CN101481261A - Titanium, zinc and pyroxene crystal glaze and preparing method thereof - Google Patents
Titanium, zinc and pyroxene crystal glaze and preparing method thereof Download PDFInfo
- Publication number
- CN101481261A CN101481261A CNA2009100371208A CN200910037120A CN101481261A CN 101481261 A CN101481261 A CN 101481261A CN A2009100371208 A CNA2009100371208 A CN A2009100371208A CN 200910037120 A CN200910037120 A CN 200910037120A CN 101481261 A CN101481261 A CN 101481261A
- Authority
- CN
- China
- Prior art keywords
- parts
- crystalline glaze
- zinc
- titanium
- pyroxene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a titanium-zinc-pyroxene crystalline glaze. Titanium oxide and zinc oxide are introduced based on pyroxene crystalline glaze and mixed in a base material of the pyroxene crystalline glaze, and then the crystalline glaze is sintered and prepared on domestic ceramic and artistic ceramic according to a firing process of the conventional pyroxene crystalline glaze. The titanium-zinc-pyroxene crystalline glaze is characterized in that the chemical composition thereof comprises 55-63% of SiO2, 8-10% of Al2O3, 8-10% of Fe2O3, 5-8% of CaO, 6-9% of MgO, 2-3% of K2O, 3-4% of Na2O, 5-10% of TiO2 and 5-15% of ZnO. The following raw ceramic materials are adopted in the titanium-zinc-pyroxene crystalline glaze and proportioned according to the following parts of the selected raw ceramic materials by weight: 8-15 parts of calcite, 10-18 parts of talc, 20-30 parts of quartz, 10-16 parts of glass powder, 10-20 parts of albite, 8-15 parts of potassium feldspar, 5-10 parts of the titanium oxide and 5-15 parts of the zinc oxide. The preparation process of the titanium-zinc-pyroxene crystalline glaze is the same as the firing process of the conventional pyroxene crystalline glaze, which needs no special treatment, thus the preparation process is very simple and convenient to be performed.
Description
Technical field:
The invention belongs to ceramic glaze, refer in particular to the glaze and the distribution thereof of a kind of domestic ceramics and craft artistic pottery and porcelain surface crystalline glaze, belong to the ceramic glaze preparation field.The surface that is used for decorative daily-use pottery and craft artistic pottery and porcelain.
Prior art:
Crystalline glaze is a famous and precious artistic glaze, is a kind of artificial lens fancy glaze, is to add crystallizing agent in basic glaze, is controlled at the glaze that forms the different shape decorative pattern in the glaze layer by burning till.But present crystalline glaze ceramic product, it is narrow to exist firing range, the difficult control of brilliant flower growth, sagging sticks in the product bottom and more seriously waits technical barrier.A kind of iron, zinc, pyroxene crystalline glaze and distribution thereof (patent No. 200710035130.9), though this invention has solved partial technical problems, the prescription of this invention is to burn till under oxidizing atmosphere, has caused crystallization glazed pottery porcelain products to be prone to rubescent phenomenon.Therefore, need research firing range broad, the more manageable ceramic crystallization glaze formula of brilliant flower.
Summary of the invention:
It is narrow to the objective of the invention is to exist firing range at existing crystalline glaze, brilliant flower growth deficiency rambunctious, research firing range broad, the more manageable ceramic crystallization glaze formula of brilliant flower, a kind of new crystalline glaze is provided, and this crystalline glaze operating procedure is simple, is easy to control.
The objective of the invention is to be achieved through the following technical solutions, a kind of pyroxene crystalline glaze, on the basis of pyroxene crystalline glaze, add a large amount of titanium oxide and zinc oxide, titanium oxide and zinc oxide are mixed according to the basestocks of certain ratio with the pyroxene crystalline glaze, according to the sintering technology of conventional pyroxene crystalline glaze, just can on domestic ceramics and craft artistic pottery and porcelain, burn till crystalline glaze.
The chemical constitution of described pyroxene crystalline glaze is:
SiO
2：55-63％ Al
2O
3：8—10％ Fe
2O
3：8—10％
CaO：5—8％ MgO：6—9％ K
2O：2—3％
Na
2O：3—4％ TiO
2：5—10％ ZnO：5—15％
This crystalline glaze adopts following ceramic raw material, selects for use parts by weight to be usually:
8-15 parts in calcite; 10-18 parts in talcum; Quartzy 20-30 parts; 10-16 parts in glass powder; 10-20 parts of albites; 8-15 parts of potassium felspar sands; 5-10 parts of titanium oxide; 5-15 parts in zinc oxide.
The manufacture craft of this crystalline glaze is the same substantially with common color glaze with sintering technology, does not need to handle especially.Therefore, implement very easy.
Main innovate point of the present invention is: by adding a large amount of titanium oxide and zinc oxide, add the effect that zinc oxide had both had dissolved iron, have the effect of the crystalline of promotion again.Add titanium oxide, easily generate Fe when having solved ferric oxide and under oxidizing atmosphere, burning till
2+And Fe
3+, be prone to the rubescent phenomenon of product, can reduce Ca in the prescription again
2+Content has solved crystallization glaze firing and has become the narrow problem of temperature range.
Embodiment:
The invention will be further described below in conjunction with specific embodiment, takes following material and carry out proportioning according to the weight deal:
12 parts in 25 parts of glass powder of 12 parts of quartz of 10 parts of talcums of calcite
10 parts in 8 parts of zinc oxide of 10 parts of titanium oxide of 13 parts of potassium felspar sands of albite
After above-mentioned batch mixes, to expect: the ratio of ball: water=1:2:0.7 joins in the ball mill, grind and went out mill in 48 hours, the slurry of gained is a glaze of the present invention behind deironing and mistake 250 mesh sieves, again glaze is imposed on that (the glaze layer thickness is controlled at 0.5-0.8mm) on the green compact, go in the shuttle kiln after the drying to burn till, top temperature is 1270 ℃, the crystallization holding temperature is 1140 ℃, and the crystallization soaking time is 3 hours, and firing period is 10 hours, its brilliant flower shape of the product that burns till belongs to tetragon or Polygons mostly, lucuriant in design, flow liner is arranged, the rainbow sense is arranged and exempt from the milli sense.
Claims (2)
1, a kind of titanium, zinc, pyroxene crystalline glaze is characterized in that: introduce titanium oxide and zinc oxide on the basis of pyroxene crystalline glaze, and mix in the basestocks of pyroxene crystalline glaze, make the chemical constitution of glaze be:
SiO
2： 55-63％ Al
2O
3：8—10％ Fe
2O
3：8—10％
CaO： 5—8％ MgO：?6—9％ K
2O：2—3％
Na
2O： 3—4％ TiO
2：5—10％ ZnO：5—15％
The sintering technology of pyroxene crystalline glaze burns till crystalline glaze on domestic ceramics, craft artistic pottery and porcelain routinely.
2, titanium as claimed in claim 1, zinc, pyroxene crystalline glaze is characterized in that: described titanium, zinc, pyroxene crystalline glaze adopt following ceramic raw material, carry out proportioning according to the following ceramic raw material of selecting for use with parts by weight: 8-15 parts in calcite; 10-18 parts in talcum; Quartzy 20-30 parts; 10-16 parts in glass powder; 10-20 parts of albites; 8-15 parts of potassium felspar sands; 5-10 parts of titanium oxide; 5-15 parts in zinc oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100371208A CN101481261A (en) | 2009-02-05 | 2009-02-05 | Titanium, zinc and pyroxene crystal glaze and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100371208A CN101481261A (en) | 2009-02-05 | 2009-02-05 | Titanium, zinc and pyroxene crystal glaze and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101481261A true CN101481261A (en) | 2009-07-15 |
Family
ID=40878577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2009100371208A Pending CN101481261A (en) | 2009-02-05 | 2009-02-05 | Titanium, zinc and pyroxene crystal glaze and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101481261A (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173869A (en) * | 2011-01-19 | 2011-09-07 | 江苏高淳陶瓷股份有限公司 | Preparation method of non-ferrous tea dust crystalline glaze |
| CN102249739A (en) * | 2011-05-26 | 2011-11-23 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102442841A (en) * | 2011-10-12 | 2012-05-09 | 上海高诚艺术包装有限公司 | Panther print glaze and preparation and use method thereof |
| CN102515858A (en) * | 2011-12-14 | 2012-06-27 | 广东长城集团有限公司 | Sintering method of crystal glaze |
| CN102557757A (en) * | 2012-03-08 | 2012-07-11 | 桂林理工大学 | Method for preparing zinc silicate crystal glaze based on alaskite as basic glaze raw material |
| CN102659453A (en) * | 2012-04-01 | 2012-09-12 | 江苏拜富科技有限公司 | Crystal glaze and its preparation method and use method |
| CN102718471A (en) * | 2012-05-31 | 2012-10-10 | 福建省德化县锦福陶瓷有限公司 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
| CN102936156A (en) * | 2012-10-30 | 2013-02-20 | 佛山市道氏陶瓷技术服务有限公司 | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof |
| CN103224727A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
| CN104193411A (en) * | 2014-08-05 | 2014-12-10 | 广东道氏技术股份有限公司 | Crystalline glaze for sanitary ceramic sanitary ware and preparation process thereof |
| CN106430964A (en) * | 2016-11-01 | 2017-02-22 | 平顶山学院 | Ceramic glaze with red bottom and black crystallization points and preparation method thereof |
| CN107032613A (en) * | 2017-04-14 | 2017-08-11 | 景德镇市九段烧瓷厂 | Sapphire blue crystalline glaze |
| CN110092580A (en) * | 2019-05-07 | 2019-08-06 | 无锡工艺职业技术学院 | A kind of greenwave crystalline glaze and preparation process |
| CN110304830A (en) * | 2019-08-19 | 2019-10-08 | 东北大学 | A kind of achmatite achmite crystalline glaze material and preparation method thereof and application method |
| CN110316968A (en) * | 2019-08-13 | 2019-10-11 | 江西陶瓷工艺美术职业技术学院 | It is a kind of to burn polymorphic multicolour crystalline glaze and its preparation method and application fastly |
| CN111003942A (en) * | 2020-01-08 | 2020-04-14 | 湖南泰鑫瓷业有限公司 | Frost crystal glaze and preparation method thereof |
| CN112408797A (en) * | 2020-12-04 | 2021-02-26 | 湖南华联瓷业股份有限公司 | Crystalline glaze and preparation method thereof |
| CN113149437A (en) * | 2021-06-24 | 2021-07-23 | 广东欧文莱陶瓷有限公司 | High-hardness digital protective glaze |
-
2009
- 2009-02-05 CN CNA2009100371208A patent/CN101481261A/en active Pending
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173869A (en) * | 2011-01-19 | 2011-09-07 | 江苏高淳陶瓷股份有限公司 | Preparation method of non-ferrous tea dust crystalline glaze |
| CN102249739A (en) * | 2011-05-26 | 2011-11-23 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102249739B (en) * | 2011-05-26 | 2013-01-16 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102442841A (en) * | 2011-10-12 | 2012-05-09 | 上海高诚艺术包装有限公司 | Panther print glaze and preparation and use method thereof |
| CN102515858B (en) * | 2011-12-14 | 2014-05-21 | 广东长城集团股份有限公司 | Sintering method of crystal glaze |
| CN102515858A (en) * | 2011-12-14 | 2012-06-27 | 广东长城集团有限公司 | Sintering method of crystal glaze |
| CN102557757A (en) * | 2012-03-08 | 2012-07-11 | 桂林理工大学 | Method for preparing zinc silicate crystal glaze based on alaskite as basic glaze raw material |
| CN102659453A (en) * | 2012-04-01 | 2012-09-12 | 江苏拜富科技有限公司 | Crystal glaze and its preparation method and use method |
| CN102659453B (en) * | 2012-04-01 | 2014-09-17 | 江苏拜富科技有限公司 | Crystal glaze and its preparation method and use method |
| CN102718471A (en) * | 2012-05-31 | 2012-10-10 | 福建省德化县锦福陶瓷有限公司 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
| CN102936156B (en) * | 2012-10-30 | 2014-03-12 | 佛山市道氏科技有限公司 | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof |
| CN102936156A (en) * | 2012-10-30 | 2013-02-20 | 佛山市道氏陶瓷技术服务有限公司 | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof |
| CN103224727A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
| CN103224727B (en) * | 2013-04-08 | 2014-12-24 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
| CN104193411A (en) * | 2014-08-05 | 2014-12-10 | 广东道氏技术股份有限公司 | Crystalline glaze for sanitary ceramic sanitary ware and preparation process thereof |
| CN106430964A (en) * | 2016-11-01 | 2017-02-22 | 平顶山学院 | Ceramic glaze with red bottom and black crystallization points and preparation method thereof |
| CN106430964B (en) * | 2016-11-01 | 2019-06-28 | 平顶山学院 | A kind of method of the black crystalline temperature ceramic glaze preparation ceramics in red bottom |
| CN107032613A (en) * | 2017-04-14 | 2017-08-11 | 景德镇市九段烧瓷厂 | Sapphire blue crystalline glaze |
| CN110092580A (en) * | 2019-05-07 | 2019-08-06 | 无锡工艺职业技术学院 | A kind of greenwave crystalline glaze and preparation process |
| CN110316968A (en) * | 2019-08-13 | 2019-10-11 | 江西陶瓷工艺美术职业技术学院 | It is a kind of to burn polymorphic multicolour crystalline glaze and its preparation method and application fastly |
| CN110304830A (en) * | 2019-08-19 | 2019-10-08 | 东北大学 | A kind of achmatite achmite crystalline glaze material and preparation method thereof and application method |
| CN110304830B (en) * | 2019-08-19 | 2022-02-11 | 东北大学 | Spodumene crystalline glaze and preparation method and use method thereof |
| CN111003942A (en) * | 2020-01-08 | 2020-04-14 | 湖南泰鑫瓷业有限公司 | Frost crystal glaze and preparation method thereof |
| CN112408797A (en) * | 2020-12-04 | 2021-02-26 | 湖南华联瓷业股份有限公司 | Crystalline glaze and preparation method thereof |
| CN113149437A (en) * | 2021-06-24 | 2021-07-23 | 广东欧文莱陶瓷有限公司 | High-hardness digital protective glaze |
| CN113149437B (en) * | 2021-06-24 | 2021-09-17 | 广东欧文莱陶瓷有限公司 | High-hardness digital protective glaze |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101481261A (en) | Titanium, zinc and pyroxene crystal glaze and preparing method thereof | |
| CN100447111C (en) | Crystalline glaze of iron, zinc and augite and its material compounding process | |
| CN102173869B (en) | Preparation method of non-ferrous tea dust crystalline glaze | |
| CN101759441B (en) | Ceramic glaze and preparation process thereof | |
| CN101913910B (en) | Multicolor furnace transmutation glaze ground coat and manufacturing method thereof | |
| CN102249739B (en) | Preparation method of carbon-golden metallic luster crystalline glaze | |
| CN101891455B (en) | Middle-low temperature sintered fine bone china and production method thereof | |
| CN105330158A (en) | Glaze of brunet ceramic and preparation method of glaze | |
| CN106977097B (en) | Raw glaze for transparent high-gloss medium-temperature hard porcelain and preparation method thereof | |
| CN105120705A (en) | Heat-resistant synthetic jewellery material | |
| CN101659567A (en) | Furnace transmutation decoration glazed brick and production technology | |
| CN102020461B (en) | High-temperature bright red ceramic and preparation method thereof | |
| CN107216127A (en) | Dehua pearl white porcelain and its preparation technology | |
| CN107777888A (en) | Black-and-blue metal-lustrous glaze and preparation method thereof | |
| CN1328223C (en) | Manufacturing method of redyohen tenmoku ceramic and ceramic glaze used therefor | |
| CN108892478B (en) | Low-temperature porcelain and preparation method thereof | |
| CN107572822A (en) | A kind of pottery plum green glaze and preparation method thereof | |
| CN113402265A (en) | White-bottom black-flower enamel and preparation method thereof | |
| CN106277792B (en) | A kind of emerald blueness glaze and its method for cooking | |
| CN109748506A (en) | Metallic crystal glaze, ceramic tile and preparation method thereof | |
| CN101659542B (en) | Crystal ceramic and preparation method thereof | |
| CN107129268A (en) | Dehua green onion root ceramic whiteware device and its preparation technology | |
| CN104909568B (en) | Ceramic with coffee crystal glaze layer on surface and preparation method therefor | |
| CN101544491A (en) | Pug formula of bone porcelain and preparation technology thereof | |
| CN103420689A (en) | Artistic pottery fancy glaze and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090715 |