CN101415696B - 制备氧化烯的方法 - Google Patents

制备氧化烯的方法 Download PDF

Info

Publication number
CN101415696B
CN101415696B CN2007800118891A CN200780011889A CN101415696B CN 101415696 B CN101415696 B CN 101415696B CN 2007800118891 A CN2007800118891 A CN 2007800118891A CN 200780011889 A CN200780011889 A CN 200780011889A CN 101415696 B CN101415696 B CN 101415696B
Authority
CN
China
Prior art keywords
reaction system
reaction
zone
minisize reaction
minisize
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2007800118891A
Other languages
English (en)
Chinese (zh)
Other versions
CN101415696A (zh
Inventor
伯恩哈德·古奇
伯恩德·法布里
斯蒂芬·弗兰岑
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cognis IP Management GmbH
Original Assignee
Cognis IP Management GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis IP Management GmbH filed Critical Cognis IP Management GmbH
Publication of CN101415696A publication Critical patent/CN101415696A/zh
Application granted granted Critical
Publication of CN101415696B publication Critical patent/CN101415696B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00783—Laminate assemblies, i.e. the reactor comprising a stack of plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00801—Means to assemble
    • B01J2219/0081—Plurality of modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00824—Ceramic
    • B01J2219/00828—Silicon wafers or plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00831—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00833—Plastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/0086—Dimensions of the flow channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/00862—Dimensions of the reaction cavity itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00867—Microreactors placed in series, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00869—Microreactors placed in parallel, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00889—Mixing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2007800118891A 2006-04-01 2007-03-23 制备氧化烯的方法 Expired - Fee Related CN101415696B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102006015268A DE102006015268A1 (de) 2006-04-01 2006-04-01 Verfahren zur Herstellung von Alkylenoxiden
DE102006015268.9 2006-04-01
PCT/EP2007/002576 WO2007112866A1 (de) 2006-04-01 2007-03-23 Verfahren zur herstellung von alkylenoxiden

Publications (2)

Publication Number Publication Date
CN101415696A CN101415696A (zh) 2009-04-22
CN101415696B true CN101415696B (zh) 2012-08-22

Family

ID=38330712

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007800118891A Expired - Fee Related CN101415696B (zh) 2006-04-01 2007-03-23 制备氧化烯的方法

Country Status (9)

Country Link
US (1) US7943790B2 (https=)
EP (1) EP2001858B1 (https=)
JP (1) JP2009532397A (https=)
KR (1) KR101384935B1 (https=)
CN (1) CN101415696B (https=)
DE (2) DE202006020415U1 (https=)
ES (1) ES2599847T3 (https=)
PL (1) PL2001858T3 (https=)
WO (1) WO2007112866A1 (https=)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007039874B9 (de) * 2007-08-20 2010-12-09 Zylum Beteiligungsgesellschaft Mbh & Co. Patente Ii Kg Verfahren zur Herstellung von Epoxiden durch Oxidation von Olefinen in der homogenen Gasphase
US8933254B2 (en) 2008-07-14 2015-01-13 Basf Se Process for making ethylene oxide
CN102099345A (zh) * 2008-07-14 2011-06-15 万罗赛斯公司 使用微通道工艺技术制造环氧乙烷的方法
US8524927B2 (en) 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
JP5742390B2 (ja) * 2011-03-31 2015-07-01 株式会社Ihi 窒化ガリウム結晶の成長方法
CN107216296B (zh) * 2016-03-22 2020-07-17 中国石油化工股份有限公司 在微通道反应器内制备环氧丙烷的方法
CN112979587B (zh) * 2019-12-12 2022-12-02 中国科学院大连化学物理研究所 一种微通道反应器合成环氧丙烷的方法
EP4368649A1 (en) 2022-11-14 2024-05-15 Cliq Swisstech (The Netherlands) B.V. Continuous processs for the manufacture of urea urethanes

