CN101415562B - 聚合物膜图形的制造方法 - Google Patents
聚合物膜图形的制造方法 Download PDFInfo
- Publication number
- CN101415562B CN101415562B CN2007800118177A CN200780011817A CN101415562B CN 101415562 B CN101415562 B CN 101415562B CN 2007800118177 A CN2007800118177 A CN 2007800118177A CN 200780011817 A CN200780011817 A CN 200780011817A CN 101415562 B CN101415562 B CN 101415562B
- Authority
- CN
- China
- Prior art keywords
- image layer
- layer
- base material
- polymer film
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 229920006254 polymer film Polymers 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 230000008569 process Effects 0.000 title abstract description 7
- 239000000853 adhesive Substances 0.000 claims abstract description 36
- 230000001070 adhesive effect Effects 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims description 61
- 239000004014 plasticizer Substances 0.000 claims description 14
- 229920001944 Plastisol Polymers 0.000 claims description 11
- 239000004999 plastisol Substances 0.000 claims description 11
- 239000004821 Contact adhesive Substances 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000004568 cement Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 abstract description 78
- 239000012790 adhesive layer Substances 0.000 abstract description 7
- 238000013461 design Methods 0.000 abstract description 7
- 239000000758 substrate Substances 0.000 abstract description 7
- 238000000151 deposition Methods 0.000 abstract description 2
- 238000004804 winding Methods 0.000 abstract 1
- 239000002585 base Substances 0.000 description 36
- -1 polyethylene Polymers 0.000 description 32
- 239000012071 phase Substances 0.000 description 24
- 239000000976 ink Substances 0.000 description 23
- 229920001577 copolymer Polymers 0.000 description 22
- 229920005989 resin Polymers 0.000 description 22
- 239000011347 resin Substances 0.000 description 22
- 229920000642 polymer Polymers 0.000 description 21
- 239000000123 paper Substances 0.000 description 19
- 239000000049 pigment Substances 0.000 description 19
- 238000000576 coating method Methods 0.000 description 18
- 239000012141 concentrate Substances 0.000 description 17
- 235000008504 concentrate Nutrition 0.000 description 17
- 239000000203 mixture Substances 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 16
- 238000007639 printing Methods 0.000 description 16
- 239000000654 additive Substances 0.000 description 13
- 230000000996 additive effect Effects 0.000 description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
- 229920013665 Ampacet Polymers 0.000 description 11
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 11
- 239000003381 stabilizer Substances 0.000 description 11
- 239000004698 Polyethylene Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 238000001723 curing Methods 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 8
- 239000003822 epoxy resin Substances 0.000 description 8
- 229920001684 low density polyethylene Polymers 0.000 description 8
- 239000004702 low-density polyethylene Substances 0.000 description 8
- 229920000647 polyepoxide Polymers 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 239000004593 Epoxy Substances 0.000 description 6
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 239000004611 light stabiliser Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 238000005266 casting Methods 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 229940117958 vinyl acetate Drugs 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012963 UV stabilizer Substances 0.000 description 3
- 229920005601 base polymer Polymers 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 125000004386 diacrylate group Chemical group 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 238000013007 heat curing Methods 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 125000001841 imino group Chemical group [H]N=* 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 description 2
