CN1042557A - Exterior wall paint of modified acrylic ester resin - Google Patents
Exterior wall paint of modified acrylic ester resin Download PDFInfo
- Publication number
- CN1042557A CN1042557A CN 88107705 CN88107705A CN1042557A CN 1042557 A CN1042557 A CN 1042557A CN 88107705 CN88107705 CN 88107705 CN 88107705 A CN88107705 A CN 88107705A CN 1042557 A CN1042557 A CN 1042557A
- Authority
- CN
- China
- Prior art keywords
- coating
- modified
- acrylic ester
- resin emulsion
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
Exterior Wall paint of modified acrylic ester resin, it belongs to a kind of resene coating.This coating is with the polyvinyl acetal thing vinylformic acid or acrylate resin modified product to be substituted general acrylate resin emulsion preparation, in dark coating, also be added with the dewatered sludge of industrial composite wastewater, advantages such as so this coating possess hydrophilic property is good, clinging power strong, good film-forming property, strong coloring force, good weatherability, so this coating can be not absolutely dry as yet at metope and the condition more than 3 ℃ under construct, the coating longevity is long, not easy to change and come off.
Description
The present invention relates to coating, relate in particular to the coating of polyacrylate(s).
In the past, the coating of domestic employing add binding agent such as Lake powder, dextrin or glue mostly with powders such as lime, Da Bai and pigment formulated; Have, then directly use phenolic resin coating and alkyd varnish; Acrylic acid or the like and acrylic resin coating are just to introduce in recent years and begin widely to use.
Above-mentioned exterior coating and metope bonding force by the powder adding additives is poor, easily dry linting or fall in flakes.Alkyd paint and phenolic resin coating have short run effect preferably, easily variable color, be full of cracks after exposing to the sun and rain for a long time, curl even drop in flakes, so nonideal exterior coating.Acrylic acid series and acrylic ester resin emulsion exterior coating just widely adopt in recent ten years; As exterior coating, it has stronger sticking power and weather resisteant preferably, is generally 3～5 years but its exterior wall is coated with the life-span of face, and is still not really desirable.Generally speaking, all there is the shortcoming that coating is peeled off easily, work-ing life is short in present exterior coating, and should not have to construct under the absolutely dry condition with metope in the winter time.
The present invention is intended to improve the structure of acrylic acid series and acrylic ester resin emulsion, provides a kind of strong adhesion, long service life, weather resisteant good, can just do modified acroleic acid system and the acrylic ester exterior wall paint that construct under the condition at metope.
The present invention realizes above-mentioned purpose like this:
Exterior coating of the present invention be with degree of acetalization be 15～45% polyvinyl acetal thing solution or and hydroxylated cellulose with by vinylformic acid or certain acrylate monomer and vinylbenzene, divinyl, iso-butylene, vinyl cyanide etc. contain that vinylformic acid that 1～5 kind of monomer copolymerization of vinyl forms or acrylic ester resin emulsion mix and the modified product that produces physical crosslinking substitutes that present acrylic acid series or acrylic ester resin emulsion prepare, and this coating is by water, ultramarine, bubble flower alkali, light alkali, talcum powder, titanium white, Tai-Ace S 150, polyvinyl acetal thing solution, methyl hydroxyl or hydroxy ethyl fiber cellulose solution, defoamer, modified acroleic acid or modification acrylate are resin emulsion, and colorant is formulated.So this coating has good hydrophilicity, cohesiveness, film-forming properties, weather resisteant, frost resistance, can be in metope south not absolutely dry and be higher than under 3 ℃ the condition and construct.
This exterior Wall paint of modified acrylic ester resin basic recipe, be divided into white and time two kinds of basic recipes of white according to desiring to join the coating color and luster depth, light-coloured coating adds required pigment preparation by whitewash, and then available time white of dark coating or whitewash add pigment and be made into.
