CN106117931A - A kind of inorganic vitreous fibre modification nanometer base material and preparation method - Google Patents
A kind of inorganic vitreous fibre modification nanometer base material and preparation method Download PDFInfo
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- CN106117931A CN106117931A CN201610631921.7A CN201610631921A CN106117931A CN 106117931 A CN106117931 A CN 106117931A CN 201610631921 A CN201610631921 A CN 201610631921A CN 106117931 A CN106117931 A CN 106117931A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention discloses a kind of inorganic vitreous fibre modification nanometer base material and preparation method method, the constitutive material that it includes is: organic siliconresin, organic solvent, glass bead, titanium dioxide, quartz sand, silicon carbide micro-powder, nano-cerium oxide, ethanedioic acid polyester, precipitated calcium carbonate, high-moisture-retention resin polyvinyl alcohol, dispersant, thickening agent, brightening agent, zinc sulfide, foamed aluminium, hydroxypropyl methyl cellulose, nano silicon, binding agent, cobalt naphthenate, molybdenum, nickel, propylene glycol, chromium.Present invention is specifically directed to external wall, be effectively increased the various aspects of performance of external wall, such as: high temperature resistant, fire prevention, anti-skidding, waterproof, the moisture absorption, wear-resisting, antioxidation and the performance, especially heat-insulating property such as anticorrosive significantly improve.Use asphalt base carbon fiber to enhance the mechanical property of material can adsorb greatly and the harmful gas of removing in tail gas and dust material.
Description
Technical field
The present invention relates to technical field of construction and decoration materials, particularly relate to a kind of inorganic vitreous fibre modification nanometer base material
And preparation method method.
Background technology
Base material is typically by four kinds of bases: film forming matter (resin), pigment (including extender pigment), solvent and interpolation
Agent.
1 film forming matter is the main component of film, including oils and fats, fats and oils processing product, cellulose derivative, natural tree
Fat and synthetic resin.Film forming matter also includes the nonvolatile reactive diluent of part, and it is to make base material be firmly attached to coated article
Form the main matter of continuous film on face, be the basis constituting base material, decide the fundamental characteristics of base material.
2 auxiliary agents such as defoamer, levelling agent etc., also have some special function additives, such as ground wetting agent etc..These help
Agent typically can not film forming, but process and durability that base material is formed film play considerable effect.
3 pigment typically divide two kinds, and one is coloring pigment, common titanium dioxide, chrome yellow etc., and also planting is extender pigment,
The filler namely often said, such as calcium carbonate, Pulvis Talci
4 solvents include varsol (mineral spirits, kerosene, gasoline, benzene,toluene,xylene etc.), alcohols, ethers, ketone and
Ester.The Main Function of solvent and water is to make film forming binder dispersion form thick liquid.It contributes to construction and changes
Some performance of kind film.
Substrate performance of the prior art is not sufficiently stable, and the especially heat-insulating property of base material is the highest.
Summary of the invention
For overcoming above-mentioned deficiency, the present invention provides a kind of inorganic vitreous fibre modification nanometer base material and preparation method side
Method.
The present invention takes techniques below scheme to realize: a kind of inorganic vitreous fibre modification nanometer base material, it includes
Constitutive material be: asphalt base carbon fiber powder 6-8 part, non-halogenated organophosphinate 5-7 part, hexamethylenetetramine 8-10
Part, tri-methyl-amyl triethoxysilane 2-4 part, conductive mica powder 0.3-0.5 weight portion, conductive nano graphite powder 0.2-0.4
Weight portion, the trimer 0.8-1 weight portion of polyisocyanates, polytetrafluoroethylene fibre 1-2 weight portion, glass bead 20-30 weight
Amount part, titanium dioxide 1-10 part, quartz sand 1-5 weight portion, silicon carbide micro-powder 2-6 weight portion, nano-cerium oxide 1-5 weight portion,
Ethanedioic acid polyester 1-5 weight portion, precipitated calcium carbonate 4-10 weight portion, high-moisture-retention resin polyvinyl alcohol 10-14 weight portion, dispersion
Agent 6-10 weight portion, thickening agent 1-5 weight portion, brightening agent 2-6 weight portion, zinc sulfide 3-7 weight portion, foamed aluminium 0.8-2.8 weight
Amount part, hydroxypropyl methyl cellulose 8-12 weight portion, nano silicon 10-14 weight portion, binding agent 8-14 weight portion.
The present invention also provides for the preparation method of a kind of inorganic vitreous fibre modification nanometer base material, comprises the steps of:
(1) pulverize after organic siliconresin, glass bead, titanium dioxide, quartz sand mixing, cross 100-200 mesh sieve, as component
A is standby；
(2) by silicon carbide micro-powder, nano-cerium oxide, ethanedioic acid polyester, precipitated calcium carbonate, high-moisture-retention resin polyvinyl alcohol, sulfur
Change zinc, foamed aluminium, hydroxypropyl methyl cellulose are placed in pulverizer pulverizing, cross 100-200 mesh sieve, prepare component B standby；
(3) under vacuum, by adding other component raw material of surplus after component A, the mixing of component B, by remaining component powder
After broken mixing, standby after crossing 100-200 mesh screen；Stir prepared base material high temperature 90-100 DEG C；Base material is put into casting
In part processing machine, first adding pressurizing melting on vulcanizing press at foundry goods, melt temperature is 160-190 DEG C, natural after constant temperature 3-5h
Cooling.
The method have the advantages that the present invention provides a kind of inorganic vitreous fibre modification nanometer base material in sum
And preparation method method, component preparation is reasonable, the raw material components that will form, such as: organic siliconresin, glass bead, titanium dioxide
Titanium, quartz sand mixing after pulverize, especially by part material component therein, effectively increase this base material have excellence
Thermal and insulating performance and fire prevention ageing-resistant performance, not hollowing cracking, intensity height, environment-protecting asepsis, free from extraneous odour, light weight, heat conduction system
Number is low, and heat-insulating property is stable, good freeze-thaw resistance and water resistance, and Fire retardant grade is high, good cohesive force and shearing force, tool
Having outstanding cracking resistance resisting wind press capacity, not hollowing cracking, the performances, especially heat-insulating property such as intensity is high significantly improve；.Add
The reinforcing agents such as rock gangue, conductive mica powder, conductive nano graphite powder can improve resistant to thermal aging cracking performance, thus improves casting
Make efficiency, reduce casting cost.The mechanical property that the present invention uses asphalt base carbon fiber to enhance material can be adsorbed greatly
With the harmful gas removed in tail gas and dust material.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with
Detailed description of the invention, is expanded on further the present invention.
Embodiment 1 one kinds inorganic vitreous fibre modification nanometer base material and preparation method method
A kind of inorganic vitreous fibre modification nanometer base material, the constitutive material that it includes is: 6 parts of asphalt base carbon fiber powder, non-halogen
Change organophosphinate 5 parts, hexamethylenetetramine 8 parts, tri-methyl-amyl triethoxysilane 2 parts, conductive mica powder 0.3 weight
Part, trimer 0.8 weight portion of conductive nano graphite powder 0.2 weight portion, polyisocyanates, polytetrafluoroethylene fibre 1 weight portion,
Glass bead 20 weight portion, titanium dioxide 1 part, quartz sand 1 weight portion, silicon carbide micro-powder 2 weight portion, nano-cerium oxide 1 weight
Part, ethanedioic acid polyester 1 weight portion, precipitated calcium carbonate 4 weight portion, high-moisture-retention resin polyvinyl alcohol 10 weight portion, dispersant 6 weight
Amount part, thickening agent 1 weight portion, brightening agent 2 weight portion, zinc sulfide 3 weight portion, foamed aluminium 0.8 weight portion, hydroxypropyl methyl fiber
Element 8 weight portions, nano silicon 10 weight portion, binding agent 8 weight portion.
The present invention also provides for the preparation method of a kind of inorganic vitreous fibre modification nanometer base material, comprises the steps of:
(1) pulverize after organic siliconresin, glass bead, titanium dioxide, quartz sand mixing, cross 100-200 mesh sieve, as component
A is standby；
(2) by silicon carbide micro-powder, nano-cerium oxide, ethanedioic acid polyester, precipitated calcium carbonate, high-moisture-retention resin polyvinyl alcohol, sulfur
Change zinc, foamed aluminium, hydroxypropyl methyl cellulose are placed in pulverizer pulverizing, cross 100-200 mesh sieve, prepare component B standby；
(3) under vacuum, by adding other component raw material of surplus after component A, the mixing of component B, by remaining component powder
After broken mixing, standby after crossing 100-200 mesh screen；Stir prepared base material high temperature 90-100 DEG C；Base material is put into casting
In part processing machine, first adding pressurizing melting on vulcanizing press at foundry goods, melt temperature is 160-190 DEG C, natural after constant temperature 3-5h
Cooling.
Embodiment 2 one kinds inorganic vitreous fibre modification nanometer base material and preparation method method
A kind of inorganic vitreous fibre modification nanometer base material, the constitutive material that it includes is: 8 parts of asphalt base carbon fiber powder, non-halogen
Change organophosphinate 7 parts, hexamethylenetetramine 10 parts, tri-methyl-amyl triethoxysilane 4 parts, conductive mica powder 0.5 weight
Amount part, conductive nano graphite powder 0.4 weight portion, trimer 1 weight portion of polyisocyanates, polytetrafluoroethylene fibre 2 weight portion,
Glass bead 30 weight portion, titanium dioxide 10 parts, quartz sand 5 weight portion, silicon carbide micro-powder 6 weight portion, nano-cerium oxide 5 weight
Part, ethanedioic acid polyester 5 weight portion, precipitated calcium carbonate 10 weight portion, high-moisture-retention resin polyvinyl alcohol 14 weight portion, dispersant 10
Weight portion, thickening agent 5 weight portion, brightening agent 6 weight portion, zinc sulfide 7 weight portion, foamed aluminium 2.8 weight portion, hydroxypropyl methyl are fine
Tie up plain 12 weight portions, nano silicon 14 weight portion, binding agent 14 weight portion.
The present invention also provides for the preparation method of a kind of inorganic vitreous fibre modification nanometer base material, comprises the steps of:
(1) pulverize after organic siliconresin, glass bead, titanium dioxide, quartz sand mixing, cross 100-200 mesh sieve, as component
A is standby；
(2) by silicon carbide micro-powder, nano-cerium oxide, ethanedioic acid polyester, precipitated calcium carbonate, high-moisture-retention resin polyvinyl alcohol, sulfur
Change zinc, foamed aluminium, hydroxypropyl methyl cellulose are placed in pulverizer pulverizing, cross 100-200 mesh sieve, prepare component B standby；
(3) under vacuum, by adding other component raw material of surplus after component A, the mixing of component B, by remaining component powder
After broken mixing, standby after crossing 100-200 mesh screen；Stir prepared base material high temperature 90-100 DEG C；Base material is put into casting
In part processing machine, first adding pressurizing melting on vulcanizing press at foundry goods, melt temperature is 160-190 DEG C, natural after constant temperature 3-5h
Cooling.Being put into by base material in Mechanical processing of casting machine, first add pressurizing melting on vulcanizing press at foundry goods, melt temperature is 160-190
DEG C, natural cooling after constant temperature 3-5h.
The above is embodiments of the invention, therefore all according to the structure described in the present patent application scope, feature and principle institute
The equivalence change done or modification, in the range of being all included in present patent application.
Claims (2)
1. an inorganic vitreous fibre modification nanometer base material, it is characterised in that the constitutive material that it includes is: pitch base carbon is fine
Dimension powder 6-8 part, non-halogenated organophosphinate 5-7 part, hexamethylenetetramine 8-10 part, tri-methyl-amyl triethoxysilane
2-4 part, conductive mica powder 0.3-0.5 weight portion, conductive nano graphite powder 0.2-0.4 weight portion, the trimer of polyisocyanates
0.8-1 weight portion, polytetrafluoroethylene fibre 1-2 weight portion, glass bead 20-30 weight portion, titanium dioxide 1-10 part, quartz sand
1-5 weight portion, silicon carbide micro-powder 2-6 weight portion, nano-cerium oxide 1-5 weight portion, ethanedioic acid polyester 1-5 weight portion, lightweight carbon
Acid calcium 4-10 weight portion, high-moisture-retention resin polyvinyl alcohol 10-14 weight portion, dispersant 6-10 weight portion, thickening agent 1-5 weight
Part, brightening agent 2-6 weight portion, zinc sulfide 3-7 weight portion, foamed aluminium 0.8-2.8 weight portion, hydroxypropyl methyl cellulose 8-12 weight
Amount part, nano silicon 10-14 weight portion, binding agent 8-14 weight portion.
2. according to the preparation method of the arbitrary described a kind of inorganic vitreous fibre modification nanometer base material of claim 1-3, its feature
It is: comprise the steps of:
(1) pulverize after organic siliconresin, glass bead, titanium dioxide, quartz sand mixing, cross 100-200 mesh sieve, as component
A is standby；
(2) by silicon carbide micro-powder, nano-cerium oxide, ethanedioic acid polyester, precipitated calcium carbonate, high-moisture-retention resin polyvinyl alcohol, sulfur
Change zinc, foamed aluminium, hydroxypropyl methyl cellulose are placed in pulverizer pulverizing, cross 100-200 mesh sieve, prepare component B standby；
(3) under vacuum, by adding other component raw material of surplus after component A, the mixing of component B, by remaining component powder
After broken mixing, standby after crossing 100-200 mesh screen；Stir prepared base material high temperature 90-100 DEG C；Base material is put into casting
In part processing machine, first adding pressurizing melting on vulcanizing press at foundry goods, melt temperature is 160-190 DEG C, natural after constant temperature 3-5h
Cooling.
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| CN201610631921.7A CN106117931A (en) | 2016-08-04 | 2016-08-04 | A kind of inorganic vitreous fibre modification nanometer base material and preparation method |
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| CN201610631921.7A CN106117931A (en) | 2016-08-04 | 2016-08-04 | A kind of inorganic vitreous fibre modification nanometer base material and preparation method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633899A (en) * | 2017-01-09 | 2017-05-10 | 上海深化实业有限公司 | Environment-friendly plastic macromolecular nano additive with flame retarding function |
| CN107353547A (en) * | 2017-07-21 | 2017-11-17 | 苏州伟安杰工程技术有限公司 | Refractory heat-insulating engineering material |
| CN112679146A (en) * | 2020-05-26 | 2021-04-20 | 马瓯丽 | High-temperature-resistant and anti-rutting asphalt mixture |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417324A (en) * | 2011-08-31 | 2012-04-18 | 王贵刚 | Inorganic active heat-insulating material for wall insulation, and preparation method thereof |
-
2016
- 2016-08-04 CN CN201610631921.7A patent/CN106117931A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417324A (en) * | 2011-08-31 | 2012-04-18 | 王贵刚 | Inorganic active heat-insulating material for wall insulation, and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633899A (en) * | 2017-01-09 | 2017-05-10 | 上海深化实业有限公司 | Environment-friendly plastic macromolecular nano additive with flame retarding function |
| CN107353547A (en) * | 2017-07-21 | 2017-11-17 | 苏州伟安杰工程技术有限公司 | Refractory heat-insulating engineering material |
| CN112679146A (en) * | 2020-05-26 | 2021-04-20 | 马瓯丽 | High-temperature-resistant and anti-rutting asphalt mixture |
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Application publication date: 20161116 |