CN101058701A - Water soluble adhesive - Google Patents
Water soluble adhesive Download PDFInfo
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- CN101058701A CN101058701A CN 200710069130 CN200710069130A CN101058701A CN 101058701 A CN101058701 A CN 101058701A CN 200710069130 CN200710069130 CN 200710069130 CN 200710069130 A CN200710069130 A CN 200710069130A CN 101058701 A CN101058701 A CN 101058701A
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- water soluble
- soluble adhesive
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- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a water-soluble adhesive, which comprises the following parts: 30-65% pregelatinized starch, 10-20% 2488 polyvinyl alcohol, 13-37% cellulose and its derivant, 0-20% redispersion emulsion powder, 0. 15-0. 5% thickener and 0. 3-0. 8% high-activity zinc oxide, wherein each component is stirred evenly under the drying condition to form the product; the grain size of pregelatinized starch is 20-40 or 80-100 order, which can be allocated into gel powder to form common glue with 6% water after stirring 30min or interior-exterior wall putty powder adhesive after blending diflying powder or cement with weight at 0. 2: 10 directly.
Description
Technical field
The present invention relates to a kind of chemical bonding agent class, especially a kind of water soluble adhesive.
Background technology
Along with expanding economy and growth in the living standard, people more and more pay attention to the quality and the class of house finishing.Chemical bonding agent continues desirable with its bonding strength height, good stability, used raw material, working life is long and particularly building materials and building trade are especially decorated and decorateed engineering and adopt by industry.For example body of wall finishing aspect generally adopts dry powder to mix 107 or 801 glue; Putty powder; Add ripe rubber powder and other caking agent for building of suitable 107 glue.Though these materials have satisfied certain requirement of material of construction, certain mildew-resistant, moisture-proof role have been played, but the integral adhesive intensity difference of glue, putty ftractures easily, comes off, and water retention property is relatively poor, and too high causing again of easy peeling, foaming, viscosity is difficult for constructing during use, and complex process, cost are higher, particularly contain a large amount of objectionable impuritiess such as formaldehyde, not only bigger to human body harm, and also environmental pollution more can not be despised.
Summary of the invention
The objective of the invention is to avoid the defective of prior art and provide that a kind of high viscosity, production cost are low, compliance with environmental protection requirements, widely used water soluble adhesive.
Purpose of the present invention is achieved through the following technical solutions:
A kind of water soluble adhesive is characterized in that the weight percent of described adhesive material component is:
Pre-gelatinization tapioca (flour) 30～65%
2488 polyvinyl alcohol 10～20%
Mierocrystalline cellulose and derivative 13～37% thereof
Redispersion latex powder 0～20%
Thickening material 0.15～0.5%
High-active zinc oxide 0.3～0.8%
By component do to mix stir product.
The particle diameter of described pre-gelatinization tapioca (flour) is 20～40 orders, is made into aqueous solution glue, or particle diameter is that 80～100 orders are made into powder.
The particle diameter of described 2488 polyvinyl alcohol is 100～120 orders.
Described Mierocrystalline cellulose and derivative thereof are that wood fibre or carboxymethyl cellulose or hydroxyl two ylmethyl Mierocrystalline celluloses or methylcellulose gum are at least a.
The staple length of described wood fibre is 200 μ m～1000 μ m.
Described carboxymethyl cellulose particle diameter is 100～120 orders, and viscosity is 800～1200MPaS.
The particle diameter of described Vltra tears, methylcellulose gum is 100～120 orders, and viscosity is 60000～200000MPaS.
The particle diameter of described redispersion latex powder is 100～120 orders, and viscosity is 5～10PaS.
Described thickening material is a polyacrylamide, and anionic, molecular weight are 1200～2,000 ten thousand, or polyoxyethylene, and molecular weight is 100～1,000 ten thousand.
Described high-active zinc oxide granularity is 10～45 μ m.
Compared with prior art, the present invention is except having high adhesion, strong adhesion, product stability is good, resistance to cleavage is good, outside the advantage of acid and alkali-resistance, also have favorable environment protection energy and antimildew and antibacterial performance simultaneously, do not contain any benzene, formaldehyde etc. are to people's objectionable impurities, production cost is low, can be widely used in building inside and outside wall putty, building coating, sand-cement slurry, wall heat insulation material, waterproof building material, dry powder paint, fields such as paper plate bonding, can replace polyvinyl alcohol glue, sodium silicate, ripe rubber powder etc., because environmental protection safe in utilization, so its market outlook are boundless, be the renewal product of traditional architecture with glue.
Embodiment
Water soluble adhesive is formed the tackiness agent rubber powder by pre-gelatinization tapioca (flour), 2488 polyvinyl alcohol, ether of cellulose, redispersion latex powder, thickening material, high-active zinc oxide.The weight percent of each component is: pre-gelatinization tapioca (flour) 30～65%, 2488 polyvinyl alcohol 10～20%, Mierocrystalline cellulose and derivative 13～37% thereof, redispersion latex powder 0～20%, thickening material 0.15～0.5%, high-active zinc oxide 0.3～0.8%, doing mixed stirring by component is the cost product.Pre-gelatinization tapioca (flour) in prescription is white powder or small-particle, plays bonding, thickening power; 2488 polyvinyl alcohol are white powder, and cementability is strong, the film forming piece, and weathering resistance is good, stable performance; Mierocrystalline cellulose and derivative thereof are white powder or velvet-like slightly, play thickening, film forming, cracking resistance, anti-layering, improve the viscosity effect; The redispersion latex powder is white free flowing powder, and its pliable and tough resistance to compression, cracking resistance, wear-resistant, bonding water retention capacity are strong; Thickening material is polyacrylamide or polyoxyethylene, and white powder plays thickening, levelling effect, promotes construction; High-active zinc oxide is the micro-yellow powder shape, plays mildew-resistant, anticorrosion, enhancement.
According to the particle diameter difference of the pre-gelatinization tapioca (flour) in the set of dispense ratio, can be made into different glue or rubber powder during use.When select pre-gelatinization tapioca (flour) particle diameter be 20～40 orders be made into this product rubber powder the time, can be made into 6% the aqueous solution (i.e. 6 parts of these products, 94 parts of water), stirs after 30 minutes water soluble glue, can be by the pure glue use of common polythene; When select pre-gelatinization tapioca (flour) particle diameter be 80～100 orders be made into this product rubber powder the time, can directly mix with dry powder or cement, add water after mixing by 0.2: 10 (i.e. 0.2 part of this product, 10 parts of dry powders or cement) then and stir promptly wall putty in batch, also can be used as the tackiness agent of inner, external wall putty powder.
Embodiment 1: the special-purpose powder glue of preparation 60kg interior wall
A, pre-gelatinization tapioca (flour) 36kg
B, 2488 polyvinyl alcohol 6kg
D, redispersion latex powder 0kg
E, thickening material (polyacrylamide) 0.3kg
F, high-active zinc oxide 0.2kg
Embodiment 2: exterior wall dual-purpose powder glue in the preparation 60kg
A, pre-gelatinization tapioca (flour) 34kg
B, 2488 polyvinyl alcohol 10kg
C, Mierocrystalline cellulose and derivative thereof-Vltra tears 8kg
D, redispersion latex powder 7.5kg
E, thickening material (polyacrylamide) 0.15kg
F, high-active zinc oxide 0.35kg
Embodiment 3: the special-purpose powder glue of preparation 60kg exterior wall
A, pre-gelatinization tapioca (flour) 20kg
B, 2488 polyvinyl alcohol 10kg
D, redispersion latex powder 7.5kg
E, thickening material (polyacrylamide) 0.15kg
F, high-active zinc oxide 0.35kg
Embodiment 4: the multi-functional powder glue of preparation 80kg
A, pre-gelatinization tapioca (flour) 25kg
B, 2488 polyvinyl alcohol 15kg
D, redispersion latex powder 14.5kg
E, thickening material (polyacrylamide) 0.15kg
F, high-active zinc oxide 0.35kg
Prepared product detects through Ningbo City's building material product quality testing station, and every performance index are as shown in table 1:
Table 1
| Sequence number | Test item | Technical standard order (no aldehyde type) | The result | Conclusion |
| 1 | Bonding strength, Mpa | ≥0.5 | 0.5 | Qualified |
| 2 | Low-temperature stability (0 ℃, 24h) | Return to flow state under the room temperature | By | Qualified |
| 3 | Free formaldehyde, g/kg | ≤0.1 | Do not detect | Qualified |
| 4 | Benzene, g/kg | ≤0.2 | Do not detect | Qualified |
| 5 | Toluene+dimethylbenzene, g/kg | ≤10 | Do not detect | Qualified |
| 6 | Total volatile organism g/L | ≤50 | 12 | Qualified |
Claims (10)
1, a kind of water soluble adhesive is characterized in that the weight percent of described adhesive material component is:
Pre-gelatinization tapioca (flour) 30～65%
2488 polyvinyl alcohol 10～20%
Mierocrystalline cellulose and derivative 13～37% thereof
Redispersion latex powder 0～20%
Thickening material 0.15～0.5%
High-active zinc oxide 0.3～0.8%
By component do to mix stir product.
