CN101422155B - Insecticide and miticide composition - Google Patents
Insecticide and miticide composition Download PDFInfo
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- CN101422155B CN101422155B CN 200710165315 CN200710165315A CN101422155B CN 101422155 B CN101422155 B CN 101422155B CN 200710165315 CN200710165315 CN 200710165315 CN 200710165315 A CN200710165315 A CN 200710165315A CN 101422155 B CN101422155 B CN 101422155B
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- water
- avermectin
- miticide composition
- compound
- desinsection
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- 239000000642 acaricide Substances 0.000 title claims abstract description 12
- 239000000203 mixture Substances 0.000 title claims description 18
- 239000002917 insecticide Substances 0.000 title description 2
- 239000005660 Abamectin Substances 0.000 claims abstract description 21
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003960 organic solvent Substances 0.000 claims abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 230000008595 infiltration Effects 0.000 claims description 10
- 238000001764 infiltration Methods 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- -1 polyoxyethylene Polymers 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 2
- GSNUFIFRDBKVIE-UHFFFAOYSA-N DMF Natural products CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 2
- 230000000740 bleeding effect Effects 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- 239000002075 main ingredient Substances 0.000 claims 1
- 230000000895 acaricidal effect Effects 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 241000607479 Yersinia pestis Species 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000575 pesticide Substances 0.000 abstract description 4
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- 241000255777 Lepidoptera Species 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 230000001276 controlling effect Effects 0.000 abstract 2
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 239000004530 micro-emulsion Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 8
- 230000000749 insecticidal effect Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 238000009313 farming Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- JPDSMZVGMSWNKR-UHFFFAOYSA-M C(C1=CC=CC=C1)(=O)[O-].C(CCCCCCCCCCC)[Ca+] Chemical compound C(C1=CC=CC=C1)(=O)[O-].C(CCCCCCCCCCC)[Ca+] JPDSMZVGMSWNKR-UHFFFAOYSA-M 0.000 description 2
- 241000258937 Hemiptera Species 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 241000500437 Plutella xylostella Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a compound of a pesticide and an acaricide which is prepared by taking Emamectin benzoate and avermectin as the main components, adding a surface active agent and a permeation synergist and mixing an organic solvent and water. The compound of the pesticide and the acaricide has the advantages of high effect, low poison, broad spectrum, safety, and the like, can be broadly used for controlling the normally seen pests and acarids in the pesticide and has excellent controlling effects on the lepidoptera, the homopteran pests and a plurality of acarids on the vegetables; and the compound is simple in production technique, does not have three wastes, and environment pollution and is convenient to be used.
Description
Technical field
The invention belongs to pesticide field, relate to a kind of Insecticidal and acaricidal agent composition.
Background technology
Emamection benaoate and Avermectin are as a kind of super-high-efficient, wide spectrum, low toxicity, biological source insecticide.Belonging to green non-pollution agricultural insecticidal, miticide, is the product that state key is advocated development.Emamection benaoate is the product synthetic take Avermectin as raw material, both mechanism of action is similar, has complementarity on this both control spectrum and effect characteristics such as quick-acting and the lasting effect, have synergistic function after both are composite and enlarged control spectrum, prove that through lot of experiments both significantly are better than the single dose product to the control efficiency of Lepidoptera, Homoptera and mite class after composite.But both complex preparations are always there are no report.
The single dose of emamection benaoate and Avermectin was used at Vegetable area in recent years in a large number as the high-end product in the Insecticidal and acaricidal agent on market, its formulation is take missible oil as main, microemulsion is take water as matrix, by dissolving former medicine, the homogeneous stability system that the processes such as microemulsified form.The micella particle diameter is less than optical wavelength in the system, therefore the microemulsion appearance transparent is like missible oil, because its surface-active contents is high, emulsified particles is little, the opening up of its liquid, wetting, infiltration and filming function are better than cream preparation, therefore the effective rate of utilization of its liquid is higher, and its drug effect is 1.2--1.5 times of missible oil under same dose.Microemulsion has not only been saved a large amount of organic solvents take water as matrix, has reduced production cost, also is conducive to alleviate environmental pollution pressure, to the development green agriculture, keeps the ecological balance significant.
Summary of the invention
The purpose of this invention is to provide a kind of efficient, low, use safety, energy savings, substantially non-staining microemulsion insecticidal, miticide agricultural chemicals.
The invention provides a kind of Insecticidal and acaricidal agent composition, it is by emamection benaoate, Avermectin, surfactant, infiltration synergist, mixed organic solvents and water, the microemulsion that processes through certain production technology.
A kind of desinsection provided by the invention, miticide composition, its composition and weight percentage are as follows: take emamection benaoate and Avermectin as main component, add surfactant, infiltration synergist, mixed organic solvents and water are formulated, and wherein: emamection benaoate is 0.1%-10%, and Avermectin is 0.1%-10%, surfactant 5-30%, infiltration synergist 0.5-15%, organic solvent 5%-40%, water supplies 100%.
A kind of desinsection of the present invention, miticide composition, wherein emamection benaoate and Avermectin are main component, its weight content is respectively 0.1%-10% and 0.1%-10%.
Be fit to organic solvent of the present invention any or the combination more than two kinds and two kinds in benzene,toluene,xylene, methyl alcohol, ethanol, acetone, DMF, cyclohexanone, dimethyl sulfoxide (DMSO), the 1-METHYLPYRROLIDONE are arranged.
Be fit to surfactant of the present invention and comprise that alkylphenol polyoxyethylene is serial, fatty alcohol-polyoxyethylene ether is serial, agricultural emulsifier NO．600 is serial, castor oil polyoxyethylene ether series, phenethyl phenol polyethenoxy ether formaldehyde condensation products, the compound of one or more in the dodecyl benzene sulfonate.
Be fit to infiltration synergist of the present invention and comprise silicone based bleeding agent, azone, thiophene ketone, alkylbenzenesulfonate, fatty alcohol sulphuric acid, rapid osmotic T, the compound of one or more in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, tertiary amine oxide, the dodecyl dimethyl benzyl ammonium chloride.
The water that is fit among the present invention is running water, any in underground water, deionized water, the distilled water.
The main technical schemes that the present invention adopts: replace a large amount of inflammable organic solvents with water, reduce toxicity and the production cost of product, improve the peaceful property of producing and casting, the surfactant of higher dosage and infiltration synergist can improve the opening up of liquid, wetting, permeability, improve utilization rate of active components, reduce actual dosage, thereby reach the raising drug effect, reduce the purpose of toxicity and use cost.
The present invention can with emamection benaoate and the former medicinal solvent dissolving of Avermectin, then add surfactant and infiltration synergist with known method preparation, and the water of the rear adding surplus that stirs fully stirs into homogeneous phase transparent liquid.The preferred using method of said composition is foliage spray, regards thing as and controlling object is generally 20-200ppm.Below in conjunction with example the present invention is done more specific description, but example does not limit the present invention.Percentage in the example is percetage by weight.
Embodiment
Example 1
0.4% emamection benaoate, avermectin micro-emulsion
The composition percentage by weight
Emamection benaoate 0.2%
Avermectin 0.2%
DMF 8.0%
OP-10 5.0％
Azone 0.5%
Running water 86.1%
The preparation method: emamection benaoate and the former medicine of Avermectin are dissolved in the DMF fully, then add OP-10 emulsifier and azone, the rear entry that slowly adds that stirs continues to be stirred to homogeneous phase transparent and gets final product.
Example 2
2.0% emamection benaoate, avermectin micro-emulsion
The composition percentage by weight
Emamection benaoate 1.0%
Avermectin 1.0%
Acetone 5.0%
Cyclohexanone 5.0%
The newborn 602# 4.5% of farming
Dodecyl calcium benzoate 2.5%
Deionized water 81.0%
The preparation method is with example 1.
Example 3
7% emamection benaoate, avermectin micro-emulsion
The composition percentage by weight
Emamection benaoate 3.0%
Avermectin 4.0%
DMF 10.0%
1-METHYLPYRROLIDONE 8.0%
The newborn 1602# 5.0% of farming
The newborn 400# 2.0% of farming
Dodecyl calcium benzoate 3.5%
Deionized water 64.5%
The preparation method is with example 1.
The physicochemical property of the microemulsion of preparation is as follows:
Outward appearance is faint yellow to the transparent homogeneous liquid of brown color
Transparency temperature scope :-5 ℃-65 ℃
Ageing stability: shelf stability is qualified under the normal temperature
Low-temperature stability :-5 ℃ store 14 days not stratified, not muddy, non-crystallizable
Heat storage stability: qualified
Stability of emulsion (20 times): qualified
Advantage of the present invention:
1, both composite rear obvious synergy and enlarged control spectrum.Measured the virulence of emamection benaoate, both built agents of Avermectin as the examination worm take diamond-back moth (Plutellaxylostellar) 3 instar larvaes, the rear synergy that is mixed of emamection benaoate and Avermectin is remarkable.Its co-toxicity coefficient is compared with single dose between 335 to 550, and this complex preparation has obviously improved killing rate.Emamection benaoate is to the lepidoptera pest super-high-efficient, Avermectin is excellent to Homoptera and mite class preventive effect, how these several insects, evil mite betide on vegetables and the crop simultaneously, so the two composite will evil in the time of obtaining in the control Vegetable area insect pest mite is applied greatly.
2, make formulation with microemulsion, namely take water as matrix, aboundresources is inexpensive, and product cost is low, and packing easily.
