CN101277981B - 二烯聚合反应 - Google Patents

二烯聚合反应 Download PDF

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Publication number
CN101277981B
CN101277981B CN200680036448.2A CN200680036448A CN101277981B CN 101277981 B CN101277981 B CN 101277981B CN 200680036448 A CN200680036448 A CN 200680036448A CN 101277981 B CN101277981 B CN 101277981B
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transition metal
mmol
butadiene
compounds
group
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Chinese (zh)
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CN101277981A (zh
Inventor
G·B·雅各布森
J·J·奇里诺斯-科利纳
V·C·吉布森
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Ineos Commercial Services UK Ltd
Ineos Sales UK Ltd
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Innovene Europe Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
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    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/08—Isoprene
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    • C08F36/045—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated conjugated hydrocarbons other than butadiene or isoprene
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    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/60003—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7095—Cobalt, nickel or compounds thereof
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    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN200680036448.2A 2005-08-02 2006-07-27 二烯聚合反应 Expired - Fee Related CN101277981B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP05254833.6 2005-08-02
EP05254833 2005-08-02
PCT/GB2006/002832 WO2007015074A1 (en) 2005-08-02 2006-07-27 Diene polymerisation

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CN101277981A CN101277981A (zh) 2008-10-01
CN101277981B true CN101277981B (zh) 2014-07-09

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US (1) US8124698B2 (enExample)
EP (1) EP1910426B1 (enExample)
JP (1) JP5535480B2 (enExample)
KR (1) KR101344198B1 (enExample)
CN (1) CN101277981B (enExample)
BR (1) BRPI0614256B1 (enExample)
CA (1) CA2617436A1 (enExample)
SG (1) SG139221A1 (enExample)
WO (1) WO2007015074A1 (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1918311A1 (en) * 2006-10-31 2008-05-07 Ineos Europe Limited Diene polymerisation
EP1918312B1 (en) * 2006-10-31 2011-12-07 Ineos Commercial Services UK Limited Diene polymerisation
RU2487137C2 (ru) * 2011-10-04 2013-07-10 ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" Способ получения разветвленных функционализированных диеновых (со)полимеров
EP2641909A1 (en) 2012-03-19 2013-09-25 LANXESS Deutschland GmbH Transition metal P-N complexes as polymerization catalysts
CN102775539B (zh) * 2012-08-21 2014-03-26 中国科学院长春应用化学研究所 一种聚丁二烯的制备方法
ITMI20122203A1 (it) * 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto
JP6864296B2 (ja) 2015-12-14 2021-04-28 エックス４ ファーマシューティカルズ， インコーポレイテッド がんを処置する方法
CN109069486A (zh) 2015-12-14 2018-12-21 X4 制药有限公司 治疗癌症的方法
WO2017112894A1 (en) 2015-12-22 2017-06-29 X4 Pharmaceuticals, Inc. Methods for treating immunodeficiency disease
EP3440112A4 (en) 2016-04-08 2019-10-09 X4 Pharmaceuticals, Inc. METHOD FOR THE TREATMENT OF CANCER
JP7054529B2 (ja) 2016-06-21 2022-04-14 エックス４ ファーマシューティカルズ， インコーポレイテッド Ｃｘｃｒ４阻害剤およびその使用
CN109640988A (zh) * 2016-06-21 2019-04-16 X4 制药有限公司 Cxcr4抑制剂及其用途
WO2017223243A1 (en) 2016-06-21 2017-12-28 X4 Pharmaceuticals, Inc. Cxcr4 inhibitors and uses thereof
JP7042122B2 (ja) * 2017-03-30 2022-03-25 日本ポリケム株式会社 オレフィン重合用触媒
US10548889B1 (en) 2018-08-31 2020-02-04 X4 Pharmaceuticals, Inc. Compositions of CXCR4 inhibitors and methods of preparation and use
CN110483385A (zh) * 2019-08-12 2019-11-22 广东石油化工学院 一种棒-线状nnn三齿配体化合物及其制备方法和应用
CA3171250A1 (en) 2020-03-10 2021-09-16 E. Lynne KELLEY Methods for treating neutropenia
KR102753269B1 (ko) * 2020-10-22 2025-01-14 금호석유화학 주식회사 고무 중합체, 그 제조방법 및 그를 포함하는 고무 조성물
JP7759749B2 (ja) * 2021-08-02 2025-10-24 株式会社ブリヂストン 触媒組成物、重合体の製造方法、重合体、ゴム組成物、及びタイヤ
WO2024107076A1 (en) * 2022-11-14 2024-05-23 Public Joint Stock Company "Sibur Holding" (Pjsc "Sibur Holding") Procatalyst for olefin polymerization, method for preparation thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5731381A (en) * 1996-11-01 1998-03-24 Union Carbide Chemicals & Plastics Technology Corporation Termination of gas phase polymerizations of conjugated dienes, vinyl-substituted aromatic compounds and mixtures thereof
CN1299377A (zh) * 1998-03-12 2001-06-13 英国石油化学品有限公司 聚合催化剂
CN1425029A (zh) * 2000-03-06 2003-06-18 英国石油化学品有限公司 降低烯烃聚合期间结片和附聚物的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3247175A (en) * 1962-07-12 1966-04-19 Copolymer Rubber & Chem Corp Process for preparing high cis-1, 4-polybutadiene
US3560405A (en) * 1968-02-26 1971-02-02 Phillips Petroleum Co Butadiene polymerization and catalyst systems therefor
GB0306430D0 (en) * 2003-03-20 2003-04-23 Bp Chem Int Ltd Polymerisation and oligomerisation catalysts
GB0425443D0 (en) * 2004-11-18 2004-12-22 Bp Chem Int Ltd Supported polymerisation catalysts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5731381A (en) * 1996-11-01 1998-03-24 Union Carbide Chemicals & Plastics Technology Corporation Termination of gas phase polymerizations of conjugated dienes, vinyl-substituted aromatic compounds and mixtures thereof
CN1299377A (zh) * 1998-03-12 2001-06-13 英国石油化学品有限公司 聚合催化剂
CN1425029A (zh) * 2000-03-06 2003-06-18 英国石油化学品有限公司 降低烯烃聚合期间结片和附聚物的方法

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CN101277981A (zh) 2008-10-01
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