CN101233157B - 担载型茂金属-烷基催化剂组合物 - Google Patents

担载型茂金属-烷基催化剂组合物 Download PDF

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Publication number
CN101233157B
CN101233157B CN2006800274999A CN200680027499A CN101233157B CN 101233157 B CN101233157 B CN 101233157B CN 2006800274999 A CN2006800274999 A CN 2006800274999A CN 200680027499 A CN200680027499 A CN 200680027499A CN 101233157 B CN101233157 B CN 101233157B
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China
Prior art keywords
catalyst composition
alkyl
metallocene
supported
group
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CN2006800274999A
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Chinese (zh)
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CN101233157A (zh
Inventor
阿加皮奥斯·K·阿加皮欧
高芳
高珊爵
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Univation Technologies LLC
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Univation Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN2006800274999A 2005-07-29 2006-07-12 担载型茂金属-烷基催化剂组合物 Active CN101233157B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/192,935 2005-07-29
US11/192,935 US7323526B2 (en) 2005-07-29 2005-07-29 Supported metallocene-alkyl catalyst composition
PCT/US2006/027447 WO2007015764A1 (en) 2005-07-29 2006-07-12 Supported metallocene-alkyl catalyst composition

Publications (2)

Publication Number Publication Date
CN101233157A CN101233157A (zh) 2008-07-30
CN101233157B true CN101233157B (zh) 2012-01-18

Family

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Family Applications (1)

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CN2006800274999A Active CN101233157B (zh) 2005-07-29 2006-07-12 担载型茂金属-烷基催化剂组合物

Country Status (10)

Country Link
US (1) US7323526B2 (https=)
EP (1) EP1915402B1 (https=)
JP (1) JP5069234B2 (https=)
CN (1) CN101233157B (https=)
AT (1) ATE455805T1 (https=)
CA (1) CA2614717C (https=)
DE (1) DE602006011911D1 (https=)
ES (1) ES2337832T3 (https=)
MY (1) MY142971A (https=)
WO (1) WO2007015764A1 (https=)

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* Cited by examiner, † Cited by third party
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BRPI0712945B1 (pt) * 2006-06-27 2018-05-08 Univation Tech Llc Processo para a produção de um Copolímero de Etileno Alfa- Olefina
US8507103B2 (en) 2007-12-18 2013-08-13 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8436114B2 (en) 2010-10-21 2013-05-07 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8431661B2 (en) 2010-10-21 2013-04-30 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
RU2486952C2 (ru) * 2008-01-07 2013-07-10 Юнивейшн Текнолоджиз, Ллк Системы подачи катализатора и способы их применения
CN102171259A (zh) 2008-10-03 2011-08-31 尤尼威蒂恩技术有限责任公司 催化剂组合物以及制备和使用其的方法
BR112012027059B1 (pt) 2010-04-28 2018-07-24 Univation Tech Llc síntese de composto de alquil ciclopentadieno
WO2012074710A1 (en) 2010-11-30 2012-06-07 Univation Technologies, Llc. Catalyst composition having improved flow characteristics and methods of making and using the same
RU2587080C2 (ru) * 2010-11-30 2016-06-10 Юнивейшн Текнолоджиз, Ллк Способы полимеризации олефинов с использованием экстрагированных карбоксилатов металлов
ES2768180T3 (es) 2013-01-30 2020-06-22 Univation Tech Llc Procedimientos para producir composiciones catalíticas con fluidez mejorada
CN106574009B (zh) * 2014-06-12 2019-06-28 道达尔研究技术弗吕公司 用于在至少一个连续搅拌釜反应器中制备聚乙烯的工艺
KR102285140B1 (ko) * 2018-12-03 2021-08-02 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법

Citations (7)

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WO2000040623A1 (en) * 1998-12-30 2000-07-13 Bp Chemicals Limited Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process
CN1307597A (zh) * 1998-07-10 2001-08-08 尤尼威蒂恩技术有限责任公司 催化剂组合物及其制备方法以及其在聚合方法中的应用
CN1382162A (zh) * 1999-10-22 2002-11-27 尤尼威蒂恩技术有限责任公司 催化剂体系及其在聚合反应方法中的应用
US20040198588A1 (en) * 2001-11-30 2004-10-07 Mink Robert I. Bimetallic catalysts with higher activity
WO2004094487A1 (en) * 2003-03-21 2004-11-04 Dow Global Technologies, Inc. Morphology controlled olefin polymerization process
US20050054520A1 (en) * 2000-06-30 2005-03-10 Hart James R. Metallocenes and catalyst compositions derived therefrom
WO2005061557A1 (en) * 2003-12-08 2005-07-07 Univation Technologies, Llc Polymerization process using metallocene catalyst systems

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FR2660926B1 (fr) * 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
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US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5466649A (en) * 1993-10-15 1995-11-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
TW454020B (en) 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
JPH11192661A (ja) * 1997-10-21 1999-07-21 Sumitomo Chem Co Ltd インフレーションフィルムの製造法とフィルム
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US6977283B1 (en) * 1998-04-07 2005-12-20 Exxonmobil Chemical Patents Inc. Polymerization process
KR100430438B1 (ko) * 1998-10-22 2004-07-19 대림산업 주식회사 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법
US6852811B1 (en) * 1998-12-30 2005-02-08 The Dow Chemical Company Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process
US6593267B2 (en) 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
AU2002365867A1 (en) * 2001-11-30 2003-06-17 Exxonmobil Chemical Patents Inc. Method of making mixed ziegler-natta/metallocene catalysts

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CN1307597A (zh) * 1998-07-10 2001-08-08 尤尼威蒂恩技术有限责任公司 催化剂组合物及其制备方法以及其在聚合方法中的应用
WO2000040623A1 (en) * 1998-12-30 2000-07-13 Bp Chemicals Limited Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process
CN1382162A (zh) * 1999-10-22 2002-11-27 尤尼威蒂恩技术有限责任公司 催化剂体系及其在聚合反应方法中的应用
US20050054520A1 (en) * 2000-06-30 2005-03-10 Hart James R. Metallocenes and catalyst compositions derived therefrom
US20040198588A1 (en) * 2001-11-30 2004-10-07 Mink Robert I. Bimetallic catalysts with higher activity
WO2004094487A1 (en) * 2003-03-21 2004-11-04 Dow Global Technologies, Inc. Morphology controlled olefin polymerization process
WO2005061557A1 (en) * 2003-12-08 2005-07-07 Univation Technologies, Llc Polymerization process using metallocene catalyst systems

Also Published As

Publication number Publication date
CA2614717C (en) 2011-11-15
MY142971A (en) 2011-01-31
US7323526B2 (en) 2008-01-29
US20070027027A1 (en) 2007-02-01
WO2007015764A1 (en) 2007-02-08
DE602006011911D1 (de) 2010-03-11
EP1915402B1 (en) 2010-01-20
JP2009502476A (ja) 2009-01-29
ES2337832T3 (es) 2010-04-29
ATE455805T1 (de) 2010-02-15
CN101233157A (zh) 2008-07-30
CA2614717A1 (en) 2007-02-08
JP5069234B2 (ja) 2012-11-07
EP1915402A1 (en) 2008-04-30

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