CN105623563A - Environment-friendly film mulching glue and preparation method thereof - Google Patents
Environment-friendly film mulching glue and preparation method thereof Download PDFInfo
- Publication number
- CN105623563A CN105623563A CN201610192743.2A CN201610192743A CN105623563A CN 105623563 A CN105623563 A CN 105623563A CN 201610192743 A CN201610192743 A CN 201610192743A CN 105623563 A CN105623563 A CN 105623563A
- Authority
- CN
- China
- Prior art keywords
- parts
- environmental protection
- resin
- laminated adhesive
- protection laminated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to glue, particularly to a mulching film suitable for various types of aluminium profiles, and disclose an environment-friendly film mulching glue which can ensure luster of the aluminium products in long term and causes no influence on the surfaces of the aluminium products as well as a preparation method of the environment-friendly film mulching glue. The environment-friendly film mulching glue is prepared by mixing the following raw materials in parts by weight: 90-110 parts of 6# solvent oil, 20-32 parts of fine methyl ester, 68-79 parts of acetic ether, 110-130 parts of styrene-isoprene-styrene block copolymer, 15-23 parts of aromatic resin, 55-67 parts of cycloaliphatic resin, and 3-7 parts of an anti-aging agent. The film mulching glue is good in product viscidity, high-temperature resistant, colorless and transparent, and non-toxic and environment-friendly, the film mulching glue can be used by machine operation or hand brushing, and coats one surface, the operation is simple and convenient, the lustrous surfaces of the aluminium profiles can be completely protected, the product quality is ensured, and the preparation method is simple.
Description
Technical field
The present invention relates to a kind of glue, particularly relate to a kind of overlay film being applicable to all kinds aluminium, section bar, the gloss of guarantee aluminium, and the environmental protection laminated adhesive that surface is not had any impact for a long time and its preparation method.
Background technology
At present, what the protection of aluminium profiles on market, Surface of profile was suitable for is non-setting adhesive, and its deficiency is: viscosity is low, easily aging, easily come off, cause aluminium material surface to damage.
Summary of the invention
It is an object of the invention to overcome deficiency of the prior art; and a kind of environmental protection laminated adhesive and its preparation method are provided; its viscosity is good, high temperature resistant, water white transparency, asepsis environment-protecting; cross machine operation or hand brush; one side gluing, easy and simple to handle, it is possible to intactly to protect the surface luster of aluminium profiles, product forms; guarantee quality product, and its preparation method is simple.
The technical solution adopted in the present invention: a kind of environmental protection laminated adhesive, it is characterized in that: it is that the mixed raw material by following weight part number is standby and become, 6# solvent oil 90-110 part, essence methyl esters 20-32 part, vinyl acetic monomer 68-79 part, styrene isoprene styrene block copolymer (SIS) 110-130 part, aromatic resin 15-23 part, alicyclic resin 55-67 part, anti-aging agent 3-7 part.
Preferably, a kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight part number is standby and become, 6# solvent oil 95-102 part, essence methyl esters 23-28 part, vinyl acetic monomer 70-78 part, styrene isoprene styrene block copolymer (SIS) 118-127 part, aromatic resin 17-22 part, alicyclic resin 58-63 part, anti-aging agent 4-6 part.
Preferably, a kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight part number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 125 parts, aromatic resin 20 parts, alicyclic resin 60 parts, 5 parts, anti-aging agent.
Above-mentioned aromatic resin is specially P580 tackifying resin.
Above-mentioned alicyclic resin is alicyclic hydrocarbon resin, is specially Exxon Mobil Escorez5400 series petroleum resin.
Above-mentioned anti-aging agent is BHT.
The preparation method of a kind of above-mentioned environmental protection laminated adhesive, it is characterized in that: comprise the following steps: first toward suction 6# solvent oil in stirring tank, essence formicester, ethyl acetate, then electric blender is opened, speed governing to 60 rev/min, add styrene isoprene styrene block copolymer (SIS), aromatic resin, alicyclic resin, afterwards motor speed is adjusted to 800 revs/min, stirs and add anti-aging agent after 3 hours, finally carry out sampling test.
