CN101065408B - 浆料相聚合法 - Google Patents

浆料相聚合法 Download PDF

Info

Publication number
CN101065408B
CN101065408B CN2005800406921A CN200580040692A CN101065408B CN 101065408 B CN101065408 B CN 101065408B CN 2005800406921 A CN2005800406921 A CN 2005800406921A CN 200580040692 A CN200580040692 A CN 200580040692A CN 101065408 B CN101065408 B CN 101065408B
Authority
CN
China
Prior art keywords
reactor
loop
froude number
average
loop reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN2005800406921A
Other languages
English (en)
Chinese (zh)
Other versions
CN101065408A (zh
Inventor
S·K·李
D·马里萨尔
B·R·沃尔沃思
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Manufacturing Belgium NV
Original Assignee
Ineos Manufacturing Belgium NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=33561437&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN101065408(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ineos Manufacturing Belgium NV filed Critical Ineos Manufacturing Belgium NV
Publication of CN101065408A publication Critical patent/CN101065408A/zh
Application granted granted Critical
Publication of CN101065408B publication Critical patent/CN101065408B/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2435—Loop-type reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00243—Mathematical modelling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00247—Fouling of the reactor or the process equipment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/918—Polymerization reactors for addition polymer preparation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Treatment Of Sludge (AREA)
CN2005800406921A 2004-11-26 2005-11-22 浆料相聚合法 Expired - Lifetime CN101065408B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0426057.6A GB0426057D0 (en) 2004-11-26 2004-11-26 Chemical process
GB0426057.6 2004-11-26
PCT/GB2005/004487 WO2006056763A1 (en) 2004-11-26 2005-11-22 Slurry phase polymerisation process

Publications (2)

Publication Number Publication Date
CN101065408A CN101065408A (zh) 2007-10-31
CN101065408B true CN101065408B (zh) 2011-07-27

Family

ID=33561437

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2005800406921A Expired - Lifetime CN101065408B (zh) 2004-11-26 2005-11-22 浆料相聚合法

Country Status (20)

Country Link
US (2) US7572866B2 (enExample)
EP (1) EP1817350B2 (enExample)
JP (1) JP5530066B2 (enExample)
KR (1) KR101245399B1 (enExample)
CN (1) CN101065408B (enExample)
AR (1) AR055693A1 (enExample)
AT (1) ATE423798T1 (enExample)
AU (1) AU2005308591B2 (enExample)
BR (1) BRPI0518667B1 (enExample)
CA (1) CA2589180C (enExample)
DE (1) DE602005012984D1 (enExample)
EA (1) EA011774B1 (enExample)
ES (1) ES2319449T5 (enExample)
GB (1) GB0426057D0 (enExample)
MX (1) MX2007006297A (enExample)
MY (1) MY138421A (enExample)
PL (1) PL1817350T3 (enExample)
TW (1) TWI392687B (enExample)
WO (1) WO2006056763A1 (enExample)
ZA (1) ZA200703922B (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0426058D0 (en) 2004-11-26 2004-12-29 Solvay Chemical process
GB0426059D0 (en) * 2004-11-26 2004-12-29 Solvay Chemical process
GB0426057D0 (en) * 2004-11-26 2004-12-29 Solvay Chemical process
BRPI0722416A2 (pt) 2006-05-26 2012-12-25 Ineos Mfg Belgium Nv processo de polimerizaÇço de fase de pasta
SG138525A1 (en) * 2006-06-13 2008-01-28 Sumitomo Chemical Co Method for measuring concentration of propylene polymer slurry, and process for producing propylene polymer
EP2033976A1 (en) 2007-09-03 2009-03-11 INEOS Manufacturing Belgium NV Slurry phase polymerisation process
US8871886B1 (en) 2013-05-03 2014-10-28 Chevron Phillips Chemical Company Lp Polymerization product pressures in olefin polymerization
DE202010018395U1 (de) 2010-03-24 2016-05-11 Antacor Ltd. Vorrichtung zur Behandlung von Fest-Flüssig-Gemischen
WO2012013807A1 (en) * 2010-07-30 2012-02-02 Total Petrochemicals Research Feluy Method for producing polyethylene
RU2607086C2 (ru) * 2011-06-24 2017-01-10 Инеос Юроуп Аг Суспензионный способ полимеризации
US8597582B2 (en) 2011-06-30 2013-12-03 Chevron Phillips Chemical Company Lp Flashline heater system and method
WO2013039619A1 (en) 2011-09-16 2013-03-21 Exxonmobil Chemical Patents Inc. Loop reactor configuration for high capacity
WO2013156491A1 (en) 2012-04-19 2013-10-24 Ineos Europe Ag Catalyst for the polymerisation of olefins, process for its production and use
US8921498B2 (en) 2012-10-31 2014-12-30 Chevron Phillips Chemical Company Lp Pressure management for slurry polymerization
US9238698B2 (en) 2012-10-31 2016-01-19 Chevron Phillips Chemical Company Lp Pressure management for slurry polymerization
US9096694B1 (en) 2014-01-20 2015-08-04 Chevron Phillips Chemical Company Lp Monomer/diluent recovery
JP6932190B2 (ja) * 2016-11-10 2021-09-08 バーゼル・ポリオレフィン・ゲーエムベーハー 上昇管ユニット及び下降管を含む気相反応器におけるオレフィン重合反応方法
CN120380029A (zh) 2022-12-20 2025-07-25 英尼奥斯欧洲股份公司 方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1208046A (zh) * 1997-07-15 1999-02-17 菲利浦石油公司 高固含量淤浆聚合
WO2005028097A1 (en) * 2003-09-24 2005-03-31 Basell Polyolefine Gmbh Loop reactor with varying diameter for olefin polymerization
CN1856357A (zh) * 2003-09-24 2006-11-01 巴塞尔聚烯烃有限公司 用于烯烃聚合反应的具有变直径的回路反应器

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3172737A (en) 1965-03-09 Coolant
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3257362A (en) 1960-11-21 1966-06-21 Phillips Petroleum Co Control of olefin polymerization reactions
US3203766A (en) 1961-07-06 1965-08-31 Phillips Petroleum Co Apparatus for the recovery of solids from pressure vessels
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3293000A (en) 1962-10-05 1966-12-20 Phillips Petroleum Co Withdrawal of solids from a flowing stream comprising a slurry of same
US3324093A (en) 1963-10-21 1967-06-06 Phillips Petroleum Co Loop reactor
NL181435B (nl) † 1973-10-17 1900-01-01 Montedison Spa Werkwijze voor polymerisatie onder druk in een buisvormige reactor.
US4121029A (en) 1976-12-06 1978-10-17 Phillips Petroleum Company Polyolefin reactor system
US4613484A (en) * 1984-11-30 1986-09-23 Phillips Petroleum Company Loop reactor settling leg system for separation of solid polymers and liquid diluent
DE3612376A1 (de) 1986-04-12 1987-10-15 Basf Ag Verfahren zum herstellen kleinteiliger homo- und copolymerisate des ethens unter verwendung eines fluessigen alkans als reaktionsmedium
CA2023745A1 (en) 1989-11-27 1991-05-28 Kelly E. Tormaschy Control of polymerization reaction
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
US5484862A (en) * 1995-03-10 1996-01-16 The Dow Chemical Company Liquid phase powder bed syndiotactic vinylaromatic polymerization
US6815511B2 (en) 1997-07-15 2004-11-09 Chevron Phillips Chemical Company, Lp Continuous withdrawal from high solids slurry polymerization
US7033545B2 (en) 1997-07-15 2006-04-25 Chevon Phillips Chemical Company, Lp Slurry polymerization reactor having large length/diameter ratio
US20040136881A1 (en) 1997-07-15 2004-07-15 Verser Donald W. Separation of polymer particles and vaporized diluent in a cyclone
US20020111441A1 (en) 1998-03-20 2002-08-15 Kendrick James Austin Continuous slurry polymerization volatile removal
US7268194B2 (en) 1998-03-20 2007-09-11 Exxonmobil Chemical Patents Inc. Continuous slurry polymerization process and apparatus
JP2002506718A (ja) 1998-03-20 2002-03-05 エクソンモービル・ケミカル・パテンツ・インク 連続的なスラリー重合の揮発成分の除去
KR100531628B1 (ko) 1998-03-20 2005-11-29 엑손모빌 케미칼 패턴츠 인코포레이티드 연속적인 슬러리 중합반응의 휘발물질 제거
US6281300B1 (en) 1998-03-20 2001-08-28 Exxon Chemical Patents, Inc. Continuous slurry polymerization volatile removal
AU755016B2 (en) 1998-05-18 2002-11-28 Chevron Phillips Chemical Company Lp Continuous slurry polymerization volatile removal
GB9822123D0 (en) * 1998-10-09 1998-12-02 Borealis As Catalyst
WO2001005842A1 (en) * 1999-07-15 2001-01-25 Phillips Petroleum Company Slotted slurry take off
US6420497B1 (en) 1999-12-03 2002-07-16 Phillips Petroleum Company Solids concentration in slurry polymerization
KR100349071B1 (ko) 2000-02-02 2002-08-14 삼성종합화학주식회사 생성물 순환 방식을 이용한 신디오탁틱 스티렌계 중합체의제조방법
EP1195388A1 (en) 2000-10-04 2002-04-10 ATOFINA Research Process for producing bimodal polyethylene resins
ES2348659T3 (es) 2001-11-06 2010-12-10 Chevron Phillips Chemical Company Lp Eliminacion continua de suspension de polimerizacion.
EP2263793B1 (en) * 2002-02-19 2018-04-11 Chevron Phillips Chemical Company Lp Process for loop polymerisation reactor
US6924340B2 (en) 2002-04-04 2005-08-02 Equistar Chemicals L.P. Process for removal of intermediate hydrogen from cascaded polyolefin slurry reactors
US7015289B2 (en) 2002-09-13 2006-03-21 Chevron Phillips Chemical Company, Lp Process and apparatus for reducing take-off valve plugging in a polymerization process
DK1556415T3 (da) 2002-09-13 2010-03-15 Chevron Phillips Chemical Co Sløjfereaktorapparat og polymerisationsfremgangsmåder med flere tilledningspunkter for olefiner og katalysatorer
WO2004026455A2 (en) 2002-09-16 2004-04-01 Chevron Phillips Chemical Company Lp Catalyst slurry feeding assembly for a polymerization reactor
AU2003272521A1 (en) 2002-09-16 2004-04-30 Chevron Phillips Chemical Company Lp Process and system for removing heavies from diluent recycled to a slurry polymerization reactor
CA2498766C (en) 2002-09-17 2009-11-24 Chevron Phillips Chemical Company Lp Improved pumping apparatus and process for slurry polymerization in loop reactors
DK1713842T3 (da) * 2004-02-13 2011-01-24 Total Petrochemicals Res Feluy Fremgangsmåde til forbedring af copolymeriseringen af ethylen og en olefincomonomer i en polymeriseringsloopreaktor
US20050272891A1 (en) * 2004-02-13 2005-12-08 Atofina Research S.A. Double loop technology
EP1611948A1 (en) 2004-07-01 2006-01-04 Total Petrochemicals Research Feluy Polymerization reactors with a by-pass line
GB0426057D0 (en) * 2004-11-26 2004-12-29 Solvay Chemical process
US7547750B2 (en) 2005-10-05 2009-06-16 Chevron Phillips Chemical Company Lp Apparatus and method for removing polymer solids from slurry loop reactor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1208046A (zh) * 1997-07-15 1999-02-17 菲利浦石油公司 高固含量淤浆聚合
WO2005028097A1 (en) * 2003-09-24 2005-03-31 Basell Polyolefine Gmbh Loop reactor with varying diameter for olefin polymerization
CN1856357A (zh) * 2003-09-24 2006-11-01 巴塞尔聚烯烃有限公司 用于烯烃聚合反应的具有变直径的回路反应器

Also Published As

Publication number Publication date
US7820116B2 (en) 2010-10-26
US7572866B2 (en) 2009-08-11
EP1817350A1 (en) 2007-08-15
US20080262171A1 (en) 2008-10-23
EA200700980A1 (ru) 2007-12-28
AR055693A1 (es) 2007-09-05
ES2319449T3 (es) 2009-05-07
JP2008521961A (ja) 2008-06-26
AU2005308591B2 (en) 2011-06-09
MX2007006297A (es) 2007-07-11
US20090252657A1 (en) 2009-10-08
EP1817350B1 (en) 2009-02-25
CN101065408A (zh) 2007-10-31
KR101245399B1 (ko) 2013-03-19
ZA200703922B (en) 2008-10-29
DE602005012984D1 (de) 2009-04-09
GB0426057D0 (en) 2004-12-29
ATE423798T1 (de) 2009-03-15
WO2006056763A1 (en) 2006-06-01
EA011774B1 (ru) 2009-06-30
BRPI0518667B1 (pt) 2017-03-21
BRPI0518667A2 (pt) 2008-12-02
TW200626620A (en) 2006-08-01
PL1817350T3 (pl) 2009-06-30
AU2005308591A1 (en) 2006-06-01
MY138421A (en) 2009-06-30
TWI392687B (zh) 2013-04-11
CA2589180A1 (en) 2006-06-01
EP1817350B2 (en) 2015-11-25
CA2589180C (en) 2013-07-23
JP5530066B2 (ja) 2014-06-25
KR20070090164A (ko) 2007-09-05
ES2319449T5 (es) 2016-01-22

Similar Documents

Publication Publication Date Title
US7820116B2 (en) Slurry phase polymerisation process
US9567408B2 (en) Slurry phase polymerisation process
CN101857653B (zh) 浆料相聚合法
CN101495224B (zh) 用于聚合的环流型反应器

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20110727