2, water soluble adhesive according to claim 1 is characterized in that the particle diameter of described pre-gelatinization tapioca (flour) is 20～40 orders, is made into aqueous solution glue, or particle diameter is that 80～100 orders are made into powder.
3, water soluble adhesive according to claim 1, the particle diameter that it is characterized in that described 2488 polyvinyl alcohol is 100～120 orders.
4, water soluble adhesive according to claim 1 is characterized in that described Mierocrystalline cellulose and derivative thereof are that wood fibre or carboxymethyl cellulose or hydroxyl two ylmethyl Mierocrystalline celluloses or methylcellulose gum are at least a.
5, water soluble adhesive according to claim 4, the staple length that it is characterized in that described wood fibre are 200 μ m～1000 μ m.
6, water soluble adhesive according to claim 4 is characterized in that described carboxymethyl cellulose particle diameter is 100～120 orders, and viscosity is 800～1200MPaS.
7, water soluble adhesive according to claim 4, the particle diameter that it is characterized in that described Vltra tears, methylcellulose gum is 100～120 orders, viscosity is 60000～200000MPaS.
8, water soluble adhesive according to claim 1, the particle diameter that it is characterized in that described redispersion latex powder is 100～120 orders, viscosity is 5～10PaS.
9, water soluble adhesive according to claim 1 is characterized in that described thickening material is a polyacrylamide, and anionic, molecular weight are 1200～2,000 ten thousand, or polyoxyethylene, and molecular weight is 100～1,000 ten thousand.
10, water soluble adhesive according to claim 1 is characterized in that described high-active zinc oxide granularity is 10～45 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710069130A CN101058701B (en) | 2007-05-30 | 2007-05-30 | Water soluble adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710069130A CN101058701B (en) | 2007-05-30 | 2007-05-30 | Water soluble adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101058701A true CN101058701A (en) | 2007-10-24 |
| CN101058701B CN101058701B (en) | 2010-05-26 |
Family
ID=38865009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710069130A Expired - Fee Related CN101058701B (en) | 2007-05-30 | 2007-05-30 | Water soluble adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101058701B (en) |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629058B (en) * | 2009-08-25 | 2011-06-08 | 江阴市北国新型建筑材料厂 | Solid rubber powder for man-made boards |
| CN102604001A (en) * | 2012-04-01 | 2012-07-25 | 天津市职业大学 | Preparation method of organosilicon modified oxidized starch antibacterial paint |
| CN102618187A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | Cold water fast dissolving rubber powder for buildings |
| CN102618191A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | High-polymer instant-dissolving environment-friendly binder powder |
| CN102877360A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| CN101580359B (en) * | 2009-06-18 | 2013-01-16 | 江阴市北国新型建筑材料厂 | Rubber power for building |
| CN102964091A (en) * | 2012-11-05 | 2013-03-13 | 成都新柯力化工科技有限公司 | Porous granular instant building glue powder and preparation method thereof |
| CN103555225A (en) * | 2013-10-11 | 2014-02-05 | 湖州光博生物科技有限公司 | Preparation method for silver ion anti-bacterial glue |
| CN103555036A (en) * | 2013-10-11 | 2014-02-05 | 湖州光博生物科技有限公司 | Silver ion anti-bacterial glue and preparation method thereof |
| CN103788889A (en) * | 2014-02-21 | 2014-05-14 | 武汉优邦新材料化工有限公司 | Putty adhesive for plant modified polymerization and preparation method thereof |
| CN104228479A (en) * | 2014-08-16 | 2014-12-24 | 中山艺展装饰工程有限公司 | Self-maintenance leak repairing honeycomb type automobile tire |
| CN105110761A (en) * | 2015-09-10 | 2015-12-02 | 吉林大学 | Environment-friendly diatom ooze composite and preparation method thereof |
| CN105368386A (en) * | 2015-11-18 | 2016-03-02 | 广德县永彬竹木工艺品厂 | Biomass-based bamboo wood processing adhesive and preparation process thereof |
| CN105623165A (en) * | 2015-12-24 | 2016-06-01 | 陕西省万安药业有限公司 | Antibacterial silver ion reagent for gynecological medical mat and preparation method of antibacterial silver ion reagent |
| CN107216829A (en) * | 2017-06-14 | 2017-09-29 | 安徽友捷包装材料有限公司 | A kind of water-soluble building powder glue formula |
| CN107353873A (en) * | 2017-08-23 | 2017-11-17 | 四川楼雕建材贸易有限公司 | Ceramic tile bonded structure glue composition and preparation method thereof |
| CN107555889A (en) * | 2017-07-24 | 2018-01-09 | 浙江阿斯克建材科技股份有限公司 | A kind of binding agent for pearlite thermal insulation product and preparation method thereof |
| CN108314362A (en) * | 2018-05-11 | 2018-07-24 | 浙江金宸建设有限公司 | A kind of building construction thermal insulation material |
| CN108641458A (en) * | 2018-05-24 | 2018-10-12 | 薛紫璇 | A kind of plank is squeegeeed with rubber powder and its application |
| CN109468094A (en) * | 2018-11-23 | 2019-03-15 | 福建闽华建材科技发展有限公司 | Multifunctional building adhesive compounding and preparation |
| CN110055805A (en) * | 2019-03-08 | 2019-07-26 | 浙江景兴纸业股份有限公司 | A kind of production method of the double-deck solvable tissue of pure wood pulp |
| CN112592665A (en) * | 2020-12-31 | 2021-04-02 | 常德环创力达环保科技有限公司 | Interior and exterior wall putty interface adhesive and preparation method thereof |
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| CN1435461A (en) * | 2002-02-01 | 2003-08-13 | 张庆华 | Elastic emulsion adhesive |
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| CN101580359B (en) * | 2009-06-18 | 2013-01-16 | 江阴市北国新型建筑材料厂 | Rubber power for building |
| CN101629058B (en) * | 2009-08-25 | 2011-06-08 | 江阴市北国新型建筑材料厂 | Solid rubber powder for man-made boards |
| CN102618187A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | Cold water fast dissolving rubber powder for buildings |
| CN102618191A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | High-polymer instant-dissolving environment-friendly binder powder |
| CN102604001A (en) * | 2012-04-01 | 2012-07-25 | 天津市职业大学 | Preparation method of organosilicon modified oxidized starch antibacterial paint |
| CN102877360B (en) * | 2012-09-05 | 2015-02-25 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| CN102877360A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| CN102964091A (en) * | 2012-11-05 | 2013-03-13 | 成都新柯力化工科技有限公司 | Porous granular instant building glue powder and preparation method thereof |
| CN102964091B (en) * | 2012-11-05 | 2014-08-13 | 成都新柯力化工科技有限公司 | Porous granular instant building glue powder and preparation method thereof |
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| CN103555036A (en) * | 2013-10-11 | 2014-02-05 | 湖州光博生物科技有限公司 | Silver ion anti-bacterial glue and preparation method thereof |
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| CN103788889B (en) * | 2014-02-21 | 2016-06-08 | 武汉优邦新材料化工有限公司 | A kind of plant modified polymer putty adhesive and preparation method thereof |
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| CN105368386A (en) * | 2015-11-18 | 2016-03-02 | 广德县永彬竹木工艺品厂 | Biomass-based bamboo wood processing adhesive and preparation process thereof |
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| CN107353873A (en) * | 2017-08-23 | 2017-11-17 | 四川楼雕建材贸易有限公司 | Ceramic tile bonded structure glue composition and preparation method thereof |
| CN108314362A (en) * | 2018-05-11 | 2018-07-24 | 浙江金宸建设有限公司 | A kind of building construction thermal insulation material |
| CN108641458A (en) * | 2018-05-24 | 2018-10-12 | 薛紫璇 | A kind of plank is squeegeeed with rubber powder and its application |
| CN109468094A (en) * | 2018-11-23 | 2019-03-15 | 福建闽华建材科技发展有限公司 | Multifunctional building adhesive compounding and preparation |
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| CN101058701B (en) | 2010-05-26 |
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