爱文具有限公司 | A kind of lightweight Noctilucent color daub |
| CN110272635A (en) * | 2019-07-09 | 2019-09-24 | 临沂市博士爱文具有限公司 | A kind of preparation method of the ultralight clay of ultralight macromolecule |
| CN110305494A (en) * | 2019-07-09 | 2019-10-08 | 临沂市博士爱文具有限公司 | A kind of preparation method of the nontoxic ultralight clay of colour |
| CN112159574A (en) * | 2020-09-23 | 2021-01-01 | 漯河市罗弗文具制造有限公司 | Titanate chelating agent, environment-friendly boron-free high-molecular polyvinyl alcohol-based ultralight clay and preparation method thereof |
| CN112679894A (en) * | 2020-12-24 | 2021-04-20 | 快思瑞科技(上海)有限公司 | Boron-free and nontoxic toy ultralight clay and preparation method thereof |
| CN112708231A (en) * | 2020-12-24 | 2021-04-27 | 快思瑞科技(上海)有限公司 | Environment-friendly nontoxic ultralight clay and preparation method thereof |
| CN114804728A (en) * | 2022-06-26 | 2022-07-29 | 重庆市女子职业高级中学 | Plastic pulp mud for artistic modeling and preparation method thereof |
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