CN101294049A - Aerosol photopolymer coating - Google Patents
Aerosol photopolymer coating Download PDFInfo
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- CN101294049A CN101294049A CNA2008101253882A CN200810125388A CN101294049A CN 101294049 A CN101294049 A CN 101294049A CN A2008101253882 A CNA2008101253882 A CN A2008101253882A CN 200810125388 A CN200810125388 A CN 200810125388A CN 101294049 A CN101294049 A CN 101294049A
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Abstract
The invention discloses an aerosol spray adhesive, which contains two components of a base material and a propellant. In the aerosol spray adhesive, the base material and the propellant are filled together in an aerosol seal pot with a valve. The formula of the base material comprises (by weight): thermo-plastic elastomer 8 to 12 parts, terpene resin 8 to 12 parts, C9 petroleum resin 5 to 8 parts, rosin glyceride 2 to 4 parts, ethyl acetate 8 to 12 parts, butyl acetate 12 to 18 parts, extraction solvent oil No.6 30 to 50 parts, BHT 0.2 to 1.0 parts, and naphthenic oil 1 to 2 parts. The aerosol spray adhesive has the advantages that the product is filled as aerosol and sealed in a pot, so that the product can be sprayed without the need of matched facilities when in use and is convenient in construction; the sprayed adhesive particles are fine and uniform to prevent wrinkling when being used for adhering fine and thin materials; and the product can be used for adhering various materials such as paper sheets, plastics, thick paper boards, foam and metal.
Description
Technical field
The present invention relates to a kind of tackiness agent of aerosol-type, specifically is aerosol photopolymer coating.
Technical background
Spray glue is a kind of as tackiness agent, has a wide range of applications in industry with in producing.It has suitable viscosity, bonding force and suitable time of drying can utilize spray gun to spray to the surface of adherend body, forms uniform adhesive linkage, and spray glue through suitably dry, by sticking face pressing, has just been finished adhesion process after spraying.Compare with coating techniques such as roller coat, brushings, consumption glue amount is little, and applying glue is even.
Spray glue product in the market mainly contains two big classes, and a class is a SBS type spray glue, is main raw material with thermoplastic elastomer SBS, and cost is low, and tack is good; Another kind of is neoprene type spray glue, is main raw material with the chloroprene rubber, the bonding strength height, and temperature tolerance is good.But this two classes spray glue all needs to use spray gun in use, and needs supporting air compressor machine, and is inconvenient in daily use.
Aerosol photopolymer coating is meant propellent and two components of base-material are filled together in the aerosol sealed can of valve is housed that the pressure by propellent sprays a kind of product that uses with base-material then, presses as long as point one, and is with using with spray, very convenient.Existing spray glue product viscosity height when directly can becomes aerosol photopolymer coating, is prone to the phenomenon of atomization badness, obstruction valve; As the half-finished base-material of aerosol photopolymer coating, also have differently with the composition of general spray glue, to guarantee that at first its viscosity can not be too high, bonding force can not be too poor simultaneously; Its less important can be stably miscible with propellent.
Summary of the invention
The purpose of this invention is to provide a kind of aerosol photopolymer coating, it comprises base-material and two components of propellent.This aerosol photopolymer coating is that base-material and propellent are filled together in the aerosol sealed can of valve is housed.The base material formulation proportioning is (by weight): 8～12 parts of thermoplastic elastomers, 8～12 parts of terpine resins, 5～8 parts of C9 petroleum resin, 2～4 parts of ester gums, 8～12 parts of ethyl acetate, 12～18 parts of butylacetates, 30～50 parts of soybean extracting solvent no.6s, 0.2～1.0 part of BHT, 1～2 part of naphthenic oil, described thermoplastic elastomer are at least a among SIS 1209, the SIS 1225; Propellent is at least a in liquefied petroleum gas (LPG), the dme.The proportioning of described base-material and propellent is 1～5: 1; Described aerosol sealed can safety filling ratio is 35～85%; The aerosol sealed can is filled pressure≤0.8MPa (50 ℃) in the safety.
The production method of aerosol photopolymer coating comprises following two steps:
1. the preparation of base-material:
(1) ethyl acetate, butylacetate, soybean extracting solvent no.6 are added in the reactor;
(2) under 400～1200 rev/mins of rotating speeds stir, terpine resin, C9 petroleum resin, ester gum are added in the reactor, stir 0.5～1.5 hour to dissolving fully;
(3) thermoplastic elastomer is added in the reactor, stir 2～4 hours to dissolving fully;
(4) BHT, naphthenic oil are added in the reactor, stir discharging after 0.5～1 hour.
2. can:
(1) with after the filtration of base-material usefulness 〉=300 mesh filter screens, in the aerosol sealed can of packing into, valve and aerosol sealed can are encapsulated with sealing machine;
(2) charge into propellent with Machine for injecting fertilisers into the roots in the aerosol sealed can, load onto head.
Aerosol photopolymer coating provided by the invention compared with prior art has following advantage:
1. product does not need auxiliary facility through the aerosol embedding during use, with using with spray easy construction; 2. the spraying micelle is thin and even, and it is wrinkle resistant to paste thin thin material; 3. can be used for pasting various material such as paper, plastics, presspaper, bubble silk floss, metal.
Embodiment
Embodiment 1
Ethyl acetate 10Kg, butylacetate 15Kg, soybean extracting solvent no.6 40Kg are added in the reactor, under 600 rev/mins of rotating speeds stir, terpine resin 9Kg, C9 petroleum resin 6Kg, ester gum 3Kg are added in the reactor, stir after 0.5 hour, add SIS 1209 10Kg, stir after 2 hours, add BHT 0.5Kg, naphthenic oil 1.5Kg, stirred 0.5 hour, and made base-material; After base-material filtered with 450 mesh filter screens, get 180g and pack in the 450ml aerosol sealed can, with sealing machine with valve and the encapsulation of aerosol sealed can; Charge into liquefied petroleum gas (LPG) 60g with Machine for injecting fertilisers into the roots, load onto head, promptly get aerosol photopolymer coating.
Embodiment 2
Ethyl acetate 12Kg, butylacetate 18Kg, soybean extracting solvent no.6 45Kg are added in the reactor, under 900 rev/mins of stirrings of rotating speed, terpine resin 10Kg, C9 petroleum resin 8Kg, ester gum 4Kg are added in the reactor, stir after 0.5 hour, add SIS 1225 12Kg, stir after 2 hours, add BHT 1Kg, naphthenic oil 2Kg, stirred 0.5 hour, and made base-material; After base-material filtered with 300 mesh filter screens, get 180g and pack in the 450ml aerosol sealed can, with sealing machine with valve and the encapsulation of aerosol sealed can; Charge into dme 53g with Machine for injecting fertilisers into the roots, load onto head, promptly get aerosol photopolymer coating.
Embodiment 3
Ethyl acetate 8Kg, butylacetate 12Kg, soybean extracting solvent no.6 41Kg are added in the reactor, under 1200 rev/mins of stirrings of rotating speed, terpine resin 8Kg, C9 petroleum resin 5Kg, ester gum 2Kg are added in the reactor, stir after 30 minutes, add SIS 1209 8Kg, stir after 2 hours, add BHT0.2Kg, naphthenic oil 1Kg, stirred 0.5 hour, and made base-material; After base-material filtered with 300 mesh filter screens, get 180g and pack in the 450ml aerosol sealed can, with sealing machine with valve and the encapsulation of aerosol sealed can; Charge into dme 55g with Machine for injecting fertilisers into the roots, load onto head, promptly get aerosol photopolymer coating.
