CN107142055A - PP, PE special glue and preparation method thereof - Google Patents
PP, PE special glue and preparation method thereof Download PDFInfo
- Publication number
- CN107142055A CN107142055A CN201710420215.2A CN201710420215A CN107142055A CN 107142055 A CN107142055 A CN 107142055A CN 201710420215 A CN201710420215 A CN 201710420215A CN 107142055 A CN107142055 A CN 107142055A
- Authority
- CN
- China
- Prior art keywords
- parts
- sis1209
- bht
- dimethyl carbonate
- ester gum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
- C09J193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The present invention relates to glue field, more particularly to a kind of PP, PE special glue and preparation method thereof, it is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, ester gum, BHT, wherein the parts by weight of each raw material are as follows：4 12 parts of 6# solvent naphthas, 14 parts of dimethyl carbonate, 39 parts of SIS1209,49 parts of ester gum, 14 parts of BHT；The present invention is by special formula and technique, and PP, PE special glue produced can reach good bond effect.
Description
Technical field
The present invention relates to glue field, more particularly to a kind of PP, PE special glue and preparation method thereof.
Background technology
The common material to PP, PE in life, also widely, PP is that polypropylene is a kind of hemicrystalline to their purposes
Thermoplastic, is mainly used in the production of various long and short polypropylene fibers, for producing polypropylene woven bag, food bag, injection system
Product etc. are used for the fire-retardant parts for producing electrical equipment, telecommunication, lamp decoration, lighting apparatus and television set；PE is polyethylene, for making agriculture
With, food and industrial packaging film, electric wire cladding and coating, composed paper etc., polypropylene（PP）Material, polyethylene
（PE）Plastics are not always too strong in bonding and repairing, and need PP, PE inorganic agent to be adhered by after handling, but bonding aftereffect
Fruit is still barely satisfactory, PP, PE Facing material is hard, it is smooth should not adhere to, be always the problem of many producers are long and pending, more according to
It is expensive by import PP, PE adhesive, nor preferred.
The content of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is to avoid effect is undesirable after treatment by PP, PE, and provides
A kind of PP, PE special glue and preparation method thereof, the present invention is by special formula and technique, PP, PE special glue produced
Good bond effect can be reached.
The purpose of the present invention is achieved by the following measures：A kind of PP, PE special glue, is made up of following raw material：6#
Solvent naphtha, dimethyl carbonate, SIS1209, ester gum, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphthas 4-
12 parts, 1-4 parts of dimethyl carbonate, 3-9 parts of SIS1209,4-9 parts of ester gum, 1-4 parts of BHT.
It is preferred that, the parts by weight of described each raw material are as follows：7-9 parts of 6# solvent naphthas, 2-3 parts of dimethyl carbonate,
5-7 parts of SIS1209,5-8 parts of ester gum, 2-3 parts of BHT.
It is preferred that, the parts by weight of described each raw material are as follows：8 parts of 6# solvent naphthas, 2 parts of dimethyl carbonate, SIS1209 6
Part, 7 parts of ester gum, 2 parts of BHT.
A kind of preparation method of above-mentioned PP, PE special glue, comprises the following steps：4-12 parts of 6# solvent naphthas are on the waiting list first,
1-4 parts of dimethyl carbonate, 3-9 parts of SIS1209,4-9 parts of ester gum, 1-4 parts of BHT；6# solvents will be pumped into stirred tank
Oil, dimethyl carbonate, open electric blender, and rotating speed is adjusted into 80 revs/min, add SIS1209, and ester gum, BHT is incited somebody to action
Motor speed is adjusted to 300 revs/min, stirs 3-4 hours and shuts down, is finally sampled test.
SIS1209 is the main function raw material in the present invention, is that styrene-isoprene-styrene tri-block is common
Polymers, is a kind of new material in SBC classes, due to excellent performance, is widely used in medicine, packaging, fixed, mark and composite wood
The ply adhesion of the material toughener indispensable with being molded the category plastic industry such as toughness reinforcing.For tire shoe bottom, contribute to the rainy day anti-skidding,
Improve security, it has rubber and plastic nature concurrently, its distinguishing feature is that adhesion strength is strong, be melt pressure sensitive viscose binder, coating,
Contain C=C in the primary raw material of solvent type adhesive, modifying plastics product, SIS, radical polymerization therein, strand increases,
Viscosity increase.