The useful effect of the present invention: environmental protection laminated adhesive product water white transparency of the present invention, asepsis environment-protecting, viscosity are good, high temperature resistant, crosses machine operation or hand brush, one side gluing, easy and simple to handle, the surface luster of aluminium profiles, product forms, it is ensured that quality product, and its preparation method is simple.
Embodiment
Embodiment 1
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 125 parts, aromatic resin 20 parts, alicyclic resin 60 parts, 5 parts, anti-aging agent.
The preparation method of a kind of above-mentioned environmental protection laminated adhesive, comprise the following steps: first toward suction 6# solvent oil in stirring tank, essence formicester, ethyl acetate, then electric blender is opened, speed governing to 60 rev/min, add styrene isoprene styrene block copolymer (SIS), aromatic resin, alicyclic resin, afterwards motor speed is adjusted to 800 revs/min, stirs and add anti-aging agent after 3 hours, finally carry out sampling test.
Embodiment 2
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 95 parts, essence methyl esters 23 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 17 parts, alicyclic resin 58 parts, 4 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 3
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 102 parts, essence methyl esters 28 parts, vinyl acetic monomer 78 parts, styrene isoprene styrene block copolymer (SIS) 127 parts, aromatic resin 22 parts, alicyclic resin 63 parts, 6 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 4
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 90 parts, essence methyl esters 20 parts, vinyl acetic monomer 68 parts, styrene isoprene styrene block copolymer (SIS) 110 parts, aromatic resin 15 parts, alicyclic resin 55 parts, 3 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 5
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 110 parts, essence methyl esters 32 parts, vinyl acetic monomer 79 parts, styrene isoprene styrene block copolymer (SIS) 130 parts, aromatic resin 23 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 6
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 17 parts, alicyclic resin 58 parts, 4 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 7
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 127 parts, aromatic resin 22 parts, alicyclic resin 63 parts, 6 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 8
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 110 parts, aromatic resin 15 parts, alicyclic resin 55 parts, 3 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 9
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 130 parts, aromatic resin 23 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 10
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 95 parts, essence methyl esters 23 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 22 parts, alicyclic resin 63 parts, 6 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 11
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 95 parts, essence methyl esters 23 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 15 parts, alicyclic resin 55 parts, 3 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 12
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 95 parts, essence methyl esters 23 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 23 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 13
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 102 parts, essence methyl esters 28 parts, vinyl acetic monomer 78 parts, styrene isoprene styrene block copolymer (SIS) 127 parts, aromatic resin 22 parts, alicyclic resin 63 parts, 6 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 14
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 102 parts, essence methyl esters 28 parts, vinyl acetic monomer 78 parts, styrene isoprene styrene block copolymer (SIS) 110 parts, aromatic resin 15 parts, alicyclic resin 55 parts, 3 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 15
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 102 parts, essence methyl esters 28 parts, vinyl acetic monomer 78 parts, styrene isoprene styrene block copolymer (SIS) 130 parts, aromatic resin 23 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 16
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 17 parts, alicyclic resin 63 parts, 6 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 17
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 17 parts, alicyclic resin 55 parts, 3 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 18
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 17 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 19
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 78 parts, styrene isoprene styrene block copolymer (SIS) 127 parts, aromatic resin 15 parts, alicyclic resin 55 parts, 3 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 20
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 78 parts, styrene isoprene styrene block copolymer (SIS) 127 parts, aromatic resin 23 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 21
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 110 parts, aromatic resin 15 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 22
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 95 parts, essence methyl esters 23 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 127 parts, aromatic resin 22 parts, alicyclic resin 55 parts, 3 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 23
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 95 parts, essence methyl esters 23 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 127 parts, aromatic resin 22 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 24
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 22 parts, alicyclic resin 63 parts, 3 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 25
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 118 parts, aromatic resin 22 parts, alicyclic resin 63 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 26
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 95 parts, essence methyl esters 28 parts, vinyl acetic monomer 78 parts, styrene isoprene styrene block copolymer (SIS) 110 parts, aromatic resin 15 parts, alicyclic resin 67 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
Embodiment 27
A kind of environmental protection laminated adhesive, it is that the mixed raw material by following weight kilogram number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 70 parts, styrene isoprene styrene block copolymer (SIS) 127 parts, aromatic resin 22 parts, alicyclic resin 55 parts, 7 parts, anti-aging agent.
The preparation method of a kind of environmental protection laminated adhesive is identical with the preparation method of environmental protection laminated adhesive in embodiment 1.
In all embodiments of the present invention, aromatic resin is all P580 tackifying resin; Alicyclic resin is alicyclic hydrocarbon resin, is specially Exxon Mobil Escorez5400 series petroleum resin; Anti-aging agent is BHT.
The anti-aging agent used in above-mentioned the present invention is BHT, styrene isoprene styrene block copolymer (SIS) D-1161P rises in the section that styrene isoprene styrene block copolymer (SIS) adopts, styrene content is 15, diblock content is 19, synthetic polyisoprene content is 85, has special excellent properties, adheres to and puts forth effort by force, hardness: 37A, suitable medical sanitary product rank. Styrene isoprene styrene block copolymer (SIS) clinging power is strong, is the main raw material of melt pressure sensitive viscose binder, coating, Solvent Adhesive, modifying plastics goods etc. It it is a kind of novel thermoplastic elastic rubber bodies. Because of its feature that to have thermoplasticity, snappiness, melting index and soltion viscosity low, good with aromatic resin consistency. Can extensively for fields such as this property of tackiness agent, coating, plastics and pitch. Alicyclic resin refers to Exxon Mobil Escorez5400 series petroleum resin Escorez 5400 series, (ethylene vinyl acetate is comprised with multiple polymer, styrene analog thermoplastic elastomer (styrene isoprene styrene block copolymer (SIS), SBS, SEBS), metallocene-polyolefin and polyalphaolefin) good compatibility. In addition, resin is the favorable substitutes of water-based acrylic product, has remarkable initial bonding strength; Aromatic resin adopts P580 tackifying resin, it is aromatic resin and the toughener of a series of aromatic series modification, there is very shallow color and luster and extraordinary color stability, can mix with multiple elastomerics and resin, dissolve in multiple different solvent, can be widely used in various tackiness agent.
At present, the weak yellow liquid that laminated adhesive traditional on market is unified on color and luster, a large amount of rosin is used to do starting material, its poor heat resistance (rosin starts to dissolve at about 40 DEG C) ageing-resistant ability (after adding a large amount of rosin, product just there will be powder phenomenon-tion in air-dry latter about 40 days), the P580 tackifying resin of the present invention, Exxon Mobil Escorez5400 series petroleum resin after tested its resistance toheat reach 100 DEG C, styrene isoprene styrene block copolymer (SIS) has good resistance of aging simultaneously, three kinds combine after, there will not be within 1 year because of coming unglued of causing of high temperature and because the time is after the aging of product problem caused for a long time. in color and luster, laminated adhesive of the present invention is transparent color liquid, at aluminium, uses and can not leave obvious vestige above glass. simultaneously owing to the main Tackifier materials of the most of laminated adhesive in market uses rosin so that it is viscosity is excessively strong, causes glue to be bonded at material surface, to cleaning inconvenience later, and laminated adhesive viscosity of the present invention is moderate, there will not be and clings material surface phenomenon. simultaneously laminated adhesive of the present invention is more of a specified duration in the open hour, it is possible to what carry out repeatedly on material surface is bonding. realize the effect of " not doing ". traditional viscose glue can only once bond.
Claims (7)
1. an environmental protection laminated adhesive, it is characterized in that: it is that the mixed raw material by following weight part number is standby and become, 6# solvent oil 90-110 part, essence methyl esters 20-32 part, vinyl acetic monomer 68-79 part, styrene isoprene styrene block copolymer (SIS) 110-130 part, aromatic resin 15-23 part, alicyclic resin 55-67 part, anti-aging agent 3-7 part.
2. environmental protection laminated adhesive according to claim 1, it is characterized in that: it is that the mixed raw material by following weight part number is standby and become, 6# solvent oil 95-102 part, essence methyl esters 23-28 part, vinyl acetic monomer 70-78 part, styrene isoprene styrene block copolymer (SIS) 118-127 part, aromatic resin 17-22 part, alicyclic resin 58-63 part, anti-aging agent 4-6 part.
