CN101444232B - Chinese herbal extract and plant protection solution - Google Patents

Chinese herbal extract and plant protection solution Download PDF

Info

Publication number
CN101444232B
CN101444232B CN 200810220575 CN200810220575A CN101444232B CN 101444232 B CN101444232 B CN 101444232B CN 200810220575 CN200810220575 CN 200810220575 CN 200810220575 A CN200810220575 A CN 200810220575A CN 101444232 B CN101444232 B CN 101444232B
Authority
CN
China
Prior art keywords
chinese herbal
plant
extract
herbal medicine
plant protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 200810220575
Other languages
Chinese (zh)
Other versions
CN101444232A (en
Inventor
胡美英
胡艳萍
张永华
徐伟松
田海峰
成秀娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEBEI TIANCHEN PLANT PROTECTION LIQUOR CO Ltd
South China Agricultural University
Original Assignee
HEBEI TIANCHEN PLANT PROTECTION LIQUOR CO Ltd
South China Agricultural University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HEBEI TIANCHEN PLANT PROTECTION LIQUOR CO Ltd, South China Agricultural University filed Critical HEBEI TIANCHEN PLANT PROTECTION LIQUOR CO Ltd
Priority to CN 200810220575 priority Critical patent/CN101444232B/en
Publication of CN101444232A publication Critical patent/CN101444232A/en
Application granted granted Critical
Publication of CN101444232B publication Critical patent/CN101444232B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a Chinese herbal extract and a plant protection solution. The Chinese herbal extract is made from the flowing crude drugs: 25-30% of kuhseng, 15-20% of stemona root, 5-10% of rangoon creeper, 20-25% of omphalia, 15-20% of pedomicrobium, 5-10% of large leaf gentian root and 5-10% of earthworm, and the percentages are weight percentages. The plant protection solution made from the Chinese herbal extract, a stabilizer and a synergistic agent is applied to agricultural production for the integrated pest control, increase of crop yield and quality improvement of farm products. Meanwhile, the plant protection solution has the advantages of low production cost, convenient use and good control effect, is suitable for large-scale use in national fruit and vegetable production and export bases or places with green food brand marks, and plays an important role in promoting production of nuisance-free fruits and vegetables and green food.

