CN1837316A - Interlaminated adhesive for waterproof carpet - Google Patents
Interlaminated adhesive for waterproof carpet Download PDFInfo
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- CN1837316A CN1837316A CN 200610043812 CN200610043812A CN1837316A CN 1837316 A CN1837316 A CN 1837316A CN 200610043812 CN200610043812 CN 200610043812 CN 200610043812 A CN200610043812 A CN 200610043812A CN 1837316 A CN1837316 A CN 1837316A
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- waterproof blanket
- adhesive
- interlaminated
- interlaminated adhesive
- vinylbenzene
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Abstract
The invention discloses an interlaminar adhesive of water-proof cap, which comprises the following parts: 10-50 rubber, 30-60 viscosifying resin, 20-40 solvent oil, 0-10 thinner, 0-20 inorganic filler and 0.5-2 antiager. The autoclave molten preparing method comprises the following steps: melting solvent oil, thinner, viscosifying resin in the autoclave at 180 deg.c; stirring and adding rubber; mixing antiager and inorganic filler; blending evenly to discharge; adding the whole raw material in the kneader at 180 deg.c. The invention is detected according to international standard GB2792-81, whose T stripping strength of heat compression equals to or is more than 20 N per cm.
Description
Technical field: the invention belongs to adhesive area, specifically about a kind of interlaminated adhesive that is used for waterproof blanket.
Background technology: at present in building trade, can be generally double-layer structure with cement material direct adherent composite water-proof blanket in process of setting: main water barrier is strong polyolefins mould material of impervious ability or similar geotechnological woven cloth material, and this layer mainly plays waterproof effect; Supplementary layer is a non-woven fabrics, and this layer can improve the roughness of material surface, improves the bonding performance of laying, and increases physical strength, improves the anti-destructiveness of coiled material.General two-layer combination mainly be under main water barrier hot melt state with the direct pressing of supplementary layer
[1] [2]The polyolefins material is the sticking material of internationally recognized difficulty, and surface energy is low, and polarity is poor, and general material is difficult to soak into.The direct heat fusion pressure has closed a lot of limitation, must not can destroy two-layer structure such as hot melting temperature, and that one deck that guarantees hot melt is not again causing the compound failure of hot melt with fashionable can the cooling because of thermal conduction is too fast of another lamination. the moistened surface of hot melt state is sprawled, mainly rely on the mutually close violent thermal motion of molecule under pressure, the continuous motion of electronics and nuclear continuous vibration in its molecule, moment, dipole produced intermolecular London force, and common intensity can be very not high; Though and polyurethane tackifier makes moderate progress to the infiltration of polyolefins material; but the requirement to construction technology is high especially; misoperation is easy to ftracture in construction process a little; and it is the construction technology complexity, so very inconvenient. above-mentioned two kinds of methods, otherwise intensity is very low; the technology more complicated; do not satisfy the requirement of construction far away, appear at two-layer tearing in the construction process, cause the waterproof effect variation through regular meeting.
Summary of the invention: the purpose of this invention is to provide a kind of tackiness agent that is easy to construct and the difficult sticking material of polyolefins and nonwoven cloth material are all had the bonds well performance.
It is main sticking body polymkeric substance that the present invention mainly adopts the synthetic rubber class, is aided with tackifying resin, solvent oil, thinner, inorganic filler and anti-aging agent again and processes, and can utilize the spraying of hot melt spray gun to get final product, and intensity is with the hot sticky the best that is combined into, and cold-adhesion also can.
Tackiness agent is respectively formed component proportioning (weight %): synthetic rubber 10-40 tackifying resin 30-60 solvent oil 20-40 thinner 0-10 inorganic filler 0-20 anti-aging agent 0.5-2
Wherein synthetic rubber is a thermoplastic elastomer, as vinylbenzene, butadiene block copolymer (SBS), and vinylbenzene, isoprene block copolymer (SIS), one or both in hydrogenation vinylbenzene, the butadiene block copolymer (SEBS); Tackifying resin is a kind of in the class resin of tackification such as rosin, terpine resin, rosin ester, petroleum resin; Solvent oil can select for use the involutory one-tenth rubber of cycloalkanes wet goods that a kind of solvent oil of excellent compatibility is arranged; Thinner is one or both in paraffin, Microcrystalline Wax, polyethylene wax, the Poly Propylene Wax; Inorganic filler is one or both in talcum powder, fine particle calcium carbonate, nano level diatom soil, the wilkinite; Anti-aging agent is a kind of among NBC (nickel dibutyl dithiocarbamate), the BHT.
Concrete complete processing can adopt reactor heating and melting or kneader to mediate and form.Adopt the reactor melting method to be: earlier with solvent oil, thinner, tackifying resin input, still temperature rise to 180 ℃ until completely melted adds synthetic rubber in the stirring, treat that it melts fully, adds anti-aging agent and inorganic filler, mixes discharging.Kneader kneading method is that whole raw materials are added kneader, is warming up to 180 ℃, mediates and stirs until even discharging.
The construction technology of this tackiness agent is to adopt the hot sticky the best that is combined into, and cold-adhesion also can.Its thermal bonding technology is for to put into 140-190 ℃ of heat fused of melten gel groove with tackiness agent, utilizes pump or other pressuring methods to make it pass through the spraying of hot melt spray gun or curtain coating at main water barrier, then rapidly with supplementary layer pressing while hot.T stripping strength 〉=the 20N/cm of hot pressing.The difference of cold-adhesion technology and heat bonding is not pressing while hot of last pressing, and all the other steps are all identical, its T stripping strength 〉=10N/cm.
Embodiment:
Embodiment one, and the set of dispense of tackiness agent of the present invention adopts the preparation of reactor melting method than (weight %) SBS 11 terpine resins 55 naphthenic oils 30 paraffin waxes 1 nano diatomite 2 antideteriorant BHTs 1, its product after tested, the T stripping strength is 21N/cm.
Embodiment two, and the set of dispense of tackiness agent adopts the preparation of kneader kneading method than (weight %) SIS 30 rosin 30 naphthenic oils 20 Microcrystalline Waxes 5 talcum powder 14 NBC 1, its product after tested, the T stripping strength is 20N/cm.
Embodiment three, and the set of dispense of tackiness agent adopts the preparation of reactor melting method than (weight %) SIS 30 rosin esters 30 naphthenic oils 30 polyethylene waxs 2 fine particle calcium carbonates 7 BHT 1, its product after tested, the T stripping strength is 22N/cm.
Embodiment four, the set of dispense of tackiness agent adopts the preparation of kneader kneading method than (weight %) SEBS 5 SBS 5 SIS10 terpine resins 30 C 5 petroleum resins 7 naphthenic oils 22 nano diatomites 20 BHT 1, its product after tested, the T stripping strength is 25N/cm
Embodiment five, and the set of dispense of tackiness agent is than (weight %) SBS 5 SEBS 10 terpine resins 30 rosin 10 naphthenic oils 35 paraffin waxes 2 polyethylene waxs 2 NBC 1
Adopt the preparation of reactor melting method, its product after tested, the T stripping strength is 24N/cm
Adhesive products of the present invention detects according to the T peel strength test method among the GB GB2792-81, and the T stripping strength of its hot pressing reaches 24N/cm.On probation through U.S. Jie Gao company, obtained beyond thought effect, have easy to use, intensity is high, the advantage of waterproof, makes every effort to defeat other producers in the engineering competitive bidding.
Reference
[1] " polyethylene/polypropylene fibre composite water-proof rolled material recombining process " Harbin University of Science and Technology's journal, 04 phase of calendar year 2001.
[2] Chinese invention patent " resin compound nonwoven cloth waterproof coiled material splicing joint glue stick and preparation method thereof " Hagaoke Suiling Second Plastics Co., Ltd..
Claims (12)
1, a kind of interlaminated adhesive that is used for waterproof blanket is characterized in that: the composition proportioning (weight %) of tackiness agent is: synthetic rubber 10-50 tackifying resin 30-60 solvent oil 20-40 thinner 0-10 inorganic filler 0-20 anti-aging agent 0.5-2.
2, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described synthetic rubber is vinylbenzene, butadiene block copolymer (SBS), vinylbenzene, isoprene block copolymer (SIS), a kind of in hydrogenation vinylbenzene, the butadiene block copolymer (SEBS).
3, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described synthetic rubber is vinylbenzene, butadiene block copolymer (SBS), vinylbenzene, isoprene block copolymer (SIS), in hydrogenation vinylbenzene, the butadiene block copolymer (SEBS) two kinds.
4, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described tackifying resin is a kind of in rosin, terpine resin, rosin ester, the petroleum resin.
5, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described solvent oil is a naphthenic oil.
6, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described thinner, select a kind of in paraffin, Microcrystalline Wax, polyethylene wax, the Poly Propylene Wax for use.
7, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described thinner, select two kinds in paraffin, Microcrystalline Wax, polyethylene wax, the Poly Propylene Wax for use.
8, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described inorganic filler, select a kind of in talcum powder, fine particle calcium carbonate, nano level diatom soil, the wilkinite for use.
9, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described inorganic filler, select two kinds in talcum powder, fine particle calcium carbonate, nano level diatom soil, the wilkinite for use.
10, according to claims 1 said a kind of interlaminated adhesive that is used for waterproof blanket, it is characterized in that: described anti-aging agent, select a kind of among NBC (nickel dibutyl dithiocarbamate), the BHT for use.
11, according to the said a kind of interlaminated adhesive that is used for waterproof blanket of claims 1-10, it is characterized in that: the preparation method of tackiness agent adopts reactor heating and melting method.
12, according to the said a kind of interlaminated adhesive that is used for waterproof blanket of claims 1-10, it is characterized in that: the preparation method of tackiness agent adopts kneader to mediate to form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610043812 CN1837316A (en) | 2006-04-18 | 2006-04-18 | Interlaminated adhesive for waterproof carpet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610043812 CN1837316A (en) | 2006-04-18 | 2006-04-18 | Interlaminated adhesive for waterproof carpet |
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| CN1837316A true CN1837316A (en) | 2006-09-27 |
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| CN 200610043812 Pending CN1837316A (en) | 2006-04-18 | 2006-04-18 | Interlaminated adhesive for waterproof carpet |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060472A (en) * | 2010-11-16 | 2011-05-18 | 昆明永瑞防腐有限公司 | High-temperature resistant anti-corrosion clay special for acid pressure oxidative leaching high-pressure autoclave and preparation method thereof |
| CN102101997A (en) * | 2010-09-14 | 2011-06-22 | 抚顺哥俩好化学有限公司 | Environmentally-friendly low-viscosity SEBS (Styrene-Ethylene-Butadiene-Styrene) spray adhesive and preparation method thereof |
| CN102604552A (en) * | 2011-12-06 | 2012-07-25 | 福建爱贝思日用品有限公司 | Thermoplastic resin film, as well as production technology, production device and adhesive tool product thereof |
| CN102618194A (en) * | 2012-04-13 | 2012-08-01 | 佛山南宝高盛高新材料有限公司 | Hot melt pressure sensitive adhesive for high speed automatic labeling and preparation method thereof |
| CN102660207A (en) * | 2012-04-28 | 2012-09-12 | 郑昭 | Method for preparing hot melt adhesive for damping interval of ceramic tile |
| CN103045139A (en) * | 2013-01-21 | 2013-04-17 | 无锡市万力粘合材料有限公司 | Hot melt adhesive composition for back voucher of express mail service and method for preparing same |
| CN103694909A (en) * | 2013-12-12 | 2014-04-02 | 江阴伟韬塑料新材料有限公司 | Hot melting adhesive membrane for adhering ethylene propylene diene monomer |
| CN103709962A (en) * | 2013-12-04 | 2014-04-09 | 浙江固特热熔胶有限公司 | Shoe rubber and production method therefor |
| CN104130469A (en) * | 2014-07-14 | 2014-11-05 | 北京中联天盛建材有限公司 | Self-adhesive rubber polymer water-proof caulking compound and preparation method thereof |
| CN104946178A (en) * | 2014-03-26 | 2015-09-30 | 江苏凯伦建材股份有限公司 | Novel hot-melt pressure-sensitive adhesive for waterproof materials and preparation method thereof |
| CN105131562A (en) * | 2015-09-18 | 2015-12-09 | 广西路佳道桥勘察设计有限公司 | Waterproof building material as well as preparation and application methods thereof |
| CN105255097A (en) * | 2015-10-28 | 2016-01-20 | 重庆特铺路面工程技术有限公司 | Light-colored asphalt cement and preparation method thereof |
| CN105255414A (en) * | 2015-11-25 | 2016-01-20 | 成都锦汇科技有限公司 | Environment-friendly adhesive and preparation method thereof |
| CN107142055A (en) * | 2017-06-06 | 2017-09-08 | 光山县博正树脂有限公司 | PP, PE special glue and preparation method thereof |
| CN110358481A (en) * | 2019-06-19 | 2019-10-22 | 甘肃金盾化工有限责任公司 | A kind of chinampa is mated formation special glue and preparation method |
| CN111500230A (en) * | 2020-05-23 | 2020-08-07 | 深圳宝利树脂有限公司 | All-purpose adhesive with good bonding effect and preparation method thereof |
-
2006
- 2006-04-18 CN CN 200610043812 patent/CN1837316A/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102101997A (en) * | 2010-09-14 | 2011-06-22 | 抚顺哥俩好化学有限公司 | Environmentally-friendly low-viscosity SEBS (Styrene-Ethylene-Butadiene-Styrene) spray adhesive and preparation method thereof |
| CN102101997B (en) * | 2010-09-14 | 2013-01-09 | 抚顺哥俩好化学有限公司 | Environmentally-friendly low-viscosity SEBS (Styrene-Ethylene-Butadiene-Styrene) spray adhesive and preparation method thereof |
| CN102060472B (en) * | 2010-11-16 | 2013-01-30 | 昆明永瑞防腐有限公司 | High-temperature resistant anti-corrosion clay special for acid pressure oxidative leaching high-pressure autoclave and preparation method thereof |
| CN102060472A (en) * | 2010-11-16 | 2011-05-18 | 昆明永瑞防腐有限公司 | High-temperature resistant anti-corrosion clay special for acid pressure oxidative leaching high-pressure autoclave and preparation method thereof |
| CN102604552A (en) * | 2011-12-06 | 2012-07-25 | 福建爱贝思日用品有限公司 | Thermoplastic resin film, as well as production technology, production device and adhesive tool product thereof |
| CN102618194A (en) * | 2012-04-13 | 2012-08-01 | 佛山南宝高盛高新材料有限公司 | Hot melt pressure sensitive adhesive for high speed automatic labeling and preparation method thereof |
| CN102660207A (en) * | 2012-04-28 | 2012-09-12 | 郑昭 | Method for preparing hot melt adhesive for damping interval of ceramic tile |
| CN103045139A (en) * | 2013-01-21 | 2013-04-17 | 无锡市万力粘合材料有限公司 | Hot melt adhesive composition for back voucher of express mail service and method for preparing same |
| CN103709962A (en) * | 2013-12-04 | 2014-04-09 | 浙江固特热熔胶有限公司 | Shoe rubber and production method therefor |
| CN103694909A (en) * | 2013-12-12 | 2014-04-02 | 江阴伟韬塑料新材料有限公司 | Hot melting adhesive membrane for adhering ethylene propylene diene monomer |
| CN104946178A (en) * | 2014-03-26 | 2015-09-30 | 江苏凯伦建材股份有限公司 | Novel hot-melt pressure-sensitive adhesive for waterproof materials and preparation method thereof |
| CN104130469A (en) * | 2014-07-14 | 2014-11-05 | 北京中联天盛建材有限公司 | Self-adhesive rubber polymer water-proof caulking compound and preparation method thereof |
| CN105131562A (en) * | 2015-09-18 | 2015-12-09 | 广西路佳道桥勘察设计有限公司 | Waterproof building material as well as preparation and application methods thereof |
| CN105255097A (en) * | 2015-10-28 | 2016-01-20 | 重庆特铺路面工程技术有限公司 | Light-colored asphalt cement and preparation method thereof |
| CN105255414A (en) * | 2015-11-25 | 2016-01-20 | 成都锦汇科技有限公司 | Environment-friendly adhesive and preparation method thereof |
| CN107142055A (en) * | 2017-06-06 | 2017-09-08 | 光山县博正树脂有限公司 | PP, PE special glue and preparation method thereof |
| CN110358481A (en) * | 2019-06-19 | 2019-10-22 | 甘肃金盾化工有限责任公司 | A kind of chinampa is mated formation special glue and preparation method |
| CN111500230A (en) * | 2020-05-23 | 2020-08-07 | 深圳宝利树脂有限公司 | All-purpose adhesive with good bonding effect and preparation method thereof |
| CN111500230B (en) * | 2020-05-23 | 2021-07-23 | 深圳宝利树脂有限公司 | All-purpose adhesive with good bonding effect and preparation method thereof |
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