- FFWSICBKRCICMR-UHFFFAOYSA-N 5-methyl-2-hexanone Chemical compound CC(C)CCC(C)=O FFWSICBKRCICMR-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- 229920003345 Elvax® Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 2
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 229940106691 bisphenol a Drugs 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000007766 curtain coating Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002118 epoxides Chemical class 0.000 description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- GTDHYNXLIKNVTJ-UHFFFAOYSA-N n-(1-hydroxy-2-methylpropan-2-yl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NC(C)(C)CO GTDHYNXLIKNVTJ-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920001083 polybutene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000003847 radiation curing Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229940116351 sebacate Drugs 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid group Chemical group C(CCC(=O)O)(=O)O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- 229920006163 vinyl copolymer Polymers 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OXDXXMDEEFOVHR-CLFAGFIQSA-N (z)-n-[2-[[(z)-octadec-9-enoyl]amino]ethyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCNC(=O)CCCCCCC\C=C/CCCCCCCC OXDXXMDEEFOVHR-CLFAGFIQSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- HXVNBWAKAOHACI-UHFFFAOYSA-N 2,4-dimethyl-3-pentanone Chemical compound CC(C)C(=O)C(C)C HXVNBWAKAOHACI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- OJIBJRXMHVZPLV-UHFFFAOYSA-N 2-methylpropyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(C)C OJIBJRXMHVZPLV-UHFFFAOYSA-N 0.000 description 1
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- ISSPUSZYYOWQJE-UHFFFAOYSA-N Lucidene Natural products C1C=CC(C)(C)CC2CC3=CC=CC=C3OC2(C)CCC2CC3=CC=CC=C3OC21C ISSPUSZYYOWQJE-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001756 Polyvinyl chloride acetate Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000008032 concrete plasticizer Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007607 die coating method Methods 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XJUNRGGMKUAPAP-UHFFFAOYSA-N dioxido(dioxo)molybdenum;lead(2+) Chemical compound [Pb+2].[O-][Mo]([O-])(=O)=O XJUNRGGMKUAPAP-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- BJAJDJDODCWPNS-UHFFFAOYSA-N dotp Chemical compound O=C1N2CCOC2=NC2=C1SC=C2 BJAJDJDODCWPNS-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000001041 dye based ink Substances 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 102000054766 genetic haplotypes Human genes 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical class CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- JTHRRMFZHSDGNJ-UHFFFAOYSA-N piperazine-2,3-dione Chemical compound O=C1NCCNC1=O JTHRRMFZHSDGNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000013464 silicone adhesive Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0081—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/162—Decalcomanias with a transfer layer comprising indicia with definite outlines such as letters and with means facilitating the desired fitting to the permanent base
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/12—Coating on the layer surface on paper layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/4023—Coloured on the layer surface, e.g. ink
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/75—Printability
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
- C09J2301/204—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive coating being discontinuous
