CN109504314A - A kind of flame-retarding and preparation method thereof - Google Patents
A kind of flame-retarding and preparation method thereof Download PDFInfo
- Publication number
- CN109504314A CN109504314A CN201811356152.XA CN201811356152A CN109504314A CN 109504314 A CN109504314 A CN 109504314A CN 201811356152 A CN201811356152 A CN 201811356152A CN 109504314 A CN109504314 A CN 109504314A
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- Prior art keywords
- flame
- retarding
- weight
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- titanium
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J111/00—Adhesives based on homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of flame-retardings and preparation method thereof, the flame-retarding, it is raw material by using neoprene, Petropols, terpene resin, rosin resin, fire retardant, nano-titanium dioxide and hum silicon dioxide titanium, solvent naphtha and carries out weight proportion appropriate, under the synergistic effect of each raw material component, the flame-retarding being prepared through ad hoc approach, it is sticky strong, tensile resistance is strong, it has no irritating odor, and has the effect of fire protection flame retarding, ingredient performance is stablized.
Description
Technical field
The invention belongs to all-purpose adhesive technical fields, and in particular to a kind of flame-retarding and preparation method thereof.
Background technique
The method that the interior trim engineering of modern architecture largely uses bond processing, it can simply glue a variety of materials
It is attached to the surface mount dalle of concrete surface or different materials.And most glue in building interior trim engineering
Stick kind is Solution Chloroprene Rubber Adhesives (being commonly called as " all-purpose adhesive ").Typical case of the all-purpose adhesive in building has: by decorative panel,
Plasterboard, heat-barrier material etc. are pasted on ceiling or cement wall surface, bond ceramic tile, varnished cloth ground, plastic floor, paste window frame
And other seal bonds etc..The usual preparation process of all-purpose adhesive is will to plasticate or be kneaded neoprene to be dissolved in toluene equal solvent
In, it adds tackifying resin and other auxiliary agents through pre-reaction and is made, containing there are many inflammable and explosive component and to human body and environment
Harmful component.
Manufacturer's marketing method of country's all-purpose adhesive is at present: by manufacturer, provincial agency, city-level agency, county
Grade agency, retail trader, finally into user hand, from manufacturer into client's hand after a lot of bother, need to repeatedly transport, and country it is right
Transport inflammable explosive article has explicit stipulation, it is necessary to using transport inflammable explosive article special-purpose vehicle, and be equipped with security official and escort, because selling
Quotient's enquiry amount is few, is unable to carload freight, have to walk logistics part load, and domestic percent ninety-nine logistics does not have inflammable and explosive
Product special-purpose vehicle will result in car crash, jeopardize personal safety once unexpected fire explosion occurs.In use because of component
Volatilization also can bring harm to environment and health of human body, and therefore, exploitation flame-retarding is of great significance.
Summary of the invention
In order to solve the above problems existing in the present technology, it is good, highly-safe, right that the present invention provides a kind of flame retardant properties
The small flame-retarding and preparation method thereof of environmental pollution.
The technical scheme adopted by the invention is as follows:
A kind of flame-retarding, raw material components include:
Neoprene, 18-25 parts by weight；
Petropols, 4-6 parts by weight；
Terpene resin, 4-6 parts by weight；
Rosin resin, 8-15 parts by weight；
Fire retardant, 5-18 parts by weight；
The mixture of nano-titanium dioxide and hum silicon dioxide titanium, 1-4 parts by weight；
Solvent naphtha, 50-75 parts by weight.
The fire retardant is the mixture of nanmeter antimong trioxide and micron antimony oxide.
The molar ratio of the nanmeter antimong trioxide and micron antimony oxide is 1-2:1-2.
The molar ratio of the nano-titanium dioxide and hum silicon dioxide titanium is 1-2:1-2.
The solvent naphtha is aliphatic hydrocarbon.
The aliphatic hydrocarbon is C6-C8Aliphatic hydrocarbon.
The preparation method of the flame-retarding, includes the following steps:
(1) solvent naphtha is taken, neoprene is added in a heated condition, stirring makes to be sufficiently mixed uniformly；
(2) Petropols, terpene resin and rosin resin is added, carries out dispersing and dissolving under high speed agitation；
(3) it is eventually adding fire retardant, nano-titanium dioxide and hum silicon dioxide titanium, is dispersed under high speed agitation
Dissolution is to get the flame-retarding.
In step (1), the temperature of heating is 28-40 DEG C.
In step (2), carry out the high-speed stirred revolving speed be 1200-1800r/min, carry out the high-speed stirred when
Between be 1-3h.
In step (3), carry out the high-speed stirred revolving speed be 1200-1800r/min, carry out the high-speed stirred when
Between be 1-3h.
The invention has the benefit that
Flame-retarding of the present invention, by using neoprene, Petropols, terpene resin, rosin
Resin, fire retardant, nano-titanium dioxide and hum silicon dioxide titanium, solvent naphtha are raw material and carry out weight proportion appropriate, each
Under the synergistic effect of raw material components, the flame-retarding being prepared through ad hoc approach, viscosity is strong, tensile resistance
By force, it has no irritating odor, and has the effect of fire protection flame retarding, ingredient performance is stablized.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, technical solution of the present invention will be carried out below
Detailed description.Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art are obtained all without making creative work
Other embodiment belongs to the range that the present invention is protected.
1g is represented in following example with 1 parts by weight.
Embodiment 1
The present embodiment provides a kind of flame-retarding, raw material components include:
Neoprene, 18 parts by weight；
Petropols, 6 parts by weight；
Terpene resin, 4 parts by weight；
Rosin resin, 15 parts by weight；
The micron antimony oxide that fire retardant is the nanmeter antimong trioxide that partial size is 40nm and partial size is 1 μm according to mole
Than the mixture of 1:2 composition, 5 parts by weight；
What the hum silicon dioxide titanium that the nano-titanium dioxide and partial size that partial size is 40nm are 1 μm was formed according to molar ratio 1:2
Mixture, 4 parts by weight；
Hexane, 50 parts by weight.
The preparation method of the flame-retarding, includes the following steps:
(1) hexane is taken, neoprene is added under 28 DEG C of heating conditions, stirring makes to be sufficiently mixed uniformly；
(2) Petropols, terpene resin and rosin resin is added, is dispersed under the conditions of 1200r/min high-speed stirred
Dissolve 3h；
(3) it is eventually adding fire retardant, nano-titanium dioxide and hum silicon dioxide titanium, in 1200r/min high-speed stirred condition
Lower progress dispersing and dissolving 3h is to get the flame-retarding.
Embodiment 2
The present embodiment provides a kind of flame-retarding, raw material components include:
Neoprene, 25 parts by weight；
Petropols, 4 parts by weight；
Terpene resin, 6 parts by weight；
Rosin resin, 8 parts by weight；
The micron antimony oxide that fire retardant is the nanmeter antimong trioxide that partial size is 60nm and partial size is 1.2 μm is according to rubbing
You are than the mixture that 2:1 is formed, 18 parts by weight；
The hum silicon dioxide titanium that the nano-titanium dioxide and partial size that partial size is 60nm are 1.2 μm is formed according to molar ratio 2:1
Mixture, 1 parts by weight；
Heptane, 75 parts by weight.
The preparation method of the flame-retarding, includes the following steps:
(1) heptane is taken, neoprene is added under 40 DEG C of heating conditions, stirring makes to be sufficiently mixed uniformly；
(2) Petropols, terpene resin and rosin resin is added, is dispersed under the conditions of 1800r/min high-speed stirred
Dissolve 1h；
(3) it is eventually adding fire retardant, nano-titanium dioxide and hum silicon dioxide titanium, in 1800r/min high-speed stirred condition
Lower progress dispersing and dissolving 1h is to get the flame-retarding.
Embodiment 3
The present embodiment provides a kind of flame-retarding, raw material components include:
Neoprene, 22 parts by weight；
Petropols, 5 parts by weight；
Terpene resin, 5 parts by weight；
Rosin resin, 11 parts by weight；
The micron antimony oxide that fire retardant is the nanmeter antimong trioxide that partial size is 50nm and partial size is 1.1 μm is according to rubbing
You are than the mixture that 1:1 is formed, 11 parts by weight；
The hum silicon dioxide titanium that the nano-titanium dioxide and partial size that partial size is 50nm are 1.1 μm is formed according to molar ratio 1:1
Mixture, 2.5 parts by weight；
Octane, 60 parts by weight.
The preparation method of the flame-retarding, includes the following steps:
(1) octane is taken, neoprene is added under 34 DEG C of heating conditions, stirring makes to be sufficiently mixed uniformly；
(2) Petropols, terpene resin and rosin resin is added, is dispersed under the conditions of 1500r/min high-speed stirred
Dissolve 2h；
(3) it is eventually adding fire retardant, nano-titanium dioxide and hum silicon dioxide titanium, in 1500r/min high-speed stirred condition
Lower progress dispersing and dissolving 2h is to get the flame-retarding.
Embodiment 4
The present embodiment provides a kind of flame-retarding, raw material components include:
Neoprene, 21 parts by weight；
Petropols, 5 parts by weight；
Terpene resin, 5 parts by weight；
Rosin resin, 12 parts by weight；
The micron antimony oxide that fire retardant is the nanmeter antimong trioxide that partial size is 45nm and partial size is 1.1 μm is according to rubbing
You are than the mixture that 1:1 is formed, 12 parts by weight；
The hum silicon dioxide titanium that the nano-titanium dioxide and partial size that partial size is 55nm are 1.1 μm is formed according to molar ratio 1:1
Mixture, 2.5 parts by weight；
Hexane, 65 parts by weight.
The preparation method of the flame-retarding, includes the following steps:
(1) hexane is taken, neoprene is added under 32 DEG C of heating conditions, stirring makes to be sufficiently mixed uniformly；
(2) Petropols, terpene resin and rosin resin is added, is dispersed under the conditions of 1500r/min high-speed stirred
Dissolve 2h；
(3) it is eventually adding fire retardant, nano-titanium dioxide and hum silicon dioxide titanium, in 1500r/min high-speed stirred condition
Lower progress dispersing and dissolving 2h is to get the flame-retarding.
Comparative example 1
This comparative example provides a kind of all-purpose adhesive, and the difference with embodiment 3 is only that, does not add nano-titanium dioxide and micron
Titanium dioxide component.
Comparative example 2
This comparative example provides a kind of all-purpose adhesive, and the difference with embodiment 3 is only that, fire retardant is micron antimony oxide.
Experimental example
According to GB8624-2012 " construction material and classification of combustion properties of building materials and products " to 1-4 of the embodiment of the present invention and comparative example
The all-purpose adhesive that 1-2 is obtained carries out combustibility detection, testing result such as table 1.
The combustibility testing result of table 1- difference all-purpose adhesive sample
From table 1 it follows that the combustibility that all-purpose adhesive is made in the method for the present invention reaches A1 grades, there is good fire prevention
Flame retardant effect, wherein embodiment 3 is optimised combination due to every reaction condition, and the flame retardant property of gained all-purpose adhesive is best；And
The combustibility of all-purpose adhesive made from 2 method of comparative example 1 and comparative example is B grades, and flame retardant property is relatively poor, wherein comparative example 1
Due to there is no addition nano-titanium dioxide and hum silicon dioxide titanium component, flame retardant property worst.
All-purpose adhesive of the invention does not use the hazardous solvents such as benzene,toluene,xylene, and highly-safe, environmental pollution is small.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
1. a kind of flame-retarding, which is characterized in that raw material components include:
Neoprene, 18-25 parts by weight；
Petropols, 4-6 parts by weight；
Terpene resin, 4-6 parts by weight；
Rosin resin, 8-15 parts by weight；
Fire retardant, 5-18 parts by weight；
The mixture of nano-titanium dioxide and hum silicon dioxide titanium, 1-4 parts by weight；
Solvent naphtha, 50-75 parts by weight.
2. flame-retarding according to claim 1, which is characterized in that the fire retardant is the oxidation of nanometer three two
The mixture of antimony and micron antimony oxide.
3. flame-retarding according to claim 2, which is characterized in that the nanmeter antimong trioxide and micron
The molar ratio of antimony oxide is 1-2:1-2.
4. flame-retarding according to claim 1, which is characterized in that the nano-titanium dioxide and micron two
The molar ratio of titanium oxide is 1-2:1-2.
5. flame-retarding according to claim 1, which is characterized in that the solvent naphtha is aliphatic hydrocarbon.
6. flame-retarding according to claim 5, which is characterized in that the aliphatic hydrocarbon is C6-C8Aliphatic hydrocarbon.
7. the preparation method of any one of -6 flame-retardings according to claim 1, which is characterized in that including as follows
Step:
(1) solvent naphtha is taken, neoprene is added in a heated condition, stirring makes to be sufficiently mixed uniformly；
(2) Petropols, terpene resin and rosin resin is added, carries out dispersing and dissolving under high speed agitation；
(3) it is eventually adding fire retardant, nano-titanium dioxide and hum silicon dioxide titanium, carries out dispersing under high speed agitation molten
Solution is to get the flame-retarding.
8. preparation method according to claim 1, which is characterized in that in step (1), the temperature of heating is 28-40 DEG C.
9. preparation method according to claim 1, which is characterized in that in step (2), carry out the revolving speed of the high-speed stirred
For 1200-1800r/min, the time for carrying out the high-speed stirred is 1-3h.
10. preparation method according to claim 1, which is characterized in that in step (3), carry out turning for the high-speed stirred
Speed is 1200-1800r/min, and the time for carrying out the high-speed stirred is 1-3h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811356152.XA CN109504314A (en) | 2018-11-14 | 2018-11-14 | A kind of flame-retarding and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811356152.XA CN109504314A (en) | 2018-11-14 | 2018-11-14 | A kind of flame-retarding and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109504314A true CN109504314A (en) | 2019-03-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811356152.XA Pending CN109504314A (en) | 2018-11-14 | 2018-11-14 | A kind of flame-retarding and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112574695A (en) * | 2020-12-08 | 2021-03-30 | 安徽芨智生物科技有限公司 | Bletilla striata adhesive wallpaper powder and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1206732A (en) * | 1997-07-30 | 1999-02-03 | 孙明 | Chlorobutyl benzene-free fire-retarded universal glue |
| JP2002114957A (en) * | 2000-10-10 | 2002-04-16 | Bando Chem Ind Ltd | Adhesive for waterproof sheet and bonded structure of waterproof sheet |
| CN1827723A (en) * | 2006-03-31 | 2006-09-06 | 中国科学院广州化学研究所 | Chloroprene rubber type flame-retardant spray adhesive and process for preparing same |
-
2018
- 2018-11-14 CN CN201811356152.XA patent/CN109504314A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1206732A (en) * | 1997-07-30 | 1999-02-03 | 孙明 | Chlorobutyl benzene-free fire-retarded universal glue |
| JP2002114957A (en) * | 2000-10-10 | 2002-04-16 | Bando Chem Ind Ltd | Adhesive for waterproof sheet and bonded structure of waterproof sheet |
| CN1827723A (en) * | 2006-03-31 | 2006-09-06 | 中国科学院广州化学研究所 | Chloroprene rubber type flame-retardant spray adhesive and process for preparing same |
Non-Patent Citations (2)
| Title |
|---|
| 扈中武等: "二氧化钛对硅丙乳液防火涂料阻燃抑烟性能的影响", 《涂料工业》 * |
| 李子东等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112574695A (en) * | 2020-12-08 | 2021-03-30 | 安徽芨智生物科技有限公司 | Bletilla striata adhesive wallpaper powder and preparation method thereof |
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Application publication date: 20190322 |