CN101002569B - Aqueous emulsion of triazophos, and its preparing method - Google Patents
Aqueous emulsion of triazophos, and its preparing method Download PDFInfo
- Publication number
- CN101002569B CN101002569B CN200610023383XA CN200610023383A CN101002569B CN 101002569 B CN101002569 B CN 101002569B CN 200610023383X A CN200610023383X A CN 200610023383XA CN 200610023383 A CN200610023383 A CN 200610023383A CN 101002569 B CN101002569 B CN 101002569B
- Authority
- CN
- China
- Prior art keywords
- weight
- aqueous emulsion
- triazophos
- solvent
- hostathion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000000839 emulsion Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000002562 thickening agent Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 24
- -1 polyoxyethylene Polymers 0.000 claims description 16
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 4
- 230000003020 moisturizing effect Effects 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 description 9
- 239000000575 pesticide Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 7
- 238000013019 agitation Methods 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 4
- 231100000053 low toxicity Toxicity 0.000 description 4
- 208000019300 CLIPPERS Diseases 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 208000021930 chronic lymphocytic inflammation with pontine perivascular enhancement responsive to steroids Diseases 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 241001249129 Scirpophaga incertulas Species 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 231100000567 intoxicating Toxicity 0.000 description 1
- 230000002673 intoxicating effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 1
Images
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Colloid Chemistry (AREA)
Abstract
An aqueous emulsion of triazophos is proportionally prepared from triazophos, solvent, emulsifier, thickening agent, anti-freezing agent, defoaming agent and water through preparing oil phase, preparing water phase and mixing while shearing.
Description
Technical field
The present invention relates to a kind of agricultural chemicals and preparation method thereof, relate in particular to a kind of aqueous emulsion of triazophos of preventing and treating crop pests such as rice-stem borer, paddy stem borer and preparation method thereof.
Background technology
Great changes have taken place in global in recent years agricultural chemicals policy, particularly developed country is very strict to the use restriction of high poison, persistent pesticide, particularly played the whole nation on January 1st, 2007 and forbid that high-toxic pesticide is after using on the agricultural, with increasing, and high malicious type pesticide species will unfeelingly be eliminated under the effect of forbidding order to the demand of the environmental protection type agricultural chemical of efficient, low toxicity, low-residual in the domestic market.Limiting the use of and further forbid the trend that high-toxic pesticide is social development, also is the needs of realizing agricultural sustainable development.At present, China's high-toxic pesticide occupies quite great proportion, accounts for 70%, and the western developed country situation is then opposite, only accounts for about 30%.
Data show, when totally supply exceed demand, low toxicity high-efficiency environment friendly class agricultural chemicals was in the tangible propagation process at agricultural chemicals, therefore, can estimate, and along with the increasing of governability dynamics, this of high-toxic pesticide and environment-protection pesticide disappears those long relations will be more obvious.
Along with improving constantly of people's living standard; people are to the raising of environmental protection consciousness; and the Chinese government is to the attention of ecotope, on the domestic and international market to be fit to controlling crop diseases and insect pests and nuisanceless production needs efficiently, the demand of low toxicity, low-residual, free of contamination environment protection biological agricultural chemicals and chemical pesticide is increasing.And the low toxicity efficient and environment-friendly type agricultural chemicals market demand is supplied less greatly in the market.
For a long time, the pesticide original medicine of every liquid state and the solid-state former medicine of sizable solvability is arranged in organic solvent, no matter be insecticide, miticide, or bactericide or weed killer herbicide etc., all be that the form of making missible oil is used mostly, emulsifiable concentrates for agricultural chemicals is the important formulation of pesticidal preparations always, but owing to contain a large amount of inflammable organic solvents in the missible oil, strict to aspects such as production, storing and uses, as poor management, intoxicating phenomenon takes place or produces poisoning in misoperation easily.Particularly in long-term use, a large amount of organic solvents evaporate in the atmosphere, and environment has been caused serious pollution, and all these problems have caused people's extensive concern.
Summary of the invention
Purpose of the present invention be exactly provide in order to overcome the defective that above-mentioned prior art exists a kind of safe in utilization, the feature of environmental protection good, lower-cost aqueous emulsion of triazophos and preparation method thereof.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of aqueous emulsion of triazophos is characterized in that, it is raw material that this aqueous emulsion adopts the material of following component and weight content:
Hostathion 5%～40%,
Solvent 1%～10%,
Emulsifier 1～20%,
Thickener 0.5%～10%,
Antifreezing agent 0.5%～10%,
Defoamer 0.1%～1%,
Moisturizing to 100%.
Described solvent is selected from one or both the mixture in dimethylbenzene, the toluene.
Described emulsifier is selected from the EO-PO block copolymer.
Described EO-PO block copolymer is selected from one or more the mixture in polyoxyethylene alkylphenol, polyoxyethylene alkaryl phenol, polyoxyethylene fatty alcohol, the sorbitol ester.
Described thickener is selected from polyvinyl alcohol or xanthans.
Described antifreezing agent is selected from one or both the mixture in ethylene glycol, the propane diols.
Described defoamer is selected from organosilicon.
A kind of preparation method of above-mentioned aqueous emulsion of triazophos is characterized in that, this method comprises following processing step:
(1) makes oil phase
Hostathion 5～40 weight % add with solvent 1～10 weight % and are in the same place, and make Hostathion be dissolved in fully in the solvent, become even oil phase;
(2) make water
Emulsifier 1～20 weight %, thickener 0.5～10 weight %, antifreezing agent 0.5～10 weight %, defoamer 0.1～1 weight % and moisturizing to 100 weight % be added in be mixed together, become the homogeneous water;
(3) shear
Under high-speed stirred, water is added oil phase, form finely disseminated aqueous emulsion.
Described speed of agitator is 1000～20000 rev/mins, and mixing time is 3～60 minutes.
Aqueous emulsion of triazophos of the present invention is the novel form agricultural chemicals that Shanghai Nongle Biological Product Co., Ltd. develops, because aqueous emulsion of triazophos does not contain poisonous inflammable benzene class equal solvent, there is not the danger of catching fire, no unpleasant poisonous smell, little to eye irritation, reduced pollution, improved safety greatly production, storing and user to environment.On the other hand, aqueous emulsion of triazophos is a matrix with cheap water, greatly reduces to use farming originally.Therefore form after the industrialization, not only economic benefit is obvious, and helps promoting the development of high-new environment friendly agricultural technology, to promoting environmental protection, has obvious social, is the Research on Sustainable Development direction.
Description of drawings
Fig. 1 is a process chart of the present invention.
Embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
Composition of raw materials:
Hostathion 5kg, solvent xylene or toluene 1kg, emulsifier polyoxyethylene alkyl phenol 1kg, thickener polyvinyl alcohol or xanthans 0.5kg, antifreeze glycol or propane diols 0.5kg, defoamer organosilicon 0.1kg, excess water 91.9kg.
The preparation method:
A. the former medicine of Hostathion is joined in organic solvent dimethylbenzene or the toluene, constantly stir, till Hostathion dissolves fully, standby as oil phase;
B. by above-mentioned prescription emulsifier, thickener, antifreezing agent and defoamer under agitation are added to the water successively, constantly stir, till being dissolved into uniform liquid fully, standby as water;
C. earlier oil phase is joined in the container of clipper, open and stir, under agitation add water then gradually in oil phase, rotating speed is controlled at 1000 rev/mins, stirred 60 minutes, the opaque shape liquid of milky, be aqueous emulsion of triazophos.
Embodiment 2
Composition of raw materials:
Hostathion 20kg, solvent xylene or toluene 5kg, emulsifier polyoxyethylene alkaryl phenol 10kg, thickener polyvinyl alcohol or xanthans 5kg, antifreeze glycol or propane diols 5kg, defoamer organosilicon 0.5kg, excess water 54.5kg.
The preparation method:
A. the former medicine of Hostathion is joined in organic solvent dimethylbenzene or the toluene, constantly stir, till Hostathion dissolves fully, standby as oil phase;
B. by above-mentioned prescription emulsifier, thickener, antifreezing agent and defoamer under agitation are added to the water successively, constantly stir, till being dissolved into uniform liquid fully, standby as water;
C. earlier oil phase is joined in the container of clipper, open and stir, under agitation add water then gradually in oil phase, rotating speed is controlled at 12000 rev/mins, stirred 30 minutes, the opaque shape liquid of milky, be aqueous emulsion of triazophos.
Embodiment 3
Composition of raw materials:
The mixture 15kg of Hostathion 38kg, solvent xylene and toluene 8kg, emulsifier polyoxyethylene fatty alcohol and sorbitol ester, thickener polyvinyl alcohol or xanthans 7kg, antifreeze glycol and propane diols 8kg, defoamer organosilicon 0.8kg, excess water 23.2kg.
The preparation method:
A. the former medicine of Hostathion is joined in organic solvent dimethylbenzene and the toluene, constantly stir, till Hostathion dissolves fully, standby as oil phase;
B. by above-mentioned prescription the former medicine of dimehypo, emulsifier, thickener, antifreezing agent and defoamer under agitation are added to the water successively, constantly stir, till being dissolved into uniform liquid fully, standby as water;
C. earlier oil phase is joined in the container of clipper, open and stir, under agitation add water then gradually in oil phase, rotating speed is controlled at 15000 rev/mins, stirred 8 minutes, the opaque shape liquid of milky, be aqueous emulsion of triazophos.
Claims (3)
1. an aqueous emulsion of triazophos is characterized in that, it is raw material that this aqueous emulsion adopts the material of following component and weight content:
Hostathion 5%～40%,
Solvent 1%～10%,
Emulsifier 1～20%,
Thickener 0.5%～10%,
Antifreezing agent 0.5%～10%,
Defoamer 0.1%～1%,
Moisturizing to 100%;
Described solvent is selected from one or both the mixture in dimethylbenzene, the toluene;
Described emulsifier is selected from the EO-PO block copolymer;
Described EO-PO block copolymer is selected from one or more the mixture in polyoxyethylene alkylphenol, polyoxyethylene alkaryl phenol, polyoxyethylene fatty alcohol, the sorbitol ester;
Described thickener is selected from polyvinyl alcohol or xanthans;
Described antifreezing agent is selected from one or both the mixture in ethylene glycol, the propane diols;
Described defoamer is selected from organosilicon.
2. the preparation method of the described aqueous emulsion of triazophos of claim 1 is characterized in that, this method comprises following processing step:
(1) makes oil phase
Hostathion 5～40 weight % add with solvent 1～10 weight % and are in the same place, and make Hostathion be dissolved in fully in the solvent, become even oil phase;
(2) make water
Emulsifier 1～20 weight %, thickener 0.5～10 weight %, antifreezing agent 0.5～10 weight %, defoamer 0.1～1 weight % and moisturizing to 100 weight % be added in be mixed together, become the homogeneous water;
(3) shear
Under high-speed stirred, water is added oil phase, form finely disseminated aqueous emulsion.
