CN101195911B - 在具有塑料表面的基底上形成涂布金属层的预处理溶液和方法 - Google Patents

在具有塑料表面的基底上形成涂布金属层的预处理溶液和方法 Download PDF

Info

Publication number
CN101195911B
CN101195911B CN2006101659030A CN200610165903A CN101195911B CN 101195911 B CN101195911 B CN 101195911B CN 2006101659030 A CN2006101659030 A CN 2006101659030A CN 200610165903 A CN200610165903 A CN 200610165903A CN 101195911 B CN101195911 B CN 101195911B
Authority
CN
China
Prior art keywords
solution
acid
preprocessing solution
metal
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006101659030A
Other languages
English (en)
Chinese (zh)
Other versions
CN101195911A (zh
Inventor
赫尔曼-约瑟夫·米德克
卢保森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atotech Deutschland GmbH and Co KG
Original Assignee
Atotech Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atotech Deutschland GmbH and Co KG filed Critical Atotech Deutschland GmbH and Co KG
Priority to CN2006101659030A priority Critical patent/CN101195911B/zh
Priority to TW95147751A priority patent/TW200827482A/zh
Priority to EP06077232A priority patent/EP1942207A1/fr
Priority to PCT/EP2007/011201 priority patent/WO2008068049A1/fr
Publication of CN101195911A publication Critical patent/CN101195911A/zh
Application granted granted Critical
Publication of CN101195911B publication Critical patent/CN101195911B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/32Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1655Process features
    • C23C18/1658Process features with two steps starting with metal deposition followed by addition of reducing agent
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/20Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/2006Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
    • C23C18/2046Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment
    • C23C18/2073Multistep pretreatment
    • C23C18/208Multistep pretreatment with use of metal first
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/20Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/22Roughening, e.g. by etching
    • C23C18/26Roughening, e.g. by etching using organic liquids
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/20Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/28Sensitising or activating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/20Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/28Sensitising or activating
    • C23C18/30Activating or accelerating or sensitising with palladium or other noble metal
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/32Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • C23C18/34Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
    • C23C18/36Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemically Coating (AREA)
CN2006101659030A 2006-12-08 2006-12-08 在具有塑料表面的基底上形成涂布金属层的预处理溶液和方法 Expired - Fee Related CN101195911B (zh)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2006101659030A CN101195911B (zh) 2006-12-08 2006-12-08 在具有塑料表面的基底上形成涂布金属层的预处理溶液和方法
TW95147751A TW200827482A (en) 2006-12-08 2006-12-18 Pre-treatment solution and method of forming a layer of a coating metal on a plastics surface containing substrate
EP06077232A EP1942207A1 (fr) 2006-12-08 2006-12-18 Solution de prétraitement et procédé de formation d'une couche d'un métal de revêtement sur un substrat doté d'une surface en plastique
PCT/EP2007/011201 WO2008068049A1 (fr) 2006-12-08 2007-12-10 Solution de prétraitement et procédé de formation d'une couche d'un métal de revêtement sur un substrat comprenant une surface en plastique

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2006101659030A CN101195911B (zh) 2006-12-08 2006-12-08 在具有塑料表面的基底上形成涂布金属层的预处理溶液和方法

Publications (2)

Publication Number Publication Date
CN101195911A CN101195911A (zh) 2008-06-11
CN101195911B true CN101195911B (zh) 2011-06-22

Family

ID=38016975

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006101659030A Expired - Fee Related CN101195911B (zh) 2006-12-08 2006-12-08 在具有塑料表面的基底上形成涂布金属层的预处理溶液和方法

Country Status (4)

Country Link
EP (1) EP1942207A1 (fr)
CN (1) CN101195911B (fr)
TW (1) TW200827482A (fr)
WO (1) WO2008068049A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2639333A1 (fr) * 2012-03-15 2013-09-18 Atotech Deutschland GmbH Procédé de métallisation de surfaces en matière synthétique non conductrices
EP2639332A1 (fr) * 2012-03-15 2013-09-18 Atotech Deutschland GmbH Procédé de métallisation de surfaces en matière synthétique non conductrices
CN104540655A (zh) * 2012-05-14 2015-04-22 汽车专利管理和利用有限公司 塑料制复合材料组件
LT6070B (lt) * 2012-12-07 2014-09-25 Atotech Deutschland Gmbh Plastikų paviršiaus paruošimo prieš jų cheminį metalizavimą būdas
US9364822B2 (en) 2013-06-28 2016-06-14 Rohm And Haas Electronic Materials Llc Catalysts for electroless metallization containing five-membered heterocyclic nitrogen compounds
CN108138323B (zh) * 2015-07-30 2020-08-04 巴斯夫欧洲公司 用于金属化的塑料表面的预处理方法
US20180202048A1 (en) * 2015-07-30 2018-07-19 Basf Se Process for metallizing plastic surfaces
EP3144414B1 (fr) * 2015-09-21 2022-11-23 Airbus Defence and Space GmbH Traitement enzymatique d'objets en polyamide à des fins de métallisation
CN109778152A (zh) * 2017-11-10 2019-05-21 中国科学院大连化学物理研究所 一种高比表面积钯/聚合物复合膜的改进化学镀方法
CN108251874B (zh) * 2018-01-24 2019-08-16 永星化工(上海)有限公司 适于电镀的功能性树脂组合物上涂布金属层的预处理溶液
CN113853452A (zh) * 2019-05-17 2021-12-28 希德泰克基金会 可透光的金属涂层及其制造方法
CN117178076A (zh) * 2021-03-29 2023-12-05 哈索赫伯特施密特有限两合公司 聚酰胺的酸洗
CN113293362B (zh) * 2021-05-25 2022-02-11 吉安宏达秋科技有限公司 一种化学镀铜膨松液及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4004051A (en) * 1974-02-15 1977-01-18 Crown City Plating Company Aqueous noble metal suspensions for one stage activation of nonconductors for electroless plating
US5296020A (en) * 1991-04-11 1994-03-22 Bayer Aktiengesellschaft Formulation for the activation of substrate surfaces for currentless metallization thereof
CN1508287A (zh) * 2002-12-18 2004-06-30 用于塑料电镀的基底的活化方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3339857A1 (de) * 1983-11-04 1985-05-15 Bayer Ag, 5090 Leverkusen Verfahren zur vorbehandlung von polyamidsubstraten fuer die stromlose metallisierung
DE4412463C3 (de) * 1994-04-08 2000-02-10 Atotech Deutschland Gmbh Verfahren zur Herstellung einer Palladium-Kolloid-Lösung und ihre Verwendung
DE19740431C1 (de) * 1997-09-11 1998-11-12 Atotech Deutschland Gmbh Verfahren zum Metallisieren eines elektrisch nichtleitende Oberflächenbereiche aufweisenden Substrats

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4004051A (en) * 1974-02-15 1977-01-18 Crown City Plating Company Aqueous noble metal suspensions for one stage activation of nonconductors for electroless plating
US5296020A (en) * 1991-04-11 1994-03-22 Bayer Aktiengesellschaft Formulation for the activation of substrate surfaces for currentless metallization thereof
CN1508287A (zh) * 2002-12-18 2004-06-30 用于塑料电镀的基底的活化方法

Also Published As

Publication number Publication date
EP1942207A1 (fr) 2008-07-09
TW200827482A (en) 2008-07-01
WO2008068049A1 (fr) 2008-06-12
CN101195911A (zh) 2008-06-11

Similar Documents

Publication Publication Date Title
CN101195911B (zh) 在具有塑料表面的基底上形成涂布金属层的预处理溶液和方法
CN1314835C (zh) 无电金属电镀的方法
EP0512724B1 (fr) Bain acide pour le dépôt d'une couche intermédiaire de palladium
JP6201153B2 (ja) 無電解ニッケル又はニッケル合金メッキ用のニッケルコロイド触媒液並びに無電解ニッケル又はニッケル合金メッキ方法
US20050266165A1 (en) Method for metallizing plastic surfaces
TW201546241A (zh) 用於金屬化非導電塑膠表面之組合物及方法
US6066406A (en) Coating compositions containing nickel and boron
CN102791907A (zh) 对表面上具有至少两种不同塑料的物体进行金属化的方法
CN104364421B (zh) 使非导电塑料表面金属化的方法
CN102549196B (zh) 用于将金属涂层施加到非电导性基体上的方法
JP6150822B2 (ja) 非導電性プラスチック表面の金属化方法
WO2014124773A2 (fr) Procédé de dépôt d'une première couche métallique sur des polymères non conducteurs
EP1988192B1 (fr) Procédé d'application d'un revêtement métallique sur un substrat non conducteur
US5019163A (en) Corrosion/wear-resistant metal alloy coating compositions
JP2001206735A (ja) めっき方法
MX2013003935A (es) Proceso para deposicion por via quimica de metales utilizando baño de chapado altamente alcalino.
JP6024044B2 (ja) 導電性皮膜形成浴
JP2015537122A (ja) 非導電性プラスチック表面の金属化方法
JP4467794B2 (ja) ニッケル/ホウ素含有塗料
CN1985023A (zh) 一种用于改善镍镀层可焊性的方法
Rytlewski et al. Metallization of Polymers and Textiles
US3637472A (en) Chemical plating baths containing an alkali metal cyanoborohydride
CN102031545A (zh) 用于将金属涂层施加到非电导性基体上的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110622

Termination date: 20171208