Main raw material(s) title, technical indicator:
1.SIS 1209
Outward appearance: white porous column or granular solids;
Structure: linear;
Proportion (g/cm
3): 0.92～0.95;
Soltion viscosity (25% toluene solution, mPas): 500;
2.SIS 1225
Outward appearance: white porous column or granular solids;
Structure: linear;
Proportion (g/cm
3): 0.92～0.95;
Soltion viscosity (25% toluene solution, mPas): 500;
3. terpine resin
Outward appearance: faint yellow crisp solid, sheet, bulk;
Softening temperature (ring and ball method, ℃): 〉=100;
Look number (iron cobalt method) :≤4;
Saponification value (mgKOH/g) :≤1.5;
Iodine number: 40-75;
Toluene insolubles (%) :≤0.05;
4.C9 petroleum resin
Outward appearance: yellow crisp solid, sheet, bulk;
Softening temperature (ring and ball method, ℃): 110～120;
Look number (iron cobalt method) :≤10;
Acid number (mgKOH/g) :≤0.5;
Ash content (%) :≤0.1;
5. ester gum
Outward appearance: faint yellow crisp solid, sheet, bulk;
Softening temperature (ring and ball method, ℃): 〉=100;
Look number (iron cobalt method) :≤4;
6. ethyl acetate, technical grade;
7. butylacetate, technical grade;
8.6 number solvent for extraction
Outward appearance: colourless transparent liquid;
Boiling range (℃): 60～90;
Proportion (g/cm
3, 20 ℃): 0.66～0.68;
9.BHT
Chemical name: 2,6 ditertiary butyl p cresol, SILVER REAGENT;
10. naphthenic oil
Outward appearance: water white transparency thick liquid;
Kinematic viscosity (100 ℃, m
2/ s): 24～32;
Condensation point (℃) :≤-15;
Refractive index (n
D 20): 〉=1.4800;
11. dme, purity 99.5%;
12. liquefied petroleum gas (LPG), purity 99%;
13. the aerosol sealed can, conformance with standard GB13042 requirement.
Product meets " HJ/T 220-2005 environmental labelling product technical requirements tackiness agent " standard, its main performance index such as following table through sampling inspection.
| Preface | Project | Standard-required | Assay |
| 1 | Outward appearance | Yellow evenly thick liquid | Meet |
| 2 | Viscosity mpas | 40～100 | 70 |
| 3 | Initial adhesive strength MPa | ≥0.7 | 0.85 |
| 4 | Tensile shear strength Mpa | ≥1.56 | 1.6 |
| 5 | Free formaldehyde mg/Kg | ≤500 | Do not detect |
| 6 | Benzene mg/Kg | ≤2000 | Do not detect |
| 7 | Toluene+dimethylbenzene mg/Kg | ≤2000 | Do not detect |
| 8 | Acetone mg/Kg | ≤750 | Do not detect |
| 9 | Halohydrocarbon mg/Kg | ≤2000 | Do not detect |
| 10 | Total volatile organism g/L | ≤750 | 480 |
| 11 | Emission rate % | ≥95 | 97 |
| 12 | Press MPa, 50 ℃ in jar | ≤0.8 | 0.6 |
Claims (7)
1. aerosol photopolymer coating is characterized in that comprising two components of base-material and propellent.This aerosol photopolymer coating is that base-material and propellent are filled together in the aerosol sealed can of valve is housed.The base material formulation proportioning is (by weight): 8～12 parts of thermoplastic elastomers, 8～12 parts of terpine resins, 5～8 parts of C9 petroleum resin, 2～4 parts of ester gums, 8～12 parts of ethyl acetate, 12～18 parts of butylacetates, 30～50 parts of soybean extracting solvent no.6s, 0.2～1.0 part of BHT, 1～2 part of naphthenic oil.
2. aerosol photopolymer coating as claimed in claim 1 is characterized in that wherein said thermoplastic elastomer, refers among SIS 1209, the SIS 1225 at least a.
3. aerosol photopolymer coating as claimed in claim 1 is characterized in that wherein said base-material, and production method may further comprise the steps:
(1) ethyl acetate, butylacetate, soybean extracting solvent no.6 are added in the reactor;
(2) under 400～1200 rev/mins of rotating speeds stir, terpine resin, C9 petroleum resin, ester gum are added in the reactor, stir 0.5～1.5 hour to dissolving fully;
(3) thermoplastic elastomer is added in the reactor, stir 2～4 hours to dissolving fully;
(4) BHT, naphthenic oil are added in the reactor, stir discharging after 0.5～1 hour.
4. aerosol photopolymer coating as claimed in claim 1 is characterized in that wherein said propellent, at least a in liquefied petroleum gas (LPG), the dme.
5. aerosol photopolymer coating as claimed in claim 1, the proportioning that it is characterized in that wherein said base-material and propellent is 1～5: 1.
6. aerosol photopolymer coating as claimed in claim 1 is characterized in that wherein said aerosol sealed can safety filling ratio is 35～85%.
7. aerosol photopolymer coating as claimed in claim 1 is characterized in that pressure≤0.8MPa (50 ℃) in the wherein said aerosol sealed can filling safety.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101253882A CN101294049A (en) | 2008-06-20 | 2008-06-20 | Aerosol photopolymer coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101253882A CN101294049A (en) | 2008-06-20 | 2008-06-20 | Aerosol photopolymer coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101294049A true CN101294049A (en) | 2008-10-29 |
Family
ID=40064598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008101253882A Pending CN101294049A (en) | 2008-06-20 | 2008-06-20 | Aerosol photopolymer coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101294049A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102277130A (en) * | 2010-06-11 | 2011-12-14 | 东莞市大洋化工有限公司 | Spray adhesive formula and technology thereof |
| CN102295912A (en) * | 2010-06-25 | 2011-12-28 | 东莞市大洋化工有限公司 | Multifunctional spray glue formula and process |
| CN104745124A (en) * | 2013-12-27 | 2015-07-01 | 比亚迪股份有限公司 | A sprayable glue solution, a preparing method thereof and a preparing method of injection moulding products with inserts |
| CN105131876A (en) * | 2015-10-19 | 2015-12-09 | 深圳市惠尔特实业有限公司 | Low-flammability aerosol adhesive |
| CN105623563A (en) * | 2016-03-30 | 2016-06-01 | 光山县博正树脂有限公司 | Environment-friendly film mulching glue and preparation method thereof |
| CN105802554A (en) * | 2016-03-30 | 2016-07-27 | 光山县博正树脂有限公司 | Transparent all-purpose adhesive and preparation method thereof |
| CN105820700A (en) * | 2016-06-06 | 2016-08-03 | 广东莱雅化工有限公司 | High-flash-point gloss silver aerial fog spraying paint and preparation method thereof |
| CN106753093A (en) * | 2016-12-23 | 2017-05-31 | 上海康达新能源材料有限公司 | A kind of aerosol photopolymer coating and preparation method thereof |
| CN110041883A (en) * | 2019-05-08 | 2019-07-23 | 王锦云 | A kind of pipe protection aerosol photopolymer coating and preparation method thereof |
-
2008
- 2008-06-20 CN CNA2008101253882A patent/CN101294049A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102277130A (en) * | 2010-06-11 | 2011-12-14 | 东莞市大洋化工有限公司 | Spray adhesive formula and technology thereof |
| CN102295912A (en) * | 2010-06-25 | 2011-12-28 | 东莞市大洋化工有限公司 | Multifunctional spray glue formula and process |
| CN102295912B (en) * | 2010-06-25 | 2013-08-28 | 东莞市大洋化工有限公司 | Multifunctional spray glue formula and process |
| CN104745124A (en) * | 2013-12-27 | 2015-07-01 | 比亚迪股份有限公司 | A sprayable glue solution, a preparing method thereof and a preparing method of injection moulding products with inserts |
| CN104745124B (en) * | 2013-12-27 | 2016-10-26 | 比亚迪股份有限公司 | Sprayable glue and preparation method thereof and the preparation method of the injecting products with inserts |
| CN105131876A (en) * | 2015-10-19 | 2015-12-09 | 深圳市惠尔特实业有限公司 | Low-flammability aerosol adhesive |
| CN105623563A (en) * | 2016-03-30 | 2016-06-01 | 光山县博正树脂有限公司 | Environment-friendly film mulching glue and preparation method thereof |
| CN105802554A (en) * | 2016-03-30 | 2016-07-27 | 光山县博正树脂有限公司 | Transparent all-purpose adhesive and preparation method thereof |
| CN105820700A (en) * | 2016-06-06 | 2016-08-03 | 广东莱雅化工有限公司 | High-flash-point gloss silver aerial fog spraying paint and preparation method thereof |
| CN106753093A (en) * | 2016-12-23 | 2017-05-31 | 上海康达新能源材料有限公司 | A kind of aerosol photopolymer coating and preparation method thereof |
| CN110041883A (en) * | 2019-05-08 | 2019-07-23 | 王锦云 | A kind of pipe protection aerosol photopolymer coating and preparation method thereof |
| CN110041883B (en) * | 2019-05-08 | 2020-07-28 | 王锦云 | Aerosol spray for pipeline protection and preparation method thereof |
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| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Open date: 20081029 |