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19741645A1 (de) 1997-09-22 1999-03-25 Bayer Ag Verfahren und Vorrichtung zur Oxidation organischer Verbindungen in flüssiger Phase unter Verwendung peroxidischer Oxidationsmittel
DE10020632A1 (de) 2000-04-27 2001-10-31 Merck Patent Gmbh Verfahren zur Expodierung von Olefinen
DE10042746A1 (de) * 2000-08-31 2002-03-28 Degussa Verfahren und Vorrichtung zum Durchführen von Reaktionen in einem Reaktor mit spaltförmigen Reaktionsräumen
DE10257239B3 (de) 2002-12-04 2004-07-01 INSTITUT FüR ANGEWANDTE CHEMIE BERLIN-ADLERSHOF E.V. Verfahren zur Photooxigenerierung von Olefinen in Mikrostrukturreaktoren
JP2004285001A (ja) 2003-03-24 2004-10-14 Sumitomo Chem Co Ltd 含酸素化合物の製造方法
DE10317451A1 (de) * 2003-04-16 2004-11-18 Degussa Ag Reaktor für heterogen katalysierte Reaktionen
CN101023068B (zh) * 2004-08-12 2013-02-13 万罗赛斯公司 使用微通道工艺技术将乙烯转化成环氧乙烷的方法
DE102004050506A1 (de) * 2004-10-15 2006-04-20 Degussa Ag Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Torsten Berndt et al..Gas-Phase Epoxidation of Propylene and Ethylene.《Ind. Eng. Chem. Res.》.2005,第44卷(第4期),645-650. *

Also Published As

Publication number Publication date
KR101384935B1 (ko) 2014-04-11
WO2007112866A1 (de) 2007-10-11
DE202006020415U1 (de) 2008-07-03
EP2001858B1 (de) 2016-07-27
US7943790B2 (en) 2011-05-17
PL2001858T3 (pl) 2017-03-31
ES2599847T3 (es) 2017-02-03
DE102006015268A1 (de) 2007-10-25
KR20080104345A (ko) 2008-12-02
EP2001858A1 (de) 2008-12-17
JP2009532397A (ja) 2009-09-10
CN101415696A (zh) 2009-04-22
US20090253944A1 (en) 2009-10-08

Similar Documents

Publication Publication Date Title
CN101415696B (zh) 制备氧化烯的方法
CN101479239B (zh) 用于合成选定的有机过氧化物的方法
US7825277B2 (en) Process for the ozonolysis of unsaturated compounds
CN1235894C (zh) 烯烃环氧化的方法
CN103764627B (zh) 在微反应体系中制备硫酸盐和/或磺酸盐的方法
Phimsen et al. Epoxidation of methyl oleate in a TiO2 coated-wall capillary microreactor
Kobayashi et al. Hydrogenation reactions using scCO 2 as a solvent in microchannel reactors
JP2009532397A5 (https=)
CN102361847B (zh) 通过微量反应技术由醛制备脂族羧酸的方法
EP1520853B1 (en) Process for preparation of hydroperoxides
CN101044129A (zh) 氧化烯烃和过氧化物的制备方法、反应器和其用途
CN101555236A (zh) 纳米SiO2材料催化烯烃与H2O2液相高选择性环氧化方法
CN109731598B (zh) 一种钛掺杂的c3n4催化剂及其制备方法和应用
KR20140019294A (ko) 올레핀 에폭시화를 통한 산화 올레핀의 제조 방법
ES2210187T3 (es) Procedimiento para la fabricacion de epoxidos mediante la oxidacion de olefinas.
WO2002088104A1 (en) Process for producing propylene oxide
CN109574898A (zh) 微通道氧化法制备芳香族异丙基过氧化氢化合物的方法
US3475505A (en) Process for the preparation of 1,2-dichlorethane
US20110218349A1 (en) Method for Producing Alkylene Oxide Addition Products
CN103562168A (zh) 异丙苯醇的制备方法和苯酚、丙酮及α-甲基苯乙烯的制备方法
Wróblewska et al. Epoxidation of 1-buten-3-ol under atmospheric pressure over the Ti-Beta catalyst
Nur A Novel Heterogeneous Catalyst Design for Liquid-Liquid and Liquid-Gas Systems
Mazanec et al. Production of Ethylene by Oxidative Dehydrogenation in Microchannel Reactors
JP2005089407A (ja) 有機過酸化物の精製方法
HK1162465A (en) Method for producing aliphatic carboxylic acids from aldehydes by microreaction technology

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120822

Termination date: 20180323