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/2486—Intermediate layer is discontinuous or differential with outer strippable or release layer
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Electromagnetism (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
- Moulding By Coating Moulds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
本发明涉及聚合物膜图形的制造方法，其包括提供在其上具有剥离层的连续基材；施加图形文字或图案形状的图像层至剥离层上；沉积粘合剂层至图像层上并且该粘合剂层具有与图像层图形文字或图案相同的形状；固化粘合剂层和图像层；以及将聚合物膜图形缠绕成卷。本发明还涉及聚合物膜图形，其包含具有上表面和下表面的基材；在基材的上表面之上的剥离层；在剥离层之上图形文字或图案形状的图像层；图像层之上的粘合剂层，该粘合剂层具有与图像层图形文字或图案相同的形状。
Description
本申请要求于2006年3月31日提出的美国临时申请第60/788,386号的优先权。该临时申请的全部公开内容通过引用由此并入。
技术领域
本发明涉及可用于字体(或印字，lettering)和自由型图案(free form design)的聚合物膜图形的制造方法，以及形成图形而无需从该聚合物膜裁切图形。
发明背景
这样的图形裁切方法是已知的，其中图像从粘附于压敏粘合剂复合材料的聚合物膜裁切，然后转移至期望的基材。这个技术被用于提供广泛的各种各样的图形应用，包括外部识别标记、字体和图案，以及在卡车、汽车、船舶等上的装饰或商业图形。通常用于这些图形应用的聚合物膜是压延或分散流延(dispersion cast)聚氯乙烯(PVC)单层膜。尽管PVC膜的使用在市场上已经获得成功，但这类膜通常生产昂贵，并且通常导致与字体或图案的裁切后丢弃的膜部分有关的薄膜废料。该切除步骤在本领域中有时被称为“除杂(weeding)”。除杂包括从剥离衬垫剥离不需要的薄膜部分，仅留下代表最终图像的所需部分粘附于剥离衬垫。
因此，期望提供一种消除了与宽卷材涂布(web coating)有关的废料膜的聚合物膜图形制造方法。还期望提供一种从表面应用中消除图形的后续裁切的聚合物膜图像形成方法。
发明概述
在一个实施方式中，本发明涉及聚合物膜图形的制造方法， 其包括：提供连续基材，其具有第一和第二表面，且在所述第一表面上具有第一剥离层；将图形文字或图案(graphic letter or design)形状的图像层应用于所述第一剥离层上；在所述图像层上沉积粘合剂层，所述粘合剂层具有与所述图像层图形文字或图案相同的形状；以及固化所述粘合剂层和图像层。所述聚合物膜图形可以被缠绕成卷。
在另一个实施方式中，本发明涉及聚合物膜图形的制造方法，其包括：提供连续基质，其具有第一表面和第二表面以及在所述第一表面上具有第一粘合剂层；在所述第一粘合剂层上印刷图形文字或图案形状的图像层；在所述图像层上沉积第二粘合层，所述第二粘合层具有与所述图像层图形文字或图案相同的形状；以及固化所述第二粘合层和图像层。
在进一步的实施方式中，本发明涉及聚合物膜图形，其包括具有上表面和下表面的基材；至少在所述基材上表面之上的剥离层；在所述剥离层之上的图形文字或图案形状的图像层；以及在所述图像层之上、具有与所述图像层图形文字或图案相同形状的粘合剂层。所述聚合物膜图形可以进一步包括在所述基材的下表面上的第二剥离层。
附图说明
图1是具体形式的、体现本发明的薄膜的的侧视图的示意性图解。
图2是本发明的可选实施方式的侧视图的示意性图解。
图3是本发明的进一步的实施方式的侧视图的示意性图解。
图4是材料输送的侧视图的示意性图解，所述材料用于形成所述图像层以制造本发明的聚合物膜图形。
图5是用于制造本发明的聚合物膜图形的分配方法的装置之图示。
图6是可选实施方式的示意性图解，其中聚合物膜图形被制备在粘合剂涂布的基材上。
图7是可选实施方式的示意性图解，其中剥离衬垫被层压于所述聚合物膜图形。
发明详述
本发明涉及图形文字和自由型图案，其从聚合物膜形成而无需裁切字体或图案。当提及一层或第一层相对于另一层或第二层的关系时，术语“在
之上”及其同类术语，如“在
之上的”和类似术语，是指第一层部分或完全覆盖在第二层之上这一事实。术语“在
之下”及其同类术语，如“在之下的”和类似术语，具有相似的意思，只是第一层部分或完全位于第二层之下，而不是第二层之上。
当提及所述图形的一个或多个层时，术语“透明”指的是可以透过该层或这些层看见油墨层或印刷层(一层或多层)。
参考附图，图解说明本发明的图形文字和图案。图1是根据本发明制造的图形1的侧视图的示意性图解。图形1包括具有上表面12和下表面14的基材或铸片(casting sheet)10。在基材10的上表面12之上的是第一剥离层20。图形文字或图案形状的图像层30在基材10上的第一剥离层20之上。具有上表面45和下表面48的粘合剂层40在图像层30之上，并且其具有与图像层30的图形文字或图案相同的形状。
图像层在基质或铸片10上形成，所述基质或铸片10可以包括纸、聚合物膜或它们的组合。由于纸基材可应用的多种应用，纸基材是有用的。纸也相对低廉，且具有期望的性质，如防粘连、抗静电、尺寸稳定性，并且潜在地可被回收。任何类型的具有足够拉伸强度的、可在传统纸涂布和处理设备中处理的纸，均可被用作基材。因此，取决于最终用途和具体的个人偏好，任何类型的纸可以被使用。在可以被使用的纸的类型中包括在内的是白土涂布纸、玻璃纸、聚合物涂布纸、麻纸、以及以诸如苏打法、亚硫酸盐法或硫酸盐(牛皮纸)法，中性硫化物蒸煮法，氯碱法，硝酸法，半化学法等方法制备的类似纤维素材料。虽然任何重量的纸都可以被用作基材，但是重量在每令约30至约120磅的纸是有用的，并且重量范围在每令约60至约100磅的纸是目前优选的。如此处所使用，术语“令”等于3000平方英尺。
可选地，基材10也可以是聚合物膜，并且聚合物膜的例子包括聚烯烃、聚酯、PET等。聚烯烃膜可以包含每分子具有2至约12个碳原子的单烯烃的聚合物和共聚物，并且在一个实施方式中为每分 子2至约8个碳原子，以及在一个实施方式中为每分子2至约4个碳原子。这类均聚物的例子包括聚乙烯、聚丙烯、聚1-丁烯等。上文定义中的共聚物的例子包括乙烯和按重量计约1％至约10％的乙烯或1-丁烯等的共聚物。由共聚物的掺合物或共聚物与均聚物的掺合物制备的膜也是有用的。膜可以以单层或多层被挤出。在一个实施方式中，基材10是聚丙烯、聚乙烯、聚丙烯酸酯或聚缩醛聚合物和共聚物、或它们的组合的自然剥离低表面能膜。这些膜的表面能将在约10达因/厘米至约30达因/厘米的范围内。
可以被用作基材10的另一类材料是多涂布牛皮纸衬垫，其基本上由牛皮纸衬垫组成，所述牛皮纸衬垫在任一面或两面用聚合物涂料涂布。所述聚合物涂料，其可以由高、中或低密度聚乙烯、聚丙烯、聚酯和其它类似聚合物膜组成，被涂布在基材表面，以增加衬垫的强度和/或尺寸稳定性。这些类型的衬垫的重量范围是每令约30至约100磅，其中每令约94至约100磅代表典型的范围。总体来说，最终的衬垫由10％至40％的聚合物和60％至90％的纸组成。对于两面涂布，聚合物的量在纸的顶面和底面之间大致均分。
在一个实施方式中，在基材10的上表面12上的是剥离层20。剥离层20的组成可以是在本领域中已知的任何剥离涂层组成。硅氧烷剥离涂层组合物是优选的，并且在本领域中已知的任何硅氧烷剥离涂层组合物均可使用。硅氧烷剥离涂层的主要成分是聚硅氧烷，以及更通常是聚二甲基硅氧烷。所用的硅氧烷剥离涂层组合物可以被室温固化、热固化、或辐射固化。一般来说，室温和热可固化的组合物包括至少一种聚硅氧烷和至少一种用于这类聚硅氧烷(一种或多种)的催化剂(或固化剂)。这类组合物还可以包括至少一种固化加速剂和/或粘合性促进剂。如同本领域中已知的，一些材料具有发挥两种功能的能力，即，作为固化加速剂发挥作用以增加速率、降低固化温度等，并且还作为粘合性促进剂发挥作用以改善硅氧烷组分与基材的粘结的能力。在合适的情况下应用这类双功能添加剂在本发明的范围之内。
应用已知的技术，剥离涂层组合物被应用于基材10。这些技术包括，例如，凹版印刷、反转凹印、间接凹印、辊式涂布、涂刷法、辊衬刮刀辊涂、计量杆(metering rod)、逆转辊涂布、刮刀、浸渍、模压涂布(die coating)、喷雾帘式涂布(spraying curtain coating)、和其它类似技术。在一个实施方式中，所得到的剥离涂层的厚度或尺寸的范围是约0.254至约50.8mm，并且在一个实施方式中为约0.508mm至约1.27mm。
在一个实施方式中，基材10在上表面12上具有第一剥离层20，在下表面14上具有第二剥离层。滚压或叠加图形后，粘合剂层40的上表面45与第二剥离层相接触。
