CN101108943A - Method of producing and painting stone similar paint for flexible flat surface - Google Patents

Method of producing and painting stone similar paint for flexible flat surface Download PDF

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Publication number
CN101108943A
CN101108943A CNA2007100707065A CN200710070706A CN101108943A CN 101108943 A CN101108943 A CN 101108943A CN A2007100707065 A CNA2007100707065 A CN A2007100707065A CN 200710070706 A CN200710070706 A CN 200710070706A CN 101108943 A CN101108943 A CN 101108943A
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China
Prior art keywords
paint
stone
water
flat surface
flexible flat
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Pending
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CNA2007100707065A
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Chinese (zh)
Inventor
郑树军
陈炎林
朱从华
郭震
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Zhejiang Huate Advanced Materials Co., Ltd.
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HUATE CHEMICAL Co Ltd HUATE INDUSTRY GROUP ZHEJIANG
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Priority to CNA2007100707065A priority Critical patent/CN101108943A/en
Publication of CN101108943A publication Critical patent/CN101108943A/en
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Abstract

A production method of a flexible stone-like paint is provided, which consists of the following raw materials and weight portion mixture ratios: 4 to 6 of water, 12 to 13 of waterborne pure acrylic acid emulsion, 68 to 80 of fillers and 0.65 to 2.8 addition agents. The method is that water, emulsion and addition agents are mixed first and are dispersed for 5min to 10min at medium speed, and are dispersed for 20min to 30min at low speed after adding the fillers; each half of antifoamers are added into the above two procedures respectively and are mixed with color and stirred evenly to form the stone-like paint. The wall is neatened first when painting and then sprayed by primer or rendered by roller coat, and tackiness paper tapes are stuck in grids; the stone-like paint is adopted to spray spots which are polished by abrasive paper after drying; the stone-like paint is adopted to level and polish twice until the spots are completely set off, to remove the dust and rip off the tackiness paper tapes and spray finishing varnish finally. The stone-like paint is applied in the decoration of the walls of construction or the table-board of the kitchens and toilets, and is beneficial for environment protection, light in quality and strong in toughness, which can be directly coated on the wall with surface low cost and energy-saving, therefore, the wall surface is not easy to store dust and the shapes and colors of the plane-imitating marble slab and the granite slab are lifelike.

Description

Stone similar paint for flexible flat surface is produced and coating process
Technical field
The present invention relates to a kind of production and coating process of house paint, particularly is tackiness agent and production and the coating process with house paint of the imitative stone visual effect in plane with the water-based emulsion.
Background technology
CN1256256A discloses Xiamen Huayushi Industry Co., Ltd.'s " a kind of artificial marble and manufacturing process thereof " patented technology, with the stone flour is that base mateiral, unsaturated polyester are that tackiness agent, interpolation promotor, stiffening agent, toner and aluminium hydrate powder are deployed into the casting material, inject mould, heat to 60 ℃ of-80 ℃ of dryings, the demoulding, surface spraying toner and transparent adhesive tape, oven dry in 130 ℃-160 ℃, polishing are waxed again.The imitative stone quality product in the plane of making is heavy, matter is crisp, can not directly application on metope, need on ground with after being molded as, and with the cementitious wall of going up, body of wall has load-bearing greatly to bear.Especially make tackiness agent with unsaturated polyester, the existence of phenyl ring runs counter to environmental requirement, unfavorable HUMAN HEALTH.CN1903954A discloses the patented technology of the applicant at " double layer rock wall imitation external wall paint and the coating process thereof " of first to file, though also be aqueous adhesive with environment-friendly type, shared operations such as color spray spot are also arranged during application, but all raw material combination and proportioning, a complete set of production technique and coating process, it is completely different to be coated on visual effect behind the body of wall etc., and production cost is low, toughness strong, be difficult for splitting.
Summary of the invention
The objective of the invention is above-mentioned deficiency at prior art, design a kind of light weight, toughness is strong, cost is low, without mould, can directly go up the wall application, not hinder stone similar paint for flexible flat surface production and coating process in environmental protection.
The present invention is realized by following measure:
This stone similar paint for flexible flat surface production method is to be formed by following raw materials according and weight part proportioning thereof: water 4-6 branch, water-based pure acrylic acid emulsion 12-13 part, stopping composition 68-80 part, auxiliary agent 0.65-2.8 part, earlier with water, auxiliary agent, water-based pure acrylic acid emulsion transfers to middling speed with high speed dispersor in normal temperature and pressure, disperse 5-10min, add stopping composition and carry out low speed dispersion 20-30min again, as defoamer is arranged in the auxiliary agent, then each adds in aforementioned first procedure earlier with half amount, restir 5-10min in the compound after finishing with residue half amount adding second operation work again, make the base paint of stone similar paint for flexible flat surface, select look more as required, color matching, the toning back is a finished product, check, barreled.
This stone similar paint for flexible flat surface coating process is to need through following several procedures:
(1) will treat the polishing dust removal of the smooth back of application metope processing;
(2) spraying of use silicon third metope infiltration seal coat or roller coat are together; ,
(3) treat priming paint do after with the metope lattice, retouch graticule, stick adhesive tape with the lines lacquer;
(4) carry out the spot spraying with the special-purpose spray gun of building coating, spraying number of times, spray gun branch number are consistent with spot look species number;
(5) spot is done the back smooth dust removal of sand papering;
(6) carry out first road with this lacquer of selected color and criticize and scrape, the polishing of dry back is carried out second road if necessary again and is criticized and scrape, and does back polishing for the second time and promptly ends after setting off out spot of all kinds fully, and adhesive tape is pulled in dust removal;
(7) coat fluorine carbon finishing paint or urethane finishing paint or water-based silicon third finishing paint one to two road on the surface, cover into inferior light or light.
The present invention also can come perfect by following measure:
Said stopping composition is that granularity 400 purpose talcum powder 20-25 weight parts, granularity are that 400 purpose water-ground limestone 40-45 weight parts and/or granularity are 200 purpose silica powder 8-10 weight parts.
Said auxiliary agent is at least a in Antisepticize and mildew preventive 0.1-0.2 weight part (down together), dispersion agent 0.3-0.5 part, defoamer 0.2-0.4 part, pH value conditioning agent 0.1-0.2 part, film coalescence aid 0.5-0.8 part, frostproofer 0.3-0.5 part, thickening material 0.1-0.2 part.
Antisepticize and mildew preventive in the said auxiliary agent is at least a in the heavy metallic salt of isothiazolinone and derivative thereof, slowly-releasing; Dispersion agent is at least a in sodium polyacrylate and remaining polycarboxylate; Defoamer is at least a in mineral oil, organosilicon, the polyethers; The pH value conditioning agent is that 2-amino-2-methyl-1-propanol is the alkamine of representative; Film coalescence aid is at least a in ten diester alcohol, propylene glycol, the glycol ether; Frostproofer is ethylene glycol and/or propylene glycol; Thickening material is at least a in cellulose ethers, alkali swelling acrylic acid or the like, the wilkinite.
The invention has the beneficial effects as follows the employing aqueous adhesive, harmless to HUMAN HEALTH, light weight, toughness are strong, it is more meaningful that this builds wall to lightweight body of wall, earthquake multiplely, can reduce the energy cost and the drying room cost of die cost and heating, drying directly in the metope application, metope after the application is than the laying dust that is difficult for of stereo imitating rock, metope is clean and tidy, imitative plane marble, and granitic shape and color is true to nature.
Embodiment
The present invention is described in detail below in conjunction with embodiment: this stone similar paint is mainly mixed by four class raw materials: water, water-based pure acrylic acid emulsion, stopping composition and auxiliary agent, preceding two kinds very clear and definite, can not select, back two classes should be selected as the case may be, but even extend range also, as stopping composition, except that talcum powder, water-ground limestone, silica powder, other light stone flour also can.Both also can singly use water-ground limestone, silica powder, no matter use several, the overall control of stopping composition in 68-80 weight part scope for well.Auxiliary agent has multiple, select according to different function needs, as be coated on the stone similar paint of torrid areas building wall, just do not need frostproofer, what be used for high and cold or desert area not necessarily wants mould inhibitor etc., and being used for seven kinds of concrete auxiliary agents that the application's material of the coastal provinces and cities of China lists should all use.Consideration cost and effect are carried out consumption and are selected.Below each raw material and weight part thereof are tabulated by five embodiment:
Figure A20071007070600071
Embodiment 1 (embodiment 1 corresponding raw material and parts by weight certificate in the synopsis):
Water with 4 weight parts (together following), 12 parts of water-based pure acrylic acid emulsions (abbreviation emulsion), 20 parts of talcum powder, 40 parts of heavy calcium carbonates (abbreviation coarse whiting), 8 parts of silica powders, 0.1 part isothiazolinone, 0.3 part sodium polyacrylate as dispersion agent, 0.2 part mineral oil antifoam agent, 0.5 part ten diester alcohol as film coalescence aid, 0.3 part ethylene glycol as frostproofer, 0.15 part Natvosol as thickening material, 0.1 part as the PH conditioning agent is the amino alcohol of representative with the 2-amino-2-methyl-1-propanol, earlier with water, emulsion, various auxiliary agents transfer to middling speed with high speed dispersor in normal temperature and pressure, carry out middling speed and disperse 5-10min, add stopping composition such as talcum powder, low speed disperses 20-30min, it should be noted the i.e. 0.2 part of mineral oil of defoamer in the auxiliary agent wherein, should when disperseing, middling speed add 0.1 part, all the other 0.1 part adds after low speed disperses, restir 5-10min, just make the base paint of this stone similar paint, mix colours according to user's needs again.Peach as furnishing, only need to add base paint (being white) because of three kinds of stopping composition are white with a small amount of red mill base, stir, check again, barreled dispatches from the factory.
The corresponding raw material of embodiment 2-5 and weight part proportioning number in the equal reference table of all the other embodiment 2-5, make with embodiment 1 same procedure, when having last toning only, the add-on of mill base can't be confined the quantity interval, as adjust to white look needn't add mill base, transfer pink with transfer bright redly, the amount that adds red mill base is very big with regard to difference.This should adjust by rule of thumb and in actually operating at any time.
Total amount that should auxiliary agent also is difficult to confine interval value, is subjected to the choice of kind and the big or small dual restriction of amount.Among 5 embodiment, preferred in the table with embodiment 3.
In the table because of being subjected to the restriction of grid, isothiazolinone as fungusproof anti-corrosion agent is also being represented its derivative, Silver Nitrate is being represented the heavy metal salt of slowly-releasing, sodium polyacrylate is represented the polycarboxylic acid salt, the defoamer mineral oil in fluid is at kerosene, diesel oil, select in the machine oil etc., organosilicon is represented with polyether-modified methyl-silicone oil, polyethers is representative with propylene oxide oxyethane polyethers, the propylene glycol ethers is representative with the propylene glycol monomethyl ether in the film coalescence aid, gylcol ether is representative with the butyl glycol ether, alkali swelling acrylic acid or the like (being called for short vinylformic acid in the table) is representative with the polyacrylic acid emulsion in the thickening material, Natvosol is represented cellulose ethers, and the PH conditioning agent is represented alkamine with 2-amino-2-methyl-1-propanol.More than describing is the limitation of explanation because of grid in the table, write a certain compound in each auxiliary agent, be to represent this compounds, whether also possesses same auxiliary agent effect as for all the other compounds in such, because of being the industry those of ordinary skill grasp on the patent law meaning, just no longer enlarge form and list one by one.Above-mentioned representative is generally the preferred feedstock in the auxiliary agent that plays specific function in this compounds.
Adopt the pure acrylic acid emulsion of water-based to make tackiness agent in this stone similar paint, as use the redispersibility rubber powder instead and cement mixing is made tackiness agent, not satisfactory, the one, Portland cement mostly is grey, toning is produced hide look, and alkalescence is crossed strong unfavorable guarantor's look, the cement water-absorbent is strong excessively, easily splits after dried.
In coating decoration, only in the 4th procedure and the 6th procedure, adopt this stone similar paint, all the other first, second and third, seven procedures are respectively with other lacquer or putty, but these autogamys and commercially available acquisition.Select the caliber size of building coating spray gun, it is fixed to come by the spot size of being sprayed, and grasps a rifle principle of the same colour, does not use with.

Claims (5)

1. stone similar paint for flexible flat surface production method, it is characterized in that forming: water 4-6 branch by following raw materials according and weight part proportioning thereof, water-based pure acrylic acid emulsion 12-13 part, stopping composition 68-80 part, auxiliary agent 0.65-2.8 part, earlier with water, auxiliary agent, water-based pure acrylic acid emulsion transfers to middling speed with high speed dispersor in normal temperature and pressure, disperse 5-10min, add stopping composition and carry out low speed dispersion 20-30min again, as defoamer is arranged in the auxiliary agent, then each adds in aforementioned first procedure earlier with half amount, restir 5-10min in the compound after finishing with residue half amount adding second operation work again, make the base paint of stone similar paint for flexible flat surface, select look more as required, color matching, the toning back is a finished product, check, barreled.
2. stone similar paint for flexible flat surface production method as claimed in claim 1 is characterized in that said stopping composition is that granularity 400 purpose talcum powder 20-25 weight parts, granularity are that 400 purpose water-ground limestone 40-45 weight parts and/or granularity are 200 purpose silica powder 8-10 weight parts.
3. stone similar paint for flexible flat surface production method as claimed in claim 1 is characterized in that said auxiliary agent and weight part thereof are at least a in Antisepticize and mildew preventive 0.1-0.2 part, dispersion agent 0.3-0.5 part, defoamer 0.2-0.4 part, pH value conditioning agent 0.1-0.2 part, film coalescence aid 0.5-0.8 part, frostproofer 0.3-0.5 part, thickening material 0.1-0.2 part.
4. stone similar paint for flexible flat surface production method as claimed in claim 3 is characterized in that Antisepticize and mildew preventive in the said auxiliary agent is at least a in the heavy metallic salt of isothiazolinone and derivative thereof, slowly-releasing; Dispersion agent is at least a in sodium polyacrylate and remaining polycarboxylate; Defoamer is at least a in mineral oil, organosilicon, the polyethers; The pH value conditioning agent is that 2-amino-2-methyl-1-propanol is the alkamine of representative; Film coalescence aid is at least a in ten diester alcohol, propylene glycol, the glycol ether; Frostproofer is ethylene glycol and/or propylene glycol; Thickening material is at least a in cellulose ethers, alkali swelling acrylic acid or the like, the wilkinite.
5. stone similar paint for flexible flat surface coating process as claimed in claim 1 needing is characterized in that through following several procedures:
(1) will treat the polishing dust removal of the smooth back of application metope processing;
(2) spraying of use silicon third metope infiltration seal coat or roller coat are together; ,
(3) treat priming paint do after with the metope lattice, retouch graticule, stick adhesive tape with the lines lacquer;
(4) carry out the spot spraying with the special-purpose spray gun of building coating, spraying number of times, spray gun branch number are consistent with spot look species number;
(5) spot is done the back smooth dust removal of sand papering;
(6) carry out first road with this lacquer of selected color and criticize and scrape, the polishing of dry back is carried out second road if necessary again and is criticized and scrape, and does back polishing for the second time and promptly ends after setting off out spot of all kinds fully, and adhesive tape is pulled in dust removal;
(7) coat fluorine carbon finishing paint or urethane finishing paint or water-based silicon third finishing paint one to two road on the surface, cover into inferior light or light.
CNA2007100707065A 2007-08-06 2007-08-06 Method of producing and painting stone similar paint for flexible flat surface Pending CN101108943A (en)

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277045A (en) * 2011-07-14 2011-12-14 深圳市嘉达节能环保科技有限公司 Waterborne stone-like multicolor coating and preparation method thereof
CN102295869A (en) * 2010-06-25 2011-12-28 苏州美亚美建筑涂料有限公司 Elastic primer
CN102295866A (en) * 2010-06-25 2011-12-28 苏州美亚美建筑涂料有限公司 Acrylic acid latex paint
CN102295865A (en) * 2010-06-25 2011-12-28 苏州美亚美建筑涂料有限公司 Pure acrylic acid elastic primer
CN102295867A (en) * 2010-06-25 2011-12-28 苏州美亚美建筑涂料有限公司 Pure acrylic acid emulsion paint
CN101307198B (en) * 2008-06-23 2012-05-23 张文斌 Method for preparing imitated granite coatings
CN102518271A (en) * 2011-11-30 2012-06-27 宁波华宝石节能建材有限公司 Coating construction method of faux stones
CN102533038A (en) * 2011-12-19 2012-07-04 河南省德嘉丽科技开发有限公司 Natural stone paint
CN102617071A (en) * 2012-03-23 2012-08-01 尚怀兴 High-gloss real stone lacquer and marble simulation lacquer
CN102615034A (en) * 2012-03-27 2012-08-01 东莞大宝化工制品有限公司 Coating method using metal baking paint to achieve imitation marble effect on metal parts
CN101230222B (en) * 2008-02-22 2012-10-31 刘春雨 Title-imitating coating and preparation method thereof
CN101659820B (en) * 2008-08-26 2013-05-08 展辰涂料集团股份有限公司 Casting paint used in foaming polyurethane die
CN103709846A (en) * 2013-12-12 2014-04-09 上海汇丽涂料有限公司 Water-based environmental agate marble coating and preparation and construction methods thereof
CN104250503A (en) * 2014-09-27 2014-12-31 安徽铁创新材料科技有限公司 Environment-friendly ageing-resistant top facing coating
CN104387115A (en) * 2014-10-20 2015-03-04 浙江华特实业集团华特化工有限公司 Simulation method for sand rock
CN104387848A (en) * 2014-11-05 2015-03-04 安徽省七博士化工新材料有限公司 Alkali-resistant natural stone paint and preparation method thereof
CN104559567A (en) * 2014-12-30 2015-04-29 三棵树涂料股份有限公司 Finishing-free stone-like paint and preparation method thereof
CN104804482A (en) * 2015-05-04 2015-07-29 常熟市优德爱涂料有限公司 Water-based coating with natural limestone imitating effect and preparation method of water-based coating
CN110016279A (en) * 2018-10-30 2019-07-16 浙江博星化工涂料有限公司 A kind of enamel effect imitation marble paint
CN110318508A (en) * 2018-03-29 2019-10-11 熊峰 A kind of decoration integrated system of external wall waterproof and its application method
CN115197620A (en) * 2022-07-21 2022-10-18 亚士漆(上海)有限公司 High-coating texture coating and preparation method and application thereof

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101230222B (en) * 2008-02-22 2012-10-31 刘春雨 Title-imitating coating and preparation method thereof
CN101307198B (en) * 2008-06-23 2012-05-23 张文斌 Method for preparing imitated granite coatings
CN101659820B (en) * 2008-08-26 2013-05-08 展辰涂料集团股份有限公司 Casting paint used in foaming polyurethane die
CN102295869A (en) * 2010-06-25 2011-12-28 苏州美亚美建筑涂料有限公司 Elastic primer
CN102295866A (en) * 2010-06-25 2011-12-28 苏州美亚美建筑涂料有限公司 Acrylic acid latex paint
CN102295865A (en) * 2010-06-25 2011-12-28 苏州美亚美建筑涂料有限公司 Pure acrylic acid elastic primer
CN102295867A (en) * 2010-06-25 2011-12-28 苏州美亚美建筑涂料有限公司 Pure acrylic acid emulsion paint
CN102277045A (en) * 2011-07-14 2011-12-14 深圳市嘉达节能环保科技有限公司 Waterborne stone-like multicolor coating and preparation method thereof
CN102518271A (en) * 2011-11-30 2012-06-27 宁波华宝石节能建材有限公司 Coating construction method of faux stones
CN102518271B (en) * 2011-11-30 2014-05-14 宁波华宝石节能建材有限公司 Coating construction method of faux stones
CN102533038A (en) * 2011-12-19 2012-07-04 河南省德嘉丽科技开发有限公司 Natural stone paint
CN102617071A (en) * 2012-03-23 2012-08-01 尚怀兴 High-gloss real stone lacquer and marble simulation lacquer
CN102615034B (en) * 2012-03-27 2014-04-02 东莞大宝化工制品有限公司 Coating method using metal baking paint to achieve imitation marble effect on metal parts
CN102615034A (en) * 2012-03-27 2012-08-01 东莞大宝化工制品有限公司 Coating method using metal baking paint to achieve imitation marble effect on metal parts
CN103709846A (en) * 2013-12-12 2014-04-09 上海汇丽涂料有限公司 Water-based environmental agate marble coating and preparation and construction methods thereof
CN104250503A (en) * 2014-09-27 2014-12-31 安徽铁创新材料科技有限公司 Environment-friendly ageing-resistant top facing coating
CN104387115A (en) * 2014-10-20 2015-03-04 浙江华特实业集团华特化工有限公司 Simulation method for sand rock
CN104387115B (en) * 2014-10-20 2016-03-09 浙江华特实业集团华特化工有限公司 A kind of emulation mode of sandstone plum
CN104387848A (en) * 2014-11-05 2015-03-04 安徽省七博士化工新材料有限公司 Alkali-resistant natural stone paint and preparation method thereof
CN104559567A (en) * 2014-12-30 2015-04-29 三棵树涂料股份有限公司 Finishing-free stone-like paint and preparation method thereof
CN104804482A (en) * 2015-05-04 2015-07-29 常熟市优德爱涂料有限公司 Water-based coating with natural limestone imitating effect and preparation method of water-based coating
CN110318508A (en) * 2018-03-29 2019-10-11 熊峰 A kind of decoration integrated system of external wall waterproof and its application method
CN110016279A (en) * 2018-10-30 2019-07-16 浙江博星化工涂料有限公司 A kind of enamel effect imitation marble paint
CN115197620A (en) * 2022-07-21 2022-10-18 亚士漆(上海)有限公司 High-coating texture coating and preparation method and application thereof
CN115197620B (en) * 2022-07-21 2023-10-20 亚士漆(上海)有限公司 High-coating texture coating and preparation method and application thereof

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