White exterior coating basic recipe
1. water 19～23%
2. ultramarine 0.01～0.02%
3. bubble is spent alkali (thickening material) 1.9～2.2%
6. titanium white (rutile-type) 2.7～3.3%
7. Tai-Ace S 150 (sterilant) 0.01～0.05%
8. polyvinyl acetal thing solution (9 ± 1%) 13～18%
9. methyl hydroxyl or hydroxy ethyl fiber cellulose solution (2%) 9～11%
10. defoamer (7010 or 680) 0.05～0.07%
⑾ modified acrylate resin emulsion (solid content 12.6～16.5%)
7～10%
The inferior whitewash basic recipe that adds dewatered sludge:
1. water 18～22%
2. ultramarine 0.01～0.03%
3. bubble is spent alkali (thickening material) 1.9～2.2%
6. titanium white (rutile-type) 3～4.2%
7. Tai-Ace S 150 (sterilant) 0.05～0.10%
8. polyvinyl acetal thing solution (9 ± 1%) 13～18%
9. methyl hydroxyl or hydroxy ethyl fiber cellulose solution (2%) 9～11%
10. dewatered sludge (water content 70～78%) 6～9%
⑾ defoamer 0.05～0.07%
⑿ modified acrylate resin emulsion (solid content 12.6～16.6%)
8～11%
This coating adds material by the preface of filling a prescription successively and makes through grinding under normal temperature and pressure and agitation condition.
Be levelling property, water-repellancy, preservative property, the ageing resistance of improving coating, can in coating, add about 0.5% propylene glycol, about 0.5% zellon, about 0.1% Red copper oxide, about 0.5% concentration respectively and be 70% OP-10 or OP-15 solution.
Other coating of all kinds adds pigment and obtains through high speed dispersion in above-mentioned white or inferior whitewash.
Above-mentioned polyvinyl acetal thing solution be single polyvinyl formal, polyvinylacetal, polyvinyl butyral acetal, polyvinyl alcohol contract urea aldehyde, with urea-modified polyvinyl formal solution or its mixing solutions, the degree of acetalization of this acetal thing with 40% be good, consider with polyvinyl formal or its urea-modified thing to be good from price; Described modified acrylate resin emulsion is the modified product that polyvinyl acetal and acrylic acid series or acrylic ester resin emulsion mix and produce physical crosslinking.Owing to be added with the polyvinyl acetal thing in this coating, modified acrylate resin emulsion wherein can substitute with solid content suitable acrylic acid series or acrylic ester resin emulsion.
When resin emulsion solid content or the change of polyvinyl acetal thing strength of solution, can calculate the actual amount of raw material by prescription and material content.
Embodiment and effect:
I have prepared the different exterior coatings different with denseness of a lot of colors according to the construction party needs by the given scope of above-mentioned prescription.Wherein, the most frequently used coating technology index is as follows:
1, outward appearance: conformance with standard and aberration scope
2, solid composition: 55 ± 2%
3、PH：9、0-9、7
4, granularity: (U) 0,1-0.2
5, construction temperature: (℃):＞3
Surface drying time 1 hour; Do solid work 24 hours time
6, hiding rare: every square meter is not more than 250g
7, sticking power: cross-hatching (a millimeter) 100%
8, heatproof degree: 80 ℃ of constant temperature 5 hours is cracking phenomena not
9, water tolerance: soak 1000 hours no foaming obscissions at tap water
10, acid resistance: 5%HCl(hydrochloric acid) the solution bubble is 500 hours, no foaming obscission
11, frost resistance: ± 27 ℃ 50 the no efflorescence foaming phenomenons of circulation
12, ageing-resistant: 6000W hernia lamp 500 hours, no powder of detached fades
13, glossiness: (60 ° of photoelectrometer measuring devices)
14, glued membrane degree: 100 kilograms per centimeter
2(kg/cm
2)
15, glue 180 degree of peeling off: 〉=3kg/25mm
16, tensile shear strength 80kg/cm
2
17, thermotolerance: 300 ℃
Claims (5)
1, a kind of acrylate resin exterior coating is characterized in that:
This exterior coating be with degree of acetalization be 15～45% polyvinyl acetal thing solution or and hydroxylated cellulose with by vinylformic acid or certain acrylate monomer and vinylbenzene, divinyl, iso-butylene, vinyl cyanide etc. contain that 1～5 kind of monomer copolymerization of vinyl forms, the modified product of vinylformic acid or the mixing of acrylic ester resin emulsion and generation physical crosslinking substitutes present acrylic acid series or the preparation of acrylic ester resin emulsion, and this coating is by water, blue or green, bubble flower alkali, light alkali, talcum powder, titanium white, Tai-Ace S 150, polyvinyl acetal thing solution, methyl hydroxyl or hydroxy ethyl fiber cellulose solution, defoamer, modified acroleic acid or modification acrylate are resin emulsion, and colorant is formulated.
2, acrylate resin exterior coating according to claim 1 is characterized in that: this exterior Wall paint of modified acrylic ester resin basic recipe is divided into white and two kinds of time whites according to desiring to join the coating color and luster depth.
White exterior coating basic recipe:
1. water 19～23%
2. ultramarine 0.01～0.03%
3. bubble is spent alkali (thickening material) 1.9～2.2%
6. titanium white (rutile-type) 2.7～3.3%
7. Tai-Ace S 150 (sterilant) 0.01～0.05%
8. polyvinyl acetal thing solution (9 ± 1%) 13～18%
9. methyl hydroxyl or hydroxy ethyl fiber cellulose solution (2%) 9～11%
10. defoamer (7010 or 680) 0.05～0.07%
⑾ modified acrylate resin emulsion (solid content 12.6～16.5%)
7～10%
The inferior whitewash basic recipe that adds dewatered sludge:
1. water 18～22%
2. ultramarine 0.01～0.03%
3. bubble is spent alkali (thickening material) 1.9～2.2%
6. titanium white (rutile-type) 3～4.2%
7. Tai-Ace S 150 (sterilant) 0.05～0.10%
8. polyvinyl acetal thing solution (9 ± 1%) 13～18%
9. methyl hydroxyl or hydroxy ethyl fiber cellulose solution (2%) 9～11%
10. dewatered sludge (water content 70～78%) 6～9%
⑾ defoamer 0.05～0.07%
⑿ modified acrylate resin emulsion (solid content 12.6～16.6%)
8～11%
This coating is under normal temperature and pressure and agitation condition, and material is added and mixing by the prescription order, forms through grinding again.
3, exterior Wall paint of modified acrylic ester resin according to claim 1 and 2 is characterized in that:
Be levelling property, water-repellancy, preservative property, the ageing resistance of improving coating, can in coating, add about 0.5% propylene glycol, about 0.5% zellon, about 0.1% Red copper oxide, about 0.3% concentration respectively and be 70% OP-10 or OP-15 solution.
Other coating of all kinds adds pigment and obtains through high speed dispersion in above-mentioned white or inferior whitewash.
4, exterior Wall paint of modified acrylic ester resin according to claim 1 and 2 is characterized in that:
Described polyvinyl acetal thing solution be single polyvinyl formal, polyvinyl butyral acetal, polyvinyl alcohol contract urea aldehyde, with urea-modified polyvinyl formal solution or its mixing solutions, the degree of acetalization of this acetal thing with 40% be good, consider with polyvinyl formal or its urea-modified thing to be good from price; Modified acrylate resin emulsion is the modified product that polyvinyl acetal thing and acrylic acid series or acrylic ester resin emulsion mix and produce physical crosslinking, owing to be added with the polyvinyl acetal thing in this coating, modified acrylate resin emulsion wherein can substitute with solid content suitable acrylic acid series or acrylic ester resin emulsion.
5, exterior Wall paint of modified acrylic ester resin according to claim 1 and 2 is characterized in that:
When resin emulsion solid content or the change of polyvinyl acetal thing strength of solution, can calculate the actual amount of raw material by prescription and material content.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88107705 CN1042557A (en) | 1988-11-07 | 1988-11-07 | Exterior wall paint of modified acrylic ester resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88107705 CN1042557A (en) | 1988-11-07 | 1988-11-07 | Exterior wall paint of modified acrylic ester resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1042557A true CN1042557A (en) | 1990-05-30 |
Family
ID=4834755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88107705 Pending CN1042557A (en) | 1988-11-07 | 1988-11-07 | Exterior wall paint of modified acrylic ester resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1042557A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1038761C (en) * | 1993-05-31 | 1998-06-17 | 大连市风彩涂料厂 | Water-proof paint |
| CN1042641C (en) * | 1992-09-16 | 1999-03-24 | 上海宝山钢铁总厂 | Method for production of color antistatic permeable adhesive |
| CN1063203C (en) * | 1996-06-10 | 2001-03-14 | 王逢论 | External wall finishing material |
| CN100340613C (en) * | 2002-12-31 | 2007-10-03 | 叶春山 | Composite paint and method for preparing the same |
| CN100340615C (en) * | 2002-12-31 | 2007-10-03 | 叶春山 | Water composite coating and preparing method thereof |
