Exfoliated red iron casting coating of sintering and preparation method thereof
technical field 3
The present invention relates to the low-cost iron casting coating using in a kind of foundry production, exfoliated red iron casting coating of especially a kind of sintering and preparation method thereof.
Background technology
In foundry production, the surface quality of foundry goods depends primarily on casting mold (core) working surface.At casting mold (core) working surface, apply coating, can not only prevent that cast(ing) surface from producing the defects such as scab, burning into sand and pit, can also reduce surface roughness, significantly reduce cast(ing) surface and level workload, obtain many-sided technique effect and good overall economic efficiency.
At present generally to take microlite ink powder and the crystalline graphite powder of black be basic refractory material to iron casting coating.Graphite powder refractoriness is high, and price is low, under pouring temperature, can separate out bright carbon, thereby forms layer protecting film at coating surface, can reduce the wettability of molten iron to casting mold, can effectively prevent the scab defect being produced by metal penetration.But the blacking of black is when preparation and use, severe contamination working environment, worsens working condition; Graphite powder also can be oxidized under high temperature liquid iron effect, and strength of coating and anti-molten iron scouring capability are reduced, and causes the anti-stick sand effect of thick large-sized iron casting bad; The blacking of black is close with the color of furan resin-sand, and inconvenience identification, easily causes holiday., although can overcome the above problems, cost is too high for albescent zircon flour coating (as patent CN86100032A " light-coloured coating for iron-casting core "), and zirconium English powder has certain radioactivity, is difficult to spread.Although tan brown corundum class coating is better to the anti-stick sand effect of thick large-sized iron casting, cost is still higher, and it is darker that painting color is still disliked.Patent CN1847336A " light-colored alcohol-base paint " for example, take brown corundum and zirconium English powder is Main Refractory, also contains 10%~25% graphite powder.
In recent years, the light color cast iron paint development and application of domestic alternative zircon flour coating has made some progress, some units have started to adopt cheap bauxite powder, silica flour, mullite powder, the light refractory material such as magnesia powder is developed the exfoliated iron casting coating of low-cost alcohol radical light color sintering for several resin sand, but these coating still exist sintering fissility still poor, anti-stick sand effect is bad, or suspension stability is poor, coating easily produces precipitation in long-term storage and transportation, coating brush mark is serious, affect the problems such as surface quality of foundry goods, and the sintering flux (or claiming Nucleating Agent) that part coatings adopts is the high ultra-fine pyroxene of price, lanthanum/strontium and rare earth class or nanometer aluminum, zirconium, the ultrafine solids dusty materials such as chromium (as patent CN101088660A " light color cast iron paint of high alumina polycrystalline composite aggregate "), most of coating still contains part graphite powder in addition, color is dark (being light gray or grey) still.
Iron casting coating divides two kinds of alcohol-base paint and water based paints.Alcohol radical iron casting coating generally adopts ethanol, methyl alcohol for example, as solvent (aforementioned patent CN1847336A and CN101088660A), has the advantages that expenditure of time is few, and after ignition, its drying process can complete.But methyl alcohol is poisonous, human body optic nerve is had to stronger excitant, workers with long time exposure easily causes eyes blind; Ethanol and methyl alcohol all belong to the dangerous material of easy volatilization and burning, and security incident easily occurs in coating material production, transportation, preservation and use procedure, are not easy to product long-distance transport and deposit; Ethanol and methyl alcohol or basic chemical raw materials and important motor vehicle fuel.In addition, after alcohol-base paint ignition, organic binder bond wherein and organic suspending agent composition produce a large amount of toxic gases, pollute working environment, affect workman healthy.Aspect coating brushability, because the polarity of alcohols is very weak, alcohol-base paint does not have time thixotropy, so brush mark is serious while brushing, and is difficult to disappear.
Table 1 has compared the characteristic of property of water based paint and alcohol-base paint.
The Performance Ratio of table 1 water based paint and alcohol-base paint
Current, energy-conserving and environment-protective and safety in production require increasingly stringent, the requirement of surface quality of continuous castings is also improved day by day.Therefore, from the viewpoint of improving operating environment, saving energy and reduce the cost, improve production security and surface quality of continuous castings etc., ethanol, methyl alcohol all should not continue to use in cast paint, and the developing direction of following iron casting coating should be take cleanliness without any pollution, safe and reliable, stable performance, convenient transportation, the cheap exfoliated water based paint of the even colored sintering of light color as main.But water based paint sintering fissility of the prior art is poor, the unpacking cooling rear coating of foundry goods is difficult to automatically peel off in flakes, and most of coating need to utilize shot-blasting machine to clear up, even if scab position adopts shot-blasting machine to be also difficult to clean out.
Summary of the invention
The invention provides red water based iron casting paint of the exfoliated low cost of a kind of sintering and preparation method thereof.This coating is completely containing zirconium English powder and graphite powder, but adopts bauxite powder (or konilite) and mullite powder to make fire-resistant base material, and talcum powder and di-iron trioxide powder are made sintering flux, and the prices of raw and semifnished materials are cheap, it is abundant, "dead" to originate.This coating not only has good sintering fissility, anti-stick sand effect and suspension stability, be difficult for producing precipitation, and production cost is low in long-term storage and transportation, also free from environmental pollution.
Technical scheme provided by the invention is: the red water based iron casting paint of the exfoliated low cost of a kind of sintering, by 20~45%(mass fraction, as follows) bauxite powder (or konilite), 0~25% mullite powder, 1~6% talcum powder, 1~5% di-iron trioxide powder, 1~3% suspending agent, 1.5~4.5% organic binder bonds, 1.5~6% inorganic binders, 0.01~0.05% wetting agent, 0.02~0.05% anticorrisive agent, 0.02~0.1% defoamer, 0~0.5% water reducer, 30~42% running water form.
The consumption mass ratio of described talcum powder and di-iron trioxide powder is preferably 5:1; More preferably talcum powder is 5%, and di-iron trioxide powder is 1%, and described percentage is mass ratio.。
The Al of above-mentioned bauxite powder
2o
3>=70%; Also can adopt konilite to replace, its SiO
2>=98%; Granularity is 25~75 μ m.Konilite is different from silica flour, and it is the quartzitic weathering disintegration of Paleozoic Era crystallite product, can directly obtain without milling processing highly purified powder, and particle is that class is spherical, and crystalline phase is alpha-quartz.
The Al of above-mentioned mullite powder
2o
3>=42%, SiO
2≤ 55%, mullite phase>=55%, granularity is 25~75 μ m.
The Fe of above-mentioned di-iron trioxide powder
2o
3>=75%, granularity is 10~75 μ m.
Above-mentioned suspending agent is sodium base rectorite powder, also can adopt sodium bentonite, attapulgite etc.
Above-mentioned organic binder bond is polyvinyl acetate emulsion (white glue with vinyl), also can adopt water-soluble phenolic resins.
Above-mentioned inorganic binder is Ludox, also can adopt waterglass.
Above-mentioned wetting agent is AEO (JFC), also can adopt polyethylene alkyl alcohol ether, Tween 80 etc.
Foregoing preservatives is Sodium Benzoate, also can adopt thymol, pentachlorophenol etc.
Above-mentioned defoamer is n-butanol, also can adopt n-octyl alcohol, n-amyl alcohol etc.
Above-mentioned water reducer is polycarboxylate water-reducer, also can adopt lignin sulfonic acid sodium salt water reducer, Ppolynuclear aromatic salt water reducer and water-soluble resin Sulfonates water reducer.
The preparation method of the exfoliated red iron casting coating of above-mentioned sintering, comprises the steps:
(1) in stirring dispersion machine A, add the water that accounts for 5 times of quality of suspending agent, start is stirred, and slowly adds suspending agent simultaneously, adds rear continuation and stirs more than 1 hour, then standing more than 2 hours, then in colloid mill cyclic process 1~3 time, obtain colloid A;
(2) in stirring dispersion machine B, add colloid A, after start is stirred more than 0.5 hour, progressively add while stirring again bauxite powder (or konilite), mullite powder, talcum powder, di-iron trioxide powder, organic binder bond, inorganic binder, wetting agent, anticorrisive agent, defoamer, water reducer and excess water, add rear continuation and stir more than 1 hour, obtain lotion B;
(3) by lotion B cyclic process 1~3 time in colloid mill, obtain the exfoliated red water based iron casting paint product of sintering.
Applicant studies discovery, adopt abundant, the cheap talcum powder in source and di-iron trioxide powder can significantly improve the sintering fissility of product as composite fluxing agent (especially talcum powder is 1~6% in product, di-iron trioxide powder is while being 1~5%), effectively prevent the defects such as foundry goods scab and pore.
Technical scheme provided by the invention has following features: the prices of raw and semifnished materials are cheap, source is sufficient; Product becomes
This is low (material cost only have zircon flour coating 10~15%, brown corundum coating 40~50%, blacking 60~100%), safety and environmental protection, convenient transportation; Product brushability, sag resistance and good leveling property, suspensibility, strength of coating and crack resistance are high, and gas forming amount is low; Particularly sintering fissility is excellent, and the unpacking cooling rear coating overwhelming majority of foundry goods can be peeled off in flakes, can effectively prevent the defects such as foundry goods scab, burning into sand, drop and pore, obtains the foundry goods of excellent surface quality.
The present invention not only can replace zircon flour coating and brown corundum coating to produce large, medium and small type ironcasting for various Reform of Resin Sand Casting fabrication techniques, applied widely; Also can replace alcohol radical blacking to use, and color is bright-coloured redness, easily identification, can avoid holiday, eliminates the pollution of black blacking to production environment.
Technical scheme provided by the invention is not only applicable to Reform of Resin Sand Casting fabrication technique and produces ironcasting, can be used for the casting techniques such as water-glass sand, clay-bonded sand, gravity metal type, centrifugal metal mould, evaporative pattern, vacuum coated yet and produces various ironcastings.
The specific embodiment
Embodiment 1:
Raw material: 45%(mass fraction, as follows) bauxite powder, 3% talcum powder, 2% di-iron trioxide powder, 2.5% sodium base rectorite powder, 4.5% white glue with vinyl, 2.7% Ludox, 0.03%JFC, 0.05% thymol, 0.1% n-butanol, 0.1% polycarboxylate water-reducer, 40% water.
Preparation method:
(1) in stirring dispersion machine A, add the water that accounts for 5 times of amounts of sodium base rectorite powder, start is stirred, and slowly adds suspending agent simultaneously, adds rear continuation and stirs more than 1 hour, then standing more than 2 hours, then in colloid mill cyclic process 1~3 time, obtain colloid A;
(2) in stirring dispersion machine B, add colloid A, after start is stirred more than 0.5 hour, progressively add while stirring again bauxite powder, talcum powder, di-iron trioxide powder, white glue with vinyl, Ludox, JFC, thymol, n-butanol, polycarboxylate water-reducer and excess water, add rear continuation and stir more than 1 hour, obtain lotion B;
(3) by lotion B cyclic process 1~3 time in colloid mill, obtain the exfoliated red water based iron casting paint product of sintering.
This coating is particularly useful for middle-size and small-size ironcasting, and (single-piece quality is no more than 5 tons, wall thickness is no more than 100mm, pouring temperature is no more than 1400 ℃) produce, coating applies 1~2 time, coating layer thickness is about 0.3 ~ 1.0mm, at the drying kiln internal heating curing of 50~450 ℃, also can adopt the flames such as natural gas, coal gas, acetylene gas to purge, coating is heating and curing, also can spontaneous curing under the condition of environment temperature >=30 ℃, circulation of air.
Material cost and the blacking of this coating are suitable, and sintering fissility is good, Area Ratio >=80% that the unpacking cooling rear coating of foundry goods is peeled off automatically in flakes, and casting cleaning is easy, any surface finish.
Embodiment 2:
Raw material: 30% konilite, 18% mullite powder, 4% talcum powder, 3% di-iron trioxide powder, 2% sodium base rectorite powder, 3% water-soluble phenolic resins, 4.7% Ludox, 0.02% polyethylene alkyl alcohol ether, 0.02% pentachlorophenol, 0.06% n-octyl alcohol, 0.2% lignin sulfonic acid sodium salt water reducer, 35% running water.
Preparation method: with embodiment 1.
This coating can be widely used in various iron casting production, and coating applies 1~3 time, and coating layer thickness is about 0.3 ~ 1.5mm.Coating curing methods is with embodiment 1.
The material cost of this coating is 60~70% of blacking, and sintering fissility is good, Area Ratio >=90% that the unpacking cooling rear coating of foundry goods is peeled off automatically in flakes, and casting cleaning ratio is easier to, any surface finish.
Embodiment 3:
Raw material: 20% bauxite powder, 23% mullite powder, 5% talcum powder, 1% di-iron trioxide powder, 1.5% sodium base rectorite powder, 1.5% white glue with vinyl, 5.5% Ludox, 0.03% JFC, 0.02% pentachlorophenol, 0.05% n-butanol, 0.4% polycarboxylate water-reducer, 42% running water.
Preparation method: with embodiment 1.
This coating is mainly applicable to big-and-middle-sized ironcasting (single-piece quality is more than 1 ton, and more than wall thickness 50mm, pouring temperature is more than 1350 ℃) and produces, and coating applies 2~3 times, and coating layer thickness is about 1.0 ~ 1.5mm.Coating curing methods is with embodiment 1.
Material cost and the blacking of this coating are suitable, and sintering fissility is good, Area Ratio >=95% that the unpacking cooling rear coating of foundry goods is peeled off automatically in flakes, and casting cleaning is easy, any surface finish.
Comparative example 1:
Raw material: 46%(mass fraction, as follows) bauxite powder, 4% di-iron trioxide powder, 2.5% sodium bentonite in powder, 4.5% white glue with vinyl, 2.7% Ludox, 0.03%JFC, 0.05% thymol, 0.1% n-butanol, 0.1% polycarboxylate water-reducer, 40% water.
Preparation method: with embodiment 1.
This comparative example coating only adds di-iron trioxide powder to make sintering flux, for medium-sized ironcasting (1~5 ton of single-piece quality, wall thickness 50~100mm, pouring temperature is no more than 1400 ℃) (coating applies 1~2 time while producing, coating layer thickness is about 0.3 ~ 1.0mm, coating curing methods is with embodiment 1), sintering fissility is poor, Area Ratio≤50% that the unpacking cooling rear coating of foundry goods is peeled off automatically in flakes, foundry goods scab (coating) defect is serious, even if adopt shot-blasting machine to be also difficult to clear up surperficial scab (coating) layer.
Comparative example 2:
Raw material: 43% konilite, 5% mullite powder, 6% talcum powder, 3% sodium bentonite in powder, 3% water-soluble phenolic resins, 4.7% Ludox, 0.02% polyethylene alkyl alcohol ether, 0.02% pentachlorophenol, 0.06% n-octyl alcohol, 0.2% lignin sulfonic acid sodium salt water reducer, 35% running water.
Preparation method: with embodiment 1.
This comparative example coating only adds talcum powder to make sintering flux, and color is shallow white; For large-sized iron casting, (single-piece quality is more than 5 tons, more than wall thickness 100mm, pouring temperature is more than 1350 ℃) (coating applies 2~3 times while producing, coating layer thickness is about 1.0 ~ 1.5mm, coating curing methods is with embodiment 1), sintering fissility is poor, Area Ratio≤60% that the unpacking cooling rear coating of foundry goods is peeled off automatically in flakes, foundry goods scab (coating) defect is more serious, even if adopt shot-blasting machine to be also difficult to clear up surperficial scab (coating) layer; For small-sized ironcasting, (single-piece quality is no more than 1 ton, wall thickness is no more than 50mm, pouring temperature is no more than 1400 ℃) (coating applies 1~2 time while producing, coating layer thickness is about 0.3 ~ 1.0mm, coating curing methods is with embodiment 1), sintering fissility is poor, Area Ratio≤50% that the unpacking cooling rear coating of foundry goods is peeled off automatically in flakes, although foundry goods is without scab defect, most of coating need to utilize shot-blasting machine to clear up.