3. environmental protection laminated adhesive according to claim 1, it is characterized in that: it is that the mixed raw material by following weight part number is standby and become, 6# solvent oil 100 parts, essence methyl esters 25 parts, vinyl acetic monomer 75 parts, styrene isoprene styrene block copolymer (SIS) 125 parts, aromatic resin 20 parts, alicyclic resin 60 parts, 5 parts, anti-aging agent.
4. environmental protection laminated adhesive according to claim 1 or 2 or 3, it is characterised in that: described aromatic resin is specially P580 tackifying resin.
5. environmental protection laminated adhesive according to claim 1 or 2 or 3, it is characterised in that: described alicyclic resin is alicyclic hydrocarbon resin, is specially Exxon Mobil Escorez5400 series petroleum resin.
6. environmental protection laminated adhesive according to claim 1 or 2 or 3, it is characterised in that: described anti-aging agent is BHT.
7. the preparation method of environmental protection laminated adhesive as described in an item as arbitrary in claim 1-6, it is characterized in that: comprise the following steps: first toward No. 6 solvent oils of suction in stirring tank, essence formicester, ethyl acetate, then electric blender is opened, speed governing to 60 rev/min, add styrene isoprene styrene block copolymer (SIS), aromatic resin, alicyclic resin, afterwards motor speed is adjusted to 800 revs/min, stirs and add anti-aging agent after 3 hours, finally carry out sampling test.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610192743.2A CN105623563A (en) | 2016-03-30 | 2016-03-30 | Environment-friendly film mulching glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610192743.2A CN105623563A (en) | 2016-03-30 | 2016-03-30 | Environment-friendly film mulching glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105623563A true CN105623563A (en) | 2016-06-01 |
Family
ID=56038927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610192743.2A Pending CN105623563A (en) | 2016-03-30 | 2016-03-30 | Environment-friendly film mulching glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105623563A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398608A (en) * | 2016-09-30 | 2017-02-15 | 光山县博正树脂有限公司 | Runway-specialized joint sealant and preparation method thereof |
| CN106433378A (en) * | 2016-09-30 | 2017-02-22 | 光山县博正树脂有限公司 | Glue special for color steel tile protection and preparation method thereof |
| CN111944463A (en) * | 2020-09-04 | 2020-11-17 | 上海路嘉胶粘剂有限公司 | Pressure-sensitive hot melt adhesive for sealing high-low temperature resistant PE express bag and preparation method thereof |
| CN112210343A (en) * | 2020-09-21 | 2021-01-12 | 太仓港亨得蕾实业有限公司 | Benzene-free laminated adhesive and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1181779A (en) * | 1995-04-03 | 1998-05-13 | 埃克森化学专利公司 | Low viscosity hot melt pressure sensitive adhesive compsns. |
| CN101294049A (en) * | 2008-06-20 | 2008-10-29 | 中山市三和气雾有限公司 | Aerosol photopolymer coating |
| CN102277112A (en) * | 2011-05-23 | 2011-12-14 | 波士胶芬得利（中国）粘合剂有限公司 | Wax-containing hot melt adhesive and disposable absorbent product |
| CN103555267A (en) * | 2013-11-07 | 2014-02-05 | 湖南神力铃胶粘剂制造有限公司 | Laminated paper sealing adhesive used in fireworks and packaging industries and preparation method thereof |
| CN105315930A (en) * | 2014-06-11 | 2016-02-10 | 中国石油化工股份有限公司 | Styrene-type thermoplastic elastomer laminating adhesive emulsion and preparation method thereof |
-
2016
- 2016-03-30 CN CN201610192743.2A patent/CN105623563A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1181779A (en) * | 1995-04-03 | 1998-05-13 | 埃克森化学专利公司 | Low viscosity hot melt pressure sensitive adhesive compsns. |
| CN101294049A (en) * | 2008-06-20 | 2008-10-29 | 中山市三和气雾有限公司 | Aerosol photopolymer coating |
| CN102277112A (en) * | 2011-05-23 | 2011-12-14 | 波士胶芬得利（中国）粘合剂有限公司 | Wax-containing hot melt adhesive and disposable absorbent product |
