CN101485328B - Insecticidal composition containing triazamate - Google Patents
Insecticidal composition containing triazamate Download PDFInfo
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- CN101485328B CN101485328B CN 200910021176 CN200910021176A CN101485328B CN 101485328 B CN101485328 B CN 101485328B CN 200910021176 CN200910021176 CN 200910021176 CN 200910021176 A CN200910021176 A CN 200910021176A CN 101485328 B CN101485328 B CN 101485328B
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- triaguron
- carbaryl
- effective active
- mtmc
- mobucin
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Abstract
The invention relates to an insecticide composition containing triazamate, which comprises an effective active component A and an effective active component B, wherein the effective active component A is the triazamate, the effective active component B is selected from one of carbaryl, etrofolan and tsumacide, and the weight ratio of the effective active component A to the effective active component B is 1:80-80:1. The composition is applied to controlling resistant pests on fruit trees, vegetables, wheat, cotton and rice.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to the composite composition of a kind of triaguron and carbamate insecticide, be used to prevent and treat aphid, rice fulgorid, aleyrodid on the crop.
Background technology
Triaguron, english common name triazamate, outward appearance is a white powder, molecular formula C
13H
22N
4O
3S, chemical name is: (3-tertiary butyl-1-dimethylamino formyl-1H-1,2,4 ,-triazole-5-base sulphur) ethyl acetate.Chemical structural formula is:
Triaguron belongs to the high selectivity systemic insecticide, and cholinesterase is had rapid inhibitory effect, and through the suction-operated and the contact action of aphid splanchnopleure, it is all effective to the various aphids on the various crop population.Dosage with the conventional control aphid is invalid to diptera and lepidoptera pest.To useful insect and honeybee safety.
Carbaryl, English name: (carbaryl), molecular formula: C
12H
11NO
2, chemical name is a 1 naphthyl N methyl carbamate, its structural formula is:
Carbaryl is a kind of broad spectrum pesticide, belongs to carbamates, insect is had tag, stomach poison function.Its mechanism of action is the acetylcholinesterase that suppresses in the insect bodies, and insects such as leafhopper, plant hopper are had preventive effect preferably, to some pests with chewing mouthparts that is difficult for control, like pink bollworm, aphid etc. good control efficiency is arranged also.Carbaryl is slower to the poisoning speed of insect, just begins to bring into play drug effect after the medication two days later.Different insecticidal mechanisms with other are composite to have obvious synergistic effect, and its insecticidal effect obviously is superior to independent use.
Mobucin, English name (isoprocarb), molecular formula: C
11H
15NO
2, chemical name is: methylamino formic acid-2-isopropyl phenyl ester,
Structural formula is:
Mobucin has stronger action of contace poison, and the power of knocking down is strong, and drug effect is rapid, but the longevity of residure is shorter.Mobucin has special efficacy to rice fulgorid, Cicadellidae insect.Can doublely control thrips and leech, to plant hopper natural enemy, spider safety.
MTMC, English name: (metolcarb), molecular formula: C
9H
11NO
2, chemical name is: a tolyl-N-methyl carbamate,
Its structural formula is:
MTMC is a kind of carbamate insecticide, has the amount of money of tagging fumigation action, and the power of knocking down is strong; But the lasting period is short; It mainly is and the acetylcholinesterase reaction after enzyme is suppressed, promptly to occur poisoning; Be mainly used in control rice fulgorid, rice leafhopper, rice thrips and stinkbug silk worm etc., rice leaf roller, oranges and tangerines blister mite, cotton pink bollworm, cotton aphid, two spotted spider mite are also had certain effect.
Aphid is claimed aphid or aphid etc. again, English aphid by name.Belong to the Homoptera Aphidiadae, fore wing 4～5 rakes, the secondary sensation circle of feeler is circular, the aphid of cornical tubulose.Contain 107 and belong to 2280 kinds.Various places all over the world distribute.Known 260 kinds of China distributes and spreads all over all parts of the country.The aphid belly has tubular protrusion (cornical), sucks water, is the major pest of plant.Aphid often troop cause harm tender leaf, tender slightly, position such as bud, suck juice, so that the irregular shrinkage of vacuum side of blade, curl, variable color, come off, bud distortion, flowers lopsided development, even complete stool is withered so that dead.Simultaneously, aphid secretes a large amount of close dew, stains branches and leaves, brings out the bituminous coal disease.The kind that has can produce insect gall, the still disseminator of plant virus who has.
