CN110016279A - A kind of enamel effect imitation marble paint - Google Patents

A kind of enamel effect imitation marble paint Download PDF

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Publication number
CN110016279A
CN110016279A CN201811273889.5A CN201811273889A CN110016279A CN 110016279 A CN110016279 A CN 110016279A CN 201811273889 A CN201811273889 A CN 201811273889A CN 110016279 A CN110016279 A CN 110016279A
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China
Prior art keywords
agent
water
imitation marble
enamel
marble paint
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CN201811273889.5A
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Chinese (zh)
Inventor
王君瑞
唐植贤
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Zhejiang Boxing Chemical & Paint Co Ltd
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Zhejiang Boxing Chemical & Paint Co Ltd
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Priority to CN201811273889.5A priority Critical patent/CN110016279A/en
Publication of CN110016279A publication Critical patent/CN110016279A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6295—Polymers of silicium containing compounds having carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/795—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of mixtures of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates with aromatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1668—Vinyl-type polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C08K2003/2272—Ferric oxide (Fe2O3)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of enamel effect imitation marble paints, and complexion is using water nano inorganic transparent iron oxide pigment as colorant；Background color is crosslinking and curing agent by components, hydrophilic modifying TDI, HDI mixed trimer of water-based hydroxyl organosilicon-modified acrylate dispersion.The present invention uses aqueous self-drying cross-linking type white paint for base coat, and background color is using TDI, HDI mixed trimer as cure-crosslinking agent, and hardness is high, and yellowing resistance is good, and gloss (60 °) is up to 95% or more, pencil hardness 3H, hard wear resistant；Complexion decorative pattern uses the aqueous inorganic transparent nano iron oxide pigment of good weatherability, and color bleeding degree is high, naturally true to nature, environmental protection, good weatherability, not fugitive color, high with background color degrees of fusion；The smooth tough and tensile, scratch resistance of composite coating film, water-fast anti-pollution, durability is good, surface-brightening such as mirror, the surface and glossiness for making parian coating of the invention have enamel equally hard, decorative strong, at low cost.

Description

A kind of enamel effect imitation marble paint
Technical field
The present invention relates to a kind of enamel effect imitation marble paints.
Background technique
Marble, which refers to, various colors decorative pattern, and for doing the limestone of building decoration materials, main ingredient is carbon Sour calcium, marmorean title is abounded with derived from it gains the name in Chinese yunnan Dali.It is very beautiful after marble polishing.It is mainly used for Various shape materials, plate are processed into, metope, ground, platform, the column of building are made, are also commonly used for monumental building such as upright stone tablet, tower, carving As etc. material, application range is very extensive, but natural marble is than great, the cost eighteenth of the twenty is expensive, erroneous for installation, and stone of marble It is non-renewable resources, exceedingly exploitation will affect the balance of natural ecology.Imitation marble paint is a kind of imitation natural marble Shell stone patterns are compared with the coating of pattern, and what is existed and widely apply on the market at present is solvent borne imitation marble paint, mainly by people's The processes such as spraying gimmick, the desalt processing of surface effect apply, and major defect is: 1, solvent type imitation marble paint exists It will use a large amount of volatile organic compounds (VOC) in production and work progress, it is harmful to human body and ambient enviroment；2, face is made Colorant used in color patterned is mainly the bad oil-soluble dyes or premetallized dye of weatherability, and durability is bad, easy It fades；3, coating abrasion performance is poor, gloss is low, surface easily scratches.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of enamel effect imitation marble paints.For this purpose, the present invention adopts With following technical scheme:
A kind of enamel effect imitation marble paint, it is characterised in that the complexion of the enamel effect imitation marble paint is with water Property nano inorganic transparent Indium iron series pigment be colorant；Background color is using water-based hydroxyl organosilicon-modified acrylate dispersion as hydroxyl Base component, hydrophilic modifying TDI, HDI mixed trimer are crosslinking and curing agent；The base coat of the coating also contains polyethylene wax liquor Scratch resistance auxiliary agent, moistening flatting agent, rutile type titanium white, hardening anti-wear agent.
Further, water-based hydroxyl organosilicon-modified acrylate dispersion is high using organic-silicon-modified hydroxy acrylate Copolymer emulsion, solid part are 44%~46%.
Further, organic-silicon-modified hydroxy acrylate high polymer is by organic silicon monomer, hydroxy acrylic acid esters list Body, acrylic ester monomer are copolymerized.
Further: the base coat is made of component A and B component, and wherein component A is by water-based hydroxyl organic-silicon-modified third Olefin(e) acid ester high polymer, water, coalescing agent, defoaming agent, R706 rutile type titanium white, hardening anti-wear agent, preservative L600 polyethers Thickener rheology agent composition；B component is TDI, HID mixed trimer；The mass percent of constituent content are as follows:
Further, the complexion paint is by water-based fluorocarbon polymer emulsion, water, water nano inorganic transparent iron oxide Pigment, moistening flatting agent, coalescing agent, propylene-glycol diacetate, defoaming agent, preservative composition；The quality percentage of constituent content Than are as follows:
Further, coalescing agent is alcohol ester 12, two acetic acid acid esters of propylene glycol, dipropylene, propylene glycol monomethyl ether, The combination of one or more of butyl.
Further, it is compound that one or more of BYK024, BYK028, TEGO-815N may be selected in defoaming agent.
Further, Japan's coronate2604 curing agent may be selected in hydrophilic modifying TDI, HDI mixed trimer, Shanghai is One of sincere chemical industry Aquolin268, Italy's OKDS color inhibition curing agent.
Further, one of Japan's VX-S glass powder, Bi Ke BYK323, EFKA3239 etc. may be selected in hardening anti-wear agent Or several combination.
Further, the water nano inorganic transparent iron oxide pigment is generation name, without surprise, Clariant, BASF product The combination of one or more of board.
The present invention uses aqueous self-drying cross-linking type white paint for base coat, and background color is solidification with TDI, HDI mixed trimer Crosslinking agent, hardness are high, and yellowing resistance is good, and gloss (60 °) is up to 95% or more, pencil hardness 3H, hard wear resistant；Complexion decorative pattern Using the aqueous inorganic transparent nano iron oxide pigment of good weatherability, color bleeding degree is high, naturally true to nature, environmental protection, weatherability Good, fugitive color, not high with background color degrees of fusion；The smooth tough and tensile, scratch resistance of composite coating film, water-fast anti-pollution, durability is good, surface Surface and glossiness as bright as a sixpence, that make parian coating of the invention have enamel equally hard, decorative strong, cost It is low.
Specific embodiment:
Enamel effect imitation marble paint provided by the invention is coloring with water nano inorganic transparent iron oxide pigment Agent, decorative pattern color good weatherability, not fugitive color；；Background color is using water-based hydroxyl organosilicon-modified acrylate dispersion as hydroxyl group Part, hydrophilic modifying TDI, HDI mixed trimer are crosslinking and curing agent；It is anti-zoned that the base coat of the coating also contains polyethylene wax liquor Hurt auxiliary agent, moistening flatting agent, rutile type titanium white, hardening anti-wear agent.
Embodiment 1:
Preparation process:
Component A: water is first put into painting cylinder, coalescing agent, defoaming agent, DFX1 preservative are sequentially added under stirring Be uniformly mixed rear lift formula and R706 rutile type titanium white, (6) be added, stir evenly rear high speed dispersion (2500rpm/min) until In fineness plate upper scraping plate without the oily phenomenon that contracts.Then it successively puts into water-based hydroxyl organosilicon-modified acrylate high polymer, use L600 Polyethers thickener rheology agent adjusts viscosity, filters, packaging.
B component: directly B component is added in component A when use and stirs evenly and can construct.
Above-mentioned each material is sequentially added in agitator tank, stirring evenly can (800rpm/min × 15min).
Embodiment 2:
Preparation process:
Component A: water is first put into painting cylinder, coalescing agent, defoaming agent, DFX1 preservative are sequentially added under stirring Be uniformly mixed rear lift formula and R706 rutile type titanium white, (6) be added, stir evenly rear high speed dispersion (2500rpm/min) until In fineness plate upper scraping plate without the oily phenomenon that contracts.Then it successively puts into water-based hydroxyl organosilicon-modified acrylate high polymer, use L600 Polyethers thickener rheology agent adjusts viscosity, filters, packaging.
B component: directly B component is added in component A when use and stirs evenly and can construct.
Above-mentioned each material is sequentially added in agitator tank, stirring evenly can (800rpm/min × 15min).
Embodiment 3:
Preparation process:
Component A: water is first put into painting cylinder, coalescing agent, defoaming agent, DFX1 preservative are sequentially added under stirring Be uniformly mixed rear lift formula and R706 rutile type titanium white, (6) be added, stir evenly rear high speed dispersion (2500rpm/min) until In fineness plate upper scraping plate without the oily phenomenon that contracts.Then it successively puts into water-based hydroxyl organosilicon-modified acrylate high polymer, use L600 Polyethers thickener rheology agent adjusts viscosity, filters, packaging.
B component: directly B component is added in component A when use and stirs evenly and can construct.
Above-mentioned each material is sequentially added in agitator tank, stirring evenly can (800rpm/min × 15min).
Coating performance test experiments:
Note: yellowing resistance is tested with 0 grade of non yellowing, best；3 grades of xanthochromias are serious, worst.
Experiment conclusion: the present invention can form one by aqueous self-drying cross-linking type base coat and the cladding coating of complexion hairline paint The composite coating of the aqueous enamel effect imitation marble effect of kind, the composite coating gloss (60 °) are up to 95% or more, pencil hardness For 3H, hard wear resistant；Color bleeding degree height, good weatherability, naturally true to nature, the smooth tough and tensile, scratch resistance of composite coating film, light Such as mirror, the decorative effect for having enamel the same.

Claims (10)

1. a kind of enamel effect imitation marble paint, it is characterised in that the complexion of the enamel effect imitation marble paint is with aqueous Nano inorganic transparent Indium iron series pigment is colorant,；Background color is using water-based hydroxyl organosilicon-modified acrylate dispersion as hydroxyl Base component, hydrophilic modifying TDI, HDI mixed trimer are crosslinking and curing agent；The base coat of the coating also contains polyethylene wax liquor Scratch resistance auxiliary agent, moistening flatting agent, rutile type titanium white, hardening anti-wear agent.
2. a kind of enamel effect imitation marble paint as described in claim 1, it is characterised in that water-based hydroxyl is organic-silicon-modified Acrylate dispersoid uses organic-silicon-modified hydroxy acrylate polymer emulsion, and solid part is 44%~46%.
3. a kind of enamel effect imitation marble paint as claimed in claim 2, it is characterised in that organic-silicon-modified hydroxy Acid esters high polymer is by organic silicon monomer, and hydroxy acrylic acid esters monomer, acrylic ester monomer are copolymerized.
4. a kind of enamel effect imitation marble paint as described in claim 1, it is characterised in that the base coat by component A and B component composition, wherein component A is by water-based hydroxyl organosilicon-modified acrylate high polymer, water, coalescing agent, defoaming agent, R706 Rutile type titanium white, hardening anti-wear agent, preservative L600 polyethers thickener rheology agent composition；B component is TDI, HID mixing trimerization Body；The mass percent of constituent content are as follows:
5. a kind of enamel effect imitation marble paint as described in claim 1, it is characterised in that the complexion paint is by aqueous Fluorine carbon polymer emulsion, water, water nano inorganic transparent iron oxide pigment, moistening flatting agent, coalescing agent, propylene glycol diethyl Acid esters, defoaming agent, preservative composition；The mass percent of constituent content are as follows:
6. a kind of enamel effect imitation marble paint as described in claim 4 or 5, it is characterised in that coalescing agent is alcohol ester ten Two, two acetic acid acid esters of propylene glycol, the combination of one or more of dipropylene, propylene glycol monomethyl ether, butyl；
Defoaming agent is that one or more of BYK024, BYK028, TEGO-815N are compound；
Moistening flatting agent is the group of one or more of BYK333, BYK346, Tego Wet kL245, Tego Wet kL270 It closes；
7. a kind of enamel effect imitation marble paint as described in claim 1, it is characterised in that hydrophilic modifying TDI, HDI mixing Tripolymer is Japan's coronate2604 curing agent, Shanghai is sincere chemical industry Aquolin268, Italy's OKDS color inhibition curing agent One of.
8. a kind of enamel effect imitation marble paint as described in claim 1, it is characterised in that hardening anti-wear agent is Japan VX- The combination of one or more of S glass powder, Bi Ke BYK323, EFKA3239 etc..
9. a kind of enamel effect imitation marble paint as described in claim 1, it is characterised in that polyethylene wax liquor is Germany bar This husband's WAX 22、 WAX 26、The combination of one or more of WAX 28 etc..
10. a kind of enamel effect imitation marble paint as described in claim 1, it is characterised in that the water nano is inorganic Bright iron oxide pigment is generation name, the combination without one or more of surprise, Clariant, BASF brand.
CN201811273889.5A 2018-10-30 2018-10-30 A kind of enamel effect imitation marble paint Pending CN110016279A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110655819A (en) * 2019-08-21 2020-01-07 广东嘉宝莉科技材料有限公司 Coating method of imitated marble pattern
CN111732879A (en) * 2020-05-28 2020-10-02 广东维拓化工股份有限公司 Antiviral healthy plant water-based enamel-like paint and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1583917A (en) * 2004-05-24 2005-02-23 西北师范大学 Organic silicon modified water double-component polyurethane coating and preparing method thereof
CN101108943A (en) * 2007-08-06 2008-01-23 浙江华特实业集团华特化工有限公司 Method of producing and painting stone similar paint for flexible flat surface
CN102702879A (en) * 2012-06-29 2012-10-03 合肥万博制漆有限公司 Water-based colorful fluorocarbon paint and preparation method thereof
CN102816483A (en) * 2012-03-12 2012-12-12 浙江博星化工涂料有限公司 Novel high-water-whitening-resistance aqueous artificial granite composite coating finishing varnish, and its preparation method
CN108311357A (en) * 2018-01-31 2018-07-24 徐州力泰钢结构有限公司 A kind of simulative marble slab based on metallic plate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1583917A (en) * 2004-05-24 2005-02-23 西北师范大学 Organic silicon modified water double-component polyurethane coating and preparing method thereof
CN101108943A (en) * 2007-08-06 2008-01-23 浙江华特实业集团华特化工有限公司 Method of producing and painting stone similar paint for flexible flat surface
CN102816483A (en) * 2012-03-12 2012-12-12 浙江博星化工涂料有限公司 Novel high-water-whitening-resistance aqueous artificial granite composite coating finishing varnish, and its preparation method
CN102702879A (en) * 2012-06-29 2012-10-03 合肥万博制漆有限公司 Water-based colorful fluorocarbon paint and preparation method thereof
CN108311357A (en) * 2018-01-31 2018-07-24 徐州力泰钢结构有限公司 A kind of simulative marble slab based on metallic plate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
朱棉霞等: "《综合 设计 研究性化学实验》", 31 August 2008 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110655819A (en) * 2019-08-21 2020-01-07 广东嘉宝莉科技材料有限公司 Coating method of imitated marble pattern
CN110655819B (en) * 2019-08-21 2021-11-26 广东嘉宝莉科技材料有限公司 Coating method of imitated marble pattern
CN111732879A (en) * 2020-05-28 2020-10-02 广东维拓化工股份有限公司 Antiviral healthy plant water-based enamel-like paint and preparation method thereof

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