| CN103555267A (en) * | 2013-11-07 | 2014-02-05 | 湖南神力铃胶粘剂制造有限公司 | Laminated paper sealing adhesive used in fireworks and packaging industries and preparation method thereof |
| CN105315930A (en) * | 2014-06-11 | 2016-02-10 | 中国石油化工股份有限公司 | Styrene-type thermoplastic elastomer laminating adhesive emulsion and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘武辉: "《纸包装印刷技术》", 31 January 2003, 化学工业出版社 * |
| 李子东等: "《现代胶粘技术手册》", 31 January 2002, 新时代出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398608A (en) * | 2016-09-30 | 2017-02-15 | 光山县博正树脂有限公司 | Runway-specialized joint sealant and preparation method thereof |
| CN106433378A (en) * | 2016-09-30 | 2017-02-22 | 光山县博正树脂有限公司 | Glue special for color steel tile protection and preparation method thereof |
| CN111944463A (en) * | 2020-09-04 | 2020-11-17 | 上海路嘉胶粘剂有限公司 | Pressure-sensitive hot melt adhesive for sealing high-low temperature resistant PE express bag and preparation method thereof |
| CN112210343A (en) * | 2020-09-21 | 2021-01-12 | 太仓港亨得蕾实业有限公司 | Benzene-free laminated adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105623563A (en) | Environment-friendly film mulching glue and preparation method thereof | |
| DE69714327T2 (en) | Star-shaped styrene-isoprene-styrene containing pressure-sensitive adhesive for labels | |
| CN102181248B (en) | Hot-melt pressure-sensitive adhesive for polyethylene materials and preparation method thereof | |
| CN103805112B (en) | Environment-friendly hot-melt pressure sensitive adhesive that can spray and preparation method thereof | |
| CN103361012B (en) | A kind of applicable wide HDPE self-adhesive coiled material hot-fusible pressure-sensitive adhesive and preparation method thereof | |
| CN103351833B (en) | A kind of preparation method of liquid strippable glue for surface protection film | |
| CN103805098B (en) | Environmental-friendhot hot melt adhesive that can spray and preparation method thereof | |
| CN103333650B (en) | A kind of melt pressure sensitive type plaster substrate glue | |
| KR20030076924A (en) | Premixes and Method of Preparing Adhesives and Caulks from Premixes | |
| CN106458755A (en) | High performance water-based adhesion compositions and applications | |
| CN103102854B (en) | High temperature resistance hot-melt pressure-sensitive adhesive | |
| CN103320067B (en) | For quick-binding hot-fusible pressure-sensitive adhesive and the preparation method of express delivery waterproof bag | |
| CN101818034B (en) | Alcohol-soluble decorative adhesive and preparation method thereof | |
| CN110437795A (en) | A kind of hot melt adhesive and preparation method thereof | |
| CN111019559A (en) | EVA hot melt adhesive for rapid box sealing and preparation method thereof | |
| CN102786898A (en) | Hot melt adhesive composition for carpet skid resistance and preparation method of hot melt adhesive composition | |
| CN104762034B (en) | Low VOC polyacrylate pressure-sensitive sticks agent and preparation method thereof | |
| CN104293255B (en) | A kind of high glue strong HDPE self-adhesive coiled material hot-fusible pressure-sensitive adhesive and preparation method thereof | |
| CN110105903A (en) | Low smell low fogging eco-friendly car melt pressure sensitive glue composition and preparation method thereof | |
| CN110437798B (en) | Adhesive wax for packaging and preparation method and application thereof | |
| US20120316260A1 (en) | High-strength glue stick formulation with color indicator | |
| WO2018184198A1 (en) | Ultra removable hotmelt and label containing same | |
| CN105802554A (en) | Transparent all-purpose adhesive and preparation method thereof | |
| CN106520031A (en) | Environment-friendly acrylate adhesive and preparation process thereof | |
| CN103361011B (en) | A kind of adhesive compound and a kind of joint sealing sealing tape |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160601 |
|
| RJ01 | Rejection of invention patent application after publication |