CN1042641C - Method for production of color antistatic permeable adhesive - Google Patents
Method for production of color antistatic permeable adhesive Download PDFInfo
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- CN1042641C CN1042641C CN92108558A CN92108558A CN1042641C CN 1042641 C CN1042641 C CN 1042641C CN 92108558 A CN92108558 A CN 92108558A CN 92108558 A CN92108558 A CN 92108558A CN 1042641 C CN1042641 C CN 1042641C
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- add
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- 239000000853 adhesive Substances 0.000 title claims abstract description 21
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 21
- 230000003068 static effect Effects 0.000 claims abstract description 13
- 150000001408 amides Chemical class 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000006185 dispersion Substances 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 5
- 238000001914 filtration Methods 0.000 claims abstract description 5
- 239000000945 filler Substances 0.000 claims abstract description 4
- 239000000049 pigment Substances 0.000 claims abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 239000004576 sand Substances 0.000 claims description 17
- 238000003801 milling Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 8
- 239000010456 wollastonite Substances 0.000 claims description 8
- 229910052882 wollastonite Inorganic materials 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 4
- 229960004217 benzyl alcohol Drugs 0.000 claims description 4
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 4
- 238000004581 coalescence Methods 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 4
- 230000008719 thickening Effects 0.000 claims description 4
- 235000010215 titanium dioxide Nutrition 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000011259 mixed solution Substances 0.000 claims 1
- 238000012423 maintenance Methods 0.000 abstract description 2
- 230000005611 electricity Effects 0.000 abstract 2
- 239000002216 antistatic agent Substances 0.000 abstract 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N cinnamic acid Chemical compound OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- HTMIBDQKFHUPSX-UHFFFAOYSA-N methdilazine Chemical group C1N(C)CCC1CN1C2=CC=CC=C2SC2=CC=CC=C21 HTMIBDQKFHUPSX-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
Abstract
With the gradually wide application of electronic computers, the harm of indoor static electricity of computer rooms, etc. to the aspects of computers, element manufacture, device maintenance, automatic control systems, command and control systems, etc. is gradually regarded by people. At present, in various static electricity prevention and treatment methods, a color antistatic permeable adhesive is a material which has decorative color, strong adhesive force and certain antistatic performance and can be directly sprayed or coated on working reference planes. The adhesive becomes a required color antistatic permeable adhesive by that dispersion agents, pigments, fillers and defoamers are orderly added in pure water, benzene-acrylate emulsion film-forming base materials and film-forming auxiliaries are added after the components are mixed evenly, amide class antistatic agents are added after the components are mixed evenly, color paste and defoamers are added through filtration and sanding after the components are mixed evenly, and thickening agents are added to regulate viscosity after the components are mixed evenly.
Description
The present invention relates to a kind of chromatic manufacture method with antistatic permeable adhesive.
Widespread use along with robot calculator, indoor at the computer house that uses robot calculator, operation department, command and control center, electronic equipment maintenance chamber (workshop), automatic assembly line etc., static more and more causes people's attention to the interference and the harm of computer, thereby the electrostatic control becomes an important problem.At present, in order to solve electrostatic harm, guiding static successfully leaks, and the method for employing has the wallpaper of anlistatig floor and anti-electrostatic etc., and these methods all realize by means of certain base material (floor, wallpaper etc.); The conductive fiber material that also has the employing adsorption of metal ions to make on tacryl paper sticks to the method on the metope, leaks with the guiding electrostatic, as the clear 58-5734 of Japanese Patent.Above-mentioned these methods all bother, and technology is complicated.
The objective of the invention is, provide a kind of manufacturing process simple, constructing operation is simple, a kind of not only to have had anti-static function, but also can directly spray or be painted on the working reference plane, strong adhesion and have the antistatic adhesive agent of certain ornamental color.
The manufacture method of color antistatic permeable adhesive of the present invention, be in pure water, to add dispersion agents such as polyacrylate and Sodium hexametaphosphate 99 while stirring in proper order, titanium white powder pigment, fillers such as ultra-fine wollastonite powder, wollastonite powder, process white, talcum powder, OT rod soil, tributyl phosphate defoamers etc. stir; Add benzene-acrylic emulsion film forming base-material, phenylcarbinol and ethylene glycol film coalescence aid, mixing; Add the amides static inhibitor again, after mixing, after filtration and sand milling, add mill base and tributyl phosphate defoamer, mixing; Add the acrylate thickening material again and adjust viscosity.
The manufacture method of color antistatic permeable adhesive of the present invention, its flow process is seen shown in Figure 1.With specific conductivity＜100 micro-ohms
-1/ centimetre pure water put into the reactor (2) that has agitator (3), make agitator speed be controlled at 250～400 rev/mins by stirring velocity controller (1), add Sodium hexametaphosphate 99 more successively, churning time is 10～60 minutes, Sodium hexametaphosphate 99 is dissolved fully, open valve (9) then, deposit in the container (14), use as dispersion agent.Afterwards, film coalescence aid ethylene glycol is added in the reactor (2), and the rotating speed of setting agitator (3) is 250～400 rev/mins, adds quantitative amides static inhibitor again and carries out stirring in 15 minutes, solution is mixed fully, open valve (9) then and deposit in another container.Afterwards, add specific conductivity＜100 micro-ohms
-1/ centimetre pure water, the rotating speed of setting agitator (3) is 760～960 rev/mins, when stirring, drops into the raw material of formula ratio in order: dispersion agent polyacrylate and Sodium hexametaphosphate 99; As the titanium dioxide of pigment with as ultra-fine wollastonite powder, wollastonite powder, process white, talcum powder, the 0T rod soil of filler; Tributyl phosphate as defoamer.Then, make agitator (3) speed in the reactor in the time of 1300～1500 rev/mins, stirred 30～60 minutes, solution is mixed.Make agitator (3) speed reduce to 760～960 rev/mins again, in reactor, add film forming base-material benzene-acrylic emulsion and film coalescence aid phenylcarbinol and ethylene glycol, restir 5～20 minutes.Afterwards, in reactor, add the amides static inhibitor that has prepared, stirred 5～20 minutes.After treating that solution mixes, open valve (10), the material that stirs is sent into strainer (4), the screen size of filtering net is 80～100 orders in the strainer, material is sent in the sand mill (5) through injection pump (13) again, sand milling materials flow amount is 15～25kg/ branch, and the sand milling time is 40～65 minutes, again the sand milling material is injected toning container (7) through injection pump (12).In the molten device of toning (7), the mill base and the froth breaking tributyl phosphate that add proportional quantity, at this moment, by the stirring controller (11) in the toning container, make agitator speed be adjusted into 40～70 rev/mins, and stirred 30～60 minutes, add the thickening material acrylate again, make soltion viscosity adjust to 20～60 seconds (the coating-4 viscosity meter method by GB1723 is measured).So just make color antistatic permeable adhesive.
After measured, the performance of this adhesive agent is as shown in table 1 below, and the dried coating performance sees Table 2.
Table 1
| Performance | Index |
| Opacifying power | 250g/m 2 |
| Sticking power (surveying) with cross-hatching | 100％ |
| Viscosity (being coated with-4 viscometer methods by GB1723 measures) | 20～60 seconds |
| PH value | 8.5～9.5 |
| Solid content | ＞45％ |
Table 2
| Performance | Index |
| Time of drying, (25 ℃) surface drying was done solid work | ＜2 hours＜24 hours |
| The surface insulation resistance value | ＜10 9Ω |
| Water tolerance | ＞250 hours |
| Alkali resistance | ＞250 hours |
The adhesive agent spraying that will make with aforesaid method or evenly be painted on the working reference plane, through after 24 hours dryings, just form on the working reference plane the required color of one deck, have than strong adhesive force and have filming of good resistance antistatic property.
The synoptic diagram 1. of Fig. 1 color antistatic permeable adhesive manufacturing process stirs controller 2. reactors 3. agitators 4. strainers 5. sand mills 6. sand milling material containers 7. toning containers 8. agitators 9. valves 10. valves 11. and stirs controller 12. injection pumps 13. valves 14. containers
Embodiment:, in reactor, add pure water (specific conductivity＜100 micro-ohms for making a certain amount of color antistatic permeable adhesive
-1/ centimetre) 38.20%, making the agitator speed in the reactor is 960 rev/mins, simultaneously, in reactor, add polyacrylate 0.15%, Sodium hexametaphosphate 99 1.00%, titanium dioxide 3.00%, ultra-fine wollastonite powder 10.00%, wollastonite powder 15.00%, process white 10.00%, talcum powder 4.00%, OT rod soil 1.20%, tributyl phosphate 0.05% in order, then, when making agitator speed be 1400 rev/mins, high-speed stirring 45 minutes.Afterwards, when agitator speed is reduced to 960 rev/mins, in reactor, add benzene-acrylic emulsion (press proportional quantity 14.00%), phenylcarbinol 0.35% and ethylene glycol 0.70%, behind reinforced the finishing, stirred 5～10 minutes.Then, in reactor, add the amide containing class static inhibitor (wherein the amides static inhibitor is 62: 38 with the ratio of ethylene glycol) 0.50% that amides static inhibitor and ethylene glycol mix, stirred 10 minutes.It is to filter in the 100 purpose strainers that the material that stirs is sent into the order number.Send filter material to sand mill with injection pump again, sand milling materials flow amount is that 20kg/ branch, sand mill rotating speed are 1400 rev/mins, behind the sand milling 50 minutes, through transition container, with pump the sand milling material is injected the toning container, add 1.25% mill base and 0.05% tributyl phosphate again, and make the agitator speed in the toning container be adjusted into 50 rev/mins, stirred 40 minutes.At last, add 0.55% acrylate, make viscosity adjustment to 20～60 second (the coating-4 viscosity meter method of pressing the GB1723 regulation is measured) of material, just become color antistatic permeable adhesive.
The above-mentioned adhesive agent of spraying on working reference plane, it is chromatic, adhere firmly and have a coating of good electrostatic discharged leaking performance just to become one deck after the drying.
Claims (4)
1. the manufacture method of a color antistatic permeable adhesive is characterized in that, at specific conductivity＜100 micro-ohms
-1/ centimetre pure water 38.20% in while stirring order add dispersion agent polyacrylate 0.15%, Sodium hexametaphosphate 99 1%, titanium white powder pigment 3%, the ultra-fine wollastonite powder 10% of filler, wollastonite powder 15%, process white 10%, talcum powder 4%, OT rod soil 1.2% and defoamer tributyl phosphate 0.05%, uniform mixing, add film forming base-material benzene-acrylic emulsion 14% again, film coalescence aid phenylcarbinol 0.35%, with ethylene glycol 0.7% uniform mixing, add again by amides static inhibitor and ethylene glycol mixtures 0.5%, the amides static inhibitor is 62: 38 with the ratio of ethylene glycol in the mixed solution, through uniform mixing, behind filtration and the sand milling, add mill base 1.25% and tributyl phosphate 0.05%, behind the uniform mixing, add thickening material acrylic acid salt again and carry out the viscosity adjustment.
2, the manufacture method of adhesive agent according to claim 1 is characterized in that, compound adds amides static inhibitor and ethylene glycol mixtures and behind uniform mixing, filter, and the order number of filter screen is 80～100 orders.
3, the manufacture method of adhesive agent according to claim 1 is characterized in that, compound also will carry out the sand mill sand milling after filtering, and the flow of sand milling material is 15～25 kilograms/minute, and the sand milling time is 40～65 minutes.
4, the manufacture method of caking agent according to claim 1 is characterized in that, compound need add the thickening material acrylate at last and adjust viscosity, and the control indexes of viscosity was 20～60 seconds (pressing coating-4 viscosity meter method mensuration among the GB1723).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92108558A CN1042641C (en) | 1992-09-16 | 1992-09-16 | Method for production of color antistatic permeable adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN92108558A CN1042641C (en) | 1992-09-16 | 1992-09-16 | Method for production of color antistatic permeable adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1084196A CN1084196A (en) | 1994-03-23 |
| CN1042641C true CN1042641C (en) | 1999-03-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92108558A Expired - Fee Related CN1042641C (en) | 1992-09-16 | 1992-09-16 | Method for production of color antistatic permeable adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1042641C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101925170B1 (en) * | 2011-11-09 | 2018-12-04 | 로디아 오퍼레이션스 | Additive mixture and composition and method for polishing glass substrates |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6023455A (en) * | 1983-07-19 | 1985-02-06 | Kubota Ltd | Water-based corrosion-resistant paint |
| CN1042557A (en) * | 1988-11-07 | 1990-05-30 | 薛志纯 | Exterior wall paint of modified acrylic ester resin |
| CN1054606A (en) * | 1990-03-07 | 1991-09-18 | 机械电子工业部北方设计研究院 | Anti-static electricity internal wall emulsion coating |
| EP0455028A1 (en) * | 1990-04-28 | 1991-11-06 | Bayer Ag | Use of emulsion copolymers in aqueous clearcoats and aqueous clearcoat |
-
1992
- 1992-09-16 CN CN92108558A patent/CN1042641C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6023455A (en) * | 1983-07-19 | 1985-02-06 | Kubota Ltd | Water-based corrosion-resistant paint |
| CN1042557A (en) * | 1988-11-07 | 1990-05-30 | 薛志纯 | Exterior wall paint of modified acrylic ester resin |
| CN1054606A (en) * | 1990-03-07 | 1991-09-18 | 机械电子工业部北方设计研究院 | Anti-static electricity internal wall emulsion coating |
| EP0455028A1 (en) * | 1990-04-28 | 1991-11-06 | Bayer Ag | Use of emulsion copolymers in aqueous clearcoats and aqueous clearcoat |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1084196A (en) | 1994-03-23 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| OR01 | Other related matters | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |