CN101120010B - 基于茂金属的磷手性膦 - Google Patents

基于茂金属的磷手性膦 Download PDF

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Publication number
CN101120010B
CN101120010B CN200680004909.8A CN200680004909A CN101120010B CN 101120010 B CN101120010 B CN 101120010B CN 200680004909 A CN200680004909 A CN 200680004909A CN 101120010 B CN101120010 B CN 101120010B
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CN
China
Prior art keywords
ligand
phosphorus
metallocene
group
ferrocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN200680004909.8A
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English (en)
Chinese (zh)
Other versions
CN101120010A (zh
Inventor
彼得·麦科马克
陈卫平
约翰·惠托尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvias AG
Original Assignee
Solvias AG
Phoenix Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Solvias AG, Phoenix Chemicals Ltd filed Critical Solvias AG
Publication of CN101120010A publication Critical patent/CN101120010A/zh
Application granted granted Critical
Publication of CN101120010B publication Critical patent/CN101120010B/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN200680004909.8A 2005-01-14 2006-01-13 基于茂金属的磷手性膦 Expired - Lifetime CN101120010B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0500702.6A GB0500702D0 (en) 2005-01-14 2005-01-14 Novel metallocene-based phosphorus chiral phosphines
GB0500702.6 2005-01-14
PCT/GB2006/000114 WO2006075166A1 (en) 2005-01-14 2006-01-13 Metallocene-based phosphorus chiral phosphines

Publications (2)

Publication Number Publication Date
CN101120010A CN101120010A (zh) 2008-02-06
CN101120010B true CN101120010B (zh) 2013-07-03

Family

ID=34224566

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200680004909.8A Expired - Lifetime CN101120010B (zh) 2005-01-14 2006-01-13 基于茂金属的磷手性膦

Country Status (11)

Country Link
US (1) US7906669B2 (https=)
EP (1) EP1844061B1 (https=)
JP (1) JP5112881B2 (https=)
CN (1) CN101120010B (https=)
AT (1) ATE476437T1 (https=)
AU (1) AU2006205652B2 (https=)
CA (1) CA2594893C (https=)
DE (1) DE602006015910D1 (https=)
ES (1) ES2348060T3 (https=)
GB (2) GB0500702D0 (https=)
WO (1) WO2006075166A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2004662B1 (en) * 2006-04-12 2013-12-25 Solvias AG Ferrocenediphosphines
WO2008055942A1 (en) * 2006-11-10 2008-05-15 Solvias Ag Preparation of optically pure ferrocenediphosphines
WO2008101868A1 (en) * 2007-02-20 2008-08-28 Solvias Ag Bis (ferrocenylphosphino) ferrocene ligands used in asymmetric hydrogenation reactions
KR20190059988A (ko) * 2011-08-08 2019-05-31 사우디 아람코 테크놀로지스 컴퍼니 폴리머 합성용 촉매 및 방법
CN116120378B (zh) * 2021-11-15 2025-06-06 中国科学院上海有机化学研究所 一种二茂铁双齿膦配体催化丁二烯制备己二腈的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001058588A1 (en) * 2000-02-10 2001-08-16 The Penn State Research Foundation Chiral ferrocene phosphines and their use in asymmetric catalytic reactions
JP2005041847A (ja) * 2003-07-25 2005-02-17 Nippon Chem Ind Co Ltd フェロセンを置換基に有する光学活性リンキラルジホスフィン化合物、該化合物の中間体、該化合物の製造方法及び該化合物を用いる不斉合成反応、並びに該化合物を配位子として有する金属錯体触媒及び該金属錯体触媒を用いる不斉合成反応をする方法
GB0400720D0 (en) * 2004-01-14 2004-02-18 Stylacats Ltd Novel ferrocene-based phosphorus chiral phosphines

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Nobuhiko Oohara, Kosuke katagiri, et al..A novel P-chirogenic phosphine ligand, (S,S)-1,2-bis-[(ferrocenyl)methylphosphino]ethane:synthesis and use inrhodium-catalyzed asymmetric hydrogenation and palladium-catalyzed asymmetric allylic alkylation..Tetrahedron: Asymmetry14.2003,142171-2175. *
Ulrike Nettekoven, Michael Widhalm, et al..Steric and electronic ligand perturbations in catalysis:asymmetric allylic substitution reactions using C2-symmetricalphosphorus-chiral (Bi)ferrocenyl donors..J. Org. Chem.66.2001,66759-770. *

Also Published As

Publication number Publication date
CN101120010A (zh) 2008-02-06
US7906669B2 (en) 2011-03-15
GB0500702D0 (en) 2005-02-23
AU2006205652B2 (en) 2010-09-09
ES2348060T3 (es) 2010-11-29
JP5112881B2 (ja) 2013-01-09
US20090137824A1 (en) 2009-05-28
CA2594893A1 (en) 2006-07-20
EP1844061B1 (en) 2010-08-04
GB2422604A (en) 2006-08-02
ATE476437T1 (de) 2010-08-15
AU2006205652A1 (en) 2006-07-20
JP2008526938A (ja) 2008-07-24
DE602006015910D1 (de) 2010-09-16
WO2006075166A1 (en) 2006-07-20
GB0600713D0 (en) 2006-02-22
EP1844061A1 (en) 2007-10-17
CA2594893C (en) 2014-05-13

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C06 Publication
PB01 Publication
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Owner name: SOLVAYAS STOCK CO., LTD.

Free format text: FORMER OWNER: PHOENIX MEDICINE CO., LTD.

Effective date: 20091106

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Effective date of registration: 20091106

Address after: Basel, Switzerland

Applicant after: SOLVIAS AG

Address before: Britain Merseyside

Applicant before: Phoenix Chemicals Ltd.

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CX01 Expiry of patent term

Granted publication date: 20130703

CX01 Expiry of patent term