CN1359619A - Insecticidal microemulsion composition of emaricin - Google Patents
Insecticidal microemulsion composition of emaricin Download PDFInfo
- Publication number
- CN1359619A CN1359619A CN 00135817 CN00135817A CN1359619A CN 1359619 A CN1359619 A CN 1359619A CN 00135817 CN00135817 CN 00135817 CN 00135817 A CN00135817 A CN 00135817A CN 1359619 A CN1359619 A CN 1359619A
- Authority
- CN
- China
- Prior art keywords
- water
- ether
- emaricin
- microemulsion
- emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 title claims description 12
- 230000000749 insecticidal effect Effects 0.000 title abstract description 3
- -1 methylamino abamectin Chemical compound 0.000 claims abstract description 19
- 239000005660 Abamectin Substances 0.000 claims abstract description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- 239000003995 emulsifying agent Substances 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 8
- 239000006184 cosolvent Substances 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 239000007859 condensation product Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 4
- 241000607479 Yersinia pestis Species 0.000 claims description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 3
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 claims description 2
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- INKDAKMSOSCDGL-UHFFFAOYSA-N [O].OC1=CC=CC=C1 Chemical compound [O].OC1=CC=CC=C1 INKDAKMSOSCDGL-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000005894 Emamectin Substances 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 claims 1
- 239000008367 deionised water Substances 0.000 claims 1
- 229910021641 deionized water Inorganic materials 0.000 claims 1
- 239000012153 distilled water Substances 0.000 claims 1
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims 1
- 239000000575 pesticide Substances 0.000 claims 1
- 229950008167 abamectin Drugs 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 241000255967 Helicoverpa zea Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001325860 Lacanobia oleracea Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000000035 biogenic effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 125000002243 cyclohexanonyl group Chemical class *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A insecticidal microemulsion is disclosed, whose main component is methylamino abamectin (and its salts).
Description
The present invention relates to a kind of agricultural plant protection Chemical composition that, is a kind of desinsection micro-emulsifier composition specifically.
Emaricin (methylamino avermectin) is 16 Yuans macrolide antibiotics Avermectin B
1Structure modified outcome, chemical name is 4 "-deoxidation-4 "-methylamino avermectin B
1Report first in early eighties by U.S. Merck company, domestic existing production at present and registration, this medicine overcome Avermectin to common lepidoptera pest as tomato moth, beet armyworm, the shortcoming that effects such as cotton bollworm are relatively poor, its specific activity Avermectin to this class pest generally improves 1-2 the order of magnitude, and only be the sixth of Avermectin to the toxicity of higher mammal, thereby be a kind of high activity, the public nuisance-free agricultural chemicals that Environmental compatibility is good, just be based on above situation, registration kind content is generally between the 0.1-1% at present, belongs to efficient low content preparation, and formulation is then based on missible oil at present, wherein consumption of organic solvent is up to 80-90%, the major defect of such preparation is: (1) consumes a large amount of organic solvents, increases cost, causes waste; (2) be easy to volatilization and burning, store and transport dangerous; (3) after organic solvent is spilled into the field with agricultural chemicals, enter river, air, contaminated environment etc. see above all points, the agreement that minority developed country even proposed forbids, therefore exploitation reduce or the novel form of useful organic solvent extremely urgent to replace traditional cream preparation;
Microemulsion is a kind of novel liquid formulation of developing in recent years, in preparation, be dispersion medium with water, use no or little organic solvent, many shortcomings of missible oil formulation have been avoided, to water-fast active ingredient, by effects such as dispersion microemulsifieds, by homogenize technology, active ingredient is dispersed in the water, form the thermodynamically stable dispersion of oil-in-water type, because disperse phase (active ingredient) particle microemulsified (general particle diameter≤0.1 μ), so appearance transparent, physics, chemical property is stable, strong to plant and insect tissue cell permeability, the preventive effect height.
The present invention combines this biogenic environment friendly agricultural of emaricin just with this nuisanceless green formulation of microemulsion, thereby makes it to become a real green non-pollution high-efficiency preparation.
The present invention realizes like this, with emaricin at cosolvent, under the effect of emulsifier, be dispersed in the water by homogenize technology, form the emaricin microemulsion of appearance transparent, the percentage by weight of each component is as follows: emaricin 0.1-10% cosolvent 5-30% emulsifier 5-30% water surplus
Described emaricin has another name called methylamino avermectin (and its esters), and chemical name is 4 "-deoxidation-4 "-methylamino avermectin B1 (and its esters).
Described cosolvent is methyl alcohol, ethanol, isopropyl alcohol, n-butanol, n-amyl alcohol, acetone, cyclohexanone, dimethyl formamide etc., and cosolvent is used for dissolving emaricin and uses.
Described emulsifier is styryl phenol APEO, phenethyl phenol polyethenoxy polyethenoxy ether, alkylphenol polyoxyethylene, alkyl phenol oxygen vinethene formaldehyde condensation products, phenethyl phenol polyethenoxy ether formaldehyde condensation products.Castor oil polyoxyethylene ether, benzylphenol polyoxyethylene groups polyoxypropylene base ether, phosphide ester class, a kind of of calcium dodecyl benzene sulfonate also can be two or more mixtures.The effect of emulsifier is disperse phase to be uniformly dispersed and stable in aqueous medium.
The water surplus meaning is that water is mended to 100%
In order to make emaricin can as far as possible effectively bring into play its effect, can add synergist in right amount, as piperonyl butoxide, Octachlorodipropyl Ether or azone, or synergy phosphorus, consumption is≤10%.
Needs according to the prescription physicochemical property also can add stabilizing agent in the microemulsion, as ethylene glycol or polyethylene glycol, polyvinyl alcohol, sorbierite and its esters, benzoate, urea, glycerine etc., consumption≤10%.Function of stabilizer is to strengthen the physics and the chemical stability of microemulsion.
Process of the present invention is as follows: the former powder of emaricin is dissolved in the cosolvent, drop into emulsifier, drop into synergist and stabilizing agent again, stir, can heat when needing, then dispersion medium water is added wherein, and mix homogenizing strongly, can heat when needing, after the homogenizing, room temperature to be returned to.It is faint yellow to water white microemulsion can arriving and obtain outward appearance.
Non-limiting examples is described below:
For sake of convenience, with code name of following raw material regulation.A: emaricin, active constituent content on average get 90%.R: be emulsifier, R
1Be styryl phenol APEO; R
2Be phenethyl phenol polyethenoxy polyethenoxy ether; R
3Be alkylphenol polyoxyethylene; R
4Be the alkyl polyoxyethylene ether formaldehyde condensation products; R
5Be phenethyl phenol polyethenoxy ether first capital condensation product; R
6Be castor oil polyoxyethylene ether; R
7Be benzylphenol polyoxyethylene groups polyoxypropylene base ether; R
8Be phosphorus phenolic ester class; R
9Be calcium dodecyl benzene sulfonate 1. 0.2% emaricin microemulsions:
Get 2.15 kilograms of A,, add R then with 5 kilograms of methyl alcohol and 3 kilograms of acetone solutions
1And R
4100 kilograms of mixing R, 10 kilograms of azones are heated to 879.85 kg of water that will measure after 40-50 ℃ and the stirring and dissolving and add wherein, strong agitation is even, keeps 15-20 minute, returns to room temperature then, obtains 1000 kilogram of 0.2% emaricin microemulsion.
2. 1% emaricin microemulsion
Get 11.15 kilograms of A, after dissolving with 20 kilograms of dimethyl formamides and 10 kilograms of cyclohexanones, add R
2And R
9200 kilograms of blended emulsifiers, 40 kilograms in synergy phosphorus is heated to about 50 ℃, after stirring and dissolving is complete, 718.85 kg of water that measure are added wherein the strong agitation homogenizing, kept 15-20 minute, and returned to room temperature then, obtain 1000 kilogram of 1% emaricin microemulsion.
3. 2% emaricin microemulsion:
Get 22.3 kilograms of A,, add R with 30 kilograms of acetone and 50 kilograms of dimethyl formamide dissolvings
6And R
8And R
9Mix 150 kilograms of R, add 40 kilograms of Octachlorodipropyl Ethers, be heated to about 50 ℃, after stirring and dissolving is complete, 707.7 kg of water that measure are added wherein the strong agitation homogenizing, kept 15-20 minute, and returned to room temperature then, can obtain 2% emaricin microemulsion.
Claims (3)
1, a kind of pest killing micro emulsion as disperse phase, under the effect of auxiliary agent, is dispersed in active component in the water through homogenize technology and forms, and it is characterized in that:
(1), the percentage by weight of each component is as follows: methylamino avermectin (and its esters) 0.01-10% cosolvent 5-30% emulsifier 5-30% water surplus
(2), described methylamino avermectin (and its esters), to refer to chemical name be 4 " deoxidation-4 " methylamino avermitilis strain B1 and hydrochloride or benzoate, Chinese common name emaricin, English general Emamectin by name.
(3), described cosolvent is a kind of in methyl alcohol, ethanol, isopropyl alcohol, n-butanol, n-amyl alcohol, acetone, cyclohexanone, the dimethyl formamide or composition more than third kind.
(4), described emulsifier is styryl phenol APEO, phenethyl phenol polyethenoxy polyethenoxy ether, alkylphenol polyoxyethylene, alkyl phenol oxygen vinethene formaldehyde condensation products, phenethyl phenol polyethenoxy ether formaldehyde condensation products.Castor oil polyoxyethylene ether, one or more blended emulsifiers of benzylphenol polyoxyethylene groups polyoxypropylene base ether, phosphide ester class, calcium dodecyl benzene sulfonate.
(5), described water is meant wherein a kind of of running water, underground water, deionized water, distilled water.
2. according to the described pest killing micro emulsion of claim, it is characterized in that, contain synergist piperonyl butoxide or Octachlorodipropyl Ether or azone or synergy phosphorus in the microemulsion, consumption≤15%;
3. a kind of series pesticide microemulsion according to claim 1 and 2, it is characterized in that containing in the microemulsion stabilizing agent ethylene glycol, polyethylene glycol, polyvinyl alcohol, urea or glycerine, benzoate one or more mixture wherein, consumption≤10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00135817 CN1188036C (en) | 2000-12-21 | 2000-12-21 | Insecticidal microemulsion composition of emaricin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00135817 CN1188036C (en) | 2000-12-21 | 2000-12-21 | Insecticidal microemulsion composition of emaricin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1359619A true CN1359619A (en) | 2002-07-24 |
| CN1188036C CN1188036C (en) | 2005-02-09 |
Family
ID=4596889
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00135817 Expired - Fee Related CN1188036C (en) | 2000-12-21 | 2000-12-21 | Insecticidal microemulsion composition of emaricin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1188036C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101002560B (en) * | 2006-01-17 | 2010-08-18 | 上海农乐生物制品股份有限公司 | Aqueous emulsion containing methyl amino abamectin benzoate, and its preparing method |
| CN102187868A (en) * | 2010-03-03 | 2011-09-21 | 中农立华生物科技股份有限公司 | Flubendiamide and emamectin benzoate blended emulsion and preparation method thereof |
| CN102613214A (en) * | 2008-12-31 | 2012-08-01 | 浙江世佳科技有限公司 | Microemulsion of propylene glycol alginate and emamectin benzoate |
| CN101422155B (en) * | 2007-10-29 | 2013-02-27 | 山东京博控股股份有限公司 | Insecticide and miticide composition |
| CN106417271A (en) * | 2016-08-31 | 2017-02-22 | 周翠华 | Rice leaf roller prevention agent capable of being sprayed by unmanned aerial vehicle |
| CN109010014B (en) * | 2018-08-08 | 2020-09-22 | 武汉中投汉嘉科技有限公司 | Ear acupoint pressing pill and its preparing method |
-
2000
- 2000-12-21 CN CN 00135817 patent/CN1188036C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101002560B (en) * | 2006-01-17 | 2010-08-18 | 上海农乐生物制品股份有限公司 | Aqueous emulsion containing methyl amino abamectin benzoate, and its preparing method |
| CN101422155B (en) * | 2007-10-29 | 2013-02-27 | 山东京博控股股份有限公司 | Insecticide and miticide composition |
| CN102613214A (en) * | 2008-12-31 | 2012-08-01 | 浙江世佳科技有限公司 | Microemulsion of propylene glycol alginate and emamectin benzoate |
| CN102187868A (en) * | 2010-03-03 | 2011-09-21 | 中农立华生物科技股份有限公司 | Flubendiamide and emamectin benzoate blended emulsion and preparation method thereof |
| CN102187868B (en) * | 2010-03-03 | 2014-07-02 | 中农立华生物科技股份有限公司 | Flubendiamide and emamectin benzoate blended emulsion and preparation method thereof |
| CN106417271A (en) * | 2016-08-31 | 2017-02-22 | 周翠华 | Rice leaf roller prevention agent capable of being sprayed by unmanned aerial vehicle |
| CN109010014B (en) * | 2018-08-08 | 2020-09-22 | 武汉中投汉嘉科技有限公司 | Ear acupoint pressing pill and its preparing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1188036C (en) | 2005-02-09 |
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Owner name: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG CHAMBROAD HOLDING CO., LTD. Effective date: 20141210 |
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Effective date of registration: 20141210 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Beijing Bo agricultural Polytron Technologies Inc Patentee after: Jingbo Agrochemicals Technology Co., Ltd. Address before: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Patentee before: Shandong Chambroad Holding Co., Ltd. |
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Address after: 256500 Boxing County Economic Development Zone, Binzhou, Shandong Patentee after: Beijing Agricultural Chemical Technology Co., Ltd. Address before: 256500 Jingbo Agrochemical Technology Co., Ltd. of Jingbo Industrial Park, Chenhu Town, Boxing County, Binzhou City, Shandong Province Patentee before: Jingbo Agrochemicals Technology Co., Ltd. |
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