| CN102876098A (en) * | 2012-09-26 | 2013-01-16 | 苏州汾湖电梯有限公司 | Tapestry-imitation decorative coating for aluminum alloy panel of elevator |
| CN103525289A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Insulating UV (ultraviolet) varnish and preparation method thereof |
| CN103553504A (en) * | 2013-11-11 | 2014-02-05 | 苏州市姑苏新型建材有限公司 | Method for using waterproof coating for building materials |
| CN105838163A (en) * | 2016-04-25 | 2016-08-10 | 南京高崎电机有限公司 | High-adhesive-force paint |
| CN105949840A (en) * | 2016-05-04 | 2016-09-21 | 南京高崎电机有限公司 | Coarseness resisting paint |
-
1988
- 1988-11-07 CN CN 88107705 patent/CN1042557A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042641C (en) * | 1992-09-16 | 1999-03-24 | 上海宝山钢铁总厂 | Method for production of color antistatic permeable adhesive |
| CN1038761C (en) * | 1993-05-31 | 1998-06-17 | 大连市风彩涂料厂 | Water-proof paint |
| CN1063203C (en) * | 1996-06-10 | 2001-03-14 | 王逢论 | External wall finishing material |
| CN100340613C (en) * | 2002-12-31 | 2007-10-03 | 叶春山 | Composite paint and method for preparing the same |
| CN100340615C (en) * | 2002-12-31 | 2007-10-03 | 叶春山 | Water composite coating and preparing method thereof |
| CN102876098A (en) * | 2012-09-26 | 2013-01-16 | 苏州汾湖电梯有限公司 | Tapestry-imitation decorative coating for aluminum alloy panel of elevator |
| CN103525289A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Insulating UV (ultraviolet) varnish and preparation method thereof |
| CN103553504A (en) * | 2013-11-11 | 2014-02-05 | 苏州市姑苏新型建材有限公司 | Method for using waterproof coating for building materials |
| CN105838163A (en) * | 2016-04-25 | 2016-08-10 | 南京高崎电机有限公司 | High-adhesive-force paint |
| CN105949840A (en) * | 2016-05-04 | 2016-09-21 | 南京高崎电机有限公司 | Coarseness resisting paint |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101348611B (en) | Acroleic acid modified polysiloxane resin and coating thereof | |
| CN101058701A (en) | Water soluble adhesive | |
| CN1042557A (en) | Exterior wall paint of modified acrylic ester resin | |
| CN102101960A (en) | High-hydroxy silicon-acrylate aqueous glass coating emulsion and synthesis method thereof | |
| CN1235935C (en) | Modified dry oil alkyd resin for protective paint for metal coating on the back of the mirror and the curtain coating paint | |
| CN1131287C (en) | Organosilicon modified acrylic paint for external wall and its preparing process | |
| CN101029110A (en) | Fluoride core-shell acrylic-resin emulsion, its production and use | |
| CN114456623A (en) | Ceramic coating with good weather resistance and preparation method thereof | |
| CN101240135B (en) | Simple painted metal imitation fluorocarbon paint | |
| CN113480898A (en) | Quick-drying transparent primer and preparation method thereof | |
| CN101440254B (en) | Anticorrosion paint for decorating inner and external walls of power station transformer, and preparation thereof | |
| CN1814676A (en) | High-strength water-resistant putty powder | |
| CN1159399C (en) | Water-based acrylic acid modified alcoholic acid amino baking paint | |
| CN101987935A (en) | Aqueous paint prepared from calcined shell powder and ash calcium powder | |
| CN1162484C (en) | Resin dedicated for coating on polypropylene plastics | |
| CN111234686A (en) | Self-crosslinking acrylic polyurethane dispersion stone-like paint and preparation method thereof | |
| CN1082573A (en) | Water soluble imitation glaze coating compound | |
| CN100349998C (en) | Fluoro resin curtain-imitating wall paint | |
| CN1157831A (en) | Soil resistant polymers | |
| CN113801531B (en) | High-environmental-protection water-based metal protective paint capable of being constructed outdoors and preparation method thereof | |
| CN104745069A (en) | Water-soluble polyurethane heat-insulating coating for external wall, and production method thereof | |
| CN1182207C (en) | High molecular polymer calking and productive method thereof | |
| CN1544553A (en) | Fluorocarbon paint color coating and its production process | |
| CN1031097A (en) | Super quick-setting amino baking finish | |
| CN1296046A (en) | Glazed tile lacquer and production method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |