CN101167452A - Double effective fatty acid preparation for improving plant growing and protecting plant - Google Patents
Double effective fatty acid preparation for improving plant growing and protecting plant Download PDFInfo
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- CN101167452A CN101167452A CNA2006100220929A CN200610022092A CN101167452A CN 101167452 A CN101167452 A CN 101167452A CN A2006100220929 A CNA2006100220929 A CN A2006100220929A CN 200610022092 A CN200610022092 A CN 200610022092A CN 101167452 A CN101167452 A CN 101167452A
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Abstract
Disclosed is a combined preparation with aliphatic acid as the core, the preparation formulation of which is combining aliphatic acid or aliphatic acid salt or derivant, inorganic acid or organic acid and inorganic salt or organic salt. The preparation can accelerate vegetation, increase plant output and control the harm of plant pests with very low aliphatic acid density, which realizes double effects of both increasing plant output and controlling the harm of plant pests with one preparation.
Description
One. technical field
The present invention relates to the new purposes of compound aspect plant protection and promotion plant growing, belong to chemistry and agricultural technology field, relate to chemistry, agronomy and biochemistry etc.
Two. technical background
Along with the development of chemical industry and the expansion of the agrochemical fertilizer scope of application, the quantity of chemical pesticide and kind are all in continuous increase, and World chemical agricultural chemicals gross yield (in active ingredient) is above 3,000,000 tons now.Because using in a large number for a long time of chemical pesticide and chemical fertilizer brought serious environmental to pollute and the drug-fast continuous increase of sick worm.Many countries have all dropped into substantial contribution and have researched and developed the novel formulation that can substitute or reduce chemical pesticide and chemical fertilizer, to keep the sustainable development of agricultural production.
Environmental pollution and residue of pesticide that agriculture chemical causes are even more serious in China.There are 1.2 hundred million hectares of arable lands in China, and the total amount of application of chemical pesticide reaches 131.2 ten thousand tons, uses 931.3 grams for average every mu, and vegetables and melon and fruit more reach 6.67 kilograms/mu.The fertilizer amount of China has then accounted for 1/3 of global consumption, has brought serious rivers and lakes and underground water eutrophication pollution thus.Causing the output because the grower covets of using in a large number on the one hand of China's fertilizer and pesticide, is owing to lack the use that can effectively reduce fertilizer and agricultural chemicals but the method and the product that can guarantee crop yield on the other hand.
The fatty acid that is present in occurring in nature in a large number of discovering in early stage has certain bacterium and Fungicidally active extremely, and the n-nonanoic acid of high concentration has very strong phytotoxicity also to be used as weed killer herbicide.S.D. people such as savart lattice has obtained good effect (CN1069391A) with direct antifungal in disease position and bacterium that fatty acid is administered to plant, the result of treatment of fatty acid by antifungal and bacterize plant disease emphasized in their research, just there is not an activity but the concentration of making statement fatty acid is very low, too highly then plant is damaged, and fatty acid and its salt or derivative do not have prophylactic activity to plant disease.In the experimental result that they provide, fatty acid and its salt or derivative are that therapeutic action is just played at the disease position that is applied directly to plant, and the minimal effective concentration that the salt of fatty acid and it or derivative are administered on the plant is 0.125%a.i. (1250 mg/litre), and concentration is low to moderate 0.063% o'clock used fatty acid or its salt or derivative and has not just controlled the effect of infection process.
The present invention relates to be used for the new purposes that plant pest is grown and prevented and treated to coordinate plant growth with the new compositions that known compound is made, by with the combination of inorganic acid or organic acid and mineral salt or organic salt, very the aliphatic acid composition of low concentration has promptly been obtained and has been promoted plant growing, increase the outstanding effect on the plant products, and the composition of this low concentration can also effectively prevent the various plants damage by disease and insect.Use chemical fertilizer in a large number and the pollution of agricultural chemicals in agricultural product and environment has very positive meaning for reducing.
