CN100357384C - Chloroprene rubber type flame-retardant spray adhesive and process for preparing same - Google Patents
Chloroprene rubber type flame-retardant spray adhesive and process for preparing same Download PDFInfo
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- CN100357384C CN100357384C CNB2006100347652A CN200610034765A CN100357384C CN 100357384 C CN100357384 C CN 100357384C CN B2006100347652 A CNB2006100347652 A CN B2006100347652A CN 200610034765 A CN200610034765 A CN 200610034765A CN 100357384 C CN100357384 C CN 100357384C
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- chloroprene rubber
- spray adhesive
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- retardant spray
- flame
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Abstract
The present invention relates to neoprene type flame-retardant spray adhesive and a preparation process thereof, and is characterized in that the chloroprene rubber type flame-retardant spray adhesive is composed of dichloromethane, a 6# oil solvent, toluene, rosin, terpene resin, triphenyl phosphate, chloroparaffin and neoprene. The flame-retardant spray adhesive of the present invention is prepared by that by a method of stirring, the rosin, the terpene resin and the triphenyl phosphate are completely dissolved in a mixed solvent composed of the dichloromethane, the 6# oil solvent and the toluene until a homogeneous transparent solution is formed; finally, the neoprene is added to the homogeneous transparent solution and is continuously stirred at normal temperature until completely dissolved. The flame-retardant spray adhesive of the present invention has the advantages of outstanding performance of fire retardance, favorable adhesiveness and high stability of products.
Description
Technical field
The present invention relates to a kind of tackiness agent, relate to a kind of chloroprene rubber type flame-retardant spray adhesive and preparation method thereof specifically.
Background technology
Spray glue is a kind of infant industry tackiness agent that development in recent years is come out.It has suitable viscosity, bonding force and suitable time of drying, can utilize spray gun to be sprayed on the adherend surface, forms uniform adhesive linkage.Spray glue through suitably dry, by sticking face pressing, has just been finished adhesion process after spraying.Compare with technique for sticking such as roll-in, brushings, consumption glue amount is little, and applying glue is even, uses more and more widely.
Spray glue is mainly used in the bonding of materials such as sponge, leather, leatheroid and timber.These materials are generally organism, easily burning.And their goods as furniture, case and bag, indoor decoration etc., often have harsh requirement to flame retardant properties.The flame retardant properties of spray glue has very big relation to the flame retardant resistance of goods.As raw materials for production, More and more factories, especially some export enterprises have proposed fire-retardant requirement to spray glue.
Spray glue product mainly contains two big classes at present.One class is a SBS type spray glue, is main raw material with the SBS Thermoplastic Elastomer, and cost is low, and tack is good.Another kind of is neoprene type spray glue, is main raw material with the chloroprene rubber, the bonding strength height, and temperature tolerance is good.Document [Chen Hui, the research of no triphen solvent-borne type neoprene spray glue, Fujian chemical industry, 2001,3:16-18] has been described the method for preparing neoprene spray glue.Yet because chloroprene rubber is easy to burning, oxygen index is lower, and after spray glue was applied to by bonding object, solvent evaporates finished, and the residual chloroprene rubber component that plays main adhesive effect can not suppress combustion processes, can't play fire retardation.
Summary of the invention
The object of the present invention is to provide a kind of chloroprene rubber type flame-retardant spray adhesive; Another purpose provides the preparation method of this spray glue.
We adopt nonflammable polymer as main raw material, and add fire retardant triphenylphosphate and clorafin, and the spray glue that obtains spraying back flame retardant properties is outstanding, can reduce disaster hidden-trouble, helps security against fire, thereby realizes purpose of the present invention.
Chloroprene rubber type flame-retardant spray adhesive provided by the invention, form by following compositions according to the mass fraction:
6～14 parts of methylene dichloride
26～46 parts of No. 6 solvent oils
8～18 parts of toluene
Rosin 10～18
1～10 part of terpine resin
1～10 part of triphenylphosphate
1～13 part of clorafin
5～19 parts of chloroprene rubbers
The preparation method of chloroprene rubber type flame-retardant spray adhesive provided by the invention may further comprise the steps:
(1) proportionally prepare methylene dichloride, No. 6 solvent oils and toluene stir under the normal temperature;
(2) in step (1) prepared solvent, proportionally add rosin, terpine resin, triphenylphosphate and clorafin stir up to dissolving fully, form the solution of transparent and homogeneous;
(3) add chloroprene rubber in the solution that step (2) obtains, normal temperature constantly stirs down, dissolves fully up to chloroprene rubber, promptly obtains flame-retardant spray adhesive.
The churning time of step (2) was generally 0.5～2 hour; The churning time of step (3) was generally 2～5 hours.
The major advantage of flame-retardant spray adhesive of the present invention comprises the following aspects:
(1) flame retardant properties is outstanding: since added can with the compatible fire retardant of spray peptizing agent-rubbery system, flame retardant effect is obvious, oxygen index can reach 23～24, can reduce disaster hidden-trouble, helps security against fire;
(2) cementability is good: have higher bonding strength, can satisfy the requirement of spraying operation commonly used;
(3) product stability is good: owing to consider the consistency of fire retardant and solvent-rubbery system especially in its preparation, so not stratified, shelf-stability is good.
Embodiment
Following examples are to further specify of the present invention, are not limitations of the present invention.
Embodiment 1
With 10 parts of methylene dichloride (quality, down with), 36 parts of No. 6 solvent oils stir under 13 parts of normal temperature of toluene.In solvent, add 14 parts of rosin, 5 parts of terpine resins, 5 parts of triphenylphosphates, clorafin stirred 1 hour for 7 parts, up to dissolving fully, formed the solution of transparent and homogeneous.Add 10 parts of chloroprene rubbers in solution, normal temperature constantly stirred 3 hours down, dissolved fully up to chloroprene rubber.Promptly obtain chloroprene rubber type flame-retardant spray adhesive, recording oxygen index is 23.5.
Embodiment 2
With 7 parts of methylene dichloride, 36 parts of No. 6 solvent oils stir under 13 parts of normal temperature of toluene.In solvent, add 10 parts of rosin, 2 parts of terpine resins, 4 parts of triphenylphosphates, clorafin stirred 0.8 hour for 3 parts, up to dissolving fully, formed the solution of transparent and homogeneous.Add 8 parts of chloroprene rubbers in solution, normal temperature constantly stirred 2.5 hours down, dissolved fully up to chloroprene rubber.Promptly obtain chloroprene rubber type flame-retardant spray adhesive, recording oxygen index is 24.
Embodiment 3
With 12 parts of methylene dichloride, 40 parts of No. 6 solvent oils stir under 10 parts of normal temperature of toluene.In solvent, add 14 parts of rosin, 9 parts of terpine resins, 4 parts of triphenylphosphates, clorafin stirred 1.5 hours for 7 parts, up to dissolving fully, formed the solution of transparent and homogeneous.Add 18 parts of chloroprene rubbers in solution, normal temperature constantly stirred 4 hours down, dissolved fully up to chloroprene rubber.Promptly obtain chloroprene rubber type flame-retardant spray adhesive, recording oxygen index is 23.8.
Claims (3)
1. chloroprene rubber type flame-retardant spray adhesive, form by following compositions according to the mass fraction:
6～14 parts of methylene dichloride
26～46 parts of No. 6 solvent oils
8～18 parts of toluene
Rosin 10～18
1～10 part of terpine resin
1～10 part of triphenylphosphate
1～13 part of clorafin
5～19 parts of chloroprene rubbers.
2. the preparation method of the described chloroprene rubber type flame-retardant spray adhesive of claim 1 may further comprise the steps:
(1) prepare methylene dichloride according to described ratio, No. 6 solvent oils and toluene stir under the normal temperature;
(2) in step (1) prepared solvent, add rosin according to described ratio, terpine resin, triphenylphosphate and clorafin stir up to dissolving fully, form the solution of transparent and homogeneous;
(3) add chloroprene rubber in the solution that step (2) obtains, normal temperature constantly stirs down, dissolves fully up to chloroprene rubber, promptly obtains flame-retardant spray adhesive.
3. according to the preparation method of a kind of chloroprene rubber type flame-retardant spray adhesive of claim 2, wherein the churning time in the step (2) is 0.5～2 hour; The churning time of step (3) is 2～5 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100347652A CN100357384C (en) | 2006-03-31 | 2006-03-31 | Chloroprene rubber type flame-retardant spray adhesive and process for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100347652A CN100357384C (en) | 2006-03-31 | 2006-03-31 | Chloroprene rubber type flame-retardant spray adhesive and process for preparing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1827723A CN1827723A (en) | 2006-09-06 |
| CN100357384C true CN100357384C (en) | 2007-12-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100347652A Expired - Fee Related CN100357384C (en) | 2006-03-31 | 2006-03-31 | Chloroprene rubber type flame-retardant spray adhesive and process for preparing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100357384C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007066765A1 (en) * | 2005-12-09 | 2007-06-14 | Denki Kagaku Kogyo Kabushiki Kaisha | Adhesive composition and adhesive using same |
| CN109504314A (en) * | 2018-11-14 | 2019-03-22 | 广东大友建材科技有限公司 | A kind of flame-retarding and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3332903A (en) * | 1962-04-27 | 1967-07-25 | Uniroyal Inc | Rubber adhesive for application from spray bomb |
| GB1211662A (en) * | 1968-02-26 | 1970-11-11 | Ppg Industries Inc | Adhesive compositions |
| CN1058416A (en) * | 1991-08-09 | 1992-02-05 | 宜昌市葛洲坝粘合剂厂 | Fire retardant adhesive and manufacture method thereof |
| CN1063120A (en) * | 1991-05-16 | 1992-07-29 | 湖北省国营后湖农场化工厂 | Burning-resistant type adhesive |
| CN1206732A (en) * | 1997-07-30 | 1999-02-03 | 孙明 | Chlorobutyl benzene-free fire-retarded universal glue |
| CN1243853A (en) * | 1998-07-30 | 2000-02-09 | 普雷马克Rwp控股公司 | Adhesive with high solid content |
| CN1342734A (en) * | 2000-09-11 | 2002-04-03 | 武汉亚特新材料科技有限公司 | Process for preparing refractory carboxyl chlorobutadiene adhesive for spraying |
-
2006
- 2006-03-31 CN CNB2006100347652A patent/CN100357384C/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3332903A (en) * | 1962-04-27 | 1967-07-25 | Uniroyal Inc | Rubber adhesive for application from spray bomb |
| GB1211662A (en) * | 1968-02-26 | 1970-11-11 | Ppg Industries Inc | Adhesive compositions |
| CN1063120A (en) * | 1991-05-16 | 1992-07-29 | 湖北省国营后湖农场化工厂 | Burning-resistant type adhesive |
| CN1058416A (en) * | 1991-08-09 | 1992-02-05 | 宜昌市葛洲坝粘合剂厂 | Fire retardant adhesive and manufacture method thereof |
| CN1206732A (en) * | 1997-07-30 | 1999-02-03 | 孙明 | Chlorobutyl benzene-free fire-retarded universal glue |
| CN1243853A (en) * | 1998-07-30 | 2000-02-09 | 普雷马克Rwp控股公司 | Adhesive with high solid content |
| CN1342734A (en) * | 2000-09-11 | 2002-04-03 | 武汉亚特新材料科技有限公司 | Process for preparing refractory carboxyl chlorobutadiene adhesive for spraying |
Non-Patent Citations (2)
| Title |
|---|
| 无三苯溶剂型氯丁喷胶的研究 陈辉.福建化工，第2001年第3期 2001 * |
| 氯丁橡胶胶粘剂的发展方向 李广宇，于敏，李子东.粘接，第24卷第6期 2003 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1827723A (en) | 2006-09-06 |
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| C14 | Grant of patent or utility model | ||
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20071226 Termination date: 20200331 |