CN101240135B - Simple painted metal imitation fluorocarbon paint - Google Patents
Simple painted metal imitation fluorocarbon paint Download PDFInfo
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- CN101240135B CN101240135B CN2008100014687A CN200810001468A CN101240135B CN 101240135 B CN101240135 B CN 101240135B CN 2008100014687 A CN2008100014687 A CN 2008100014687A CN 200810001468 A CN200810001468 A CN 200810001468A CN 101240135 B CN101240135 B CN 101240135B
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- paint
- dimethylbenzene
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- fluorocarbon paint
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Abstract
The invention discloses a metal-like fluorocarbon paint for simple painting of outer wall, composed of components A, B and C packaged independently, and preparation method thereof; wherein, the component A (paint) comprises: fluorocarbon resin, anti-settling agent, flake cellulose vinyl acetate, anti-foam agent, butyl acetate, dimethylbenzene, fluorocarbon modified polyacrylic acid leveling agent, organic modified siloxane smoothening leveling agent, metal pigment paste, photo-stabilizer, and Ultraviolet absorber UV-1; the component B comprises: solidifier; the component C comprises: dilutingagent; detailed proportion and preparation method thereof are referred to specification. The invention is provided with the following advantages of: 1, low cost; 2, easy to paint without surface paint glazing; 3, uniform color and luster; 4, extremely long weathering resistance; 5, excellent chemical resistance; 6, excellent pollution resistance. The invention is appropriate for painting and protecting outer wall surface.
Description
Technical field
The invention discloses simple painted imitation metal fluorocarbon paint of a kind of exterior wall and preparation method.
Technical background
The product that is applied to the application of exterior wall high-performance at present mainly contains aluminium-plastic panel, glass curtain wall, ceramic tile etc., not only consumes ample resources, contaminate environment, also has a potential safety hazard.Now the imitation metal fluorocarbon paint that occurs on the market exists also that low, the anti-chemical of fluorocarbon resin content is poor, fullness ratio is poor, color and lustre lacking uniformity, working procedure complexity, needs shortcomings such as finish paint Lacquer finish, cost height.
Summary of the invention
The purpose of this invention is to provide a kind of end, the general simple painted imitation metal fluorocarbon paint of finish paint, not only simplified working procedure, improved the construction tolerance, reduced whole construction cost, also solved shortcomings such as color and lustre lacking uniformity, fullness ratio difference.
The present invention is achieved in that a kind of simple painted imitation metal fluorocarbon paint and preparation method, formulation ratio:
Component A:
Fluorocarbon resin 65-75 part
Anti-settling agent 8-12 part
Vinyl acetate between to for plastic cellulose slurry 5-8 part
Defoamer 0.2-0.5 part
N-BUTYL ACETATE 2-8 part
Dimethylbenzene 2-10 part
Fluorine-carbon modified polyacrylic acid flow agent 0.1-0.5 part
Organically-modified siloxanes increases sliding flow agent 0.1-0.3 part
Metallic pigment slurry 7-10 part
Photostabilizer 0.1-0.5 part
UV light absorber UV-1 0.1-0.5 part
Described anti-settling agent is polyamide wax and dimethylbenzene to be stirred earlier in 4: 1 ratio make.
Described vinyl acetate between to for plastic cellulose slurry is that vinyl acetate between to for plastic Mierocrystalline cellulose and dimethylbenzene are evenly made in 4: 1 ratio dissolving.
Described metallic pigment slurry is that metallic pigment powder (as aluminium silver powder, gold copper powder) and N-BUTYL ACETATE are evenly made by dissolving earlier in 3: 1.
Processing sequence is to disperse the fluorocarbon resin input in the cylinder and add anti-settling agent, vinyl acetate between to for plastic cellulose slurry, defoamer stirred 5 minutes under 800 rev/mins rotating speed, drop into N-BUTYL ACETATE, dimethylbenzene, fluorine-carbon modified polyacrylic acid flow agent, organically-modified siloxanes then successively and increase sliding flow agent, metallic pigment slurry, photostabilizer, UV light absorber UV-1, press 1000-1200 rev/min rotating speed high speed dispersion 10-15 minute again, treat that the metallic pigment slurry is uniformly dispersed fully, detect qualified back discharging, promptly make component A finished product.
Described B component (solidifying agent) is to be the aliphatic isocyanates of base-material with six inferior vulcabond (HDI).
Described component C (thinner) is formed by N-BUTYL ACETATE, pimelinketone and the dimethylbenzene mixed by 2: 1: 1.
By set of dispense than A: B: C=1: 0.1: 0.3-0.5, the imitation metal fluorocarbon paint of making are painted on the good cement works exterior wall surface of sealing treatment, and following characteristics are compared with prior art arranged: 1. cost is low; 2. application is simple and easy, does not need the finish paint Lacquer finish; 3. color and gloss are even; 4. super weathering resistance of a specified duration; 5. You Yi chemical resistant properties; 6. outstanding stain resistance.
Embodiment
Embodiment 1
Take by weighing raw material at first in proportion, disperse 65 parts of fluorocarbon resins input in the cylinder and add 10 parts of anti-settling agents, 6 parts of vinyl acetate between to for plastic cellulose slurries, defoamer stirred 5 minutes under 800 rev/mins rotating speed for 0.2 part, drop into 6 parts of N-BUTYL ACETATEs then successively, 4.1 parts of dimethylbenzene, 0.2 part of fluorine-carbon modified polyacrylic acid flow agent, organically-modified siloxanes increases 0.1 part of sliding flow agent, 8 parts in metallic pigment slurry, 0.2 part of photostabilizer, UV light absorber UV-10.2 part, press 1000-1200 rev/min rotating speed high speed dispersion 10-15 minute again, treat that the metallic pigment slurry is uniformly dispersed fully, detect qualified back discharging, promptly make finished product component A.Set of dispense is than A (lacquer): B (solidifying agent): C (thinner)=1: 0.1: 0.3-0.5.
Embodiment 2
Take by weighing raw material at first in proportion, disperse 68 parts of fluorocarbon resins input in the cylinder and add 11 parts of anti-settling agents, 6 parts of vinyl acetate between to for plastic cellulose slurries, defoamer stirred 5 minutes under 800 rev/mins rotating speed for 0.2 part, drop into 4 parts of N-BUTYL ACETATEs then successively, 2 parts of dimethylbenzene, 0.2 part of fluorine-carbon modified polyacrylic acid flow agent, organically-modified siloxanes increases 0.1 part of sliding flow agent, 8.1 parts in metallic pigment slurry, 0.3 part of photostabilizer, UV light absorber UV-10.1 part, press 1000-1200 rev/min rotating speed high speed dispersion 10-15 minute again, treat that the metallic pigment slurry is uniformly dispersed fully, detect qualified back discharging, promptly make finished product component A.Set of dispense is than A (lacquer): B (solidifying agent): C (thinner)=1: 0.1: 0.3-0.5.
Embodiment 3
Take by weighing raw material at first in proportion, disperse 72 parts of fluorocarbon resins input in the cylinder and add 9 parts of anti-settling agents, 5 parts of vinyl acetate between to for plastic cellulose slurries, defoamer stirred 5 minutes under 800 rev/mins rotating speed for 0.2 part, drop into 3.1 parts of N-BUTYL ACETATEs then successively, 2 parts of dimethylbenzene, 0.2 part of fluorine-carbon modified polyacrylic acid flow agent, organically-modified siloxanes increases 0.1 part of sliding flow agent, 8 parts in metallic pigment slurry, 0.3 part of photostabilizer, UV light absorber UV-10.1 part, press 1000-1200 rev/min rotating speed high speed dispersion 10-15 minute again, treat that the metallic pigment slurry is uniformly dispersed fully, detect qualified back discharging, promptly make finished product component A.Set of dispense is than A (lacquer): B (solidifying agent): C (thinner)=1: 0.1: 0.3-0.5.
Main raw material(s) title, technical indicator:
1. fluorocarbon resin
Outward appearance: colourless or light yellow transparent liquid
Solid content %:52
Fluorine content %:24
Hydroxyl value mgKOH/g:47 ± 5
Acid number mgKOH/g:5 ± 1
Viscosity (being coated with-4 glasss) s:53 ± 5
Molecular weight: 20000
Tg，℃：35
Proportion g/ml:1.1～1.15
Solvent: N-BUTYL ACETATE, dimethylbenzene
Characteristic: low viscosity
2. polyamide wax, the modest Desetele.229 of moral
Outward appearance: little yellow soft wax shape
Admittedly contain: 20%
Solvent: dimethylbenzene
Proportion: 0.88
3. defoamer: EFKA-2018
4. fluorine-carbon modified polyacrylic acid flow agent: EFKA3777
Effective ingredient: 100%
5. organically-modified siloxanes increases sliding flow agent: EFKA3033
Effective ingredient: 15%
Solvent: N-BUTYL ACETATE
6. vinyl acetate Mierocrystalline cellulose: CAB-551-0.2
The deionization type.
7. photostabilizer: chemical name: two (1,2,2,6,6-pentamethyl--4-piperidyl) sebate.
8. UV light absorber UV-1:
Chemical name: N-(ethoxy carbonyl phenyl)-N '-methyl-N '-phenyl methyl ether
9. solidifying agent: chemical name: six inferior vulcabond (HDI) N-75
By standard HG/T3792-2005I type standard sampling inspection, its main performance index such as following table 1.
| Sequence number | Project | Technical indicator | Assay |
| 1 | Condition in container | Stir evenly no lump of back | Stir evenly no lump of back |
| 2 | Fineness, μ m | Decide through consultation | 35 |
| 3 | Solvent solvend fluorine content, % | ≥18 | 21 |
| 4 | Appearance of film | Normally | Normally |
| 5 | Working life (5h) | By | By |
| 6 | Recoatability | Recoat is accessible | Recoat is accessible |
| 7 | Sticking power, level | ≤1 | 1 |
| 8 | Acid resistance (168H) | No abnormal | No abnormal |
| 9 | Mortar resistance (24H) | No abnormal | No abnormal |
| Sequence number | Project | Technical indicator | Assay |
| 10 | Water tolerance (168H) | No abnormal | No abnormal |
| 11 | Moisture-proof cold cycling (10 times) | No abnormal | No abnormal |
| 12 | Abrasion resistance, inferior | ≥10000 | 12000 |
| 13 | Stain resistance | By | By |
| 14 | Anti-solvent wiping, inferior (dimethylbenzene) | ≥100 | 120 |
| 15 | The artificial weathering ageing resistance | 2500 hours non-foaming, do not come off, do not ftracture | 5000 hours non-foaming, do not come off, do not ftracture |
| Decide through consultation | Efflorescence: 1 grade | ||
| Decide through consultation | Variable color: 1 grade | ||
| Decide through consultation | Loss of gloss: 1 grade |
Claims (6)
1. simple painted imitation metal fluorocarbon paint is characterized in that its formulation ratio:
Component A:
Fluorocarbon resin 65-75 part
Anti-settling agent 8-12 part
Vinyl acetate between to for plastic cellulose slurry 5-8 part
Defoamer 0.2-0.5 part
N-BUTYL ACETATE 2-8 part
Dimethylbenzene 2-10 part
Fluorine-carbon modified polyacrylic acid flow agent 0.1-0.5 part
Organically-modified siloxanes increases sliding flow agent 0.1-0.3 part
Metallic pigment slurry 7-10 part
Photostabilizer 0.1-0.5 part
UV light absorber UV-1 0.1-0.5 part.
2. a kind of simple painted imitation metal fluorocarbon paint as claimed in claim 1, its feature part is: anti-settling agent is polyamide wax and dimethylbenzene to be stirred earlier in 4: 1 ratio make.
3. a kind of simple painted imitation metal fluorocarbon paint as claimed in claim 1, its feature part is: the vinyl acetate between to for plastic cellulose slurry is that vinyl acetate between to for plastic Mierocrystalline cellulose and dimethylbenzene are evenly made in 4: 1 ratio dissolving.
4. a kind of simple painted imitation metal fluorocarbon paint as claimed in claim 1, its feature part is: the metallic pigment slurry is that metallic pigment powder and N-BUTYL ACETATE are evenly made by dissolving earlier in 3: 1.
5. a kind of simple painted imitation metal fluorocarbon paint as claimed in claim 1, its feature part is: B component (solidifying agent): be to be the aliphatic isocyanates of base-material with hexamethylene diisocyanate (HDI); Component C (thinner): be to form by N-BUTYL ACETATE, pimelinketone and dimethylbenzene mixed by 2: 1: 1, by set of dispense than A: B: C=1: 0.1: 0.3-0.5, the imitation metal fluorocarbon paint of making are painted on the good cement works exterior wall surface of sealing treatment.
6. the preparation method of a kind of simple painted imitation metal fluorocarbon paint as claimed in claim 1, its feature part is: take by weighing raw material in proportion, disperse the fluorocarbon resin input in the cylinder and add anti-settling agent, the vinyl acetate between to for plastic cellulose slurry, defoamer, under 800 rev/mins rotating speed, stirred 5 minutes, drop into N-BUTYL ACETATE then successively, dimethylbenzene, fluorine-carbon modified polyacrylic acid flow agent, organically-modified siloxanes increases sliding flow agent, the metallic pigment slurry, photostabilizer, UV light absorber UV-1, press 1000-1200 rev/min rotating speed high speed dispersion 10-15 minute again, treat that the metallic pigment slurry is uniformly dispersed fully, detect qualified back discharging, promptly make finished product component A.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100014687A CN101240135B (en) | 2008-01-21 | 2008-01-21 | Simple painted metal imitation fluorocarbon paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100014687A CN101240135B (en) | 2008-01-21 | 2008-01-21 | Simple painted metal imitation fluorocarbon paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101240135A CN101240135A (en) | 2008-08-13 |
| CN101240135B true CN101240135B (en) | 2010-11-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100014687A Active CN101240135B (en) | 2008-01-21 | 2008-01-21 | Simple painted metal imitation fluorocarbon paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN101240135B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735714B (en) * | 2009-11-27 | 2011-11-16 | 深圳市威凯士化工涂料有限公司 | Environmentally-friendly low-temperature curing metallic gold coating, manufacturing process and application of coating serving as iron printed tank coating in directly coating roll |
| CN101857745A (en) * | 2010-06-18 | 2010-10-13 | 太仓市高分子材料研发中心有限公司 | Fluorocarbon flash quick drying baking paint for curtain coating |
| CN103045027A (en) * | 2012-12-26 | 2013-04-17 | 青岛科瑞新型环保材料有限公司 | Finishing varnish |
| CN104100064B (en) * | 2014-07-11 | 2016-08-24 | 浙江泰基涂料有限公司 | Illusion-colour metal face overlay stone |
| CN104790809A (en) * | 2015-03-13 | 2015-07-22 | 四川省川源塑胶有限公司 | Aluminum plastic composite profile/PVC profile and machining method thereof |
| CN106752445A (en) * | 2016-12-14 | 2017-05-31 | 立邦涂料(成都)有限公司 | A kind of interiro wall latex paint and preparation method thereof |
| CN106675153B (en) * | 2017-01-09 | 2020-01-31 | 上海新大余氟碳喷涂材料有限公司 | fluorocarbon spraying paint additive and its use method |
| CN109098378A (en) * | 2018-07-25 | 2018-12-28 | 四川海聚环保科技有限责任公司 | A kind of imitative metal lagging and production technology |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1341688A (en) * | 2001-09-24 | 2002-03-27 | 大连明辰振邦氟涂料股份有限公司 | Imitation metal fluorocarbon paint |
| US20020081389A1 (en) * | 1999-05-26 | 2002-06-27 | Entire Interest | Metal roffing shingle stock and method for making it |
| CN1511901A (en) * | 2002-12-27 | 2004-07-14 | 深圳市海川实业股份有限公司 | High performance metal filling building decorative paint |
-
2008
- 2008-01-21 CN CN2008100014687A patent/CN101240135B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020081389A1 (en) * | 1999-05-26 | 2002-06-27 | Entire Interest | Metal roffing shingle stock and method for making it |
| CN1341688A (en) * | 2001-09-24 | 2002-03-27 | 大连明辰振邦氟涂料股份有限公司 | Imitation metal fluorocarbon paint |
| CN1511901A (en) * | 2002-12-27 | 2004-07-14 | 深圳市海川实业股份有限公司 | High performance metal filling building decorative paint |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2005-199605A 2005.07.28 |
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| CN101240135A (en) | 2008-08-13 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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| CP01 | Change in the name or title of a patent holder |
Address after: 528429, Guangdong City, Zhongshan Province Huang Town, Tai Cheng Industrial Zone dedicated road, Zhongshan three and aerosol Co., Ltd. Patentee after: Guangdong Sanhe Chemical Industry Technology Co., Ltd. Patentee after: Shunde Guangdong Three Chemical Co., Ltd. Address before: 528429, Guangdong City, Zhongshan Province Huang Town, Tai Cheng Industrial Zone dedicated road, Zhongshan three and aerosol Co., Ltd. Patentee before: Guangdong Sanhe Chemical Industry Technology Co., Ltd. Patentee before: Foshan Futian Coatings Chemicals Co., Ltd. |