3, flash-point is high, does not fire not quick-friedly, produces, storing and use safety.
4, consumption of organic solvent reduces more than the 50%-90%, and environmental pollution is little, and the producer and user's murder by poisoning is greatly alleviated, and is conducive to the improvement of eco-environmental quality.
5, emulsion particle is ultra tiny, and plant and insect cell are had good permeability, and absorption ratio is high, so low dosage just better drug effect can occur.
Claims (5)
1. a desinsection, miticide composition, it is characterized in that: its constituent and weight percentage amount are as follows: take emamection benaoate and Avermectin as Main Ingredients and Appearance, add surfactant, infiltration synergist, mixed organic solvents and water are formulated, and wherein: emamection benaoate is 0.1-10%, and Avermectin is 0.1-10%, the consumption of surfactant is 5-30%, infiltration synergist 0.5-15%, organic solvent 5%-40%, water supplies 100%.
2. a kind of desinsection according to claim 1, miticide composition, it is characterized in that described surfactant is selected from alkylphenol polyoxyethylene series, fatty alcohol-polyoxyethylene ether is serial, agricultural emulsifier NO．600 is serial, castor oil polyoxyethylene ether series, phenethyl phenol polyethenoxy ether formaldehyde condensation products, the compound of one or more in the dodecyl benzene sulfonate.
3. a kind of desinsection according to claim 1, miticide composition, it is characterized in that described infiltration synergist is selected from silicone based bleeding agent, azone, thiophene ketone, alkylbenzenesulfonate, aliphatic alcohol sulfate, fast penetrant T, the compound of one or more in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, tertiary amine oxide, the dodecyl dimethyl benzyl ammonium chloride.
4. a kind of desinsection according to claim 1, miticide composition, it is characterized in that described organic solvent is selected from any or the combination more than two kinds and two kinds in benzene,toluene,xylene, methyl alcohol, ethanol, acetone, DMF, cyclohexanone, dimethyl sulfoxide (DMSO), the 1-METHYLPYRROLIDONE.
5. a kind of desinsection according to claim 1, miticide composition is characterized in that in running water, underground water, deionized water, distilled water any of described wet concentration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710165315 CN101422155B (en) | 2007-10-29 | 2007-10-29 | Insecticide and miticide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710165315 CN101422155B (en) | 2007-10-29 | 2007-10-29 | Insecticide and miticide composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101422155A CN101422155A (en) | 2009-05-06 |
| CN101422155B true CN101422155B (en) | 2013-02-27 |
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|---|---|---|---|
| CN 200710165315 Active CN101422155B (en) | 2007-10-29 | 2007-10-29 | Insecticide and miticide composition |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101366387B (en) * | 2008-09-18 | 2010-09-29 | 陈章艳 | Agricultural chemical composition |
| CN103719116B (en) * | 2014-01-13 | 2015-10-28 | 中国热带农业科学院环境与植物保护研究所 | A kind of biogenic Mixed Pharmacy preventing and treating banana flowers thrips |
| CN109452269B (en) * | 2018-12-21 | 2021-06-01 | 硅羿科技（上海）有限公司 | Abamectin emulsion preparation and preparation method and application thereof |
| CN111568886B (en) * | 2020-06-16 | 2022-09-13 | 福建师范大学福清分校 | Chinese and western medicine compound film coating agent for treating bovine acariasis and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1359619A (en) * | 2000-12-21 | 2002-07-24 | 温沛宏 | Insecticidal microemulsion composition of emaricin |
| CN1911018A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. fluacrypyrim and vermectins or methyl amino Avermectins benzoate, and its application Avermectins |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1359619A (en) * | 2000-12-21 | 2002-07-24 | 温沛宏 | Insecticidal microemulsion composition of emaricin |
| CN1911018A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. fluacrypyrim and vermectins or methyl amino Avermectins benzoate, and its application Avermectins |
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| CN101422155A (en) | 2009-05-06 |
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Owner name: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG CHAMBROAD HOLDING CO., LTD. Effective date: 20141203 |
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Effective date of registration: 20141203 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Beijing Bo agricultural Polytron Technologies Inc Patentee after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Patentee before: SHANDONG CHAMBROAD HOLDING Co.,Ltd. |
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| CP03 | Change of name, title or address |
Address after: 256500 Boxing County Economic and Technological Development Zone, Binzhou City, Shandong Province Patentee after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Jingbo Agrochemical Technology Co., Ltd. of Jingbo Industrial Park, Chenhu Town, Boxing County, Binzhou City, Shandong Province Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |
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| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee after: Shandong Jingbo Agrochemical Technology Co.,Ltd. Address before: 256500 Boxing County Economic and Technological Development Zone, Binzhou City, Shandong Province Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |
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| CP03 | Change of name, title or address |