Description

A kind of plant liquid extract and plant protecting liquid
Technical field
The invention belongs to the agriculture and forestry production technical field, be specifically related to a kind of plant protecting liquid, relate in particular to a kind of plant liquid extract and the composite plant protecting liquid that obtains.
Background technology
The application of agricultural chemicals is anti-curing the disease, worm and crop smothering, guarantee one of important means of grain-production good harvest, for a long time, chemical pesticide is efficient with it, quick-acting, the economic dispatch advantage and occupy pesticide research and use in leading position, but, continuous progress along with scientific knowledge, people more and more recognize long-term a large amount of environmental pollution of using chemical synthetic pesticide to cause, the serious problems such as disruption of ecological balance and person poultry poisoning, social sustainable development receives much attention, simultaneously, pest is growed in intensity to the pesticide resistance of chemical synthetic pesticide, therefore, people urgently wish to find the unique also environment amenable novel agrochemical of mechanism of action.
Theoretically; the effect that disinfests, prevents and treats disease that has according to Chinese herbal medicine herbal medicine itself; compatibility principle according to " monarch, the minister, make, help " of the traditional Chinese medical science; the plant protecting liquid that extraction forms is applied in the agricultural production; reaching the harm of integrated control damage by disease and insect, the output that improves crops, the quality of improving its agricultural product can realize; plant extract material and Environmental compatibility are good simultaneously; selection pressure to pest is little; meet the requirement of social sustainable development, agricultural and production of forestry are significant.
But in experimental study, actual production, only find correct drug matching, reasonably choose Chinese herbal medicine and carry out scientific matching, obtain the significant Chinese herbal medicine formula of effect, could be improving the effect of prevention and elimination of disease and pests, and reach the immune decorum that activated plant itself has, the effect of the resistance of raising plant in the self-sow environment.The Chinese herbal medicine kind of motherland is very abundant, find the Chinese herbal medicine formula that is fit to plant protection to prepare required extract undoubtedly as looking for a needle in a haystack, must be through long-term a large amount of experimental summary.At present, also not using both at home and abroad academic documents and the application technology that traditional Chinese medical science compatibility theory carries out the integrated pest prevention and control of plant openly reports.
Summary of the invention
An object of the present invention is to fill up the blank of prior art, a kind of plant liquid extract is provided, have the effect that improves the plant prevention damage by disease and insect, and can reach the immune decorum that activated plant itself has, the effect of the resistance of raising plant in the self-sow environment.
Another object of the present invention provides one of described extract typical case and uses, and is equipped with stabilizing agent and additive compound and obtains a kind of plant protecting liquid that can directly use.
Purpose of the present invention is achieved by the following technical programs:
A kind of plant liquid extract is provided, is prepared by the former medicine of the Chinese herbal medicine of following weight percentage:
Kuh-seng 25~30%; The tuber of stemona 15~20%;
The fruit of Rangoon creeper's 5~10% stone-like omphalias 20~25%;
Soil bacterium 15~20%; The Mountain-spring of the Qin 5~10%;
Earthworm 5~10%.
The present invention preferably take the former medicine of Chinese herbal medicine as raw material, prepares described plant liquid extract through solvent extraction; Described solvent is selected the mixture of any or two or more any ratios in conventional other solvent that uses of ethanol, dimethylbenzene or this area, uses when multiple, and total usage amount can not be greater than the total content of plant liquid extract;
The present invention provides one of described extract typical case to use simultaneously, is about to described Chinese medicine extract and is equipped with stabilizing agent and additive compound and obtains a kind of plant protecting liquid that can directly use.Concrete technical scheme is:
A kind of plant protecting liquid is provided, comprises the component that forms by following percentage by weight:
Plant liquid extract 80~99%; Stabilizing agent 0.1~10%;
Builder 0.1~10%.
Described stabilizing agent is epoxidized soybean oil, epoxidized linseed, 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyvinyl one glycol diglycidyl ether or the sodium sorbate any one or multiple, use when multiple, total usage amount can not be greater than the maximum of deal;
Described builder is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat or the formaldehyde, uses when multiple, and total usage amount can not be greater than the maximum of deal.
As one preferred, plant protecting liquid of the present invention is comprised of according to described percentage by weight following component:
Plant liquid extract 85%;
Stabilizing agent: sodium sorbate is 9%;
Builder: alkyl carbonate is 6%;
In above-mentioned preferred plant protecting liquid technical scheme, described Chinese medicine extract is preferably prepared through solvent extraction according to described percentage by weight by following component:
Kuh-seng 30%; The tuber of stemona 20%;
The fruit of Rangoon creeper 5%; Stone-like omphalia 20%;
Soil bacterium 15%; The Mountain-spring of the Qin 5%;
Earthworm 5%.
Plant protecting liquid of the present invention is multiple Chinese herbal medicine to be extracted according to a certain percentage the extract that obtains according to traditional Chinese medical science monarch, minister, the compatibility principle that makes, help, is equipped with the multiple-effect ecological vegetable source plant protection product that stabilizing agent and auxiliary agent are prepared from again.In the process of using, plant liquid extract can effectively promote the growth of plant in the plant body-internal-circulation, can better promote growth under the gravitation of the moon, recover the original natural quality of crop.The natural active matter of plant liquid extract can be remembered and metabolism is decomposed, and reaches the growth conditions of expelling parasite, disease-resistant recovery crop nature by using immune system that Chinese herbal medicine protection liquid excites plant corpus originally to have.Therefore, this plant protecting liquid has really been realized having demonstrated fully the theory of environment protective plant protecting and ecological plant protection at the overall process Harmless of producing, using, and innovation ground is successfully applied to the plant protection field with the Chinese herbal medicine theory.
Chinese medicine extract of the present invention and plant protecting liquid, its raw material and active ingredient are Chinese herbal medicine, reach the immune decorum that activated plant itself has by correct medicine compatibility method and ratio, so the present invention has following beneficial effect:
1, the present invention has found a kind of correct drug matching, reasonably choose Chinese herbal medicine and carry out scientific matching, obtain the significant Chinese herbal medicine formula of effect, the Chinese medicine extract for preparing can improve plant prevention damage by disease and insect ability, and reaches the immune decorum that activated plant itself has, improves the effect of the resistance of plant in the self-sow environment
2, the plant protection liquid product that is prepared by the Chinese medicine extract in the application in practice process for Crop securify; Efficient to the pest that occurs crops; Using its protection liquid not only can prevention and elimination of disease and pests, can also ensure the agricultural product of producing green standard.
3, long-term use can improve soil, reduces the remaining heavy metal that exceeds standard and the violated chemical pesticide to be eliminated in the soil, and plant protection product of the present invention is environmentally friendly, and lasting use can recover disrupted ecological balanced system.
4, use the realization agricultural that plant protection product of the present invention can be truly volume increase, increase income, for modernized high-new technology farming to a higher levels, have positive impetus.
5, solve the problem of agricultural product edible safety; the crops that application Chinese herbal medicine protection liquid is protected can be produced the agricultural product of green, nutrition, health; be the agricultural product that ensure that people are edible upward safely, healthy, positive contribution is made in high-quality life on the mistake.
Embodiment
In order to understand better essence of an invention, the below describes technology contents of the present invention in detail with some typical embodiment, but content of the present invention is not limited to this.
Embodiment 1: according to following weight percentage the former medicine of Chinese herbal medicine is obtained the Chinese medicine extract according to this area conventional method behind ethanol extraction:
Kuh-seng 30%; The tuber of stemona 20%;
The fruit of Rangoon creeper 5%; Stone-like omphalia 20%;
Soil bacterium 15%; The Mountain-spring of the Qin 5%;
Earthworm 5%.
With said herbal medicine extract and stabilizing agent and auxiliary agent according to composite No. 1, the plant protecting liquid (C1) that obtains of following weight percentage:
Plant liquid extract 85%;
Stabilizing agent: epoxidized soybean oil is 5%;
Builder: Butacide is 10%.
Embodiment 2: according to following weight percentage the former medicine of Chinese herbal medicine is obtained the Chinese medicine extract behind ethanol extraction:
Kuh-seng 25%; The tuber of stemona 15%;
The fruit of Rangoon creeper 5%; Stone-like omphalia 25%;
Soil bacterium 15%; The Mountain-spring of the Qin 10%;
Earthworm 5%.
With said herbal medicine extract and stabilizing agent and auxiliary agent according to composite No. 2, the plant protecting liquid (C2) that obtains of following weight percentage:
Plant liquid extract 90%;
Stabilizing agent: phenyl glycidyl ether is 2%;
Builder: alkyl carbonate is 8%.
Embodiment 3: according to following weight percentage the former medicine of Chinese herbal medicine is obtained the Chinese medicine extract behind ethanol extraction:
Kuh-seng 30%; The tuber of stemona 20%;
The fruit of Rangoon creeper 5%; Stone-like omphalia 20%;
Soil bacterium 15%; The Mountain-spring of the Qin 5%;
Earthworm 5%.
With said herbal medicine extract and stabilizing agent and auxiliary agent according to composite No. 3, the plant protecting liquid (C3) that obtains of following weight percentage:
Plant liquid extract 85%;
Stabilizing agent: sodium sorbate is 9%;
Builder: alkyl carbonate is 6%.
Embodiment 4: according to following weight percentage the former medicine of Chinese herbal medicine is obtained the Chinese medicine extract behind ethanol extraction:
Kuh-seng 25%; The tuber of stemona 15%;
The fruit of Rangoon creeper 5%; Stone-like omphalia 25%;
Soil bacterium 15%; The Mountain-spring of the Qin 10%;
Earthworm 5%.
With said herbal medicine extract and stabilizing agent and auxiliary agent according to composite No. 4, the plant protecting liquid (C4) that obtains of following weight percentage:
Plant liquid extract 95%;
Stabilizing agent: epoxidized linseed is 2%;
Builder: alkyl carbonate is 3%.
Embodiment 5: according to following weight percentage the former medicine of Chinese herbal medicine is obtained the Chinese medicine extract behind ethanol extraction:
Kuh-seng 26%; The tuber of stemona 16%;
The fruit of Rangoon creeper 9%; Stone-like omphalia 21%;
Soil bacterium 16%; The Mountain-spring of the Qin 6%;
Earthworm 6%.
With said herbal medicine extract and stabilizing agent and auxiliary agent according to composite No. 5, the plant protecting liquid (C5) that obtains of following weight percentage:
Plant liquid extract 89.9%;
Stabilizing agent: 3-chloro-1,2-expoxy propane are 10%;
Builder: formaldehyde is 0.1%.
Embodiment 6: according to following weight percentage the former medicine of Chinese herbal medicine is obtained the Chinese medicine extract behind ethanol extraction:
Kuh-seng 22%; The tuber of stemona 15%;
The fruit of Rangoon creeper 10%; Stone-like omphalia 18%;
Soil bacterium 20%; The Mountain-spring of the Qin 5%;
Earthworm 10%.
With said herbal medicine extract and stabilizing agent and auxiliary agent according to composite No. 6, the plant protecting liquid (C6) that obtains of following weight percentage:
Plant liquid extract 99%;
Stabilizing agent: 3-chloro-1,2-expoxy propane are 0.1%;
Builder: formaldehyde is 0.9%.
Embodiment 7: the present embodiment is chosen Chinese herbal medicine extraction plant protecting liquid C1, C2, C3, C4 and is carried out the indoor cytotoxicity experiment to cabbage caterpillar
Adopt leaf dish method to measure: fresh smooth cabbage leaves is broken into the leaf dish with circular card punch, put into liquid to be measured and soak 5s, CK (blank assay) processes with control solvent.Put into culture dish after drying under the room temperature, every ware is put into 5 leaf dish of processing with liquid, and CK puts into the leaf dish of processing with solvent.Then access the examination worm of 1 hungry 4h, 20~30 repetitions of every processing.After processing certain hour, check examination worm death condition and record, calculate lethality and corrected mortality by formula (1), (2), experimental result sees Table 1.
Figure G2008102205759D00091
Figure G2008102205759D00092
The protection liquid of table 1 different formulations is to the cytotoxicity of cabbage caterpillar
Figure G2008102205759D00093
Lethality, corrected mortality are the mean value of three repetitions in the table.
Embodiment 8: Chinese herbal medicine extraction plant protecting liquid C3 is to the indoor virulence of cabbage caterpillar
Adopt leaf dish method to measure: fresh smooth cabbage leaves is broken into the leaf dish with circular card punch, put into liquid to be measured and soak 5s, CK processes with control solvent.Put into culture dish after drying under the room temperature, every ware is put into processing and is contrasted the same number of leaf dish, alternate putting, and perform mark.Then access the examination worm of 1 hungry 4h, 15 repetitions of every processing.After processing certain hour, check examination worm death condition and record, calculate lethality and corrected mortality by formula (1), (2), and take the probit value of corrected mortality as Y value, the concentration logarithm is the X value, adopts method of least squares to obtain virulence regression equation, calculates correlation coefficient r, LC 50, LC 90Experimental result sees Table 2.
The table 2 C3 number indoor virulence to cabbage caterpillar
Figure G2008102205759D00101
Embodiment 9: Chinese herbal medicine extraction plant protecting liquid C3 is to the lepidoptera pest control efficiency
Test site is dragon's cave-stalactite cave vegetable plot, GuangZhou, Guangdong Province city and paddy field.The plantation insect high-incidence season sprays with the manual compression sprayer.4 repetitions of every processing were respectively investigated once before dispenser and after the dispenser in 1 day, 3 days and 7 days, and the full phase is investigated 4 times altogether.Diagonal 5 samplings in every residential quarter are decided strain at every and are investigated 5 strain dishes, and every residential quarter is investigated the borer population amount alive of 25 strain dishes altogether.Calculate insect population decline rate and control efficiency by formula (3), (4), the results are shown in Table 3.
Figure G2008102205759D00102
Figure G2008102205759D00103
The table 3 C3 number control efficiency to lepidoptera pest 7d
Figure G2008102205759D00104
Embodiment 10: Chinese herbal medicine extraction plant protecting liquid C3 prevents and treats statistical indicator to fungal disease
Test site is dragon's cave-stalactite cave vegetable plot, GuangZhou, Guangdong Province city.The plantation disease high-incidence season sprays with the manual compression sprayer.4 repetitions of every processing were respectively investigated once before dispenser and after the dispenser in 1 day, 3 days and 7 days, and the full phase is investigated 4 times altogether.Diagonal 5 samplings in every residential quarter are decided strain at every and are investigated 5 strain dishes, and every residential quarter is investigated 25 strain dishes altogether.Calculate disease index and control efficiency by formula (5), (6), experimental result sees Table 4.
Figure G2008102205759D00112
Figure G2008102205759D00113
The table 4 C3 number 7d control efficiency to fungal disease
Figure G2008102205759D00114
Embodiment 11: the field control effectiveness test of Chinese herbal medicine extraction plant protecting liquid C3 control cabbage caterpillar
Test site is dragon's cave-stalactite cave vegetable plot, GuangZhou, Guangdong Province city.Behind the plantation cabbage mustard 35d, dark greyish green low instar larvae (1~3 age) occurrence in peak period dispenser is sprayed with the manual compression sprayer.4 repetitions of every processing were respectively investigated once before dispenser and after the dispenser in 1 day, 3 days and 7 days, and the full phase is investigated 4 times altogether.Diagonal 5 samplings in every residential quarter are decided strain at every and are investigated 5 strain dishes, and every residential quarter is investigated the borer population amount alive of 25 strain dishes altogether.Calculate insect population decline rate and control efficiency by formula (3), (4), the results are shown in Table 5.
Table 5 C3 control cabbage caterpillar field control effectiveness test result
Figure G2008102205759D00121
Figure G2008102205759D00131