Three. summary of the invention
The technical problem that solves
Purpose one of the present invention provides the pharmaceutical formulation that the combination of the salt of a kind of fatty acid or fatty acid or derivative and inorganic acid or organic acid and mineral salt or organic salt is made, this preparation just can realize promoting plant growing with low-down fatty acid concentration, improve plant products, and the harm of controlling plant damage by disease and insect, realized that a preparation can improve plant products, can prevent the economic benefits and social benefits effect of plant pest again.
Purpose two of the present invention is seeds that the preparation made can be applied to plant, leaf, and root, stem or fruit, the application process of preparation is for spraying, and pouring is soaked seed and is soaked fruit.
Technical scheme
Those skilled in the art know that compound can obtain synergy by suitable combination, and the function of this synergy performance usually exceeds much than single compound.Main method of the present invention is that the salt of saturated and unsaturated fatty acid or fatty acid or derivative and inorganic acid or organic acid and mineral salt or organic salt are made up a kind of pharmaceutical formulation of making, by the synergy between compound, make preparation just obtain the promotion plant growing with the content of fatty acid of low concentration very, improve plant products, the remarkable result of prevention plant pest.
Described fatty acid is including, but not limited to saturated or undersaturated fatty acid from C5 to C24, including, but not limited to palmitic acid, and palmitoleic acid, stearic acid, linoleic acid, oleic acid, certain herbaceous plants with big flowers acid, lauric acid, myristic acid, n-nonanoic acid, arachidonic acid etc.The salt of described fatty acid or derivative including, but not limited to: by potassium, sodium, soap or derivative that ammonium plasma or group of containing amido etc. are combined into.Described inorganic acid or organic acid are including, but not limited to sulfuric acid, acetic acid, phosphoric acid, nitric acid, hydrochloric acid, phosphorous acid, sulfurous acid, boric acid, formic acid, acetate, glacial acetic acid, butyric acid, phthalic acid, terephthalic acid (TPA), succinic acid, humic acid, salicylic acid, p-aminobenzoic acid, ortho-aminobenzoic acid, benzoic acid etc.Described mineral salt or organic salt are including, but not limited to calcium chloride, sodium chloride, potassium chloride, superphosphate, sodium tripolyphosphate, sodium polyphosphate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate, sodium sulphate, potassium sulphate, calcium carbonate, calcium bicarbonate, calcium sulphate, nitrate of lime, calisanin etc.
Implementation step of the present invention is:
1) get sodium palmitate 15 grams, odium stearate 2 grams all available from Sigma-Aldrich company, add water to 1 liter, fully mix, and make sodium palmitate and odium stearate mixed liquor.
2) get in the hydrochloric acid solution that 100 milligrams of nitrate of lime join 120 milliliter 10%, fully stir, adds 10 milliliters and contain 20% sodium tripolyphosphate solution, join in the above-mentioned mixed liquor after fully stirring, fully the fatty acid combination preparation is promptly made in stirring.
Embodiment:
Example 1.
1) get sodium palmitate 15 grams, odium stearate 2 grams all available from Sigma-Aldrich company, add water to 1 liter, fully mix, and make sodium palmitate and odium stearate mixed liquor.
2) get in the hydrochloric acid solution that 100 milligrams of nitrate of lime join 120 milliliter 10%, fully stir, adds 10 milliliters and contain 20% sodium tripolyphosphate solution, join in the above-mentioned mixed liquor after fully stirring, fully the fatty acid combination preparation is promptly made in stirring.
Example 2. is got 100 milliliters of fatty acid combination preparations, and 100 times of thin ups evenly are sprayed onto on the annual grape seedlings, sprays once every 15 days, does not use any chemical pesticide and topdresses, and adjacent plot spray chemical pesticide and the Routine Management that topdresses compare.Spray 3 " Invest, Then Investigate " results such as table 1, the fatty acid combination preparation has significantly promoted the growth of grapevine seedling.
Table 1 fatty acid combination preparation promotes the effect of grapevine seedling growth
| Handle | Plant height (rice) | The thick girth of stem (cm) |
| Contrast | 0.93 | 4.9 |
| The fatty acid combination preparation | 1.35 | 7.1 |
The plot of peach yellows took place with precocious peach kind ball peach arrangement field trial in example 3. at known continuous 3 years.The reason that causes the peach yellows is not made final conclusion as yet, but preliminary investigation thinks it may is because the physiological disease that causes of iron deficiency or infect the pathologic yellow that causes by a kind of viroids, or the peach yellow that causes of the immixture of these two kinds of reasons.Test is divided into two groups, and one group is that peach occurs promptly beginning to handle before the yellow, and another group just begins to handle after the yellow symptom has appearred in peach blade.
100 milliliters of fatty acid combination preparations are got in processing, and 100 times of thin ups evenly are sprayed onto on the blade of peach, spray once every 15 days, do not use any chemical pesticide and topdress, and compare with spray chemical pesticide and the Routine Management that topdresses.Handle and each 5 strain of contrast, repeat 3 times.Investigation result such as table 2.
The effect of table 2 fatty acid combination preparation on control peach yellows
| Handle | The yellows incidence (%) of beginning spray preparation before yellows take place | Yellows begin spray preparation after taking place |
| The fatty acid combination preparation | 0.00 | Yellow leaf vein changes green after spraying fatty acid combination preparation, and it is green spray 3 rear blades commentaries on classics |
| Contrast | 78.3 | The yellow of complete stool blade, serious blade is little and bleach |
Example 3. is got and is subjected to the serious cauliflower blade of vegetable aphid harm, soaks to take out after 30 seconds in the fatty acid combination preparation of variable concentrations to place culture dish, covers the culture dish lid and prevents that aphid from escaping from.The lethality of 24 hours " Invest, Then Investigate " aphids.See Fig. 1, the fatty acid combination preparation reaches at 5% o'clock in concentration and promptly manifests insecticidal effect, and concentration reaches more than 80% to 10% o'clock fatty acid combination preparation insecticidal effect.
Description of drawings:
Fig. 1 is the anti-design sketch that eliminates aphis of fatty acid combination preparation, and among the figure, abscissa is the concentration (%) of fatty acid combination preparation, and ordinate is the lethality (%) of aphid.
Example 4. Insecticidal effect at the bamboo test aliphatic acid combination preparation that is subjected to arrowhead scales harm. 100 milliliters of aliphatic acid combination preparations are got in processing, and 100 times of thin ups evenly are sprayed onto on the leaf of bamboo, spray once every 7 days, compare with the spray clear water. Process and each 5 strain of contrast, 2 months " Invest, Then Investigate " results such as table 3, the aliphatic acid combination preparation has the effect of good control arrowhead scales.
The effect of table 3 aliphatic acid combination preparation control arrowhead scales
| Process | The death rate % of arrowhead scales |
| Contrast | 1.2 |
| The aliphatic acid combination preparation | 89.7 |
Claims (14)
1. one kind is used for the double effective fatty acid preparation that plant pest is grown and prevented and treated to coordinate plant growth.It is characterized in that: be selected from one or more fatty acid, or the salt of fatty acid or derivative, with be selected from one or more inorganic acids or organic acid and be selected from that the combination of one or more mineral salt or organic salt makes coordinate plant growth grow, increase plant products, the double effective fatty acid preparation of control plant pest.
2. fatty acid as claimed in claim 1 is including, but not limited to saturated or undersaturated fatty acid from C5 to C24, including, but not limited to palmitic acid, and palmitoleic acid, stearic acid, linoleic acid, oleic acid, certain herbaceous plants with big flowers acid, lauric acid, myristic acid, n-nonanoic acid, arachidonic acid etc.
According to claim 1 the salt of fatty acid or derivative including, but not limited to: by potassium, sodium, soap or derivative that ammonium plasma or group of containing amido etc. are combined into.
4. inorganic acid or organic acid are including, but not limited to sulfuric acid, acetic acid, phosphoric acid, nitric acid as described in wanting 1 as right, hydrochloric acid, phosphorous acid, sulfurous acid, boric acid, formic acid, acetate, glacial acetic acid, butyric acid, phthalic acid, terephthalic acid (TPA), succinic acid, humic acid, salicylic acid, p-aminobenzoic acid, ortho-aminobenzoic acid, benzoic acid etc.
According to claim 1 mineral salt or organic salt including, but not limited to calcium chloride, sodium chloride, potassium chloride, superphosphate, sodium tripolyphosphate, sodium polyphosphate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate, sodium sulphate, potassium sulphate, calcium carbonate, calcium bicarbonate, calcium sulphate, nitrate of lime, calisanin etc.
6. plant pest according to claim 1 is characterized in that: including, but not limited to by fungi, and bacterium, virus, viroids, nematode etc. are infected the pathologic plant disease that causes, or because nitrogen stress, phosphorus, potassium, calcium, magnesium, sulphur, iron, zinc, manganese, the physiological plant disease that nutritive elements such as boron cause, or by aphid, coccid, the insect pest that mite etc. cause.
7. preparation according to claim 1, it is characterized in that: described preparation can only contain the salt or the derivative of a kind of fatty acid or fatty acid.
8. preparation according to claim 1, it is characterized in that: more preferably described preparation contains the salt of two or more fatty acid and fatty acid or fatty acid or the composition of derivative.
9. preparation according to claim 1 is characterized in that: the target site that described preparation can be applied to is including, but not limited to the seed of plant, leaf, root, stem or fruit, or any solid-state or liquid object of plant attaching.
10. preparation according to claim 1, it is characterized in that: the mass concentration of institute's fatty acids is 0.001 mg/litre-20 grams per liter in the liquid when being administered on the target site behind the described preparation dilute with water.
11. preparation according to claim 1, it is characterized in that: the mass concentration of institute's fatty acids is 0.01 mg/litre-1249.9999 mg/litre in the liquid when being administered on the target site behind the preferred described preparation dilute with water.
12. preparation according to claim 1, it is characterized in that: the preparation method of preparation can be from microbial fermentation solution, extract aliphatic acid composition in plant or the animal body, with aliphatic acid composition be selected from one or more inorganic acids or organic acid and be selected from one or more mineral salt or organic salt stirs and is mixed and made into.
13. preparation according to claim 1, it is characterized in that: the preparation method of preferred preparation be selected from after one or more fatty acid emulsifications or the salt of fatty acid or derivative by required mass concentration, and be selected from one or more inorganic acids or organic acid and be selected from one or more mineral salt or organic salt stirs and is mixed and made into.
14. as described in claim 8, it is characterized in that described fatty acid accounts for total grease in composition ratio is: palmitic acid 0-95%, stearic acid 0-20%, linoleic acid 0-85%, oleic acid 0-90%, certain herbaceous plants with big flowers acid 0-20%, lauric acid 0-25%, myristic acid 0-20%, n-nonanoic acid 0-20%.
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| CN101637156A (en) * | 2008-07-30 | 2010-02-03 | 黄永 | Composite of fatty acids and derivatives thereof |
| CN102326542A (en) * | 2011-10-24 | 2012-01-25 | 中国农业大学 | New use of palmitic acid as meloidogyne incognita repellent |
| CN102326541A (en) * | 2011-10-24 | 2012-01-25 | 中国农业大学 | New use of lauric acid in prevention and control of meloidogyne incognita |
| WO2011135121A3 (en) * | 2010-04-19 | 2012-03-08 | Iden Biotechnology, S.L. | Method for changing the development pattern, increasing the growth and accumulation of starch, changing the structure of starch and increasing the resistance to hydric stress in plants |
| ES2376734A1 (en) * | 2010-08-13 | 2012-03-16 | Iden Biotechnology, S.L. | Improvements introduced in the object of the main patent no. P201000499 by "procedure to alter the development pattern, increase growth and accumulation of starch and alter the structure of starch in plants". (Machine-translation by Google Translate, not legally binding) |
| CN102438456A (en) * | 2009-04-07 | 2012-05-02 | 塔明克股份有限公司 | Pollination improver |
| CN102524254A (en) * | 2011-12-27 | 2012-07-04 | 中国农业大学 | Application of tridecanoic acid in aspect of preventing and controlling Meloidogyne incognita |
| CN102524255A (en) * | 2011-12-27 | 2012-07-04 | 中国农业大学 | Application of linoleic acid in aspect of preventing and controlling Meloidogyne incognita |
| CN103483069A (en) * | 2013-09-10 | 2014-01-01 | 天津坂结土壤肥料技术开发有限公司 | All-nutrition type liquid fertilizer |
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| CN105007725A (en) * | 2012-12-26 | 2015-10-28 | 巴西农业研究公司-恩布拉帕 | Nematicide composition with a synergistic effect, use of nematicide composition with a synergistic effect |
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| FR2634103B1 (en) * | 1988-07-13 | 1991-08-30 | Sogard Services Sarl | PROCESS AND PRODUCT FOR ELIMINATING PEST INSECTS AND ACCELERATING THE DEVELOPMENT OF TREATED PLANTS |
| US5366995A (en) * | 1991-05-01 | 1994-11-22 | Mycogen Corporation | Fatty acid based compositions for the control of established plant infections |
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| CN101637156A (en) * | 2008-07-30 | 2010-02-03 | 黄永 | Composite of fatty acids and derivatives thereof |
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| WO2011135121A3 (en) * | 2010-04-19 | 2012-03-08 | Iden Biotechnology, S.L. | Method for changing the development pattern, increasing the growth and accumulation of starch, changing the structure of starch and increasing the resistance to hydric stress in plants |
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| CN102326541A (en) * | 2011-10-24 | 2012-01-25 | 中国农业大学 | New use of lauric acid in prevention and control of meloidogyne incognita |
| CN102326542A (en) * | 2011-10-24 | 2012-01-25 | 中国农业大学 | New use of palmitic acid as meloidogyne incognita repellent |
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| CN102524255A (en) * | 2011-12-27 | 2012-07-04 | 中国农业大学 | Application of linoleic acid in aspect of preventing and controlling Meloidogyne incognita |
| CN102524255B (en) * | 2011-12-27 | 2014-07-09 | 中国农业大学 | Application of linoleic acid in aspect of preventing and controlling Meloidogyne incognita |
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| CN104510729A (en) * | 2013-09-26 | 2015-04-15 | 黄永 | Animal immune resistance-activating composition of fatty acid and derivatives thereof |
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| CN108605957A (en) * | 2018-06-19 | 2018-10-02 | 郑州信联生化科技有限公司 | A kind of plant stimulants composition and its preparation and application |
| CN110483169A (en) * | 2018-09-03 | 2019-11-22 | 中国农业大学 | Application of the palmitinic acid in banana planting |
| CN110483168A (en) * | 2018-09-03 | 2019-11-22 | 中国农业大学 | A kind of banana planting growth promoter special and its preparation method and application |
| WO2020178067A1 (en) * | 2019-03-01 | 2020-09-10 | Bayer Aktiengesellschaft | Active compound combinations having insecticidal/acaricidal properties |
| CN109964937A (en) * | 2019-04-12 | 2019-07-05 | 东北林业大学 | Medicament containing DCA is improving the application in pine tree disease resistance |
| CN109964937B (en) * | 2019-04-12 | 2021-02-09 | 东北林业大学 | Application of DCA-containing medicament to improvement of disease resistance of pine trees |
| CN111493099A (en) * | 2020-06-02 | 2020-08-07 | 上海交通大学 | Compound extracted from peanut branches and leaves and used for preventing and treating tetranychus cinnabarinus and application of compound |
| CN115997766A (en) * | 2022-11-21 | 2023-04-25 | 云南农业大学 | Mixtures of phthalic acid, palmitic acid and azelaic acid and their use |
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| Publication number | Publication date |
|---|---|
| CN101167452B (en) | 2012-10-31 |
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