CN106753093A - A kind of aerosol photopolymer coating and preparation method thereof - Google Patents
A kind of aerosol photopolymer coating and preparation method thereof Download PDFInfo
- Publication number
- CN106753093A CN106753093A CN201611208324.XA CN201611208324A CN106753093A CN 106753093 A CN106753093 A CN 106753093A CN 201611208324 A CN201611208324 A CN 201611208324A CN 106753093 A CN106753093 A CN 106753093A
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- Prior art keywords
- aerosol
- glue
- photopolymer
- antioxidant
- photopolymer coating
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of aerosol photopolymer coating disclosed by the invention, is mixed by the glue and propellant that are seated in aerosol hermetically sealed can, and glue is 1~5 with the mass ratio of propellant:1, wherein glue is made up of the component of following weight portion content：12 parts of thermoplastic elastomer (TPE), 10~30 parts of resin, 0~5 part of plasticizer, 0~5 part of stabilizer, 0~5 part of antirust agent, 0~5 part of filler, 50~75 parts of solvent.The invention also discloses the preparation method of the aerosol photopolymer coating.Advantages of the present invention：Do not need extra pressure equipment, spraying all facilitated at any time, glue spraying atomizing effect is good, and do not float silk, particulate fines and it is uniform, penetration is low, and not perishable ground, has no irritating odor；Can be used for tinsel, glass fibre, polystyrene, glued membrane, foamed glue, cloth, paper, leather etc. and metal, timber, the homogeneity of large area or heterogeneous bonding between glass and other materials are largely used to Primary Location stickup.
Description
Technical field
The present invention relates to a kind of adhesive, specifically, it is related to a kind of aerosol photopolymer coating and preparation method thereof.
Background technology
Glue spraying is related to many industries as one kind of adhesive, is widely applied in industrial and civilian being obtained for.Glue spraying
With relatively low viscosity, rapid draing, initial alignment is quick, relative to other resin application methods, with uniform adhesive linkage, saves
With glue and manually.
Glue spraying in the market mainly has two major classes：One class is thermoplastic elastomer (TPE) glue spraying, with thermoplastic elastomer (TPE)
SBS, SEBS, SIS, SBR etc. be main component, low cost, just glue, it is convenient for production；Another kind of is exactly the spray of neoprene class
Glue,, with neoprene as main component, the glue sticking performance is good, and temperature tolerance is high, and production technology is more complicated for it.But traditional spray
Apply generally carries out spraying of having ready conditions, and tradition spray in the case where there is electricity to drive air compressor machine using spray gun, air compressor machine and pipeline
Apply territory restriction, inconvenience transfer spraying.
The sprayable property of other non-adhesive products is used for reference, inhalator jar is employed after carrying out performance upgrade to adhesive products
Dress carries pressure glue spraying, i.e. aerosol photopolymer coating.Aerosol photopolymer coating is to fill valvular gas by glue is filling together with propellant
In mist hermetically sealed can, then glue is sprayed a kind of product for using by the pressure of propellant.The glue spraying of this can type is more
It is suitable for the industry of often transfer spraying.Traditional glue spraying product viscosity is high, be not suitable for it is this spraying it is filling, the product must be protected
Card viscosity can not it is too high, can not have wire drawing phenomenon (otherwise atomizing effect is bad), to have certain initial bonding strength, it is often more important that also
It is miscible uniform with propellant stabilization.
Industry, embroidery industry, Decoration Industry etc. is molded in wind electricity blade at present to be all widely used.
The content of the invention
An object of the present invention is to provide a kind of aerosol photopolymer coating, and it includes two components of glue and propellant.By glue
Liquid is filling together with propellant to be filled in valvular aerosol hermetically sealed can.To solve the inconvenience transfer spraying of conventional spray paint, can be with
Spray whenever and wherever possible.
The second object of the present invention is the preparation method for providing above-mentioned aerosol photopolymer coating.
To realize the purpose of the present invention, the technical scheme is that：
A kind of aerosol photopolymer coating, is mixed by the glue and propellant that are seated in aerosol hermetically sealed can, the glue with
The mass ratio of the propellant is 1~5:1；Wherein
The glue, is made up of the component of following weight portion content：
In the preferred embodiment of the present invention, the glue is made up of the component of following weight portion content：
In the preferred embodiment of the present invention, the thermoplastic elastomer (TPE) be SBS (line style or hub-and-spoke configuration), SEBS,
One kind or any two or more mixing in SIS, SBR.
In the preferred embodiment of the present invention, the SBS is linear structure or hub-and-spoke configuration.
In the preferred embodiment of the present invention, the resin is rosin, modified rosin resin, coumarone indene resin, terpenes
One kind in resin, terpene phenol resin, tertiary butyl phenol resin, tertiary butyl phenol formaldehyde resin, styrene resin, Petropols or any two
Plant the mixing of the above.
In the preferred embodiment of the present invention, the plasticizer is 2,2,4- trimethyl -1, the isobutyric acid of 3- pentanediols two
One kind or any two or more mixing in ester, phthalic ester plasticizer.
In the preferred embodiment of the present invention, the stabilizer is oil product antioxidant, Hinered phenols antioxidant, phosphorous acid
In esters antioxidant, the composite antioxidant, the sulphur ester antioxidant that are made up of Hinered phenols antioxidant and phosphite ester kind antioxidant
One kind or any two or more mixing.
In the preferred embodiment of the present invention, the oil product antioxidant is 2,6- di-tert-butyl -4- methylphenols
(BHT)。
In the preferred embodiment of the present invention, the Hinered phenols antioxidant is antioxidant 1010.
In the preferred embodiment of the present invention, the phosphite ester kind antioxidant is irgasfos 168.
In the preferred embodiment of the present invention, the sulphur ester antioxidant is dilauryl thiodipropionate (DLTP).
In the preferred embodiment of the present invention, the antirust agent is morpholine.
In the preferred embodiment of the present invention, described filler is calcium carbonate, silicon powder, kaolin, barium sulfate, diatomite
With the one kind in silica or any two or more mixing.
In a more preferred embodiment of the invention, the calcium carbonate is nano-calcium carbonate, precipitated calcium carbonate, heavy carbonic acid
One kind or any two or more mixing in calcium.
In the preferred embodiment of the present invention, the solvent is toluene, dimethylbenzene, chlorobenzene, gasoline, solvent naphtha, raffinate
Oil, n-hexane, hexamethylene, isohexane, normal heptane, ethyl acetate, butyl acetate, isoamyl acetate, dichloromethane, two chloroethenes
One kind in alkane, tetrachloro-ethylene, tetrachloroethanes, carbon tetrachloride, butanone, cyclohexanone, dimethyl carbonate, methyl acetate or any two
Plant the mixing of the above.
In the preferred embodiment of the present invention, the propellant is one or two mixing of the third butane, dimethyl ether.
In the preferred embodiment of the present invention, the safe filling rate 15%~85% of the aerosol hermetically sealed can, aerosol sealing
Safe internal pressure≤the 1.0MPa of the filling (55 DEG C) of tank.
The preparation method of aerosol photopolymer coating of the invention, comprises the following steps：
It is prepared by step 1, glue：
At 5 DEG C -40 DEG C, to solvent and plasticizer is added in reactor, then low rate mixing adds resin, adds steady
Determine agent, add antirust agent stirring 30 minutes；Moderate-speed mixer adds thermoplastic elastomer (TPE), adds filler, and high-speed stirred 2h~
Aerosol photopolymer coating glue is obtained after 4h；
Step 2：It is filling：
After the filter screen filtration of glue use >=100 mesh prepared by step 1, clean dry aerosol sealing is loaded by quantitative
In tank, valve and aerosol hermetically sealed can are encapsulated with sealing machine, quantitative propellant is irrigated to aerosol hermetically sealed can with bottler placer, spray is installed
Mouth (the optimal spray site of alignment) and cover.
In the preferred embodiment of the present invention, described valve is one kind of female or male valve.
Aerosol photopolymer coating of the invention its advantage compared with traditional glue spraying is：
Do not need extra pressure equipment, spraying all facilitated at any time, glue spraying atomizing effect is good, and do not float silk, particulate fines and it is uniform,
Penetration is low, and not perishable ground, has no irritating odor；Can be used for tinsel, glass fibre, polystyrene, glued membrane, hair
Bubble glue, cloth, paper, leather etc. and metal, timber, the homogeneity of large area or heterogeneous bonding between glass and other materials,
It is largely used to Primary Location stickup.
Specific embodiment
The present invention is further illustrated below by embodiment, but present disclosure is not limited to this completely.
Embodiment 1：
Glue is formulated：
Glue preparation method：
In the 1000ml there-necked flasks with agitator, by above weight expand 5 times, add hexamethylene, solvent naphtha,
TXIB, after adding rosin, terpene resin, BHT, morpholine to stir in the case of low rate mixing 30 minutes, moderate-speed mixer add SBS (S/B
=4/6), calcium carbonate, high-speed stirred 2h~4h is made glue.
Packaging process：
By glue with 150 mesh nylon net filters after, take glue 360g and be fitted into clean dry 847ml aerosols hermetically sealed can,
Valve and aerosol hermetically sealed can are encapsulated with sealing machine, the butane of 120g third is irrigated to aerosol hermetically sealed can with bottler placer, nozzle is installed (right
Accurate optimal spray site) and cover.
By the present embodiment prepare obtained by aerosol and glue spraying be used to be bonded llowing group of materials (surface is only carried out at decontamination drying
Reason), according to《The measure of GB/T532-2008 vulcanized rubbers or thermoplastic elastomer and fabric bonding strength》Standard, determines solidification
Adhesive strength (23 DEG C) data of sticky object after 24h are as shown in table 1：
Table 1
180 ° of peel strengths of bonded object title, N/2.5 ㎝
Canvas/canvas 17.8
Glass/glass glass deformation
The glue spraying that in the market is commonly used in embroidery is used to be bonded 180 ° of peel strength 8.5N/2.5 ㎝ of canvas, it is seen that this
The aerosol photopolymer coating of invention is good to the adhesive effect of canvas, is adapted to glass positioning bonding.
Embodiment 2：
Glue is formulated：
Glue preparation method：
In the 1000ml there-necked flasks with agitator, 5 times are expanded by above weight, add dimethyl carbonate, solvent
Oil, DBP, in the case of low rate mixing add rosin, terpene resin, Petropols, BHT, morpholine stir 30 minutes after, moderate-speed mixer
SIS, calcium carbonate, high-speed stirred 2h~4h is added to be made glue.
Packaging process：
By glue with 150 mesh nylon net filters after, take glue 300g and be fitted into clean dry 847ml aerosols hermetically sealed can,
Valve and aerosol hermetically sealed can are encapsulated with sealing machine, the butane of 180g third is irrigated to aerosol hermetically sealed can with bottler placer, nozzle is installed (right
Accurate optimal spray site) and cover.
By the present embodiment prepare obtained by aerosol and glue spraying be used to be bonded llowing group of materials (surface is only carried out at decontamination drying
Reason), according to《The measure of GB/T532-2008 vulcanized rubbers or thermoplastic elastomer and fabric bonding strength》Standard, determines solidification
Adhesive strength (23 DEG C) data of sticky object after 24h are as shown in table 2：
Table 2
180 ° of peel strengths of bonded object title, N/2.5 ㎝
Canvas/canvas 15.7
Glass/glass glass deformation
The glue spraying that in the market is commonly used in embroidery is used to be bonded 180 ° of peel strength 8.5N/2.5 ㎝ of canvas, it is seen that this
The aerosol photopolymer coating of invention is good to the adhesive effect of canvas, is adapted to glass positioning bonding.
Embodiment 3：
Glue is formulated：
Glue preparation method：
In the 1000ml there-necked flasks with agitator, by above weight expand 5 times, add hexamethylene, n-hexane,
DBP, in the case of low rate mixing add rosin, terpene resin, ester gum, BHT, morpholine stir 30 minutes after, moderate-speed mixer
SBR, silica, high-speed stirred 2h~4h is added to be made glue.
Packaging process：
By glue with 150 mesh nylon net filters after, take glue 300g and be fitted into clean dry 847ml aerosols hermetically sealed can,
Valve and aerosol hermetically sealed can are encapsulated with sealing machine, the butane of 100g third is irrigated to aerosol hermetically sealed can with bottler placer, 80g dimethyl ether,
Nozzle (the optimal spray site of alignment) and cover are installed.
Claims (19)
1. a kind of aerosol photopolymer coating, is mixed by the glue and propellant that are seated in aerosol hermetically sealed can, the glue and institute
The mass ratio for stating propellant is 1~5:1；Wherein
The glue, is made up of the component of following weight portion content：
2. aerosol photopolymer coating according to claim 1, it is characterised in that the glue, by the group of following weight portion content
It is grouped into：
3. aerosol photopolymer coating according to claim 1 or claim 2, it is characterised in that the thermoplastic elastomer (TPE) of the adhesive, refers to
It is SBS, SEBS, SIS, one kind or any two or more mixing in SBR.
4. aerosol photopolymer coating according to claim 3, it is characterised in that the SBS is linear structure or hub-and-spoke configuration.
5. aerosol photopolymer coating according to claim 1 or claim 2, it is characterised in that the resin be rosin, modified rosin resin,
Coumarone indene resin, terpene resin, terpene phenol resin, tertiary butyl phenol resin, tertiary butyl phenol formaldehyde resin, styrene resin, Petropols
In one kind or any two or more mixing.
6. adhesive according to claim 1 or claim 2, it is characterised in that the plasticizer is 2,2,4- trimethyl -1,3- penta 2
One kind or any two or more mixing in alcohol diisobutyrate (TXIB), phthalic ester plasticizer.
7. aerosol photopolymer coating according to claim 1 or claim 2, it is characterised in that the stabilizer is oil product antioxidant, hindered phenol
Kind antioxidant, phosphite ester kind antioxidant, the composite antioxidant being made up of Hinered phenols antioxidant and phosphite ester kind antioxidant,
One kind or any two or more mixing in sulphur ester antioxidant.
8. aerosol photopolymer coating as claimed in claim 7, it is characterised in that the oil product antioxidant is 2,6- di-tert-butyl -4- first
Base phenol (BHT).
9. aerosol photopolymer coating as claimed in claim 7, it is characterised in that the Hinered phenols antioxidant is antioxidant 1010.
10. aerosol photopolymer coating as claimed in claim 7, it is characterised in that the phosphite ester kind antioxidant is irgasfos 168.
11. aerosol photopolymer coatings as claimed in claim 7, it is characterised in that the sulphur ester antioxidant is thiodipropionic acid dilauryl
Osmanthus ester (DLTP).
12. aerosol photopolymer coatings according to claim 1 or claim 2, it is characterised in that the antirust agent is morpholine.
13. aerosol photopolymer coatings according to claim 1 or claim 2, it is characterised in that described filler is calcium carbonate, silicon powder, kaolinite
One kind or any two or more mixing in soil, barium sulfate, diatomite and silica.
14. according to claim 13 aerosol photopolymer coating, it is characterised in that the calcium carbonate be nano-calcium carbonate, lightweight carbon
One kind or any two or more mixing in sour calcium, powdered whiting.
15. aerosol photopolymer coatings according to claim 1 or claim 2, it is characterised in that the solvent be toluene, dimethylbenzene, chlorobenzene,
Gasoline, solvent naphtha, raffinate oil, n-hexane, hexamethylene, isohexane, normal heptane, ethyl acetate, butyl acetate, isoamyl acetate,
Dichloromethane, dichloroethanes, tetrachloro-ethylene, tetrachloroethanes, carbon tetrachloride, butanone, cyclohexanone, dimethyl carbonate, methyl acetate
In one kind or any two or more mixing.
16. aerosol photopolymer coatings according to claim 1 or claim 2, it is characterised in that the propellant is the third butane, dimethyl ether
One or two mixing.
17. aerosol photopolymer coatings according to claim 1 or claim 2, it is characterised in that the safe filling rate 15% of aerosol hermetically sealed can
~85%, the safe internal pressure≤1.0MPa of the filling (55 DEG C) of aerosol hermetically sealed can.
The preparation method of the aerosol photopolymer coating described in 18. claim 1 to 17 any one claims, crowd fighting is characterised by, wraps
Include following steps：
It is prepared by step 1, glue：
At 5 DEG C -40 DEG C, to solvent and plasticizer is added in reactor, then low rate mixing adds resin, adds stabilization
Agent, add antirust agent stir 30 minutes；Moderate-speed mixer adds thermoplastic elastomer (TPE), adds filler, high-speed stirred 2h~4h
Aerosol photopolymer coating glue is obtained afterwards；
Step 2：It is filling：
After the filter screen filtration of glue use >=100 mesh prepared by step 1, clean dry aerosol hermetically sealed can is loaded by quantitative
In, valve and aerosol hermetically sealed can are encapsulated with sealing machine, quantitative propellant is irrigated to aerosol hermetically sealed can with bottler placer, nozzle is installed
And cover.
19. preparation methods according to claim 18, it is characterised in that described valve is the one of female or male valve
Kind.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611208324.XA CN106753093A (en) | 2016-12-23 | 2016-12-23 | A kind of aerosol photopolymer coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611208324.XA CN106753093A (en) | 2016-12-23 | 2016-12-23 | A kind of aerosol photopolymer coating and preparation method thereof |
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| CN106753093A true CN106753093A (en) | 2017-05-31 |
Family
ID=58920113
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| CN201611208324.XA Pending CN106753093A (en) | 2016-12-23 | 2016-12-23 | A kind of aerosol photopolymer coating and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142055A (en) * | 2017-06-06 | 2017-09-08 | 光山县博正树脂有限公司 | PP, PE special glue and preparation method thereof |
| CN107987760A (en) * | 2017-11-15 | 2018-05-04 | 江门保实捷化工有限公司 | A kind of novel environment friendly adhesive and its preparation method and application |
| CN108048002A (en) * | 2017-11-19 | 2018-05-18 | 朱呈利 | A kind of timber special environment protection adhesive |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101294049A (en) * | 2008-06-20 | 2008-10-29 | 中山市三和气雾有限公司 | Aerosol photopolymer coating |
| CN102604588A (en) * | 2012-03-06 | 2012-07-25 | 福建省南安市大洋气雾剂制造有限公司 | Universal adhesive and preparation technology thereof |
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2016
- 2016-12-23 CN CN201611208324.XA patent/CN106753093A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101294049A (en) * | 2008-06-20 | 2008-10-29 | 中山市三和气雾有限公司 | Aerosol photopolymer coating |
| CN102604588A (en) * | 2012-03-06 | 2012-07-25 | 福建省南安市大洋气雾剂制造有限公司 | Universal adhesive and preparation technology thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142055A (en) * | 2017-06-06 | 2017-09-08 | 光山县博正树脂有限公司 | PP, PE special glue and preparation method thereof |
| CN107987760A (en) * | 2017-11-15 | 2018-05-04 | 江门保实捷化工有限公司 | A kind of novel environment friendly adhesive and its preparation method and application |
| CN107987760B (en) * | 2017-11-15 | 2020-03-24 | 江门保实捷化工有限公司 | Environment-friendly adhesive and preparation method and application thereof |
| CN108048002A (en) * | 2017-11-19 | 2018-05-18 | 朱呈利 | A kind of timber special environment protection adhesive |
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Application publication date: 20170531 |