CN105820700A - High-flash-point gloss silver aerial fog spraying paint and preparation method thereof - Google Patents
High-flash-point gloss silver aerial fog spraying paint and preparation method thereof Download PDFInfo
- Publication number
- CN105820700A CN105820700A CN201610398663.2A CN201610398663A CN105820700A CN 105820700 A CN105820700 A CN 105820700A CN 201610398663 A CN201610398663 A CN 201610398663A CN 105820700 A CN105820700 A CN 105820700A
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- CN
- China
- Prior art keywords
- trimethylbenzene
- metallic aluminium
- aluminium pigment
- petropols
- flash
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to high-flash-point gloss silver aerial fog spraying paint and a preparation method thereof. The spraying paint is prepared from, by mass, 5-15% of petroleum resin, 5-15% of n-butyl acetate, 1-10% of xylene, 15-25% of trimethylbenzene, 1-10% of acetic ether, 4-10% of metal aluminum pigment and 30-50% of dimethyl ether aerosol propellant. The flash point of the spraying paint is 21 DEG C or above, and the safety performance is high; the pigment storage stability is high, and the heat storage stability reaches up to 90 d or longer; use is easy and convenient.
Description
Technical field
The present invention relates to a kind of high-flash silver lustre aerosol spray paint.
Background technology
Flash-point refers to that the steam that flammable liquid surface volatilizes be enough to cause the minimum temperature of flash burn.Flash-point is flammable liquid storage
The safety index deposited, transport and use, is to weigh the important parameter that flammable liquid is dangerous.The sudden strain of a muscle of flammable liquid
Point is the lowest, and its fire risk is the biggest.
In Japan, according to fire-fighting rule, by danger, flammable liquid is divided three classes: the first petroleum-type (flash-point ＜ 21 DEG C
Liquid), the second petroleum-type (liquid of flash-point 21-70 DEG C), the 3rd petroleum-type (liquid that flash-point ＞ is 70 DEG C).The U.S.,
The country such as West Germany has the most all formulated the hazardous classification requirement of its domestic use.Although various countries and different industries are for flammable liquid
The understanding of body and require not quite identical, but flash-point is low, be readily burned caused public security Vigilance this point is complete
Consistent.The most a lot of countries, this index of flash-point for paint of coating product has corresponding requirement and restriction,
Its main purpose is to ensure that the safety during producing, store, transport and using of the paint of coating product.
Domestic traditional silver color aerosol paint is in order to reach preferable metal effect, and formula design is rapid draing type, use
Dicyandiamide solution flash-point is relatively low, and even below 0 DEG C, this is the most unfavorable to storing and safety in utilization；Although foreign market has
The silver color aerosol paint of higher flash point, but owing to film-forming resin selects the improper and defect of formula composition, cause product storage stable
Property bad, placing the paint film of ejection after a period of time, without the metal sense of brilliant white, becomes dull gray, the beautifying and decorating effect of product
Fruit drastically declines.
Summary of the invention
For overcoming disadvantages described above, this application provides a kind of high-flash, the silver lustre aerosol spray paint that stability is high.
This sprays paint and on the one hand uses special low acid value resin, keeps the color and luster of metallic pigments, it is ensured that the stability of product；Separately
On the one hand use the organic solvent of multiple middle high-flash to be combined, make the flash-point of product reach more than 21 DEG C, it is ensured that product
Safety.
Described spraying paint is made up of following components by mass percentage: Petropols 5-15%, butyl acetate 5-15%；Diformazan
Benzene 1-10%；Trimethylbenzene 15-25%；Ethyl acetate 1-10%, metallic aluminium pigment 4-10%, dimethyl ether propellant 30-50%.
Optimum ratio is: mass percent is made up of following components: Petropols 10%, butyl acetate 8%；Dimethylbenzene
2%；Trimethylbenzene 23%；Ethyl acetate 2%, metallic aluminium pigment 5%, dimethyl ether propellant 50%.
The optional group aliphatic resin of described Petropols or, alicyclic resin, aromatic resin or aliphatic/aromatic copolymerization tree
One or more mixing in fat or hydrogenated petroleum resin.
Originally spray paint and prepared by following methods:
1, metallic aluminium pigment trimethylbenzene solution: metallic aluminium pigment is put into scuffing of cylinder bore, adds the trimethylbenzene of equivalent, seals,
Soak 24 hours, stir, to without bulk granule, form metallic aluminium pigment trimethylbenzene solution；
2, Petropols trimethylbenzene solution: remaining trimethylbenzene is put into scuffing of cylinder bore, with the speed of 800 revs/min, with dispersion
Machine stirs；It is slowly added to solid petroleum resin while stirring；With the speed of 2000 revs/min after adding, dispersed with stirring 60
Minute, as clear as crystal to solution, fineness of the particles ＜ 5 microns；
3, dispensing: Petropols trimethylbenzene solution is put in scuffing of cylinder bore, sequentially adds metallic aluminium pigment trimethylbenzene solution,
Other solvent, uniform with the speed stirring at low speed of 500 revs/min, form metallic aluminium pigment feed liquid, fill, fill liquefaction
Dimethyl ether, makes the product that sprays paint.
The present invention sprays paint and has the advantage that relative to existing silver lustre aerosol spray paint
Traditional product flash-point is typically at about-10 DEG C, and the technology of the present invention product, more than 21 DEG C, exceeds than traditional product
About 30 DEG C, greatly enhance the security performance of product；Traditional product storage at normal temperature sprays i.e. to go out after about 1 year
The phenomenon that existing burnt hair is dimmed, metal bright white effect is remarkably decreased, but product of the present invention can storage at normal temperature spraying effect after about 3 years
The most constant, metal effect still brilliant white is as before.The present invention can be made into aerosol, easy to use.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further.
One, the preparation method of the present embodiment product:
1, metallic aluminium pigment trimethylbenzene solution: metallic aluminium pigment is put into scuffing of cylinder bore, adds the trimethylbenzene of equivalent, seals,
Soak 24 hours, stir, to without bulk granule, form metallic aluminium pigment trimethylbenzene solution.
2, Petropols trimethylbenzene solution: remaining trimethylbenzene is put into scuffing of cylinder bore, with the speed of 800 revs/min, with dispersion
Machine stirs；It is slowly added to solid petroleum resin while stirring；With the speed of 2000 revs/min after adding, dispersed with stirring 60
Minute, as clear as crystal to solution, fineness of the particles ＜ 5 microns.
3, dispensing: Petropols trimethylbenzene solution is put in scuffing of cylinder bore, sequentially adds metallic aluminium pigment trimethylbenzene solution,
Other solvent, uniform with the speed stirring at low speed of 500 revs/min, form metallic aluminium pigment feed liquid.
4, metallic aluminium pigment feed liquid is after quality inspection is qualified, filters and removes mechanical admixture, filling fill, adds valve compacting
Sealing, fill liquefied dimethyl ether, check weighing leaks hunting, and installs button and lid additional, enters case packing.
Two, bin stability detection method: use 50 DEG C of calorstat heat storages, hand spray, the side of visualization spray plate effect
Method.Heat storage is roughly equivalent to natural conditions for 1 month and stores 1 year.
Three, flash-point detection method: use GB/T 5208-2008 " flashing test Fast-Balance closed-cup method ".
Four, with existing silver lustre aerosol spray paint as a control group, matched group formula is: acrylic resin 10%, butyl acetate 6%,
Ethyl acetate 15%, toluene 14%, acetone 20%, metallic aluminium pigment 5%, dimethyl ether propellant 30%, preparation is sprayed paint,
Standby.
Formula and the testing result of embodiment are shown in Table 1.
Table 1
As can be seen from Table 1, traditional formula for a product selects acrylic resin to be film forming matter, owing to acrylic acid carboxyl is tied
Structure easily corrodes the surface of aluminum pigment, makes aluminum pigment gradually lose original glossy surface structure in storage process, thus
The stability causing product is bad；And the selection of the technology of the present invention product is Petropols, its chemical constitution will not be to aluminum pigment
Surface damages, so can guarantee that the bin stability of product, keeps original metallic luster.Traditional formula for a product
Structure in solvent major part is low-flash solvent, and the flash-point causing product is the lowest；And the technology of the present invention product employs substantial amounts of height
Flash point solvents, to ensure that product has sufficiently high flash-point.But extremely complex in the selection of component, and not necessarily in regular
Dependency relation.
Claims (4)
1. a high-flash silver lustre aerosol spray paint, it is characterised in that described in spray paint by mass percentage by following components system
Become: Petropols 5-15%, butyl acetate 5-15%；Dimethylbenzene 1-10%；Trimethylbenzene 15-25%；Ethyl acetate 1-10%,
Metallic aluminium pigment 4-10%, dimethyl ether propellant 30-50%.
Spray paint the most as claimed in claim 1, it is characterised in that described in spray paint by mass percentage by following components system
Become: Petropols 10%, butyl acetate 8%；Dimethylbenzene 2%；Trimethylbenzene 23%；Ethyl acetate 2%, metallic aluminium pigment 5%,
Dimethyl ether propellant 50%.
Spray paint the most as claimed in claim 1 or 2, it is characterised in that described Petropols be group aliphatic resin or, fat
Ring hydroxy-aromatic resin, aromatic resin or aliphatic/aromatic copolymer resins or hydrogenated petroleum resin.
The preparation method sprayed paint the most as claimed in claim 1, it is characterised in that comprise the following steps:
(1) metallic aluminium pigment trimethylbenzene solution: metallic aluminium pigment is put into scuffing of cylinder bore, adds the trimethylbenzene of equivalent, seals,
Soak 24 hours, stir, to without bulk granule, form metallic aluminium pigment trimethylbenzene solution；
(2) Petropols trimethylbenzene solution: remaining trimethylbenzene is put into scuffing of cylinder bore, with the speed of 800 revs/min, with dispersion
Machine stirs；It is slowly added to solid petroleum resin while stirring；With the speed of 2000 revs/min after adding, dispersed with stirring 60
Minute, as clear as crystal to solution, fineness of the particles ＜ 5 microns；
(3) dispensing: Petropols trimethylbenzene solution is put in scuffing of cylinder bore, add metallic aluminium pigment trimethylbenzene solution and other
Component, uniform with the speed stirring at low speed of 500 revs/min, form metallic aluminium pigment feed liquid, fill, fill liquefaction diformazan
Ether, makes target product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610398663.2A CN105820700B (en) | 2016-06-06 | 2016-06-06 | A kind of high-flash silver lustre aerosol spray paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610398663.2A CN105820700B (en) | 2016-06-06 | 2016-06-06 | A kind of high-flash silver lustre aerosol spray paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105820700A true CN105820700A (en) | 2016-08-03 |
| CN105820700B CN105820700B (en) | 2018-12-21 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610398663.2A Active CN105820700B (en) | 2016-06-06 | 2016-06-06 | A kind of high-flash silver lustre aerosol spray paint and preparation method thereof |
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| Country | Link |
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| CN (1) | CN105820700B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519858A (en) * | 2016-11-02 | 2017-03-22 | 美国三和（香港）化工科技集团有限公司 | Spray paint and preparation method thereof |
| CN116082897A (en) * | 2022-10-18 | 2023-05-09 | 广东自由能科技股份有限公司 | Aerosol paint suitable for underground parking lot scribing and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10249716A1 (en) * | 2002-10-25 | 2004-05-06 | Josef Kalder | Conditioning plastic surfaces against dirt and graffiti, e.g. acrylic sheet on bridges and bus shelters, involves shot peening with micro-spheres and coating with protective, anti-soiling varnish which fills the micro-craters |
| CN101294049A (en) * | 2008-06-20 | 2008-10-29 | 中山市三和气雾有限公司 | Aerosol photopolymer coating |
| CN101580667A (en) * | 2009-06-03 | 2009-11-18 | 李明友 | Anti-corrosion spray painting on metal surface and preparation method thereof |
| CN102604588A (en) * | 2012-03-06 | 2012-07-25 | 福建省南安市大洋气雾剂制造有限公司 | Universal adhesive and preparation technology thereof |
| CN103484003A (en) * | 2013-09-03 | 2014-01-01 | 三棵树涂料股份有限公司 | Polishable bright varnish for electrostatic spraying and preparation method thereof |
| CN103709863A (en) * | 2013-12-13 | 2014-04-09 | 杨健明 | Flame-retardant aerosol paint for mine marking |
| CN103756499A (en) * | 2014-01-17 | 2014-04-30 | 中山市大田汽车护理用品有限公司 | Chroming automatic spray paint and preparation method thereof |
-
2016
- 2016-06-06 CN CN201610398663.2A patent/CN105820700B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10249716A1 (en) * | 2002-10-25 | 2004-05-06 | Josef Kalder | Conditioning plastic surfaces against dirt and graffiti, e.g. acrylic sheet on bridges and bus shelters, involves shot peening with micro-spheres and coating with protective, anti-soiling varnish which fills the micro-craters |
| CN101294049A (en) * | 2008-06-20 | 2008-10-29 | 中山市三和气雾有限公司 | Aerosol photopolymer coating |
| CN101580667A (en) * | 2009-06-03 | 2009-11-18 | 李明友 | Anti-corrosion spray painting on metal surface and preparation method thereof |
| CN102604588A (en) * | 2012-03-06 | 2012-07-25 | 福建省南安市大洋气雾剂制造有限公司 | Universal adhesive and preparation technology thereof |
| CN103484003A (en) * | 2013-09-03 | 2014-01-01 | 三棵树涂料股份有限公司 | Polishable bright varnish for electrostatic spraying and preparation method thereof |
| CN103709863A (en) * | 2013-12-13 | 2014-04-09 | 杨健明 | Flame-retardant aerosol paint for mine marking |
| CN103756499A (en) * | 2014-01-17 | 2014-04-30 | 中山市大田汽车护理用品有限公司 | Chroming automatic spray paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519858A (en) * | 2016-11-02 | 2017-03-22 | 美国三和（香港）化工科技集团有限公司 | Spray paint and preparation method thereof |
| CN116082897A (en) * | 2022-10-18 | 2023-05-09 | 广东自由能科技股份有限公司 | Aerosol paint suitable for underground parking lot scribing and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105820700B (en) | 2018-12-21 |
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Effective date of registration: 20190807 Address after: 512029 South 7 Gantang Avenue, Xilian Town, Wujiang District, Shaoguan City, Guangdong Province Patentee after: Guangdong Laiya New Chemical Technology Co., Ltd. Address before: 528333 Guangdong province Foshan city Shunde District Daliang Shunfengshan Industrial Zone Patentee before: Guangdong Laya Chemical Co., Ltd. |
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