3. the preparation method of aqueous emulsion of triazophos according to claim 2 is characterized in that, described speed of agitator is 1000～20000 rev/mins, and mixing time is 3～60 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610023383XA CN101002569B (en) | 2006-01-17 | 2006-01-17 | Aqueous emulsion of triazophos, and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610023383XA CN101002569B (en) | 2006-01-17 | 2006-01-17 | Aqueous emulsion of triazophos, and its preparing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101002569A CN101002569A (en) | 2007-07-25 |
| CN101002569B true CN101002569B (en) | 2010-08-18 |
Family
ID=38702128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610023383XA Active CN101002569B (en) | 2006-01-17 | 2006-01-17 | Aqueous emulsion of triazophos, and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101002569B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1348696A (en) * | 2001-11-02 | 2002-05-15 | 浙江新农化工有限公司 | Diazinone emulsion and its prepn. |
-
2006
- 2006-01-17 CN CN200610023383XA patent/CN101002569B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1348696A (en) * | 2001-11-02 | 2002-05-15 | 浙江新农化工有限公司 | Diazinone emulsion and its prepn. |
Non-Patent Citations (3)
| Title |
|---|
| 戴权.三唑磷水乳剂的研究与开发.安徽化工 第129期.2004,(第129期),45-46. * |
| 肖乾芬,王晓栋,魏忠波,周芳,高士祥,孙成,王连生.三唑磷农药水解动力学研究.农药第44卷 第8期.2005,第44卷(第8期),356-358. * |
| 陈蔚林,韩谋国,温家钧.绿色农药新剂型的开发.安徽化工 128期.2004,(128期),2-5. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101002569A (en) | 2007-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101002559B (en) | Aqueous emulsion containing abamectin, and its preparing method | |
| CN104365591B (en) | A kind of pesticide synergistic agent, preparation method and application thereof | |
| CN101002566A (en) | High performance aqueous emulsion of cypermethrin, and its preparing method | |
| CN101002560B (en) | Aqueous emulsion containing methyl amino abamectin benzoate, and its preparing method | |
| CN105052931A (en) | Synergistic water emulsion for weeding | |
| CN101558761A (en) | Compound insecticidal aqueous emulsion containing abamectin and chlorpyrifos, and preparation method thereof | |
| CN101513180A (en) | Cyhalofop-butyl aqueous emulsion and preparing method thereof | |
| CN102726414A (en) | Microemulsion containing fomesafen and quizalofop-p-ethyl, and preparation method thereof | |
| CN101406189B (en) | Aqueous emulsion containing chlorfenapyr and preparation method thereof | |
| CN107593758B (en) | The missible oil and its preparation method and application of gamma cyhalothrin and chlorpyrifos mixture | |
| CN101507438A (en) | Emamectin-benzoate aqueous emulsion | |
| CN101002569B (en) | Aqueous emulsion of triazophos, and its preparing method | |
| CN105010367A (en) | Sterilization composition containing copper quinolate and zhongshengmycin | |
| CN101379961A (en) | Lufenuron aqueous emulsion and preparation method thereof | |
| CN101933509A (en) | Methylamino abamectin benzoate micro-emulsion serving as agricultural insecticide and preparation method | |
| CN101647462B (en) | Bifenthrin emulsion in water and preparation method thereof | |
| CN101530089A (en) | Acetamiprid suspending agent and method for preparing same | |
| CN107593696B (en) | Clodinafop-propargyl missible oil of high-efficiency environment friendly and its preparation method and application | |
| CN104255746A (en) | Botanical insecticide composition and preparation method thereof | |
| CN101379965A (en) | Water emulsion sterilization compound and preparation method thereof | |
| CN100431415C (en) | Prepn process of efficient safe and environment friendly herbicide composition | |
| CN101530079A (en) | Aqueous emulsion containing acetochlor | |
| CN101790990B (en) | High-efficiency concentrated abamectin and high-efficiency cypermethrin water emulsion and method for preparing same | |
| CN103355299A (en) | Insecticide composition containing pyridalyl and nereistoxin | |
| CN103125501A (en) | Abamectin-spinosad emulsion in water and preparing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Water emulsion of hostathion and preparation method thereof Effective date of registration: 20190813 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS CO.,LTD. Registration number: Y2019310000006 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20201009 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2019310000006 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Triazophos EW and its preparation method Effective date of registration: 20201010 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2020310000044 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20210929 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2020310000044 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Triazophos water emulsion and its preparation method Effective date of registration: 20210930 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2021310000091 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230223 Granted publication date: 20100818 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS CO.,LTD. Registration number: Y2021310000091 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |