CN106633899A - Environment-friendly plastic macromolecular nano additive with flame retarding function - Google Patents
Environment-friendly plastic macromolecular nano additive with flame retarding function Download PDFInfo
- Publication number
- CN106633899A CN106633899A CN201710013876.3A CN201710013876A CN106633899A CN 106633899 A CN106633899 A CN 106633899A CN 201710013876 A CN201710013876 A CN 201710013876A CN 106633899 A CN106633899 A CN 106633899A
- Authority
- CN
- China
- Prior art keywords
- parts
- antimony oxide
- antimony
- base material
- friendly plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the field of plastic materials, and in particular discloses an environment-friendly plastic macromolecular nano additive with a flame retarding function and a manufacturing method thereof. The environment-friendly plastic macromolecular nano additive is prepared from the following components in percentage by weight: 20 to 25 parts of organosilicon resin, 15 to 20 parts of vitrified microsphere, 30 to 35 parts of antimony trioxide ultrafine powder, 5 to 10 parts of quartz sand, 25 to 35 parts of scolecite, 30 to 40 parts of hollow glass microsphere, 5 to 10 parts of modified SiO2, 20 to 60 parts of a plastic carrier, 0.1 to 1.5 parts of a coupling agent, 1 to 7 parts of a plasticizer, 0.2 to 3 parts of a lubricant, 0.5 to 2.5 parts of an antioxygen, 0.1 to 4 parts of a dispersant and the like. The material prepared by the method does not cause environment pollution; oxygen in hydroxyl on the surfaces of the glass microspheres and carbon atoms in a base material of the material prepared by the method have very high affinity, and a rare earth compound with a very stable structure is generated. Excellent heat-preservation and heat-insulation performance and fireproof and anti-ageing performance of the base material are effectively added.
Description
Invention field
The invention belongs to plastic material field, concretely relates to a kind of environmentally-friendly plastic macromolecule with anti-flaming function
Nanometer additive its manufacture method.
Background technology
Masterbatch is by a high proportion of pigment or additive and thermoplastic resin, the coloring plastic of Jing fine dispersions
Agent, the resin selected by it has good wet and peptizaiton to colouring agent, and has good phase with material is colored
Capacitive.Masterbatch coloring is the coloring plastic method for most generally adopting now.The colouring agent for being scattered in carrier, with this Masterbatch color
Resin is used to manufacture plastic products after simply mixing.
At this stage, with expanding economy and the quickening of the process of Process of Urbanization Construction, Masterbatch consumption increases severely, while to it
Performance also has various requirement.Accordingly, it would be desirable to add additive protect to it, there is performance list in existing color masterbatch additive
One, the problem of flame retardant effect difference.
The content of the invention
To solve above-mentioned technical problem, the present invention provides a kind of addition of the environmentally-friendly plastic high molecular nanometer with anti-flaming function
Agent its manufacture method.To solve the problems, such as that flame retardant effect is reduced.
To reach above-mentioned purpose, the technical solution used in the present invention is：
A kind of environmentally-friendly plastic high molecular nanometer additive with anti-flaming function, it is characterised in that by weight percentage,
Including composition：Organic siliconresin 20-25 parts, glass bead 15-20 parts, antimony oxide superfine powder 30-35 part, quartz sand 5-10
Part, scolecite 25-35 parts, hollow glass micropearl 30-40 parts, modified SiO2 5-10 parts, plastic carrier 20-60 parts, coupling agent
0.1-1.5 parts, plasticizer 1-7 parts, lubricant 0.2-3 parts, antioxidant 0.5-2.5 parts, dispersant 0.1-4 parts；
The waterproofing agent is the mixture of octyltri-ethoxysilane and poly- MTES, and mass ratio is 3:
1。
The plastic carrier be biodegradable plastic carrier, the biodegradable plastic carrier be polyhydroxyalkanoate,
Appointing in poly- ethanedioic acid/butylene terephthalate, poly butylene succinate, PLA, PTT
Meaning is a kind of.
The modified SiO2 preparation methods are：To be directly added into CTAB in 70% polyether amine solution, the CTAB with it is poly-
The mass volume ratio of ether amines solution is：1g:30ml, CTAB are cetyl trimethyl ammonium, and CTAB flocculates to polyetheramine
Modified polyether amine aqueous solution is obtained with modified-reaction；Modified polyether amine aqueous solution is grafted and SiO2 tables with the mode of electric electrostatic spray
The ratio of face, the modified polyether amine aqueous solution and SiO2 is 10ml:1g.
