CN101220049A - 三乙基铝的合成工艺方法 - Google Patents
三乙基铝的合成工艺方法 Download PDFInfo
- Publication number
- CN101220049A CN101220049A CNA2007100601130A CN200710060113A CN101220049A CN 101220049 A CN101220049 A CN 101220049A CN A2007100601130 A CNA2007100601130 A CN A2007100601130A CN 200710060113 A CN200710060113 A CN 200710060113A CN 101220049 A CN101220049 A CN 101220049A
- Authority
- CN
- China
- Prior art keywords
- triethyl aluminum
- hydrogenation
- aluminum
- hexane
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 36
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 title claims description 50
- 230000002194 synthesizing effect Effects 0.000 title abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 83
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 48
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 47
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 36
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000004821 distillation Methods 0.000 claims abstract description 17
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010936 titanium Substances 0.000 claims abstract description 13
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 13
- 230000008016 vaporization Effects 0.000 claims abstract description 12
- 239000012535 impurity Substances 0.000 claims abstract description 9
- 239000011261 inert gas Substances 0.000 claims abstract description 5
- 239000004411 aluminium Substances 0.000 claims description 34
- 230000007062 hydrolysis Effects 0.000 claims description 19
- 238000006460 hydrolysis reaction Methods 0.000 claims description 19
- 238000006200 ethylation reaction Methods 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 230000007704 transition Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 238000009834 vaporization Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- -1 stirs Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000005977 Ethylene Substances 0.000 abstract description 3
- 238000006555 catalytic reaction Methods 0.000 abstract description 3
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 235000010210 aluminium Nutrition 0.000 description 32
- 238000003786 synthesis reaction Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000700 radioactive tracer Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 241000282326 Felis catus Species 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- VPCAAUUIFCAFRZ-UHFFFAOYSA-N butylalumane Chemical compound CCCC[AlH2] VPCAAUUIFCAFRZ-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000013456 study Methods 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002760 rocket fuel Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WZYRLFGQKYQXLU-UHFFFAOYSA-N tributylalumane;triethylalumane Chemical compound CC[Al](CC)CC.CCCC[Al](CCCC)CCCC WZYRLFGQKYQXLU-UHFFFAOYSA-N 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100601130A CN100551925C (zh) | 2007-12-24 | 2007-12-24 | 三乙基铝的合成工艺方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100601130A CN100551925C (zh) | 2007-12-24 | 2007-12-24 | 三乙基铝的合成工艺方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101220049A true CN101220049A (zh) | 2008-07-16 |
| CN100551925C CN100551925C (zh) | 2009-10-21 |
Family
ID=39630155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100601130A Expired - Fee Related CN100551925C (zh) | 2007-12-24 | 2007-12-24 | 三乙基铝的合成工艺方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100551925C (ko) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805364A (zh) * | 2010-04-22 | 2010-08-18 | 浙江福瑞德化工有限公司 | 一种三乙基铝的生产方法 |
| CN101805363A (zh) * | 2010-04-22 | 2010-08-18 | 浙江福瑞德化工有限公司 | 一种三乙基铝的连续生产方法 |
| CN101830922A (zh) * | 2010-05-21 | 2010-09-15 | 天津联力化工有限公司 | 三乙基铝的生产设备 |
| CN102584879A (zh) * | 2012-01-19 | 2012-07-18 | 营口市向阳催化剂有限责任公司 | 一种三乙基铝的制备方法 |
| CN103752027A (zh) * | 2014-01-22 | 2014-04-30 | 南京金陵塑胶化工有限公司 | 一种闪蒸罐及其用于乙烯—丙烯共聚弹性体生产后的处理工艺 |
| CN103768819A (zh) * | 2013-12-13 | 2014-05-07 | 营口市风光化工有限公司 | 一种三乙基铝粗品的精馏系统及精馏方法 |
| CN103772423A (zh) * | 2013-12-13 | 2014-05-07 | 营口市风光化工有限公司 | 一种三乙基铝的合成工艺 |
| CN104710446A (zh) * | 2013-12-13 | 2015-06-17 | 营口市风光化工有限公司 | 三乙基铝的生产方法 |
| RU2773423C1 (ru) * | 2021-04-23 | 2022-06-03 | Акционерное общество "Государственный Ордена Трудового Красного Знамени научно-исследовательский институт химии и технологии элементоорганических соединений" (АО "ГНИИХТЭОС") | Способ получения триэтилалюминия |
| CN118651821A (zh) * | 2024-08-19 | 2024-09-17 | 宁波三石工业技术有限公司 | 铝烷的制备方法、制备系统及其应用 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE549410A (ko) * | 1955-07-13 | 1900-01-01 |
-
2007
- 2007-12-24 CN CNB2007100601130A patent/CN100551925C/zh not_active Expired - Fee Related
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805363A (zh) * | 2010-04-22 | 2010-08-18 | 浙江福瑞德化工有限公司 | 一种三乙基铝的连续生产方法 |
| CN101805363B (zh) * | 2010-04-22 | 2012-06-06 | 浙江福瑞德化工有限公司 | 一种三乙基铝的连续生产方法 |
| CN101805364B (zh) * | 2010-04-22 | 2012-11-21 | 浙江福瑞德化工有限公司 | 一种三乙基铝的生产方法 |
| CN101805364A (zh) * | 2010-04-22 | 2010-08-18 | 浙江福瑞德化工有限公司 | 一种三乙基铝的生产方法 |
| CN101830922A (zh) * | 2010-05-21 | 2010-09-15 | 天津联力化工有限公司 | 三乙基铝的生产设备 |
| CN102584879B (zh) * | 2012-01-19 | 2014-05-07 | 营口市向阳催化剂有限责任公司 | 一种三乙基铝的制备方法 |
| CN102584879A (zh) * | 2012-01-19 | 2012-07-18 | 营口市向阳催化剂有限责任公司 | 一种三乙基铝的制备方法 |
| CN103768819A (zh) * | 2013-12-13 | 2014-05-07 | 营口市风光化工有限公司 | 一种三乙基铝粗品的精馏系统及精馏方法 |
| CN103772423A (zh) * | 2013-12-13 | 2014-05-07 | 营口市风光化工有限公司 | 一种三乙基铝的合成工艺 |
| CN103768819B (zh) * | 2013-12-13 | 2015-05-13 | 营口市风光化工有限公司 | 一种三乙基铝粗品的精馏系统及精馏方法 |
| CN104710446A (zh) * | 2013-12-13 | 2015-06-17 | 营口市风光化工有限公司 | 三乙基铝的生产方法 |
| CN103772423B (zh) * | 2013-12-13 | 2015-11-11 | 营口市风光化工有限公司 | 一种三乙基铝的合成工艺 |
| CN104710446B (zh) * | 2013-12-13 | 2017-01-18 | 营口市风光化工有限公司 | 三乙基铝的生产方法 |
| CN103752027A (zh) * | 2014-01-22 | 2014-04-30 | 南京金陵塑胶化工有限公司 | 一种闪蒸罐及其用于乙烯—丙烯共聚弹性体生产后的处理工艺 |
| CN103752027B (zh) * | 2014-01-22 | 2015-09-09 | 南京金陵塑胶化工有限公司 | 一种闪蒸罐及其用于乙烯—丙烯共聚弹性体生产后的处理工艺 |
| RU2773423C1 (ru) * | 2021-04-23 | 2022-06-03 | Акционерное общество "Государственный Ордена Трудового Красного Знамени научно-исследовательский институт химии и технологии элементоорганических соединений" (АО "ГНИИХТЭОС") | Способ получения триэтилалюминия |
| CN118651821A (zh) * | 2024-08-19 | 2024-09-17 | 宁波三石工业技术有限公司 | 铝烷的制备方法、制备系统及其应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100551925C (zh) | 2009-10-21 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C14 | Grant of patent or utility model | ||
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091021 Termination date: 20181224 |
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| CF01 | Termination of patent right due to non-payment of annual fee |