Claims (6)

1. plant liquid extract is characterized in that being prepared by the former medicine of the Chinese herbal medicine of following weight percentage:
Kuh-seng 25~30%; The tuber of stemona 15~20%;
The fruit of Rangoon creeper's 5~10 % stone-like omphalias 20~25%;
Soil bacterium 15~20%; The Mountain-spring of the Qin 5~10%;
Earthworm 5~10%.
2. the preparation method of the described plant liquid extract of claim 1 is characterized in that preparing through solvent extraction with the former medicine of Chinese herbal medicine.
3. the preparation method of described plant liquid extract according to claim 2, it is characterized in that described solvent select in ethanol or the dimethylbenzene any or both are with the mixed mixture of any ratio.
4. plant protecting liquid is characterized in that comprising the component that forms by following percentage by weight:
The described plant liquid extract of claim 1: 80~99%;
Stabilizing agent: 0.1~10%;
Builder: 0.1~10%;
Wherein, described stabilizing agent is epoxidized soybean oil, epoxidized linseed, 3-chloro-1, any one in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyvinyl one glycol diglycidyl ether or the sodium sorbate or multiple;
Described builder is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat or the formaldehyde.
5. described plant protecting liquid according to claim 4 is characterized in that comprising the component that forms by following percentage by weight:
The described plant liquid extract of claim 1: 85%;
Stabilizing agent: sodium sorbate is 9%;
Builder: alkyl carbonate is 6%.
6. described plant protecting liquid according to claim 5 is characterized in that what described Chinese medicine extract was prepared through solvent extraction according to described percentage by weight by following component:
Kuh-seng 30%; The tuber of stemona 20%;
The fruit of Rangoon creeper 5%; Stone-like omphalia 20%;
Soil bacterium 15%; The Mountain-spring of the Qin 5%;
Earthworm 5%.
CN 200810220575 2008-12-30 2008-12-30 Chinese herbal extract and plant protection solution Expired - Fee Related CN101444232B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200810220575 CN101444232B (en) 2008-12-30 2008-12-30 Chinese herbal extract and plant protection solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200810220575 CN101444232B (en) 2008-12-30 2008-12-30 Chinese herbal extract and plant protection solution

Publications (2)

Publication Number Publication Date
CN101444232A CN101444232A (en) 2009-06-03
CN101444232B true CN101444232B (en) 2013-01-02

Family

ID=40740345

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200810220575 Expired - Fee Related CN101444232B (en) 2008-12-30 2008-12-30 Chinese herbal extract and plant protection solution

Country Status (1)

Country Link
CN (1) CN101444232B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104757039A (en) * 2014-09-26 2015-07-08 刘宁 Biological pesticide for killing longicorn
CN105532747A (en) * 2016-02-04 2016-05-04 史运江 Plant pesticide for controlling tomato canker and preparation method
CN106172558A (en) * 2016-07-29 2016-12-07 安徽徽王农业有限公司 Anti-crop smothering medicament for blue berry and its preparation method and application
CN106234475A (en) * 2016-08-12 2016-12-21 国红福 A kind of clinical microbiology laboratory technique Chinese medicine antiseptic
CN106259575A (en) * 2016-08-16 2017-01-04 胡艳萍 A kind of plant liquid extract and plant protecting liquid
CN106614790A (en) * 2016-11-25 2017-05-10 安徽云鼎生态农林开发有限公司 Special plant protection liquid for Chinese softshell turtle culture rice
CN107409732A (en) * 2017-09-06 2017-12-01 张忠友 A kind of implantation methods of organic paddy rice

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
何昆等.中草药萃取液对植物病原真菌、细菌的抑制作用.《湖南农业科学》.2003,(第01期), *
李晓等.中草药萃取液在卷烟中的减害作用研究.《河南农业科学》.2008,(第10期), *
田新华等.马铃薯试管苗不同培养方式中添加抑菌中草药萃取液的作用.《中国马铃薯》.2005,(第06期), *

Also Published As

Publication number Publication date
CN101444232A (en) 2009-06-03

Similar Documents

Publication Publication Date Title
CN101444232B (en) Chinese herbal extract and plant protection solution
CN101999418B (en) Plant source pesticide for preventing and controlling golden autumn pear diseases and insect pests and preparation and application thereof
CN101720791B (en) Matrine pure plant source pesticide
CN101194606A (en) Pesticide missible oil preparation containing biological diesel oil solvent
CN102599201A (en) Compound plant-derived pesticide and preparation method thereof
CN101258861A (en) Use of southernwood extract as plant growth regulator and adverse-resistant agent
CN106259575A (en) A kind of plant liquid extract and plant protecting liquid
CN101940229A (en) Berberine plant source insecticide and preparation method thereof
CN103329943A (en) Insecticide composition containing natural celastrus angulatus and natural pyrethrin
CN104496668A (en) Green organic chemical fertilizer and preparation method thereof
CN105347905A (en) Medium-trace element environmental protection fertilizer with characteristics of plant disease and insect pest resistance and high stress resistance
CN101606536A (en) Wood vinegar soil disinfectant and preparation method thereof
CN107125265A (en) A kind of rotten hurt healing paint of ancient tree disease and preparation method thereof
CN103315006A (en) Insecticidal composition containing natural celastrus angulatus and natural vitex negundo and application thereof
CN103271099B (en) Artemisia annua micro emulsion and preparation method thereof
CN102550612A (en) Ecological environment-friendly pesticide
CN101720777A (en) Emamectin benzoate and efficient cyfluthrin pesticide mixture preparation
CN102365939B (en) Botanical sterilization preparation and application thereof for controlling anthracnose of grape
CN1422531A (en) 0.36% kuh-seng lye emulsion farm chemical and production method thereof
CN102617429A (en) Preparation method of athomin for preventing and treating rice planthopper
CN111449077B (en) Metiram compound bactericide and application thereof
CN102885042A (en) Environment-friendly potato field weeding combination
CN101455203B (en) Osthole and carbendazim compound composition and use thereof
CN101919332A (en) Method for biologically preventing and controlling leaf mold of tomatoes
CN101623009A (en) Botanical pesticide for inhibiting vegetable botrytis cinerea and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: QINGDAO JIAMINGYUAN TEA CO., LTD.

Free format text: FORMER OWNER: HEBEI TIANCHEN PLANT PROTECTION LIQUOR CO., LTD.

Effective date: 20121126

C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20121126

Address after: 266000 Shandong province Qingdao City, Shandong Road No. 111 Building No. 1 South Beauty unit 503

Applicant after: Hebei Tianchen Plant Protection Liquor Co., Ltd.

Applicant after: South China Agricultural University

Address before: 266000 Shandong province Qingdao City, Shandong Road No. 111 Building No. 1 South Beauty unit 503

Applicant before: Hebei Tianchen Plant Protection Liquor Co., Ltd.

Applicant before: South China Agricultural University

C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130102

Termination date: 20181230

CF01 Termination of patent right due to non-payment of annual fee