Dimethyl carbonate has been applied successfully many as a kind of new low poison solvent in the industry such as paint and adhesive
Year, the alternative toluene used at present, ethyl acetate, butyl acetate, acetone or butanone equal solvent, product environmental protection, technology maturation,
Moderate cost, is applicable not only to nitrate paint, furniture lacquer, automobile coating etc., it may also be used for adhesive industry, application prospect is very wide
It is general.
Ester gum is a kind of tackifying resin, and it increases the effect of viscosity.
BHT is antioxidant, and antioxidant refers to that some can suppress or delay high polymer and other organic compounds in sky
The organic compound of thermal oxide in gas, is the material that polymeric material can be prevented rotten because oxidation causes, can suppress or delay
The oxidative degradation of plastics or rubber and increase the service life.
The beneficial effects of the invention are as follows：PP, PE that the present invention is produced by special formula and simple technological process
Special glue has the advantages that high-performance, high intensity, pliability be good, moisture-proof is good, and positioning time is fast, non-whitening after solidification,
Burn into waterproof, antifreeze, effect be not very good, and the step of being handled before eliminating with PP, PE inorganic agent is easy to use.
Embodiment
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described.
Embodiment 1：A kind of PP, PE special glue, is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, pine
Fragrant glyceride, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphtha 4Kg, dimethyl carbonate 1 Kg, SIS1209 3
Kg, ester gum 4 Kg, BHT 1 Kg.
A kind of preparation method of PP, PE special glue comprises the following steps：The Kg of 6# solvent naphthas 4, dimethyl carbonate are on the waiting list first
The Kg of 1 Kg, SIS1209 3, ester gum 4 Kg, BHT 1 Kg；6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank,
Electric blender is opened, rotating speed is adjusted to 80 revs/min, SIS1209 is added, motor speed is adjusted to 300 by ester gum, BHT
Rev/min, stir 3 hours and shut down, be finally sampled test.
Embodiment 2：A kind of PP, PE special glue, is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, pine
Fragrant glyceride, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphtha 12Kg, dimethyl carbonate 4 Kg, SIS1209
9 Kg, ester gum 9 Kg, BHT 4 Kg.
A kind of preparation method of PP, PE special glue comprises the following steps：6# solvent naphtha 12Kg, dimethyl carbonate are on the waiting list first
The Kg of 4 Kg, SIS1209 9, ester gum 9 Kg, BHT 4 Kg；6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank,
Electric blender is opened, rotating speed is adjusted to 80 revs/min, SIS1209 is added, motor speed is adjusted to 300 by ester gum, BHT
Rev/min, stir 4 hours and shut down, be finally sampled test.
Embodiment 3：A kind of PP, PE special glue, is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, pine
Fragrant glyceride, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphtha 7Kg, dimethyl carbonate 2 Kg, SIS1209 5
Kg, ester gum 5 Kg, BHT 2 Kg.
A kind of preparation method of PP, PE special glue comprises the following steps：6# solvent naphtha 7Kg, dimethyl carbonate are on the waiting list first
The Kg of 2 Kg, SIS1209 5, ester gum 5 Kg, BHT 2 Kg；6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank,
Electric blender is opened, rotating speed is adjusted to 80 revs/min, SIS1209 is added, motor speed is adjusted to 300 by ester gum, BHT
Rev/min, stir 3.5 hours and shut down, be finally sampled test.
Embodiment 4：A kind of PP, PE special glue, is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, pine
Fragrant glyceride, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphtha 9Kg, dimethyl carbonate 3 Kg, SIS1209 7
Kg, ester gum 8 Kg, BHT 3 Kg.
A kind of preparation method of PP, PE special glue comprises the following steps：6# solvent naphtha 9Kg, dimethyl carbonate are on the waiting list first
The Kg of 3 Kg, SIS1209 7, ester gum 8 Kg, BHT 3 Kg；6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank,
Electric blender is opened, rotating speed is adjusted to 80 revs/min, SIS1209 is added, motor speed is adjusted to 300 by ester gum, BHT
Rev/min, stir 3.5 hours and shut down, be finally sampled test.
Embodiment 5：A kind of PP, PE special glue, is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, pine
Fragrant glyceride, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphtha 8Kg, dimethyl carbonate 2 Kg, SIS1209 6
Kg, ester gum 7 Kg, BHT 2 Kg.
A kind of preparation method of PP, PE special glue comprises the following steps：6# solvent naphtha 8Kg, dimethyl carbonate are on the waiting list first
The Kg of 2 Kg, SIS1209 6, ester gum 7 Kg, BHT 2 Kg；6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank,
Electric blender is opened, rotating speed is adjusted to 80 revs/min, SIS1209 is added, motor speed is adjusted to 300 by ester gum, BHT
Rev/min, stir 3.5 hours and shut down, be finally sampled test.
Embodiment 6：A kind of PP, PE special glue, is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, pine
Fragrant glyceride, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphtha 5Kg, dimethyl carbonate 3 Kg, SIS1209 4
Kg, ester gum 7 Kg, BHT 1 Kg.
A kind of preparation method of PP, PE special glue comprises the following steps：6# solvent naphtha 5Kg, dimethyl carbonate are on the waiting list first
The Kg of 3 Kg, SIS1209 4, ester gum 7 Kg, BHT 1 Kg；6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank,
Electric blender is opened, rotating speed is adjusted to 80 revs/min, SIS1209 is added, motor speed is adjusted to 300 by ester gum, BHT
Rev/min, stir 3.2 hours and shut down, be finally sampled test.
Embodiment 7：A kind of PP, PE special glue, is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, pine
Fragrant glyceride, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphtha 12Kg, dimethyl carbonate 3 Kg, SIS1209
6 Kg, ester gum 5 Kg, BHT 4 Kg.
A kind of preparation method of PP, PE special glue comprises the following steps：6# solvent naphtha 12Kg, dimethyl carbonate are on the waiting list first
The Kg of 3 Kg, SIS1209 6, ester gum 5 Kg, BHT 4 Kg；6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank,
Electric blender is opened, rotating speed is adjusted to 80 revs/min, SIS1209 is added, motor speed is adjusted to 300 by ester gum, BHT
Rev/min, stir 4 hours and shut down, be finally sampled test.
Embodiment 8：A kind of PP, PE special glue, is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209, pine
Fragrant glyceride, BHT, wherein the parts by weight of each raw material are as follows：6# solvent naphtha 9Kg, dimethyl carbonate 1 Kg, SIS1209 6
Kg, ester gum 6 Kg, BHT 3 Kg.
A kind of preparation method of PP, PE special glue comprises the following steps：6# solvent naphtha 9Kg, dimethyl carbonate are on the waiting list first
The Kg of 1 Kg, SIS1209 6, ester gum 6 Kg, BHT 3 Kg；6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank,
Electric blender is opened, rotating speed is adjusted to 80 revs/min, SIS1209 is added, motor speed is adjusted to 300 by ester gum, BHT
Rev/min, stir 3 hours and shut down, be finally sampled test.
This invention PP, PE glue special is widely used：The materials such as PP, PE, leather, plastic cement, sheet material, film, stone material, metal
Matter, by adherend surface cleaning and keeps drying, natural air drying 5-10 minutes directly after adherend surface coating（With tack-free
It is defined）, by the laminating of another adherend alignment adherend, firmly pressurization is brought into close contact adhesive surface, fixed to keep after placing 1 hour
, permanent adhesive is reached after 24 hours, sturdy and durable never glue falls, the effect that surface is mutually combined together, be plastic products,
The optimal jointing material of the industry such as art toyses, household electrical appliances industry.
The experimental data made of the glue in the present invention to PP, PE laminating load-bearing conditions is as follows：
PP laminatings PP：Initial stage, 2-3Kg；Later stage, 13-21Kg.
PP laminatings PE：Initial stage, 2-3Kg；Later stage, 15-23Kg.
Claims (4)
1. a kind of PP, PE special glue, it is characterised in that：It is made up of following raw material：6# solvent naphthas, dimethyl carbonate, SIS1209,
Ester gum, BHT, wherein the parts by weight of each raw material are as follows：4-12 parts of 6# solvent naphthas, 1-4 parts of dimethyl carbonate,
3-9 parts of SIS1209,4-9 parts of ester gum, 1-4 parts of BHT.
2. PP, PE special glue according to claim 1, it is characterised in that：The parts by weight of described each raw material are as follows：6#
7-9 parts of solvent naphtha, 2-3 parts of dimethyl carbonate, 5-7 parts of SIS1209,5-8 parts of ester gum, 2-3 parts of BHT.
3. PP, PE special glue according to claim 1, it is characterised in that：The parts by weight of described each raw material are as follows：6#
8 parts of solvent naphtha, 2 parts of dimethyl carbonate, 6 parts of SIS1209,7 parts of ester gum, 2 parts of BHT.
4. a kind of preparation method of PP, PE special glue as claimed in claim 1, it is characterised in that：Comprise the following steps：First
It is on the waiting list 4-12 parts of 6# solvent naphthas, 1-4 parts of dimethyl carbonate, 3-9 parts of SIS1209,4-9 parts of ester gum, 1-4 parts of BHT；
6# solvent naphthas, dimethyl carbonate will be pumped into stirred tank, open electric blender, rotating speed is adjusted to 80 revs/min, addition
Motor speed is adjusted to 300 revs/min by SIS1209, ester gum, BHT, is stirred 3-4 hours and is shut down, is finally sampled survey
Examination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710420215.2A CN107142055A (en) | 2017-06-06 | 2017-06-06 | PP, PE special glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710420215.2A CN107142055A (en) | 2017-06-06 | 2017-06-06 | PP, PE special glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107142055A true CN107142055A (en) | 2017-09-08 |
Family
ID=59779714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710420215.2A Pending CN107142055A (en) | 2017-06-06 | 2017-06-06 | PP, PE special glue and preparation method thereof |
Country Status (1)
| Country | Link |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1837316A (en) * | 2006-04-18 | 2006-09-27 | 山东久隆高分子材料有限公司 | Interlaminated adhesive for waterproof carpet |
| CN105802554A (en) * | 2016-03-30 | 2016-07-27 | 光山县博正树脂有限公司 | Transparent all-purpose adhesive and preparation method thereof |
| CN106244103A (en) * | 2016-08-15 | 2016-12-21 | 广东三和化工科技有限公司 | A kind of glue spraying and preparation method thereof |
| CN106398608A (en) * | 2016-09-30 | 2017-02-15 | 光山县博正树脂有限公司 | Runway-specialized joint sealant and preparation method thereof |
| CN106753093A (en) * | 2016-12-23 | 2017-05-31 | 上海康达新能源材料有限公司 | A kind of aerosol photopolymer coating and preparation method thereof |
-
2017
- 2017-06-06 CN CN201710420215.2A patent/CN107142055A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1837316A (en) * | 2006-04-18 | 2006-09-27 | 山东久隆高分子材料有限公司 | Interlaminated adhesive for waterproof carpet |
| CN105802554A (en) * | 2016-03-30 | 2016-07-27 | 光山县博正树脂有限公司 | Transparent all-purpose adhesive and preparation method thereof |
| CN106244103A (en) * | 2016-08-15 | 2016-12-21 | 广东三和化工科技有限公司 | A kind of glue spraying and preparation method thereof |
| CN106398608A (en) * | 2016-09-30 | 2017-02-15 | 光山县博正树脂有限公司 | Runway-specialized joint sealant and preparation method thereof |
| CN106753093A (en) * | 2016-12-23 | 2017-05-31 | 上海康达新能源材料有限公司 | A kind of aerosol photopolymer coating and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170908 |
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| RJ01 | Rejection of invention patent application after publication |