CN101002560B - Aqueous emulsion containing methyl amino abamectin benzoate, and its preparing method - Google Patents
Aqueous emulsion containing methyl amino abamectin benzoate, and its preparing method Download PDFInfo
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- CN101002560B CN101002560B CN2006100233844A CN200610023384A CN101002560B CN 101002560 B CN101002560 B CN 101002560B CN 2006100233844 A CN2006100233844 A CN 2006100233844A CN 200610023384 A CN200610023384 A CN 200610023384A CN 101002560 B CN101002560 B CN 101002560B
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- China
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- benzoate
- emamectin
- aqueous emulsion
- solvent
- Prior art date
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- 239000000839 emulsion Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 5
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 title abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000002562 thickening agent Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 24
- -1 polyoxyethylene Polymers 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 4
- 230000003020 moisturizing effect Effects 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims 5
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 description 9
- 239000000575 pesticide Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 7
- 238000013019 agitation Methods 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 4
- 231100000053 low toxicity Toxicity 0.000 description 4
- 208000019300 CLIPPERS Diseases 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 208000021930 chronic lymphocytic inflammation with pontine perivascular enhancement responsive to steroids Diseases 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 231100000567 intoxicating Toxicity 0.000 description 1
- 230000002673 intoxicating effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2006100233844A CN101002560B (en) | 2006-01-17 | 2006-01-17 | Aqueous emulsion containing methyl amino abamectin benzoate, and its preparing method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2006100233844A CN101002560B (en) | 2006-01-17 | 2006-01-17 | Aqueous emulsion containing methyl amino abamectin benzoate, and its preparing method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101002560A CN101002560A (en) | 2007-07-25 |
CN101002560B true CN101002560B (en) | 2010-08-18 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006100233844A Active CN101002560B (en) | 2006-01-17 | 2006-01-17 | Aqueous emulsion containing methyl amino abamectin benzoate, and its preparing method |
Country Status (1)
Country | Link |
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CN (1) | CN101002560B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101507438B (en) * | 2009-03-06 | 2012-05-09 | 福建农林大学 | Emamectin-benzoate aqueous emulsion |
CN102187868B (en) * | 2010-03-03 | 2014-07-02 | 中农立华生物科技股份有限公司 | Flubendiamide and emamectin benzoate blended emulsion and preparation method thereof |
CN103563892A (en) * | 2013-10-14 | 2014-02-12 | 广东中迅农科股份有限公司 | Novel water-based preparation formulation of methylamino abamectin benzoate |
CN104738031A (en) * | 2013-12-31 | 2015-07-01 | 汕头市深泰新材料科技发展有限公司 | Abamectin emulsion in water and preparation method thereof |
CN104522015A (en) * | 2015-01-22 | 2015-04-22 | 苏州佳辉化工有限公司 | Compound insecticide containing emamectin benzoate and diafenthiuron |
CN109197882B (en) * | 2018-09-14 | 2021-07-30 | 河北威远生物化工有限公司 | Emamectin benzoate emulsion B2a/B2B and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1194832A (en) * | 1997-03-27 | 1998-10-07 | 王玉万 | Antiparasitic medicine containing avermectin/ivermectin for animals |
CN1359619A (en) * | 2000-12-21 | 2002-07-24 | 温沛宏 | Insecticidal microemulsion composition of emaricin |
CN1448052A (en) * | 2002-04-04 | 2003-10-15 | 王正权 | Methyl-abamectin benzoate microemulsion and prep. thereof |
CN1478391A (en) * | 2003-07-08 | 2004-03-03 | 云大科技股份有限公司 | Pirate mixture pesticide preparation and its preparation method |
-
2006
- 2006-01-17 CN CN2006100233844A patent/CN101002560B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1194832A (en) * | 1997-03-27 | 1998-10-07 | 王玉万 | Antiparasitic medicine containing avermectin/ivermectin for animals |
CN1359619A (en) * | 2000-12-21 | 2002-07-24 | 温沛宏 | Insecticidal microemulsion composition of emaricin |
CN1448052A (en) * | 2002-04-04 | 2003-10-15 | 王正权 | Methyl-abamectin benzoate microemulsion and prep. thereof |
CN1478391A (en) * | 2003-07-08 | 2004-03-03 | 云大科技股份有限公司 | Pirate mixture pesticide preparation and its preparation method |
Non-Patent Citations (1)
Title |
---|
章淑艳,李春辉.0.5%甲胺基阿维菌素苯甲酸盐水乳剂对鳞翅目害虫的防效研究.河北省科学院学报第22卷 第3期.2005,第22卷(第3期),67-70. * |
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Publication number | Publication date |
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CN101002560A (en) | 2007-07-25 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: Aqueous emulsion containing methyl amino abamectin and benzoate, and its preparing method Effective date of registration: 20190813 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS CO.,LTD. Registration number: Y2019310000006 |
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Date of cancellation: 20201009 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2019310000006 |
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Denomination of invention: Emamectin benzoic acid salt emulsion and its preparation method Effective date of registration: 20201010 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2020310000044 |
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Date of cancellation: 20210929 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2020310000044 |
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Denomination of invention: Emamectin benzoic acid brine emulsion and its preparation method Effective date of registration: 20210930 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2021310000091 |
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Date of cancellation: 20230223 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS CO.,LTD. Registration number: Y2021310000091 |