The body surface of aleyrodid has wax, and breeding is fast, generation overlap, very easily develops immunity to drugs; Bring many difficulties to chemical control; Therefore the science medication is very important, when selecting for use medicament to carry out emergence control, requires mixture preparation that quick-acting is preferably arranged; Can reduce the agricultural chemicals access times, suspension of pesticide resistance generation.
The present composition can effectively be prevented and treated resistance aphid, aleyrodid, and dosage is little, quick-acting is high, and the complex preparation of triaguron and carbaryl, Mobucin or MTMC does not also appear in the newspapers so far.
Summary of the invention
The objective of the invention is to propose a kind of Pesticidal combination that contains triaguron; Be specifically related to the complex composition of triaguron and carbamate insecticide carbaryl, Mobucin or MTMC, be mainly used in aphid, rice fulgorid and aleyrodid on control cotton, wheat, paddy rice, the vegetables.
The present invention realizes through following technical scheme:
A kind of Pesticidal combination that contains triaguron is made up of effective active composition A and effective active composition B.
Described Pesticidal combination is characterized in that: effective active composition A is a triaguron, and effective active composition B is selected from carbaryl, Mobucin or MTMC.
Described Pesticidal combination is characterized in that: effective active composition A and effective active composition B weight ratio are 1: 80～80: 1.
Described Pesticidal combination is characterized in that: active ingredient adds conventional auxiliary agent and can be made into wetting powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion.
Composition of the present invention comprises following group component composition when processing wetting powder: effective active composition A is 1%～80%, effective active composition B is 1%～80%, wetting agent 1～4%, dispersant 1～8%, filler surplus.
Above-mentioned formulation material is mixed, in stirred tank, evenly stir, behind airslide disintegrating mill, mixing, promptly can be made into WP.
Comprise following group component composition when the present composition is processed water dispersible granules: effective active composition A is 1%～60%, effective active composition B is 1%～60%, wetting agent 1～4%, dispersant 1%～10%, disintegrant 1%～4%, filler surplus.
Formulation material is mixed, pulverize,, add then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis is processed water dispersible granules through mediating with micro jet.
Comprise following group component composition when the present composition is processed suspending agent: effective active composition A is 1%～60%, effective active composition B is 1%～60%, emulsifier 1%～4%, dispersant 3%～6%, antifreezing agent 1%～5%, thickener 0.1%～1%, antifoaming agent 0.1%～0.5%, water surplus.
Back in the above-mentioned formulation material except that crossing all the other components of active ingredient, is mixed through high speed shear, adding active ingredient, ball milling is 2～3 hours in ball mill, makes particle diameter all below 5 μ m, makes suspending agent.
Comprise following group component composition when the present composition is processed aqueous emulsion: effective active composition A is 1%～40%, effective active composition B is 1%～60%, solvent 1%～30%, emulsifier 1%～10%, antifreezing agent 1%～5%, thickener 0.1%～1%, antifoaming agent 0.1%～0.5%, water surplus.
Above-mentioned formulation material is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, antifoaming agent are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, can make aqueous emulsion.
Comprise following group component composition when the present composition is processed microemulsion: effective active composition A is 1%～40%, effective active composition B is 1%～60%, solvent 1%～25%, emulsifier 15%～20%, antifreezing agent 1%～5%, antifoaming agent 0.1%～0.5%, water surplus.
The compound method of microemulsion: be that emulsifier and water are mixed and made into water, then former medicine under agitation added water, process transparent O/W type microemulsion.
Above-mentioned solvent is selected from N, dinethylformamide, cyclohexanone, toluene, xylol, dimethyl sulfoxide (DMSO), methyl alcohol, ethanol, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, propyl alcohol, butanols, ethylene glycol, diethylene glycol, EGME, butyl ether, ethyl acetate, vegetable oil, acetonitrile one or more.
Above-mentioned emulsifier is selected from farming breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (NPE phosphate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), peaceful breast 36
#(phenethyl fluosite polyoxy ethyl ether), farming breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (NPE), By series (castor oil polyoxyethylene ether), farming breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), farming breast 34
#In (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), the AEO series (the pure APEO of fat) one or more.
Above-mentioned dispersant is selected from one or more in polycarboxylate, lignosulfonates, APES formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, APES, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO.
Above-mentioned wetting agent is selected from one or more in lauryl sodium sulfate, DBSA, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.
Above-mentioned antifreeze is selected from one or more in ethylene glycol, propane diols, glycerine, the urea.
Above-mentioned thickener is selected from one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Above-mentioned antifoaming agent is selected from one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Above-mentioned filler is selected from one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
The Pesticidal combination that contains triaguron of the present invention is used to prevent and treat the insect on fruit tree, vegetables, cotton, wheat, the paddy rice.
The advantage of the present composition is: (1) antagonism aphid, rice fulgorid, aleyrodid have good control efficiency; (2) enlarged the control of insect spectrum, a medicine is controlled more, has reduced dosage and medication number of times, has reduced cost; (3) compare the generation that drug effect is high, the lasting period is long, delayed pest resistance to insecticide with single agent.
Embodiment
Below in conjunction with embodiment the present invention is further explained.
Embodiment 1,70% triaguron carbaryl wetting powder
10g triaguron, 60g carbaryl, 4g lauryl sodium sulfate, 6g sodium lignin sulfonate, 8g white carbon, kaolin are mended to 100g, mix to be crushed into 70% triaguron carbaryl wetting powder.
The part by weight of triaguron and carbaryl can change between (example 1: 69,10: 60,60: 10,69: 1) at 1: 80～80: 1 in the present embodiment, and both total weight items are 70%, form new embodiment.
Can also carbaryl be replaced with Mobucin or MTMC forms new embodiment.
Embodiment 2:60% triaguron carbaryl water dispersible granules
15g triaguron, 45g carbaryl, 6g neopelex, 4g alkylnaphthalene sulfonate formaldehyde condensation products, diatomite are mended to 100g.Mix the pulverizing granulation and become 60% triaguron carbaryl water dispersible granules.
The part by weight of triaguron and carbaryl can change between (example 1: 59,10: 50,50: 10,59: 1) at 1: 80～80: 1 in the present embodiment, and both total weight items are 60%, form new embodiment.
Can also carbaryl be replaced with Mobucin or MTMC forms new embodiment.
Embodiment 3:42% triaguron carbaryl suspending agent
12g triaguron, 30g carbaryl, 5g farming breast 500
#, 5g polycarboxylate, 3g ethylene glycol, 0.1g xanthans, 1g aluminium-magnesium silicate, 0.5g silicone compound, water mend to 100g.42% triaguron carbaryl suspending agent is processed in mixed grinding.
The part by weight of triaguron and carbaryl can change between (example 1: 41,5: 37,30: 12,41: 1) at 1: 80～80: 1 in the present embodiment, and both total weight items are 42%, form new embodiment.
Can also carbaryl be replaced with Mobucin or MTMC forms new embodiment.
Embodiment 4:50% triaguron carbaryl aqueous emulsion
10g triaguron, 40g carbaryl, 10gN, dinethylformamide, 5g vegetable oil, 3g OP series phosphate, 4g farming breast 1600
#, 3gBy series, 5g ethylene glycol, water mends to 100g, stir shear 50% triaguron carbaryl aqueous emulsion.
The part by weight of triaguron and carbaryl can change between (example 1: 49,20: 30,40: 10,49: 1) at 1: 80～80: 1 in the present embodiment, and both total weight items are 50%, form new embodiment.
Can also carbaryl be replaced with Mobucin or MTMC forms new embodiment.
Embodiment 5:60% triaguron carbaryl microemulsion
30g triaguron, 30g carbaryl, 10gN, dinethylformamide, 3g vegetable oil, 6g 600
#Phosphate, 7g farming breast 500
#, 8g farming breast 1600
#, water mends to 100g, being mixed into is 60% triaguron carbaryl microemulsion.
The part by weight of triaguron and carbaryl can change between (example 1: 59,20: 40,50: 10,59: 1) at 1: 80～80: 1 in the present embodiment, and both total weight items are 60%, form new embodiment.
Can also carbaryl be replaced with Mobucin or MTMC forms new embodiment.
Application implementation example one: triaguron and carbaryl are composite to be tested the cotton aphid Toxicity Determination
This EE is in Shandong Agricultural University, result of the test such as table 1:
Table 1 triaguron and carbaryl are composite to the cotton aphid toxicity test
| Handle title | Proportioning | Virulence regression equation (y=a+bx) | LC 50(μg/mL) | Co-toxicity coefficient (CTC) |
| Triaguron | - | y＝3.5831+1.5278x | 12.52 | ?- |
| Carbaryl | - | y＝2.1934+2.0040x | 31.28 | ?- |
| Triaguron: carbaryl | 2∶2 | y＝2.8935+1.6273x | 14.0 | ?127.73 |
| Triaguron: carbaryl | 2∶5 | y＝2.4428+1.7432x | 14.2 | ?154.24 |
| Triaguron: carbaryl | 2∶7 | y＝2.5990+1.8823x | 14.03 | ?167.25 |
| Triaguron: carbaryl | 2∶10 | y＝2.6371+1.5808x | 15.68 | ?159.61 |
| Triaguron: carbaryl | 2∶20 | y＝2.6631+1.4962x | 22.24 | ?123.77 |
Find out by table 1; After triaguron and carbaryl are composite, have obvious role in synergism, the two weight ratio is to have remarkable role in synergy at 2: 5,2: 7,2: 10 o'clock; Triaguron wherein: carbaryl=synergistic effect in 2: 7 o'clock is the most outstanding, can be used as the best proportioning of said composition.
Application implementation example two: triaguron and MTMC are composite to be tested the rice hoppers Toxicity Determination
This EE is in Agricultural University Of Nanjing, result of the test such as table 2:
Table 2 triaguron and MTMC are composite to the rice hoppers toxicity test
| Handle title | Proportioning | Virulence regression equation (y=a+bx) | LC 50(μg/mL) | Co-toxicity coefficient (CTC) |
| Triaguron | - | y＝3.3749+1.6245x | 12.87 | ?- |
| MTMC | - | y＝2.3195+1.9852x | 27.36 | ?- |
| Triaguron: MTMC | 2∶1 | y＝2.9135+1.4273x | 13.64 | ?114.58 |
| Triaguron: MTMC | 2∶2 | y＝2.8428+1.5032x | 13.92 | ?125.76 |
| Triaguron: MTMC | 2∶4 | y＝2.7990+1.8223x | 13.74 | ?144.79 |
| Triaguron: MTMC | 2∶8 | y＝2.6371+1.8908x | 16.37 | ?136.42 |
| Triaguron: MTMC | 2∶15 | y＝2.6131+1.9162x | 19.86 | ?121.65 |
Find out by table 2; After triaguron and MTMC were composite, the two weight ratio was to show as addition at 2: 1 o'clock, and weight ratio is to show as synergistic effect at 2: 2,2: 4,2: 8,2: 15 o'clock; Wherein with triaguron: MTMC=synergistic effect in 2: 4 o'clock is the most outstanding, and co-toxicity coefficient is 144.79.
Application implementation example three: triaguron and Mobucin are composite to be tested cucumber Bemisia tabaci Toxicity Determination
This EE is in Xibei Univ. of Agricultural & Forest Science & Technology, result of the test such as table 3:
Table 3 triaguron and Mobucin are composite to cucumber Bemisia tabaci toxicity test
| Handle title | Proportioning | Virulence regression equation (y=a+bx) | LC 50(μg/mL) | Co-toxicity coefficient (CTC) |
| Triaguron | - | y＝3.5267+1.4672x | 14.24 | ?- |
| Mobucin | - | y＝2.1554+2.1759x | 37.55 | ?- |
| Triaguron: Mobucin | 1∶1 | y＝2.9135+1.4713x | 15.78 | ?130.86 |
| Triaguron: Mobucin | 1∶2 | y＝2.8428+1.5032x | 16.68 | ?145.65 |
| Triaguron: Mobucin | 1∶3 | y＝2.7990+1.8223x | 16.82 | ?158.42 |
| Triaguron: Mobucin | 1∶5 | y＝2.5371+1.9008x | 18.89 | 156.18 |
| Triaguron: Mobucin | 1∶8 | y＝2.4131+1.9862x | 22.37 | 142.03 |
Find out that by table 3 after triaguron and Mobucin are composite, the control of cucumber Bemisia tabaci is all shown as synergistic function, the two weight proportion is that synergistic effect in 1: 3 o'clock is the most outstanding.
Application implementation example four: handle chemical control cotton aphid field control effectiveness test
Handle medicament: the composite product of triaguron carbaryl, the composite product of triaguron MTMC, the composite product of triaguron Mobucin (above medicament is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd.).
Contrast medicament: 25% triaguron missible oil (Jiangsu Changlong Chemical Co; Commercial), 25% carbaryl wetting powder (Nantong, Jiangsu Province Li Huanongization Co., Ltd; Commercial), 25% MTMC wetting powder (Shanghai east wind insecticide factory; Commercial), 20% Mobucin missible oil (Anhui Sheng Linongization Co., Ltd, commercial).
EE is plant protection unit in the Pucheng County, Shaanxi Province, July 3 investigation insect population radix, July 4 was sprayed medicine for the first time, 1 day, 3 days, 10 days remaining borer populations alive of investigation behind the medicine, and calculate insect population go down rate, proofread and correct anti-efficient, result of the test such as table 4:
Table 4 is handled chemical control cotton aphid field control effectiveness test
Can know by table 4; Medicament of the present invention is prevented and treated cotton aphid; Compare with the contrast medicament, have the advantage that quick-acting is good, the lasting period is long, dosage is little, in test; To target crop and beneficial organism safety, the inventor also finds that 15% triaguron+30% MTMC has good control efficiency to the cotton cotton bollworm to the processing medicament in trial stretch.
Application implementation example five: handle chemical control rice hoppers field control effectiveness test
Experimental result is as shown in table 5:
Table 5 is handled chemical control rice hoppers field control effectiveness test
Can know that by table 5 medicament of the present invention is prevented and treated rice hoppers, compare to have preventive effect height, quick-acting is good, the lasting period is long, dosage is little advantage with the contrast medicament, in test, handle medicament in trial stretch to target crop and beneficial organism safety.
Application implementation example six: handle chemical control cucumber Bemisia tabaci field control effectiveness test
This test arrangement is Haining City Ding Qiao town in Zhejiang Province, and investigation Bemisia tabaci insect population radix was investigated the residual borer population of each sub-district Bemisia tabaci respectively in 1,3,7 day behind the medicine before the dispenser, and the calculation correction preventive effect.Five point samplings are adopted in pilot survey, every some fixed point investigation 1 strain, and every strain blade is all investigated.
Result of the test is as shown in table 6:
Table 6 is handled chemical control cucumber Bemisia tabaci field control effectiveness test
Can know that by table 6 medicament of the present invention obviously is superior to contrasting medicament to cucumber Bemisia tabaci control efficiency, have the advantage that dosage is little, the lasting period is long.According to the field range estimation, in the test dose scope, plant growth is normal, and each is handled medicament and the poisoning phenomenon to cucumber all do not occur, explains that it is safe to cucumber.
In sum; Medicament of the present invention all has good control efficiency to aphid, rice fulgorid, aleyrodid; Compare with the contrast medicament, have the preventive effect height, quick-acting is good, the lasting period is long, to the advantage of crop safety, and medicament of the present invention need not or reduce consumption of organic solvent; Reduced pollution, reduced cost environment.So R&D and promotion of the present invention has crucial meaning.
Claims (2)
1. Pesticidal combination that contains triaguron and carbaryl, wherein the weight ratio of triaguron and carbaryl is 2: 2～2: 20.
2. Pesticidal combination according to claim 1 is characterized in that: active ingredient adds conventional auxiliary agent and can be made into wetting powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion.
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| CN 200910021176 CN101485328B (en) | 2009-02-18 | 2009-02-18 | Insecticidal composition containing triazamate |
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|---|---|---|---|
| CN 200910021176 CN101485328B (en) | 2009-02-18 | 2009-02-18 | Insecticidal composition containing triazamate |
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| CN101485328B true CN101485328B (en) | 2012-04-04 |
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Non-Patent Citations (2)
| Title |
|---|
| 白雪.三唑类化合物研究与应用.《化工之友》.2007,(第7期),50-51. * |
| 陈明.高纯度甲萘威的合成与生产.《江西化工》.2001,(第4期),48-51. * |
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