CN101412782B - 压敏胶用网络梯度结构丙烯酸酯聚合物乳液的制备方法 - Google Patents
压敏胶用网络梯度结构丙烯酸酯聚合物乳液的制备方法 Download PDFInfo
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- CN101412782B CN101412782B CN2008101535484A CN200810153548A CN101412782B CN 101412782 B CN101412782 B CN 101412782B CN 2008101535484 A CN2008101535484 A CN 2008101535484A CN 200810153548 A CN200810153548 A CN 200810153548A CN 101412782 B CN101412782 B CN 101412782B
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- emulsion
- sensitive adhesive
- gradient
- acrylate polymer
- pressure
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- 239000000839 emulsion Substances 0.000 title claims abstract description 86
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 53
- 229920000058 polyacrylate Polymers 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000000178 monomer Substances 0.000 claims abstract description 32
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 22
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004945 emulsification Methods 0.000 claims abstract description 10
- 239000012986 chain transfer agent Substances 0.000 claims description 25
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 23
- 239000003995 emulsifying agent Substances 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 17
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 16
- 239000003999 initiator Substances 0.000 claims description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 239000011259 mixed solution Substances 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 2
- 230000007423 decrease Effects 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 13
- 239000000853 adhesive Substances 0.000 abstract description 9
- 230000001070 adhesive effect Effects 0.000 abstract description 9
- 230000008859 change Effects 0.000 abstract description 8
- -1 poly(butyl acrylate) Polymers 0.000 abstract description 6
- 238000004132 cross linking Methods 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 238000005457 optimization Methods 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 abstract description 2
- 238000007598 dipping method Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 31
- 229920000642 polymer Polymers 0.000 description 17
- 239000000463 material Substances 0.000 description 12
- 238000009826 distribution Methods 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 239000002390 adhesive tape Substances 0.000 description 7
- 238000007720 emulsion polymerization reaction Methods 0.000 description 6
- FRQQKWGDKVGLFI-UHFFFAOYSA-N 2-methylundecane-2-thiol Chemical compound CCCCCCCCCC(C)(C)S FRQQKWGDKVGLFI-UHFFFAOYSA-N 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000006276 transfer reaction Methods 0.000 description 4
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000008204 material by function Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229940074404 sodium succinate Drugs 0.000 description 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- IKCQWKJZLSDDSS-UHFFFAOYSA-N 2-formyloxyethyl formate Chemical compound O=COCCOC=O IKCQWKJZLSDDSS-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000002473 artificial blood Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 210000004204 blood vessel Anatomy 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
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CN2008101535484A CN101412782B (zh) | 2008-11-27 | 2008-11-27 | 压敏胶用网络梯度结构丙烯酸酯聚合物乳液的制备方法 |
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CN2008101535484A CN101412782B (zh) | 2008-11-27 | 2008-11-27 | 压敏胶用网络梯度结构丙烯酸酯聚合物乳液的制备方法 |
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CN101412782A CN101412782A (zh) | 2009-04-22 |
CN101412782B true CN101412782B (zh) | 2010-11-10 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102352002B (zh) * | 2011-07-15 | 2012-08-29 | 河北工业大学 | 聚酯树脂增韧改性用丙烯酸酯聚合物乳液的制备方法 |
CN105602490B (zh) * | 2016-01-25 | 2017-06-06 | 华南理工大学 | 一种双组份乳液型聚丙烯酸酯压敏胶及其制备方法与应用 |
CN108395494B (zh) * | 2018-03-26 | 2020-09-08 | 瑞固新能(上海)材料科技有限公司 | 一种渐变式玻璃化温度的乳胶粒子的制备方法 |
CN113667056B (zh) * | 2021-09-01 | 2022-07-12 | 万华化学集团股份有限公司 | 一种丙烯酸酯类悬浮增稠剂的制备工艺及应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11193368A (ja) | 1997-12-29 | 1999-07-21 | Toagosei Co Ltd | 感熱粘着剤組成物及び感熱粘着シート |
CN1814629A (zh) * | 2005-02-05 | 2006-08-09 | 广州宏昌胶粘带厂 | 含无机纳米粒子的核-壳无机-有机复合压敏胶乳液及其制备方法和应用 |
CN1944480A (zh) * | 2006-10-24 | 2007-04-11 | 河北工业大学 | 压敏胶粘剂用聚丙烯酸酯复合乳液的制备方法 |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11193368A (ja) | 1997-12-29 | 1999-07-21 | Toagosei Co Ltd | 感熱粘着剤組成物及び感熱粘着シート |
CN1814629A (zh) * | 2005-02-05 | 2006-08-09 | 广州宏昌胶粘带厂 | 含无机纳米粒子的核-壳无机-有机复合压敏胶乳液及其制备方法和应用 |
CN1944480A (zh) * | 2006-10-24 | 2007-04-11 | 河北工业大学 | 压敏胶粘剂用聚丙烯酸酯复合乳液的制备方法 |
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CB03 | Change of inventor or designer information |
Inventor after: Qu Xiongwei Inventor after: Wang Nongyue Inventor after: Yang Jianguang Inventor after: Zhang Yu Inventor after: Zhang Guanglin Inventor after: Yao Yanmei Inventor before: Qu Xiongwei Inventor before: Yang Jianguang Inventor before: Wang Nongyue Inventor before: Zhang Yu Inventor before: Zhang Guanglin Inventor before: Yao Yanmei |
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Free format text: CORRECT: INVENTOR; FROM: QU XIONGWEI YANG JIANGUANG WANG NONGYUE ZHANG YU ZHANG GUANGLIN YAO YANMEI TO: QU XIONGWEI WANG NONGYUE YANG JIANGUANG ZHANG YU ZHANG GUANGLIN YAO YANMEI |
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Assignee: Weifang Shengda Technology Co.,Ltd. Assignor: Hebei University of Technology Contract record no.: 2011370000100 Denomination of invention: Preparation of acrylate polymer emulsion with gradient network structure for pressure-sensitive adhesive Granted publication date: 20101110 License type: Exclusive License Open date: 20090422 Record date: 20110418 |
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Assignee: WEIFANG SHENGDA PLASTIC Co.,Ltd. Assignor: Hebei University of Technology Contract record no.: 2011370000100 Date of cancellation: 20160426 |
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Application publication date: 20090422 Assignee: Weifang Shengda Technology Co.,Ltd. Assignor: Hebei University of Technology Contract record no.: 2016370000027 Denomination of invention: Preparation of acrylate polymer emulsion with gradient network structure for pressure-sensitive adhesive Granted publication date: 20101110 License type: Exclusive License Record date: 20160513 |
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