如图2所示，在一个实施方式中，当图形1被叠加或另外自卷时，本发明的聚合物图形1可以任选地包含载体50，其为剥离涂布衬垫，具有与粘合剂层40的否则暴露的上表面45相接触的一面(剥离涂布面)。载体50用于在制备、处理、储存、运输图形1的过程中保护粘合剂层40的上表面45。载体50在将图形1定位并粘附于表面之前被从图形1除去。剥离涂布衬垫50可包括用剥离组合物涂布的纸基片、聚合物膜或它们的组合。这类材料参考基材10进行描述。
图像层30以字母或自由型图案的形状形成，并应用于剥离层20上。在一个实施方式中，图像层30包含增塑溶胶或有机溶胶。术语增塑溶胶或有机溶胶一般是指细粒塑料粉末或颗粒在软化剂中的分散液，软化剂在加热至更高温度时硬化或胶凝。被应用于基材10的增塑溶胶制剂包括树脂、增塑剂，以及任选地包括活化剂/稳定剂、减粘剂、颜料和填料。塑料粉末或颗粒由细粒聚合物和共聚物组成，包括氯乙烯聚合物、聚氯乙烯-醋酸乙烯酯共聚物、丙烯酸酯聚合物和共聚物例如聚甲基丙烯酸甲酯(PMMA)和聚甲基丙烯酸烷基酯(PAMA)；聚烯烃例如聚乙烯，包括高密度聚乙烯、低密度聚乙烯、线型低密度聚乙烯和线型超低密度聚乙烯，聚丙烯和聚丁烯；聚酯；聚碳酸酯；聚丙烯腈；丁二烯-苯乙烯聚合物；聚酰胺；乙烯-乙酸乙烯酯共聚物；处理的和未处理的聚对苯二甲酸乙二酯；聚苯乙烯；乙烯系共聚物；聚乙酸乙烯酯；烯烃共聚物，例如乙烯/甲基丙烯酸酯共聚物、乙烯/乙酸乙烯酯共聚物；丙烯腈-丁二烯-苯乙烯共聚物；乙烯/丙烯共聚物；丙烯酸聚合物和共聚物；聚氨酯；以及上述的组合。可以使用的氯乙烯聚合物是通过氯乙烯在另一种可共聚的乙烯系化合物存在或不存在的情况下聚合而获得的树脂性产物。术语“氯乙烯树脂”包括氯乙烯 均聚物以及共聚物，例如在氯乙烯和至少一种其它可共聚的乙烯基单体——例如乙酸乙烯酯、丙酸乙烯酯、丁酸乙烯酯、亚乙烯基二氯、苯乙烯、甲基丙烯酸甲酯等——之间形成的那些。在一个实施方式中，增塑溶胶包含PVC树脂。
用于制造聚氯乙烯增塑溶胶的增塑剂是本领域中熟知的并且是商业可得的。典型的增塑剂包括邻苯二甲酸二(2-乙基己基)酯、邻苯二甲酸二(2-乙基-4-甲基戊基)酯、邻苯二甲酸二辛酯、邻苯二甲酸二异癸酯、癸二酸二(2-乙基己基)酯、壬二酸二(2-乙基己基)酯、单体型环氧(2-乙基-己基环氧树脂酸酯)、三甘醇二辛酸酯、柠檬酸乙酰基三丁酯、2，2，4-三甲基戊烷-1，3-二醇二异丁酸酯、新戊二醇和己二酸的聚酯(M.W.＝1,200-1,300)、环氧化豆油(分子量(M.W.)约1,000)、部分氢化三联苯和棕榈酸异辛酯的高沸点(约200℃以上)液体混合物、邻苯二甲酸二辛酯、含具有7至11个碳原子的醇部分的混合邻苯二甲酸酯、邻苯二甲酸二异壬酯、邻苯二甲酸二异辛酯、对苯二甲酸二辛酯、基于异构壬醇的混合邻苯二甲酸酯、含具有6至12个碳原子的醇部分的混合邻苯二甲酸酯、偏苯三酸三辛酯、邻苯二甲酸丁苄酯以及高分子型增塑剂例如用2，2，4-三甲基-1，3-戊二醇的单异丁酸酯封端的聚(2，2，4-三甲基-1，3-戊二醇己二酸酯)和以2-乙基己醇封端的聚(2，2-二甲基-1，3-丙二醇己二酸酯)等等。成本考虑因素以及该系统所需的粘度和粘合性影响具体的增塑剂选择。在较低的粘度是期望的而无需另外的增塑剂的情况下，如用于喷涂应用，少量的稀释剂(5-15％)如甲苯、二甲苯、甲基·异戊基酮、二异丁基甲酮、甲基·乙基酮等可被加入以形成喷涂型有机溶胶。
如果需要，可以使用上述示出的增塑剂的混合物。通常，增塑剂在增塑溶胶中以每百份氯乙烯树脂约20至约130份(pph)的量存在。通过适合的工艺，如成分的压延、混合或捏和，增塑剂可在含有或不含有其它添加剂的情况下被掺入单独的氯乙烯树脂中。理想的步骤包括形成乙烯基树脂分散液，其可以被浇铸成膜或较厚体，然后被加热形成增塑树脂均一体。这类分散液是氯乙烯树脂颗粒在非水液体中的悬浮液，所述非水液体包括增塑剂，其在常温下不溶解树脂，但在升高的温度下溶解。如果液相仅由增塑剂组成，则分散相经常被称 作“增塑溶胶”，而如果分散液还含有加热后蒸发的挥发性组分，则分散相通常被称作“有机溶胶”。在本发明中有用的增塑溶胶/有机溶胶聚合物的商业可得的例子包括由Polyone和Chemionics生产的那些聚合物。
在一个实施方式中，图像层30由聚合材料如聚乙烯、聚丙烯、丙烯酸、环氧化物、共聚物等形成。用于形成液体材料层30的有用的丙烯酸酯聚合物和共聚物包括C1-C12丙烯酸酯或甲基丙烯酸酯单体——诸如丙烯酸或甲基丙烯酸的甲酯、乙酯、丙酯、丁酯、己酯或辛酯——的聚丙烯酸酯和甲基丙烯酸酯均聚物或共聚物。可利用的聚合物的商业例子包括通过巴斯夫(BASF)的
Acrylics、罗门哈斯(Rohm and Haas)的
和Lucidene的产品生产的那些。
可用于制备图像层30的环氧树脂包括环氧树脂和聚合环氧树脂。这些树脂在它们的骨架和取代基方面可以变化很大。在添加合适的光引发剂的情况下，通过自由基机理，本发明的环氧树脂在暴露于UV照射后可经历初步固化。环氧树脂层的最终固化通过加热环氧树脂而完成。一种特别有用的环氧层由双酚A二环氧甘油醚、环氧二丙烯酸酯和胺固化剂的混合物形成。
825，一种可从壳牌化学公司(Shell Chemical Co.)商业得到的双酚A表氯醇环氧树脂(bisphenolA epichlorohydrin epoxy resin)，是双酚A二环氧甘油醚的一个例子。在本发明中有用的环氧二丙烯酸酯是
3700，一种可从UCBChemical Corp.商业得到的双酚A环氧二丙烯酸酯。
在一个实施方式中，图像层30由可以分散或溶解在溶剂或水中的聚合物形成，如本领域所知。这类聚合物包括但不限于聚碳酸酯、聚丙烯腈、丁二烯-苯乙烯聚合物、聚(甲基丙烯酸甲酯)、聚酰胺、乙烯-乙酸乙烯酯共聚物、处理的和未处理的聚对苯二甲酸乙二酯、聚苯乙烯、聚烯烃例如聚乙烯——包括高密度聚乙烯、低密度聚乙烯、线型低密度聚乙烯和线型超低密度聚乙烯，聚丙烯和聚丁烯；乙烯系共聚物和聚乙酸乙烯酯，烯烃共聚物例如乙烯/甲基丙烯酸酯共聚物、乙烯/乙酸乙烯酯共聚物、丙烯腈-丁二烯-苯乙烯共聚物和乙烯/丙烯共聚物；丙烯酸聚合物和共聚物；聚氨酯；和它们的混合物。
图像层30可以是带颜色的或是透明的。在一个实施方式中，图像层30是带颜色的。颜料可以是金属颜料、重金属基颜料、不含重金属的颜料或有机颜料。重金属在本文中被定义为铅、镉、铬或锑。可以使用的颜料包括二氧化钛，包括金红石型和锐钛型晶体结构两种。二氧化钛可以是涂布的或未涂布的(例如，氧化铝涂布的TiO2)。
在一个实施方式中，颜料以含有颜料和树脂载体的提浓物的形式被加入到图像层30。提浓物可以含有例如按重量计约20％至约80％的颜料和按重量计约20％至约80％的树脂载体。树脂载体可以是任何热塑性聚合物，所述热塑性聚合物在一个实施方式中具有约-70℃至约150℃的玻璃化转变温度，而在一个实施方式中具有从约100℃至约175℃的玻璃化转变温度。载体树脂包括聚烯烃、乙烯和丙烯的热塑性聚合物、聚酯、聚碳酸酯、苯乙烯衍生的聚合物、聚氨酯、聚丙烯酸、聚甲基丙烯酸、聚乙烯醇、聚酰胺、聚酰亚胺、聚砜、聚甲基戊烯、聚乙酰化合物(polyacetyl)、卤乙烯衍生的聚合物、聚(乙烯乙烯醇)(poly(ethylene vinyl alcohol))、醋酸乙烯酯衍生的聚合物、离子交联聚合物、以及它们的混合物。在一个实施方式中，二氧化钛提浓物被应用，其由按重量计约30％至约70％的聚丙烯和按重量计约70％至约30％的二氧化钛的掺合物组成。可被应用的商业可得的颜料提浓物的例子可从A.Schulman以商品名Polybatch White P8555SD获得，其被鉴定为在聚丙烯均聚物载体树脂中按重量计50％的白色提浓物。其它颜料提浓物的例子包括但不限于鉴定为红色颜料提浓物的Ampacet150380、鉴定为黑色颜料提浓物的Ampacet190303、鉴定为钼酸铅提浓物的Ampacet LR-87132Orange PE MB，所有这些都可以从Ampacet公司得到。可以使用的不含重金属的颜料提浓物包括AmpacetLR-86813Yellow UV PE MB、Ampacet LR-86810Red PE MB、AmpacetLR-86816Orange PE MB、和Ampacet LR-86789Red UV PE MB。在液体膜材料中的颜料浓度按重量计可达约25％，并且在一个实施方式中，为按重量计约5％至约25％，以及在一个实施方式中，为按重量计约10％至约20％。
在一个实施方式中，利用染料基油墨，赋予图像层30颜色。所用的油墨包括商业可得的水基油墨、溶剂型油墨或辐射固化油墨。这类油墨的例子包括Sun Sheet(Sun Chemical的产品，鉴定为醇可稀释的聚酰胺油墨)、Suntex MP(Sun Chemical的产品，鉴定为溶剂型油墨)、X-Cel(Water Ink Technologies的产品，鉴定为水性膜油墨)、UvilithAR-109Rubine Red(Daw Ink的产品，鉴定为UV油墨)和CLA91598F(Sun Chemical的产品，鉴定为multibond黑色溶剂型油墨)。
在一个实施方式中，图像层30由印刷油墨产生。适合的油墨包括可以从在堪萨斯州的堪萨斯市的Fujifilm Sericol USA，Inc.商业获得的Color+系列溶剂型油墨。通过使用数字格式印刷机(digitalformat printer)例如可从Hewitt Packard或Palo Alto，California得到的 
印刷机，或者宽格式印刷机(wide format printer)例如可从日本的Mimaki Engineering Company以商品名Mimaki得到的那些，油墨可以被应用。
在一个实施方式中，颜料被加入到粘合剂层40。当加入颜料时，粘合剂层40可含有一种或多种上述颜料。压敏粘合剂层40可以是任何本领域中已知的压敏粘合剂。这些包括橡胶基粘合剂、丙烯酸粘合剂、乙烯醚粘合剂、有机硅粘合剂和它们的两种或更多种的混合物。包括在内的是描述在″Adhesion and Bonding，″Encyclopedia ofPolymer Science and Engineering，Vol.1，第476-546页，IntersciencePublishers 2nd Ed.1985中的压敏粘合剂材料，其公开内容通过引用由此并入。有用的压敏粘合剂材料可含有作为主要成分的粘性聚合物，例如丙烯酸型聚合物、嵌段共聚物、天然的、可再生的、或苯乙烯-丁二烯橡胶、粘性的或合成的橡胶、乙烯和乙酸乙烯酯的无规共聚物、乙烯-乙烯基-丙烯酸三元共聚物、聚异丁烯、聚乙烯醚等。压敏粘合剂材料的特征通常在于具有约-70℃至约10℃的玻璃化转变温度。
除前述树脂之外，其它材料可以被包括在压敏粘合剂层40之内。这些包括固体粘性树脂、液体增粘剂(通常称为增塑剂)、抗氧化剂、填料、颜料、蜡等。粘合剂材料可以包含固体粘性树脂和液体粘性树脂(或液体增塑剂)的掺合物。
压敏粘合剂的层40通常具有约0.508至约6.35mm的厚度，并且在一个实施方式中为约1.27至约3.81mm。在一个实施方式中，压敏粘合剂的涂布重量在每平方米约10至约50克(gsm)的范围内，并 且在一个实施方式中为约20至约35gsm。
图像层30也可包括通常掺入乙烯基树脂中的除增塑剂外的添加剂。通常，这类组合物包括一种或多种稳定剂，以赋予对热降解的抗性。无机填料——或纤维填料或非纤维填料——均可以在需要的时候使用。另外，其它添加剂，例如溶剂、稀释剂、粘合剂等也可以使用。图像层30也可以包含其它材料，例如抗氧化剂、抗光剂(或光稳定剂)如(UV)光吸收剂和/或其它抗光剂、粘度改进剂、防粘连剂和/或增滑剂、增强剂、加工助剂、矿物油、以及类似物。在一个实施方式中，除了通常存在于PVC增塑溶胶制剂中的那些稳定剂之外的稳定剂可以被包括在内。这类稳定剂的例子包括紫外光稳定剂，其包括受阻胺光稳定剂。受阻胺光稳定剂可以是例如2，2，6，6-四烷基哌啶或取代的哌嗪二酮(piperizinediones)的衍生物。许多在本发明中可以使用的受阻胺光稳定剂是可以从商业渠道获得的，例如从汽巴-嘉基公司(Ciba-Geigy Corporation)以通用商品名“Tinuvin”和“Chemissorb”获得，以及从Cytec以通用商品名“Cyasorb-UV”获得。例子包括Tinuvin783，其被鉴定为聚[[60[1，1，3，3-四甲基丁基)氨基]-1，3，5-三嗪-2，4-二基][[2，2，6，6-四甲基-4-哌啶基)亚氨基]六亚甲基[2，2，6，6-四甲基-4-哌啶基亚氨基]]和丁二酸二甲酯聚合物与4-羟基-2，2，6，6-四甲基-1-哌啶乙醇的混合物；Tinuvin 770，其被鉴定为双-(2，2，6，6-四甲基-4-哌啶基)-癸二酸酯；Tinuvin 765，其被鉴定为双-(1，2，2，6，6-五甲基-4-哌啶基)-癸二酸酯；Tinuvin 622，其是丁二酸和N-β-羟乙基-2，2，6，6-四甲基-4-羟基-哌啶的聚酯；以及Chemissorb 944，其是聚[6-(1，1，3，3-四甲基丁基)氨基]-s-三嗪-2，4-二基[[2，2，6，6-四甲基-4-哌啶基)亚氨基]六亚甲基(2，2，6，6-四甲基-4-哌啶基)亚氨基]。有用的稳定剂可以以商品名Ampacet 10561获得，其是Ampacet公司的的产品，被鉴定为UV稳定剂提浓物，含有按重量计20％的UV稳定剂和按重量计80％的低密度聚乙烯载体树脂；该产品中的UV稳定剂是Chemissorb 944。有用的光稳定剂也被提供在Ampacet 150380和Ampacet 190303中，这两种都是上文讨论的颜料提浓物。Ampacet 150380具有按重量计7.5％的UV稳定剂浓度。Ampacet190303具有按重量计4％的UV稳定剂浓度。这些产品的每一种中的UV稳定剂都是Chemissorb 944。Ampacet LR-89933是按重量计UV稳 定剂浓度为4.5％的灰色提浓物，其中UV稳定剂是Tinuvin 783。热稳定剂包括环氧化物，例如Thermcheck 909，以及钡/锌热稳定剂，例如Crompton Industries的Mark 121。
图像层30可以包含防粘连添加剂和/或增滑添加剂。防粘连添加剂包括天然硅石、硅藻土、合成硅石、玻璃球、陶瓷颗粒等。增滑添加剂包括伯胺，例如硬脂酰胺、山嵛酸酰胺、油酰胺、芥酸酰胺等；仲胺，例如硬脂基芥酸酰胺、瓢儿菜基芥酸酰胺、油基棕榈酰胺、硬脂基硬脂酰胺、瓢儿菜基硬脂酰胺等；亚乙基双酰胺，例如N，N′-亚乙基双硬脂酰胺、N，N′-亚乙基双油酰胺等；以及上述酰胺的任意两种或多种的组合。有用的增滑添加剂的例子可从Ampacet以商品名10061获得；该产品被鉴定为一种含有按重量计6％的硬脂酰胺增滑添加剂的提浓物。防粘连和增滑添加剂可以树脂提浓物的形式一起被添加。这样的提浓物的例子可以从DuPont以商品名Elvax CE9619-1获得。这种树脂提浓物含有按重量计20％的二氧化硅、按重量计7％的酰胺类增滑添加剂、以及按重量计73％的Elvax 3170(DuPont的产品，其被鉴定为乙酸乙烯酯含量按重量计18％的乙烯/乙酸乙烯酯共聚物)。防粘连添加剂可以在按重量计可达约1％的浓度范围内使用，在一个实施方式中为按重量计约0.01％至约0.5％。增滑添加剂可以在按重量计可达约1％的浓度范围使用，在一个实施方式中为按重量计约0.01％至约0.5％。
参照图4，在横截面中描绘了向基材10输送用于产生图像层30的材料的方法的一个实施方式。分配头50a、50b、50c附着于分配头滑轨60上。在一个实施方式中，分配头50a、50b、50c由计算机(未示出)数字化驱动，以按期望以字母或图案的形式分配层30。在一个实施方式中，基材10经过分配头50a、50b、50c的运动是由计算机(未示出)数字驱动的。图像层30的材料被分配在具有剥离层20的基材10上。在一个实施方式中，图像层30的材料通过喷雾加以分配。在一个实施方式中，图像层30的材料通过粉末涂布加以分配。所分配的层的厚度取决于意图的应用，并且在一个实施方式中，厚度为约0.00254mm至约38.1，以及在一个实施方式中，厚度为约2.54mm至约12.7mm。所分配的膜30的厚度由涂布辊的速度以及分配头50a、50b、50c和涂布辊之间的距离和施用于喷嘴的压力来控制。
本发明方法的一个实施方式的图示在图5中示出，其中涂布辊运送涂布有剥离层20的基材10。基材10继续通过在分配头滑轨60上、布置于基材10上方的分配头50a、50b、50c，并分配材料，以在基材10上形成期望字母或图案形式的图像层30。在一个实施方式中，基材10连续通过第二组分配头(未示出)，由此，粘合剂层40被分配在图像层30上，以便与粘合剂层40图形一致。然后，具有分配的图像层30和粘合剂层40的基材10被热固化或辐射固化。在一个实施方式中，在图像层30涂布于基材10上之后，基材10然后在粘合剂层40的涂布之前进行固化。
在一个实施方式中，如图3所示，基材10的上表面12涂布有形状为所需字母或图案的粘合剂层40。用于生成图像层30的材料然后被分配在粘合剂层40之上，以便符合粘合剂层40的字母或图案并与之具有相同的形状。
通过使经过涂布的基材通过被设计来为层30、40提供充足的停留时间以完全固化层30、40的设备，图像层30和粘合剂层40的固化可以以连续的方式实现。固化可以在大气压下或接近大气压下实现，在一个实施方式中，在惰性气氛例如氮气或氩气下进行。固化层30、40所需的暴露时长随着诸如所用的具体制剂、辐射的类型和波长、剂量率、气氛、能通量、光引发剂(当需要时)的浓度、以及层30、40的厚度之类的因素而变化。通常，暴露十分短暂，并且固化在约1分钟以下完成。对于各种涂层而言获得适当的固化所需的实际暴露时间可以由本领域普通技术人员通过最少的试验容易地确定。如果使用热固化，炉温范围为从约110℃至约216℃。
在图6和图7所示的一个实施方式中，产生图形的方法包括在粘合剂层60之上或层压到粘合剂层60上，印刷具有期望形状的油墨层或图案30，所述粘合剂层60粘附于纸或高分子基材10。通过覆盖或产生油墨膜30，例如通过使用数字打印机64，印刷得以完成。允许油墨有时间固化，例如通过紫外线能量的应用，和/或在向所述油墨表面涂布第二粘合层62之前允许溶剂蒸发。如图7所示，通过层压辊，剥离衬垫可被应用于第二粘合剂层62。
图像层30可以以反转图像格式制成，特别是如果使用了清澈或透明的基材10更是如此。可选地，印刷或制成图像，使得图像在正常的视野结构下是可见的，这取决于产品的设计和编排。一旦用于形成图像层的材料退出打印机，则将涂布于或层压于粘合剂层。
透明的油墨或在固化后变透明的油墨可以被涂布在图像层上或作为图像层的一部分，这可消除在图像层的顶部添加透明保护膜层的需要。可选地，透明的油墨层可以被用于补充保护层，例如通过形成屏蔽或遮蔽。
尽管已经就其优选的实施方式对本发明进行了说明，应当理解，在阅读本说明书后，对于本领域技术人员而言，各种修改将变得明显。因此，应该理解，本文所公开的发明意欲覆盖落入所附权利要求书的范围之内的这类修改。
Claims (9)
1.聚合物膜图形的制造方法，其包括：
提供连续基材，其具有第一和第二表面，并且在所述第一表面上具有第一剥离层；
将具有图形文字或图案的形状的图像层施加于所述第一剥离层，所述图像层包括有机溶胶或增塑溶胶；
沉积粘合剂层于所述图像层上，所述粘合剂层具有与所述图像层的图形文字或图案相同的形状；和
固化所述粘合剂层和图像层，其中固化的所述图像层具有2.54mm至12.7mm的厚度。
2.权利要求1所述的方法，其中所述连续基材包括纸、聚合物膜或它们的组合。
3.权利要求1或2所述的方法，其中所述连续基材在所述第二表面上具有第二剥离层。
4.权利要求1所述的方法，其中所述粘合剂包括压敏粘合剂。
5.权利要求4所述的方法，其中所述粘合剂包括丙烯酸粘合剂。
6.权利要求1所述的方法，其中所述图像层包含聚氯乙烯树脂和增塑剂。
7.权利要求1所述的方法，其中所述粘合剂层和图像层在110℃至216℃范围内的温度下固化1分钟以下的时间。
8.权利要求1所述的方法，其中所述图像层通过将所述有机溶胶或增塑溶胶印刷在所述粘合剂层上而被施加。
9.权利要求8所述的方法，其中所述连续基材包含透明聚合物膜。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78838606P | 2006-03-31 | 2006-03-31 | |
| US60/788,386 | 2006-03-31 | ||
| PCT/US2007/064588 WO2007115008A2 (en) | 2006-03-31 | 2007-03-22 | Process for manufacture of polymer film graphics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101415562A CN101415562A (zh) | 2009-04-22 |
| CN101415562B true CN101415562B (zh) | 2011-04-20 |
Family
ID=38535575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800118177A Expired - Fee Related CN101415562B (zh) | 2006-03-31 | 2007-03-22 | 聚合物膜图形的制造方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US9725624B2 (zh) |
| EP (1) | EP2001683B1 (zh) |
| KR (1) | KR20080109046A (zh) |
| CN (1) | CN101415562B (zh) |
| AT (1) | ATE455651T1 (zh) |
| AU (1) | AU2007233292B2 (zh) |
| BR (1) | BRPI0710031B1 (zh) |
| DE (1) | DE602007004459D1 (zh) |
| RU (1) | RU2008143193A (zh) |
| WO (1) | WO2007115008A2 (zh) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009040359A1 (de) * | 2009-09-07 | 2011-03-10 | Heidelberger Druckmaschinen Ag | Verfahren zum Erzeugen eines drucktechnischen Merkmals auf einem Substrat eines Druckprodukts |
| US8299387B2 (en) * | 2009-09-25 | 2012-10-30 | Stahls' Inc. | Method and system for generating graphic elements |
| CN102114737A (zh) * | 2009-12-31 | 2011-07-06 | 鸿富锦精密工业（深圳）有限公司 | 转印膜及转印膜的制造方法 |
| RU2628598C2 (ru) * | 2011-08-31 | 2017-08-21 | Авери Деннисон Корпорейшн | Самоклеящаяся пленка и способ минимизации или устранения дефектов печати в таких пленках |
| US8851592B2 (en) | 2012-01-24 | 2014-10-07 | CondomNation LLC | Latex articles imprinted with full-length indicia and systems and methods for imprinting latex articles |
| EP2772507A1 (en) * | 2013-02-28 | 2014-09-03 | 3M Innovative Properties Company | Antigrafiti layer for polyvinyl chloride based graphics film |
| KR20150130507A (ko) * | 2013-03-15 | 2015-11-23 | 처치 앤드 드와이트 캄파니 인코포레이티드 | 기재 상에의 임프린트의 퇴적 |
| CA2905964A1 (en) | 2013-03-15 | 2014-09-25 | Church & Dwight Co., Inc. | A system for depositing an imprint onto a substrate |
| CN103289479B (zh) * | 2013-07-01 | 2014-07-09 | 国家电网公司 | 一种线缆印字油墨 |
| GB2569608B (en) | 2017-12-21 | 2022-10-26 | Altro Ltd | Plasticiser composition |
| US10286689B1 (en) * | 2018-02-08 | 2019-05-14 | Xerox Corporation | UV printed transferrable materials |
| DE102018110522A1 (de) * | 2018-05-02 | 2019-11-07 | Olbrich Gmbh | Verfahren zur Herstellung einer bedruckten Plastisol- oder Lackschicht |
| TWI720328B (zh) * | 2018-07-16 | 2021-03-01 | 勤倫有限公司 | 可重複黏貼之刻字膜及其製法 |
| JP7201389B2 (ja) * | 2018-07-20 | 2023-01-10 | プロクラフト、ディベロップメント、ベスローテン、フェンノートシャップ | 多層生成物を製造する方法 |
| US11028581B2 (en) * | 2018-12-18 | 2021-06-08 | Awi Licensing Llc | Face coating for acoustical monolithic ceilings |
| US20210221157A1 (en) * | 2020-01-21 | 2021-07-22 | Ready, Set, Co., LLC | Multiple layered print structure and apparatus for fabric or cloth |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4028474A (en) * | 1973-01-03 | 1977-06-07 | Francois Martin | Weatherproof decal |
| EP0241212A2 (en) * | 1986-04-01 | 1987-10-14 | Minnesota Mining And Manufacturing Company | Transfer graphic article |
| US6074721A (en) * | 1996-12-18 | 2000-06-13 | Moore; George | Temporary tattoo decals |
| US20030035933A1 (en) * | 2001-08-16 | 2003-02-20 | Stahl Brett A. | Heat applied graphics and method |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4038123A (en) | 1976-02-27 | 1977-07-26 | Mach Iii, Inc. | Method for printing a color design on a release paper for heat transfer to a fabric material |
| US4898848A (en) * | 1986-11-12 | 1990-02-06 | Ricoh Electronics, Inc. | Thermal label with remoistenable adhesive |
| US5186787A (en) | 1988-05-03 | 1993-02-16 | Phillips Roger W | Pre-imaged high resolution hot stamp transfer foil, article and method |
| US5021275A (en) | 1989-04-06 | 1991-06-04 | Kim Jae Duck | Ornamental stickers necessitating no separate cutting process and the manufacturing method thereof |
| US5169681A (en) | 1989-04-06 | 1992-12-08 | Kim Jae Duck | Method of producing an ornamental sticker without a separate cutting step |
| US5312645A (en) | 1991-12-10 | 1994-05-17 | Dressler Donald R | Heat-applied athletic lettering |
| US5284688A (en) * | 1992-04-16 | 1994-02-08 | Unique Label Systems, Inc. | Pressure sensitive adhesive labels and manufacture thereof |
| US5262215A (en) | 1992-06-19 | 1993-11-16 | Package Service Company | Laminated article for having separable pieces for detachable placement on a background |
| US5814402A (en) | 1993-04-20 | 1998-09-29 | Decora Incorporated | Pressure sensitive dry transfer graphics article and method of manufacture |
| CA2132679C (en) | 1993-09-24 | 2006-11-28 | Donald R. Dressler | Carrier for decorative graphics and lettering |
| US5686170A (en) | 1995-12-21 | 1997-11-11 | Minnesota Mining And Manufacturing Company | Labor-saving process and article for making dimensional sign graphics |
| WO1997026136A1 (en) | 1996-01-16 | 1997-07-24 | Peter Shaw Lingamfelter | A method for transferring vinyl designs from a host backing material to a substrate |
| US5779370A (en) * | 1996-02-20 | 1998-07-14 | Premark Feg L.L.C. | Apparatus for printing labels and a self-releasing print roller therefor |
| US6811840B1 (en) | 1996-02-23 | 2004-11-02 | Stahls' Inc. | Decorative transfer process |
| US6482285B2 (en) | 1998-01-20 | 2002-11-19 | Stahls' Inc. | Method of creating a transfer |
| JP2000089677A (ja) | 1998-09-02 | 2000-03-31 | Hoei Yo | 装飾用ホログラム・ステッカー及びその製造方法 |
| US6333073B1 (en) * | 1999-02-25 | 2001-12-25 | Premark Rwp Holdings, Inc. | Adhesive tape and products made therefrom |
| US20030104179A1 (en) * | 1999-08-11 | 2003-06-05 | Weder Donald E. | Holographic material |
| US6440533B1 (en) * | 2000-09-22 | 2002-08-27 | Tredegar Film Products Corporation | PVC replacement film |
| WO2002028634A1 (en) | 2000-10-06 | 2002-04-11 | Imperial Home Decor Group Management, Inc. | Bleed-resistant dry-transfer wallcoverings |
| US6630043B2 (en) * | 2001-01-25 | 2003-10-07 | Printmark Industries, Inc. | Plastic trimmed fabric product and method of manufacturing the same |
| CN100440076C (zh) * | 2001-05-28 | 2008-12-03 | 株洲工学院科技开发部 | 纸基材激光全息图文成像技术及大量复制工艺 |
| US20020192415A1 (en) * | 2001-06-15 | 2002-12-19 | 3M Innovative Properties Company | Stack of adhesive articles |
| DE10134867B4 (de) * | 2001-07-18 | 2007-08-02 | Schreiner Gmbh & Co Kg | Verfahren und Vorrichtung zur Herstellung von Etiketten und aus diesem Verfahren erhältliches Etikett |
| US6805933B2 (en) * | 2001-07-31 | 2004-10-19 | 3M Innovative Properties Company | Articles comprising a release liner having a high coefficient of friction and good roll stability |
| CN1281403C (zh) * | 2001-07-31 | 2006-10-25 | 艾弗里·丹尼森公司 | 可整合的全息标签 |
| JP4646508B2 (ja) * | 2003-10-01 | 2011-03-09 | 日東電工株式会社 | 両面接着テープ又はシートおよびその製造方法 |
| US7758938B2 (en) * | 2004-01-09 | 2010-07-20 | Avery Dennison Corporation | Label assembly and method of using the same to label articles durably yet removably |
| JP2005350650A (ja) * | 2004-05-14 | 2005-12-22 | Nitto Denko Corp | 剥離ライナー及びそれを用いた感圧性接着テープ又はシート |
-
2007
- 2007-03-22 RU RU2008143193/12A patent/RU2008143193A/ru unknown
- 2007-03-22 CN CN2007800118177A patent/CN101415562B/zh not_active Expired - Fee Related
- 2007-03-22 EP EP07759071A patent/EP2001683B1/en not_active Not-in-force
- 2007-03-22 AU AU2007233292A patent/AU2007233292B2/en not_active Ceased
- 2007-03-22 BR BRPI0710031-0A patent/BRPI0710031B1/pt not_active IP Right Cessation
- 2007-03-22 DE DE602007004459T patent/DE602007004459D1/de active Active
- 2007-03-22 WO PCT/US2007/064588 patent/WO2007115008A2/en active Application Filing
- 2007-03-22 AT AT07759071T patent/ATE455651T1/de not_active IP Right Cessation
- 2007-03-22 US US11/689,617 patent/US9725624B2/en active Active
- 2007-03-22 KR KR1020087026098A patent/KR20080109046A/ko not_active Application Discontinuation
-
2017
- 2017-06-29 US US15/636,755 patent/US20170327716A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4028474A (en) * | 1973-01-03 | 1977-06-07 | Francois Martin | Weatherproof decal |
| EP0241212A2 (en) * | 1986-04-01 | 1987-10-14 | Minnesota Mining And Manufacturing Company | Transfer graphic article |
| US6074721A (en) * | 1996-12-18 | 2000-06-13 | Moore; George | Temporary tattoo decals |
| US20030035933A1 (en) * | 2001-08-16 | 2003-02-20 | Stahl Brett A. | Heat applied graphics and method |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0710031B1 (pt) | 2018-02-14 |
| BRPI0710031A2 (pt) | 2011-08-02 |
| EP2001683B1 (en) | 2010-01-20 |
| EP2001683A2 (en) | 2008-12-17 |
| US9725624B2 (en) | 2017-08-08 |
| KR20080109046A (ko) | 2008-12-16 |
| ATE455651T1 (de) | 2010-02-15 |
| DE602007004459D1 (de) | 2010-03-11 |
| AU2007233292B2 (en) | 2011-05-26 |
| WO2007115008B1 (en) | 2008-02-14 |
| CN101415562A (zh) | 2009-04-22 |
| WO2007115008A2 (en) | 2007-10-11 |
| AU2007233292A1 (en) | 2007-10-11 |
| RU2008143193A (ru) | 2010-05-10 |
| US20070231525A1 (en) | 2007-10-04 |
| WO2007115008A3 (en) | 2007-12-06 |
| US20170327716A1 (en) | 2017-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101415562B (zh) | 聚合物膜图形的制造方法 | |
| EP1091852B1 (en) | Multilayered thermoplastic film and sign cutting method using the same | |
| CN100566995C (zh) | 地板材料用装饰材料 | |
| EP3502204B1 (en) | Faceless labels and related systems and methods | |
| CN103717396B (zh) | 图形制品 | |
| JP5562974B2 (ja) | 印刷可能な難燃性高分子フィルム | |
| CN103906626A (zh) | 层压材料组合物、膜及相关方法 | |
| CN103732416A (zh) | 图形制品 | |
| CN103732417A (zh) | 图形制品 | |
| CN101003043A (zh) | 制备具有择优耐磨表面的通用塑料制品的方法 | |
| JP2001302991A (ja) | 塗装用粘着テープ | |
| CN105346296B (zh) | 一种多色预涂膜 | |
| CN103717405A (zh) | 图形制品 | |
| JP2008087303A (ja) | インサート成形用加飾シート | |
| KR101759167B1 (ko) | 폴리에틸렌수지 표면 전사용 전사지 | |
| DE10227430B4 (de) | Heißprägefolie mit erhöhtem UV- und Abriebschutz sowie deren Verwendung zum Prägen | |
| EP1520690A1 (de) | Adhäsionsfolie | |
| JP4470527B2 (ja) | 化粧シート | |
| US20160257153A1 (en) | A printable media with self adhering printable compositions | |
| KR101759166B1 (ko) | 금속 표면 전사용 전사지 | |
| EP3337677B1 (de) | Verfahren zur herstellung eines bedruckten dekorativen verbundkörpers sowie hierdurch erhältlicher bedruckter dekorativer verbundkörper | |
| JP2890838B2 (ja) | 外装用化粧シートの製造方法 | |
| JPH0562069B2 (zh) | ||
| JP2020117676A (ja) | カレンダー成形用アクリル系樹脂組成物、該樹脂組成物からなるフィルム | |
| JP2001131497A (ja) | マーキングフィルム |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110420 Termination date: 20190322 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |