CN104164150A - Water-based roller coating paint for curtain blades and preparation method thereof - Google Patents
Water-based roller coating paint for curtain blades and preparation method thereof Download PDFInfo
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- CN104164150A CN104164150A CN201410385141.XA CN201410385141A CN104164150A CN 104164150 A CN104164150 A CN 104164150A CN 201410385141 A CN201410385141 A CN 201410385141A CN 104164150 A CN104164150 A CN 104164150A
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Abstract
The invention provides a water-based roller coating paint for curtain blades, which comprises 50-70% of acrylic acid emulsion, 20-40% of polyurethane dispersion, 0.1-0.5% of wetting agent, 0.5-0.8% of defoaming agent, 2-6% of first film formation assistant, 1-5% of second film formation assistant, 0.5-2% of thickener, 2-4% of wax slurry, 0.1-0.5% of first leveling agent, 0.1-0.5% of second leveling agent, 0-0.2% of pH regulator and 3-6% of water. By using the acrylic acid emulsion as one of the main materials, the paint has the advantages of excellent light fastness, excellent adhesive force, quick drying and the like; the polyurethane dispersion is adopted to further enhance the adhesive force, flexibility, fullness and other effects of multiple plastic substrates; specific amounts of functional assistants are adopted to further enhance the effects of the paint, so that the paint is finally suitable for sunshade products; and the paint has the advantages of favorable light fastness, favorable leveling property, quick drying and favorable blocking resistance, and is comparable with oil paints.
Description
Technical field
The invention belongs to cold coating technical field, be specifically related to a kind of water-based roller coating coating for curtain blade and preparation method thereof.
Background technology
On the curtain article of existing indoor sunshade and decoration, mostly use oil paint roller coating construction, within about interval time of 10 seconds, wet and touch wet continuous roller coating 2 times, then room temperature is dodged dry after approximately 5 seconds, send into through transport tape that tunnel type baking oven is dry comes out of the stove for approximately 2 minutes, cooling packing.During due to the roller coating of use oil paint, need supporting a large amount of benzene class and ketones solvent Tianna solution, make the solvent strength of working space very high, these malicious secondary organic solvents are unfavorable for environmental protection, also have toxicity hazard safety.Therefore compare oil paint, water-borne coatings environmental protection, security aspect are high.But due to the character that water-borne coatings itself is moisture and surface tension is larger, its vaporization heat is large, it is poor many that the character such as dry and levelling are compared oil paint, therefore common water-borne coatings cannot be as the oil paint, reach at short notice quick surface drying and levelling, therefore cannot on roller coating production line, construct.And become paint film to be difficult to adhere on PVC material.
Summary of the invention
The object of the embodiment of the present invention is to overcome the above-mentioned deficiency of prior art, and a kind of low smell is provided, and is suitable for shading product and uses; And photostabilization, levelling property and rapid drying and resistance to blocking are good, be applicable to streamline roller coating construction, the water-based roller coating coating for curtain blade of the oil paint that can match in excellence or beauty.
In order to realize foregoing invention object, the technical scheme of the embodiment of the present invention is as follows:
A water-based roller coating coating for curtain blade, comprises following component:
ACRYLIC EMULSION 50～70%, polyurethane dispersions 20～40%, wetting agent 0.1～0.5%, defoamer 0.5～0.8%, the first film coalescence aid 2～6%, the second film coalescence aid 1～5%, thickening material 0.5～2%, wax slurry 2～4%, the first flow agent 0.1～0.5%, the second flow agent 0.1～0.5%, pH adjusting agent 0～0.2%, water 3～6%.
In the present invention, adopt acryllic acid emulsion as one of major ingredient for the water-based roller coating coating of curtain blade, make coating there is the advantages such as fabulous photostabilization, sticking power, fast drying; And further adopt polyurethane dispersions to promote sticking power, snappiness, the fullness ratio texts of multiple plastic bottom material; And the functional agent that further adopts specified quantitative ratio promotes the effect of coating jointly, make it finally be suitable for shading product and use; And photostabilization, levelling property and rapid drying and resistance to blocking are good, the water-based roller coating coating of the curtain blade of the oil paint that can match in excellence or beauty.
The application further also proposes a kind of preparation method of the water-based roller coating coating for curtain blade, comprises the steps:
Described ACRYLIC EMULSION, polyurethane dispersions are added in reaction vessel and evenly mixed;
In reaction vessel, add described wetting agent and defoamer, evenly mix;
Described the first film coalescence aid, the second film coalescence aid are carried out to pre-mixing formation with water and mix film forming compounding agent solution, more described mixing film forming compounding agent solution is slowly added in reaction vessel, evenly mix;
Described thickening material and water pre-mixing are formed to thickener soln, more described thickener soln is slowly added in reaction vessel, evenly mix;
Wax slurry, the first flow agent, the second flow agent are added in reaction vessel, evenly mix;
With described pH adjusting agent adjusting pH to 7.8～8.5.
Finally can also be according to the demand using, with appropriate water adjusting viscosity.
Adopt the above-mentioned preparation method of the present invention, the water-based roller coating coating for curtain blade of the simple gained of its process, can construct in multiple plastic rubber substrates such as ABS, PS, PVC, is also applicable to Wooden curtain blade; There is outstanding fullness ratio, good decorating effect; Good photostabilization, is suitable for shading product; Low smell, is applicable to indoor product and uses; Good levelling property and rapid drying and resistance to blocking, be applicable to streamline roller coating application and operation, the effect oil paint that can match in excellence or beauty.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The embodiment of the present invention provides a kind of water-based roller coating coating for curtain blade, comprises following component:
ACRYLIC EMULSION 50～70%, polyurethane dispersions 20～40%, wetting agent 0.1～0.5%, defoamer 0.5～0.8%, the first film coalescence aid 2～6%, the second film coalescence aid 1～5%, thickening material 0.5～2%, wax slurry 2～4%, the first flow agent 0.1～0.5%, the second flow agent 0.1～0.5%, pH adjusting agent 0～0.2%, water 3～6%.
Wherein, in major ingredient, ACRYLIC EMULSION is the anionic acrylate copolymer emulsion of self-crosslinking under room temperature, second-order transition temperature Tg own is 35 DEG C of left and right, and this kind of emulsion has good adhesion on various plastic rubber substrates and woodwork, and after quick-drying and drying and forming-film, hardness is higher.The second-order transition temperature Tg of ACRYLIC EMULSION is in the selection of 35 DEG C of left and right, and that carries out for the characteristic of curtain blade product considers, balance the elasticity of flexure that needs of hardness of paint film and curtain blade; The selection of room-temperature self crosslinking type is considering for resistance to blocking and hardness
Above-mentioned polyurethane dispersions is the polyester-polyurethane ester dispersion of anionic, wherein not containing free isocyanic ester, multiple plastic rubber substrate is had to good sticking power, good film-forming property, fullness ratio is good, and snappiness is good, fragility that can balance ACRYLIC EMULSION, there is extraordinary modification performance, thereby promote script water-borne coatings in this defect on the one hand.
Further, above-mentioned defoamer is non-silicone, the molecule defoamer that does not contain hydrophobic nature silane; Wetting agent is acetylenic diols polyfunctional surfactant.Defoamer is the molecule defoamer of non-ionic type, not containing silicone, also not containing hydrophobic nature silane, avoid conventional surfactant because very strong hydrophobic chain interaction and polymer chain are wound around the elimination that hinders foam, also avoided conventional surfactant due to the repulsive interaction of the ionic group inhibition to coating interior discharge opeing, more easily make foam attenuation and break, thering is stronger froth breaking and press down bubble function.Therefore can not produce shrinkage cavity, pin hole, flake and some other unmanageable surface imperfection because bubble causes yet.And acetylenic diols polyfunctional surfactant is typical double type tensio-active agent, molecular weight is little, has hydrophobic-hydrophilic-hydrophobic structure, and water-wet side is little and compact, and outwards stretch hydrophobic side, and the broken bubble that this structure has been given its uniqueness presses down bubble ability; In its structure, hydrophilic radical is positioned at hydrophobic carbochain central authorities, makes it have extremely strong wettability, lower equilibrium surface tension and dynamic surface tension, and surfactivity is strong, and migration is fast.Therefore for the water-borne coatings product of the present embodiment, wettability can play wetting ground, press down the several functions such as bubble froth breaking, surperficial levelling in the processes such as paint rolling applying, dry, film forming.
Further, above-mentioned the first film coalescence aid is elected propylene glycol monobutyl ether as, and the second film coalescence aid is elected Diethylene Glycol butyl ether as; The two is used in conjunction with, and can have good film-forming properties to the water-base resin in the present invention, hydrophilic and hydrophobic and evaporation rate that again can equilibrium system.Wherein, in the present invention for the film forming demand of coating own, film coalescence aid in use need with coating film forming in the character such as minimum film-forming temperature of solvency power, wetting ability, evaporation rate, coating adapt; Adopt above-mentioned these two kinds of film coalescence aid combination collocations to use, because these two kinds of film coalescence aid are in use implementation process, nature stresses to realize complementary, and is more suitable for collaborative film-forming properties, the levelling property that promotes resin major ingredient of the present invention, gloss, the performances such as viscosity stability.
And in the above-described embodiment, thickening material is elected the hydrophobically modified polyurethane-type rheological agent of non-ionic type as, the scratch resistance that wax slurry the is fine grain size polyethylene wax that resistance to wears.Wherein, the selection of above-mentioned thickening material has the function of adjusting viscosity and thixotroping simultaneously, insensitive to the pH value of system, does not reduce gloss and the transparency of paint film.Also participate in film forming simultaneously, improve levelling property.
Wax slurry preferably adopts the polythene wax emulsion of solid content 37% in the present invention, preferably adopts less on gloss impact and in drying varniss process, is easy to the scratch resistance of the fine grain size of the coating surface migration polyethylene wax that resistance to wears; Its object is to improve scuffing and the wearing and tearing of the curtain blade that had been coated with paint film in the post-treatment processes such as transport, installation, and adhesion in packed and transported process.
On the basis of the above, the application's the first flow agent is that modified organic silicon flow agent, the second flow agent are Siloxane-Oxyalkylene Copolymers; Wherein the first flow agent is except strong reduction surface tension, also to increasing slippery, to improve feel very effective, the second flow agent reduces surface tension, promotes ground wetting, antiblocking, prevents the generation of shrinkage cavity.
Finally, on the basis of the above, the present invention adopts AMP-95 organic amine as pH adjusting agent, regulates the potential of hydrogen of water-borne coatings.Certainly, select on basis at above-mentioned material, than regulating the also water yield to supplement, make coating whole synthesis performance can meet similar effect of oil paint to amount.
In the present invention, adopt ACRYLIC EMULSION as one of major ingredient, make coating there is the advantages such as fabulous photostabilization, sticking power, fast drying; And further adopt polyurethane dispersions to promote sticking power, snappiness, the fullness ratio texts of multiple plastic bottom material; And the functional agent that further adopts specified quantitative ratio promotes the effect of coating jointly, make it finally be suitable for shading product and use; And photostabilization, levelling property and rapid drying and resistance to blocking are good, the water-based roller coating coating of the curtain blade of the oil paint that can match in excellence or beauty.
The present invention further proposes a kind of preparation method of water-based roller coating coating of above-mentioned curtain blade, comprises the steps:
S10, obtains a reaction vessel, adds successively the ACRYLIC EMULSION of 50-70%, the polyurethane dispersions of 20-40% according to above-mentioned weight percent, and stirring at low speed is even;
S20, add successively the wetting agent of 0.1-0.5%, the defoamer of 0.5-0.8%, and stirring at low speed is even according to above-mentioned weight percent;
S30, carries out pre-mixing by the water of the second film coalescence aid of the first film coalescence aid of 2-6%, 1-5% and 2-3% and forms mixing film forming compounding agent solution; Mixing film forming compounding agent solution is slowly added in reaction vessel, and stirring at low speed is even;
S40, forms thickener soln by the water pre-mixing of the thickening material of 0.5-2% and 0.5-2%, then thickener soln is slowly added in reaction vessel, and stirring at low speed is even;
S50, is added to the wax slurry of 2-4%, the first flow agent of 0.1-0.5%, the second flow agent of 0.1-0.5% in reaction vessel, and middling speed stirs;
S60, adds the pH adjusting agent of 0-0.2%, regulates pH.
In above-mentioned preparation process, according to the stability requirement of emulsion system, final hierarchy of control pH value is in the slight alkalinity of 7.8-8.5.And the employing of above-mentioned water is preferably deionized water or ultrapure water, avoid foreign metal ion to cause the destruction of emulsion system.
In the process of above-mentioned mix and blend, stirring at low speed is to control the rotating speed of agitating vane between 500 revs/min～800 revs/min, and middling speed stirs rotating speed for referring to agitating vane between 800 revs/min～1500 revs/min.
It is to be noted, being chosen as for major ingredient of above-mentioned functions auxiliary agent in the application, the optimal selection of carrying out in conjunction with required functional effect, under the guidance of above-mentioned principle mechanism, those skilled in the art can carry out according to auxiliary agent general knowledge other the selecting of similar functions auxiliary agent, and can realize equally identical effect and function.
In order to make, aforesaid method process of the present invention is clearer, easy to understand, below is illustrated by multiple embodiment.
Embodiment 1
Obtain raw material according to following weight per-cent: ACRYLIC EMULSION 60%, polyurethane dispersions 24%, wetting agent acetylenic diols multifunctional assistant 0.1%, molecule defoamer 0.5%, the first film coalescence aid propylene glycol monobutyl ether 4.5%, the second film coalescence aid Diethylene Glycol butyl ether 3%, thickening material Acrysol RM-2020NPR (ROHM AND HAAS) 1%, the first flow agent Borchi Gol LA232 (OMG Borchers) 0.3%, the second flow agent Tego410 (enlightening is high) 0.3%, polyethylene wax slurry AQUASLIP671 (Lu Borun) 2%, pH adjusting agent AMP-95 organic amine 0.05%, and surplus deionized water.Preparation process is described below:
S10 adds 60% ACRYLIC EMULSION, 24% polyurethane dispersions in reaction vessel, according to the rotating speed stirring at low speed of 500 revs/min～800 revs/min, and churning time 5 minutes to 10 minutes;
S20, in whipping process, continues to add 0.1% wetting agent, 0.5% defoamer, continues to stir fully to mix for 5 minutes to 10 minutes;
S30, carries out pre-mixing by the deionized water of the first film coalescence aid of 4.5%, the second film coalescence aid of 2.5% and 2% and forms film coalescence aid mixture; Under the state that maintains stirring, film coalescence aid mixture is slowly added in reaction vessel;
S40, carries out pre-mixing by the deionized water of 1% thickening material and 1% and forms thickener soln; Under the state that maintains stirring, thickener soln is slowly joined in reaction vessel to churning time 10 minutes to 20 minutes;
S50, continues to add 2% wax slurry, the first flow agent of 0.4%, the second flow agent of 0.3% in reaction vessel; And promote stirring velocity to 800 rev/min～1500 revs/min, continue to stir 20 minutes to 30 minutes; Finally add 0.05% PH conditioning agent, hierarchy of control pH value is 7.9.
S60, adds surplus deionized water, and stirring at low speed 10 minutes, obtains coating pre-product; Coating pre-product is carried out to filtration treatment, and the packaging of weighing, is coating product.
Embodiment 2
Obtain raw material according to following weight per-cent: ACRYLIC EMULSION 55%, polyurethane dispersions 30%, wetting agent 0.1%, defoamer 0.5%, the first film coalescence aid propylene glycol monobutyl ether 3.5%, the second film coalescence aid Diethylene Glycol butyl ether 2%, thickening material Acrysol RM-2020NPR (ROHM AND HAAS) 1%, the first flow agent Borchi Gol LA232 (OMG Borchers) 0.4%, the second flow agent BYK337 (BYK) 0.3%, polyethylene wax slurry AQUASLIP671 (Lu Borun) 3%, pH adjusting agent 0.05%, and surplus ultrapure water.
Preparation process is carried out with reference to the step in embodiment 1.
Embodiment 3
Obtain raw material according to following weight per-cent: ACRYLIC EMULSION: 58%; Polyurethane dispersions: 26%; Wetting agent 0.2%; Defoamer 0.5%; Propylene glycol monobutyl ether: 4.5%; Diethylene Glycol butyl ether: 2.5%; The hydrophobically modified polyurethane-type rheological agent of non-ionic type: 1%; The first flow agent Tego482 (enlightening is high) 0.4%; The second flow agent BYK337 (BYK) 0.3%; Polyethylene wax slurry AQUACER513 (BYK) 2%; AMP-95 organic amine 0.05%, and the water of surplus.
Preparation process is carried out with reference to the step in embodiment 1.
By the product of above-described embodiment 1-3 in the application, construct on PVC blade, ABS blade PS blade and wood chip, carry out performance test, carry out performance test, its result is as follows:
Wherein, above-mentioned B is sticking power rank, and 5B is the highest, and 0B sticking power is minimum.
From the effect of the above-mentioned construction testing of the present invention, can just find out, the performance of the water-borne coatings in the present invention is selected through above-mentioned material, amount ratio, and its construction at curtain blade can reach the effect of similar oil paint completely.
Adopt the water-based roller coating coating of the above-mentioned curtain blade of preparing gained of the present invention, can construct in multiple plastic rubber substrates such as ABS, PS, PVC, be also applicable to Wooden curtain blade.It has outstanding fullness ratio, good decorating effect; Good photostabilization, is suitable for shading product; Low smell, is applicable to indoor product and uses; Good levelling property and rapid drying and anti-after tackiness, be applicable to streamline roller coating application and operation, the functional effect oil paint that can match in excellence or beauty.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Claims (10)
1. for a water-based roller coating coating for curtain blade, it is characterized in that, comprise following component:
ACRYLIC EMULSION 50～70%, polyurethane dispersions 20～40%, wetting agent 0.1～0.5%, defoamer 0.5～0.8%, the first film coalescence aid 2～6%, the second film coalescence aid 1～5%, thickening material 0.5～2%, wax slurry 2～4%, the first flow agent 0.1～0.5%, the second flow agent 0.1～0.5%, pH adjusting agent 0～0.2%, water 3～6%.
2. the water-based roller coating coating for curtain blade as claimed in claim 1, is characterized in that, described ACRYLIC EMULSION is the anionic acrylate copolymer emulsion of self-crosslinking under room temperature.
3. the water-based roller coating coating for curtain blade as claimed in claim 1 or 2, is characterized in that the polyester-polyurethane ester dispersion that described polyurethane dispersions is anionic.
4. the water-based roller coating coating for curtain blade as claimed in claim 1 or 2, is characterized in that, described the first film coalescence aid is propylene glycol monobutyl ether, and/or described the second film coalescence aid is Diethylene Glycol butyl ether.
5. the water-based roller coating coating for curtain blade as claimed in claim 1 or 2, is characterized in that, described wetting agent is acetylenic diols polyfunctional surfactant.
6. the water-based roller coating coating for curtain blade as claimed in claim 1 or 2, is characterized in that, described defoamer is non-silicone, the molecule defoamer that does not contain hydrophobic nature silane.
7. the water-based roller coating coating for curtain blade as claimed in claim 1 or 2, is characterized in that, the hydrophobically modified polyurethane-type rheological agent that described thickening material is non-ionic type.
8. the water-based roller coating coating for curtain blade as claimed in claim 1 or 2, is characterized in that, described wax slurry is polyethylene wax;
And/or
Described pH adjusting agent is AMP-95 organic amine.
9. the water-based roller coating coating for curtain blade as claimed in claim 1 or 2, is characterized in that, described the first flow agent is modified organic silicon flow agent, and/or described the second flow agent is Siloxane-Oxyalkylene Copolymers.
10. the water-based roller coating preparation method for coating for curtain blade described in claim 1 to 9 any one, is characterized in that, comprises the steps:
Described ACRYLIC EMULSION, polyurethane dispersions are added in reaction vessel and evenly mixed;
In described reaction vessel, add described wetting agent and defoamer, evenly mix;
Described the first film coalescence aid, the second film coalescence aid are carried out to pre-mixing formation with water and mix film forming compounding agent solution, more described mixing film forming compounding agent solution is slowly added in described reaction vessel, evenly mix;
Described thickening material and water pre-mixing are formed to thickener soln, more described thickener soln is slowly added in described reaction vessel, evenly mix;
Described wax slurry, the first flow agent, the second flow agent are added in described reaction vessel, evenly mix;
With described pH adjusting agent adjusting pH to 7.8～8.5.
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| CN113480933A (en) * | 2021-06-07 | 2021-10-08 | 君子兰涂料（天津）有限公司 | Hard PVC water-based white coating and preparation method thereof |
| CN115142266A (en) * | 2022-08-02 | 2022-10-04 | 常州雅美特窗饰股份有限公司 | Manufacturing method of stay-rope-free pleated curtain fabric |
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| CN104164150B (en) | 2016-05-18 |
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