The ultra-fine powder, preparation method thereof of the antimony oxide is：
1) 280～400 parts of antimony ore, 80～120 parts of anthracite, 50～100 parts of lime stone will be contained equal in stirrer for mixing
It is even, obtain compound；
2) by step 1) in the compound that obtains smelt at 1000～1180 DEG C, and successively oxidized room, expansion chamber, table
Cold pipe enters bagroom, obtains antimony oxide powder；
3) by step 2) in the antimony oxide powder that obtains with plasma generator as thermal source, Jing gasification oxidation-condensation methods,
Under 3600～7500 DEG C of high-temperature plasma jet, make antimony oxide powder all gasify, obtain gaseous oxidation antimony；
4) by step 3) in the gaseous oxidation antimony that obtains of gasification with inert gas quenching, gas temperature is declined rapidly, gas
Jing nucleation, crystal are grown up process detached with impurity after phase oxidation antimony elder generation, obtain antimony oxide superfine powder, wherein, three oxidations two
The granularity of antimony superfine powder is less than 0.25m；
5) step 4) in the encapsulation of weighing of the antimony oxide superfine powder for preparing preserve.
The dispersant is the one kind in Tissuemat E, pentaerythritol stearate and calcium stearate.
The manufacture method of described environmentally-friendly plastic high molecular nanometer base material, it is characterised in that comprise the following steps：
(1) will crush after organic siliconresin, glass bead, titanium dioxide, quartz sand mixing, cross 100-200 mesh sieves, as
Component A is standby；
(2) the antimony oxide superfine powder, the coupling agent are added in reactor, and at 90-110 DEG C, with
3000-5000r/min high-speed stirreds 15-35min obtain component B；
(3) then reduce kneading machine rotating speed, addition component A is pulverized and mixed after, then temperature drop is carried out to less than 70 DEG C
Cooling, carries out break process after cooling, material is obtained after screening.
Beneficial effects of the present invention：Material obtained in invention, the oxygen and base in the hydroxyl on glass microballoon surface
Carbon atom in material has very strong affinity, the highly stable rare earth compounding of generating structure.The present invention is environmentally friendly, pollution-free,
There is very strong dispersiveness in resin, not easy to change and coloring effect is good.Organic siliconresin, glass bead, titanium dioxide, stone
Sand mixing after crush, especially by part material component therein, effectively increase the base material with excellent thermal insulation separation
Hot property is with fire prevention ageing-resistant performance, hollowing cracking, intensity is not high, and environment-protecting asepsis, free from extraneous odour, light weight, thermal conductivity factor is low, protects
Warm stable performance, good freeze-thaw resistance and water resistance, Fire retardant grade is high, good cohesive force and shearing force, with outstanding
Cracking resistance resisting wind press capacity, not hollowing cracking, performance, the especially heat-insulating property such as intensity height are significantly improved.
Specific embodiment
Technical scheme of the present invention is further described with reference to specific embodiment.
Embodiment 1：
A kind of environmentally-friendly plastic high molecular nanometer additive with anti-flaming function, it is characterised in that by weight percentage,
Including composition：20 parts of organic siliconresin, 15 parts of glass bead, 30 parts of antimony oxide superfine powder, 5 parts of quartz sand, scolecite 25
Part, 30 parts of hollow glass micropearl, modified SiO25 parts, 20 parts of plastic carrier, 0.1 part of coupling agent, plasticizer 1-7 parts, lubricant
0.2 part, 0.5 part of antioxidant, 0.1 part of dispersant；
The waterproofing agent is the mixture of octyltri-ethoxysilane and poly- MTES, and mass ratio is 3:
1。
The plastic carrier be biodegradable plastic carrier, the biodegradable plastic carrier be polyhydroxyalkanoate,
Appointing in poly- ethanedioic acid/butylene terephthalate, poly butylene succinate, PLA, PTT
Meaning is a kind of.
The modified SiO2 preparation methods are：To be directly added into CTAB in 70% polyether amine solution, the CTAB with it is poly-
The mass volume ratio of ether amines solution is：1g:30ml, CTAB are cetyl trimethyl ammonium, and CTAB flocculates to polyetheramine
Modified polyether amine aqueous solution is obtained with modified-reaction；Modified polyether amine aqueous solution is grafted on into SiO2 tables with the mode of electric electrostatic spray
The ratio of face, the modified polyether amine aqueous solution and SiO2 is 10ml:1g.
The ultra-fine powder, preparation method thereof of the antimony oxide is：
1) 280 parts of antimony ore, 80 parts of anthracite, 50 parts of lime stone will be contained uniform in stirrer for mixing, will obtain compound；
2) by step 1) in the compound that obtains smelt at 1000 DEG C, and successively oxidized room, expansion chamber, air cooling pipe enter
Enter bagroom, obtain antimony oxide powder；
3) by step 2) in the antimony oxide powder that obtains with plasma generator as thermal source, Jing gasification oxidation-condensation methods,
Under 3600 DEG C of high-temperature plasma jet, make antimony oxide powder all gasify, obtain gaseous oxidation antimony；
4) by step 3) in the gaseous oxidation antimony that obtains of gasification with inert gas quenching, gas temperature is declined rapidly, gas
Jing nucleation, crystal are grown up process detached with impurity after phase oxidation antimony elder generation, obtain antimony oxide superfine powder, wherein, three oxidations two
The granularity of antimony superfine powder is less than 0.25m；
5) step 4) in the encapsulation of weighing of the antimony oxide superfine powder for preparing preserve.
The dispersant is the one kind in Tissuemat E, pentaerythritol stearate and calcium stearate.
The manufacture method of described environmentally-friendly plastic high molecular nanometer base material, it is characterised in that comprise the following steps：
(1) will crush after organic siliconresin, glass bead, titanium dioxide, quartz sand mixing, 100 mesh sieves are crossed, as component
A is standby；
(2) the antimony oxide superfine powder, the coupling agent are added in reactor, and at 90 DEG C, with 3000r/
Min high-speed stirreds 15min obtain component B；
(3) then reduce kneading machine rotating speed, addition component A is pulverized and mixed after, then temperature drop is carried out to less than 70 DEG C
Cooling, carries out break process after cooling, material is obtained after screening.
Embodiment 2：
A kind of environmentally-friendly plastic high molecular nanometer additive with anti-flaming function, it is characterised in that by weight percentage,
Including composition：25 parts of organic siliconresin, 20 parts of glass bead, 35 parts of antimony oxide superfine powder, 10 parts of quartz sand, scolecite 35
Part, 40 parts of hollow glass micropearl, modified 10 parts of SiO2,60 parts of plastic carrier, 1.5 parts of coupling agent, 7 parts of plasticizer, lubricant 3
Part, 2.5 parts of antioxidant, 4 parts of dispersant；
The waterproofing agent is the mixture of octyltri-ethoxysilane and poly- MTES, and mass ratio is 3:
1。
The plastic carrier be biodegradable plastic carrier, the biodegradable plastic carrier be polyhydroxyalkanoate,
Appointing in poly- ethanedioic acid/butylene terephthalate, poly butylene succinate, PLA, PTT
Meaning is a kind of.
The modified SiO2 preparation methods are：To be directly added into CTAB in 70% polyether amine solution, the CTAB with it is poly-
The mass volume ratio of ether amines solution is：1g:30ml, CTAB are cetyl trimethyl ammonium, and CTAB flocculates to polyetheramine
Modified polyether amine aqueous solution is obtained with modified-reaction；Modified polyether amine aqueous solution is grafted and SiO2 tables with the mode of electric electrostatic spray
The ratio of face, the modified polyether amine aqueous solution and SiO2 is 10ml:1g.
The ultra-fine powder, preparation method thereof of the antimony oxide is：
1) 400 parts of antimony ore, 120 parts of anthracite, 100 parts of lime stone will be contained uniform in stirrer for mixing, will obtain compound；
2) by step 1) in smelt at 1180 DEG C of compound obtaining, and successively oxidized room, expansion chamber, air cooling pipe are entered
Bagroom, obtains antimony oxide powder；
3) by step 2) in the antimony oxide powder that obtains with plasma generator as thermal source, Jing gasification oxidation-condensation methods,
Under 7500 DEG C of high-temperature plasma jet, make antimony oxide powder all gasify, obtain gaseous oxidation antimony；
4) by step 3) in the gaseous oxidation antimony that obtains of gasification with inert gas quenching, gas temperature is declined rapidly, gas
Jing nucleation, crystal are grown up process detached with impurity after phase oxidation antimony elder generation, obtain antimony oxide superfine powder, wherein, three oxidations two
The granularity of antimony superfine powder is less than 0.25m；
5) step 4) in the encapsulation of weighing of the antimony oxide superfine powder for preparing preserve.
The dispersant is the one kind in Tissuemat E, pentaerythritol stearate and calcium stearate.
The manufacture method of described environmentally-friendly plastic high molecular nanometer base material, it is characterised in that comprise the following steps：
(1) will crush after organic siliconresin, glass bead, titanium dioxide, quartz sand mixing, 200 mesh sieves are crossed, as component
A is standby；
(2) the antimony oxide superfine powder, the coupling agent are added in reactor, and at 110 DEG C, with 5000r/
Min high-speed stirreds 35min obtain component B；
(3) then reduce kneading machine rotating speed, addition component A is pulverized and mixed after, then temperature drop is carried out to less than 70 DEG C
Cooling, carries out break process after cooling, material is obtained after screening.
Raw material purchasing channel and manufacturer in following examples is respectively：
Pigment, coupling agent, starch channel lid obtain chemical industry net, the sincere one bright Chemical Co., Ltd. in Guangzhou；Plasticizer, lubricant
The wise net of channel, Jiangsu Jing Ruite environmental friendly materials Co., Ltd；
Antioxidant, dispersant and carrier channel Alibaba, Anyang Guo Chang ferroalloys Co., Ltd；Other raw material canals
Road cloves is led to, Shanghai Jiang Lai bio tech ltd.
Key property evaluation is carried out to environmentally-friendly plastic high molecular nanometer base material obtained in embodiment 1-2.Concrete comparing result
Such as following table：
Claims (6)
1. a kind of environmentally-friendly plastic high molecular nanometer base material with anti-flaming function, it is characterised in that by weight percentage, including
Composition：Organic siliconresin 20-25 parts, glass bead 15-20 parts, antimony oxide superfine powder 30-35 part, quartz sand 5-10 parts,
Scolecite 25-35 parts, hollow glass micropearl 30-40 parts, modified SiO2 5-10 parts, plastic carrier 20-60 parts, coupling agent 0.1-
1.5 parts, plasticizer 1-7 parts, lubricant 0.2-3 parts, antioxidant 0.5-2.5 parts, dispersant 0.1-4 parts；
The waterproofing agent is the mixture of octyltri-ethoxysilane and poly- MTES, and mass ratio is 3:1.
2. environmentally-friendly plastic high molecular nanometer base material according to claim 1, it is characterised in that：The plastic carrier is biology
Degradative plastics carrier, the biodegradable plastic carrier be polyhydroxyalkanoate, poly- ethanedioic acid/butylene terephthalate,
Any one in poly butylene succinate, PLA, PTT.
3. environmentally-friendly plastic high molecular nanometer base material according to claim 1, it is characterised in that：The modified SiO2 preparation sides
Method is：CTAB will be directly added in 70% polyether amine solution, the CTAB is with the mass volume ratio of polyether amine solution：1g:
30ml, CTAB are cetyl trimethyl ammonium, CTAB is flocculated to polyetheramine and modified-reaction to obtain modified polyether amine molten
Liquid；Modified polyether amine aqueous solution is grafted on into SiO2 surfaces, the modified polyether amine aqueous solution and SiO2 with the mode of electric electrostatic spray
Ratio be 10ml:1g.
4. environmentally-friendly plastic high molecular nanometer base material according to claim 1, it is characterised in that：The antimony oxide is ultra-fine
Powder, preparation method thereof is：
1) 280～400 parts of antimony ore, 80～120 parts of anthracite, 50～100 parts of lime stone will be contained uniform in stirrer for mixing, will be obtained
Compound；
2) by step 1) in the compound that obtains smelt at 1000～1180 DEG C, and successively oxidized room, expansion chamber, air cooling pipe
Into bagroom, antimony oxide powder is obtained；
3) by step 2) in the antimony oxide powder that obtains with plasma generator as thermal source, Jing gasification oxidation-condensation methods,
Under 3600～7500 DEG C of high-temperature plasma jet, make antimony oxide powder all gasify, obtain gaseous oxidation antimony；
4) by step 3) in the gaseous oxidation antimony that obtains of gasification with inert gas quenching, gas temperature is declined rapidly, gas phase oxygen
Change Jing nucleation, crystal after antimony elder generation to grow up process detached with impurity, obtain antimony oxide superfine powder, wherein, antimony oxide surpasses
The granularity of fine powder is less than 0.25m；
5) step 4) in the encapsulation of weighing of the antimony oxide superfine powder for preparing preserve.
5. environmentally-friendly plastic high molecular nanometer base material according to claim 1, it is characterised in that：The dispersant is polyethylene
One kind in wax, pentaerythritol stearate and calcium stearate.
6. a kind of manufacture method of the environmentally-friendly plastic high molecular nanometer base material as described in any one of claim 1-5, its feature exists
In comprising the following steps：
(1) will crush after organic siliconresin, glass bead, titanium dioxide, quartz sand mixing, 100-200 mesh sieves are crossed, as component
A is standby；
(2) the antimony oxide superfine powder, the coupling agent are added in reactor, and at 90-110 DEG C, with 3000-
5000r/min high-speed stirreds 15-35min obtain component B；
(3) then reduce kneading machine rotating speed, addition component A is pulverized and mixed after, temperature drop carries out cold to less than 70 DEG C, then
But, break process is carried out after cooling, material is obtained after screening.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710013876.3A CN106633899A (en) | 2017-01-09 | 2017-01-09 | Environment-friendly plastic macromolecular nano additive with flame retarding function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710013876.3A CN106633899A (en) | 2017-01-09 | 2017-01-09 | Environment-friendly plastic macromolecular nano additive with flame retarding function |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106633899A true CN106633899A (en) | 2017-05-10 |
Family
ID=58843781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710013876.3A Pending CN106633899A (en) | 2017-01-09 | 2017-01-09 | Environment-friendly plastic macromolecular nano additive with flame retarding function |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106633899A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107903594A (en) * | 2017-11-13 | 2018-04-13 | 青岛卓森纳生物工程有限公司 | A kind of resistance to compression environmentally-friendly plastic high molecular nanometer Masterbatch and its manufacture method |
| CN107955347A (en) * | 2017-11-13 | 2018-04-24 | 青岛卓森纳生物工程有限公司 | A kind of its manufacture method of the environmentally-friendly plastic high molecular nanometer Masterbatch of zero VOC content |
| CN107955349A (en) * | 2017-11-14 | 2018-04-24 | 青岛卓森纳生物工程有限公司 | A kind of environmentally-friendly plastic high molecular nanometer Masterbatch its manufacture method with anti-haze |
| CN108047666A (en) * | 2017-11-13 | 2018-05-18 | 青岛卓森纳生物工程有限公司 | A kind of tensile strength environmentally-friendly plastic Masterbatch macromolecule carrier and its manufacturing method |
| CN108912686A (en) * | 2018-07-16 | 2018-11-30 | 江苏万纳普新材料科技有限公司 | A kind of high-efficiency antimicrobial toughening flame-proof Multi-functional plastic masterbatch and preparation method thereof |
| CN109403149A (en) * | 2018-09-10 | 2019-03-01 | 天津大学 | Heat preservation wallpaper |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1786064A (en) * | 2005-11-16 | 2006-06-14 | 朱家牧 | Synthetic paper made of environmental protection plastic and its preparation method |
| CN1903949A (en) * | 2005-07-27 | 2007-01-31 | 台茂高分子科学股份有限公司 | Functional composite mother material and its manufacturing method |
| CN106117931A (en) * | 2016-08-04 | 2016-11-16 | 苏州锐特捷化工制品有限公司 | A kind of inorganic vitreous fibre modification nanometer base material and preparation method |
-
2017
- 2017-01-09 CN CN201710013876.3A patent/CN106633899A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1903949A (en) * | 2005-07-27 | 2007-01-31 | 台茂高分子科学股份有限公司 | Functional composite mother material and its manufacturing method |
| CN1786064A (en) * | 2005-11-16 | 2006-06-14 | 朱家牧 | Synthetic paper made of environmental protection plastic and its preparation method |
| CN106117931A (en) * | 2016-08-04 | 2016-11-16 | 苏州锐特捷化工制品有限公司 | A kind of inorganic vitreous fibre modification nanometer base material and preparation method |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107903594A (en) * | 2017-11-13 | 2018-04-13 | 青岛卓森纳生物工程有限公司 | A kind of resistance to compression environmentally-friendly plastic high molecular nanometer Masterbatch and its manufacture method |
| CN107955347A (en) * | 2017-11-13 | 2018-04-24 | 青岛卓森纳生物工程有限公司 | A kind of its manufacture method of the environmentally-friendly plastic high molecular nanometer Masterbatch of zero VOC content |
| CN108047666A (en) * | 2017-11-13 | 2018-05-18 | 青岛卓森纳生物工程有限公司 | A kind of tensile strength environmentally-friendly plastic Masterbatch macromolecule carrier and its manufacturing method |
| CN107955349A (en) * | 2017-11-14 | 2018-04-24 | 青岛卓森纳生物工程有限公司 | A kind of environmentally-friendly plastic high molecular nanometer Masterbatch its manufacture method with anti-haze |
| CN108912686A (en) * | 2018-07-16 | 2018-11-30 | 江苏万纳普新材料科技有限公司 | A kind of high-efficiency antimicrobial toughening flame-proof Multi-functional plastic masterbatch and preparation method thereof |
| CN109403149A (en) * | 2018-09-10 | 2019-03-01 | 天津大学 | Heat preservation wallpaper |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106633899A (en) | Environment-friendly plastic macromolecular nano additive with flame retarding function | |
| CN107641221B (en) | A kind of hydroxide-modified expansible graphite fire retardant and preparation method thereof | |
| Wang et al. | Double-layered co-microencapsulated ammonium polyphosphate and mesoporous MCM-41 in intumescent flame-retardant natural rubber composites | |
| CN102153820A (en) | Preparation method of flame retarding styrene polymer composite material | |
| CN101531885A (en) | Environment-friendly inflaming retarding smoke-inhibiting shaping phase-changing energy storage material and preparing method thereof | |
| CN110079012B (en) | graphene/POSS composite synergistic halogen-free flame-retardant polypropylene composite material and preparation method thereof | |
| CN101284947A (en) | Silastic of high intensity and method for preparing same | |
| CN109575443A (en) | A kind of graphite tailing composite material and preparation method | |
| CN103387695A (en) | White carbon black dispersing agent and preparation method thereof | |
| CN107778638A (en) | A kind of halogen-free flame-retardant ultra-high molecular weight polyvinyl material and preparation method thereof | |
| CN103396675A (en) | Raw material treatment method for injection molding grade micro-foaming wood-plastic composite material | |
| CN114085552A (en) | Modified wollastonite, preparation method thereof and application thereof in fluororubber | |
| CN106380731A (en) | PVC film for wallpaper and preparation method thereof | |
| CN103351477B (en) | Modified microsphere master batch of foaming agent and preparation method for modified microsphere master batch of foaming agent | |
| CN104194193A (en) | Special filler for antistatic wear-resistant PVC (polyvinyl chloride) tube and preparation method thereof | |
| CN104672609A (en) | Flame-retardant toughened polypropylene loudspeaker box material | |
| CN105037895A (en) | Novel high-temperature-resistant low-smoke flame-retardant composite cable material and preparation method thereof | |
| CN107057302B (en) | Smoke-inhibiting type Flame-retardant PET composite material and preparation method | |
| CN104177656A (en) | Light-resistant light calcium carbonate filler and preparation method thereof | |
| CN104194400A (en) | High-dispersibility modified calcium carbonate filler and preparation method thereof | |
| CN108587217A (en) | A kind of environmental protection anti-static wearable plastic cement race track material and preparation method thereof | |
| CN107556723A (en) | Fire-retardant automobile air conditioner control panel sheathing material of high rigidity and preparation method thereof | |
| CN107955349A (en) | A kind of environmentally-friendly plastic high molecular nanometer Masterbatch its manufacture method with anti-haze | |
| CN108690243A (en) | A kind of preparation method of Novel conductive rubber | |
| CN104356690A (en) | Modified calcium carbonate with flame-retardant effect and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170510 |
|
| RJ01 | Rejection of invention patent application after publication |