CN1727424A - Biologic waterproof glue and usage - Google Patents
Biologic waterproof glue and usage Download PDFInfo
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- CN1727424A CN1727424A CN 200410009391 CN200410009391A CN1727424A CN 1727424 A CN1727424 A CN 1727424A CN 200410009391 CN200410009391 CN 200410009391 CN 200410009391 A CN200410009391 A CN 200410009391A CN 1727424 A CN1727424 A CN 1727424A
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Abstract
A biologic water-proof adhesive for building, wood, metal, ceramic, glass, etc is prepared from glutinous rice, water, ethene-vinyl acetate emulsion, dioctyl phthalate, PVC, tung oil, acrylic emulsion and natural rubber. Its advantages are high weatherability, adhesion, tension strength, elongation percentage for breaking and resistance to water, acid and alkali.
Description
Technical field
The invention belongs to the waterproof paint field, particularly biological waterproof glue and uses thereof.
Background technology
At present, ointment is mostly adopted in the crack on domestic remedial cement road surface, bituminous material, but from result of use, their waterproof effects are poor, make roadbed can not get permanent protection; The waterproof roll that roof waterproof adopts has LHG, APP, SBS, ZYP etc., that adopts coating water-proof series has LIP, an IS, BR, JS etc., but these water-proof materials all are difficult for construction, operational difficulty to the complex region in the construction, and there is a weathering of water-proof material nature, it is not durable to chap, and poor water resistance is because temperature Change is big, through the several times freeze-thaw cycle, base material and matrix are very easily thrown off, and cause the hollowing phenomenon, and joint easily splits, waterproof layer and basal plane produce a lot of water bands, the water route is ganged up, and leaks if any a place, often causes large-scale water leakage.
Though scientific and technical personnel are updating the prescription of waterproof paint, number be 03111857.7 patent application as Chinese patent application, its prescription consists of: macromolecule emulsion, dispersion agent, softening agent, defoamer, membrane-forming agent, reinforced filling.Chinese patent application number is 03117197.4 patent application, and its prescription consists of: ordinary Portland cement, acrylic acid esters co-polymer, defoamer, wetting agent.But see existing waterproof paint from integral body, no matter its how conversion of filling a prescription does not all have a kind of waterproof paint that makes based on biomaterial.
Summary of the invention
One of purpose of the present invention is to overcome the deficiency of existing water-proof material, and a kind of once construction is provided, and the biological waterproof glue of lifelong waterproof (with the same life-span of buildings) with the trouble of avoiding construction surface to keep in repair every year, is saved human and material resources and financial resources simultaneously.
Two of purpose of the present invention is to provide the preparation method of biological waterproof glue.
Three of purpose of the present invention is to provide the purposes of biological waterproof glue.
Biological waterproof glue of the present invention contains following component, in weight part:
Glutinous rice 1.5～43
Ethene-vinyl acetate (VAE) emulsion 13～70
Dioctyl phthalate (DOP) 0～8
Tung oil 0～6.5
In biological waterproof glue, can further add in sanitas, polyethers, filler, the dispersion agent raw material one or more.
Add sanitas 0.05～0.2 weight part in the described biological waterproof glue.
Add polyethers 0.5～6 weight part in the described biological waterproof glue.
Add filler 0～20 weight part in the described biological waterproof glue.
Add dispersion agent 0.1.～0.3 weight part in the described biological waterproof glue.
Described sanitas is benzoglyoxaline Urethylane, 2-n-octyl-4 isothiazolines-3-ketone or their mixture etc.
Described filler is selected from one or more in 150～1200 purpose porcelain powder, talcum powder, dry powder, light calcium carbonate, kaolin, cement, the zinc sulfide white.
Described dispersion agent is polycarboxylate (producing as the Beijing Chemical Research Institute), polyacrylic acid sodium salt (producing as Tianjin chemical research institute) or their mixture etc.
Biological waterproof glue of the present invention is nontoxic, tasteless, do not fire, pollution-free, no burn into does not have any injury to human body, main raw material glutinous rice is taken from the Nature, have: waterproof, ageing-resistant, have good cohesiveness and a watertightness, and mortar, cement and concrete substrate all there are the stronger ability of sticking, good bonding strength are arranged again with materials such as Polyurethane, pitches.Biological waterproof glue of the present invention is not only directly constructed and is had waterproof, leak preventing effect in building dignity layer, and at former waterproof material, doing finish coat on the leakproofing material basis also has excellent waterproof, leak preventing effect.Biological waterproof glue chemical property of the present invention is stable, can have good UV resistant for a long time through the gentle time condition effect of exposure, high temperature does not trickle, and low temperature has flexibility, form waterproof layer after waterproof respond well.Biological waterproof glue of the present invention is the coating strength height not only, and good springiness has higher elongation at break and good anti-vibration, anti-basal plane deformability, but also have alkali corrosion resistance ability preferably.
The preparation method of biological waterproof glue of the present invention is:
Glutinous rice, water are put into reactor and stirred, progressively heat up and boil, temperature can rise to 100 ℃, stirs into paste, adds the VAE emulsion when cooling to normal temperature (general 25 ℃～35 ℃), stirs, and filters at last, obtains biological waterproof glue.
Or
Glutinous rice, water put into further to add when reactor stirs after polyvinyl alcohol boils dissolving, stir into paste, add the VAE emulsion when cooling to normal temperature (general 25 ℃～35 ℃), stir, filter at last, obtain biological waterproof glue; Or when adding the VAE emulsion, further add one or more raw materials in dioctyl phthalate (DOP), tung oil, acrylic acid emulsion, natural rubber powder, sanitas, polyethers, filler, the dispersion agent raw material again, stir, filter at last, obtain biological waterproof glue.
Or
Glutinous rice, water are put into reactor and stirred, progressively heat up and boil, temperature can rise to 100 ℃, stir into paste, add the VAE emulsion when cooling to normal temperature (general 25 ℃～35 ℃), stir, further add one or more raw materials in dioctyl phthalate (DOP), tung oil, acrylic acid emulsion, natural rubber powder, sanitas, polyethers, filler, the dispersion agent raw material again, stir, filter at last, obtain biological waterproof glue.
Can add defoamer in the biological waterproof glue of the present invention, the add-on of general defoamer is 1/1000th～3 of a biological waterproof glue weight.
Described defoamer is saturated alcohol, lipid acid, tributyl phosphate, higher fatty acid metallic soap, sulphonated oil or organosilicon wet goods.
Biological waterproof glue of the present invention can be used for the waterproof of cement roof, external wall waterproof, toilet warterproof, basement waterproofing protection against the tide within doors; Be used for waterproofing wood, protection against the tide, anticorrosion; Be used for anti-corrosion of metal; Be used for the repairing of ointment, pitch, cement top-crack, and as the cakingagent of pottery, glass, plastics etc.
Principle of the present invention is to utilize biological waterproof glue and cement mixing modification, and the embodiment of its function is finished in two steps.
It is the forming process of the hydration process and the latex film of cement.The film forming process of biological waterproof glue is called coalescent usually.When mixing mutually with fresh cement and mortar or concrete, biological waterproof glue is evenly dispersed in the middle of the cement, in the biological waterproof glue of this cement, because the hydration of cement little by little forms cement gel, along with the continuation development of this gel structure and the evaporation gradually of water, latex particle also begins to accumulate in the pore of cement gel structure, and makes its sealing, stop the too fast evaporation of moisture content, promote cement---the carrying out of hydration process.When the evaporation of hydrated cementitious and water is proceeded; water in the pore reduces more; thereby make latex particle at cement gel with do not condense into a successive dense layer on the surface of aquation granular mixture; at last; when the complete aquation of cement; intensive latex particle will form continuous thin film on hydrated cement, they have constituted an integral body of melting altogether.The porosity and the pore volume that show a biological waterproof glue modified cement mortar by experiment are different from unmodified cement plaster, the former radius is less greater than the number in 0.2 micron hole, and radius is less than the number showed increased in 0.002 micron hole, and latter's radius accounts for many greater than the number in 0.2 micron hole.Along with the increase and the cement mixing of biological waterproof glue amount, this big number of perforations will reduce more, and the micropore number increases.In other words, owing to the sealing effect that the formation of biological waterproof glue film produces, make resistant to water penetration, the resistance to acids and bases of cement of modification get and improve.On the other hand, because latex has snappiness, particularly biological waterproof latex has permanent softness, in addition some active genes of biological waterproof glue can with water metal ion generation Chemical bond in cement, therefore biological waterproof glue modified cement is greatly improved in wear resistance, shock-resistance, freeze-thaw resistance, crack resistance etc., has also improved the bending resistance curvature and the tensile strength of cement simultaneously.
1. biological waterproof glue is used for mortar and mixes
Biological waterproof glue is used for silt particle slurry or concrete modifying.The inventor has done theory narrative in front, is described further with some test results here.
(1) water yield of minimizing mortar
Biological waterproof glue mixes the many performances that can improve mortar in sand-cement slurry.These performances are relevant with the biological waterproof glue of adding, and from performance and economic comprehensive viewpoint, 20～40% of biological waterproof glue weight by mass of cement is advisable.
Sand-cement slurry must have enough water to make cement carry out aquation, the enough intensity of final acquisition, otherwise intensity will reduce, can reduce water consumption if biological waterproof glue just mixed with sand-cement slurry, and can obtain fine and close hardening thing, the shrinking percentage and the water-absorbent of sand-cement slurry are descended, increased the processing intensity of sand-cement slurry simultaneously.
(2) improve mortar fragility
Pure sand-cement slurry process of setting mainly is the hydration by Calucium Silicate powder and calcium hydroxide, these materials are hard and crisp, therefore the impact capacity of this cement products is very little, and when add biological waterproof glue in sand-cement slurry after, the biological waterproof glue that fills up the cement space can absorb extraneous vibration force.Thereby making the impact resistance of biological waterproof glue mortar to be improved, Fig. 1 has shown the shock-resistance (the biological waterproof glue of embodiment 1) of the mortar that contains biological waterproof glue.
(3) many base mateirals there is good bonding force (the biological waterproof glue of embodiment 1).
The plain cement mortar does not have bonding strength to timber, metal, plastics etc., if add biological waterproof glue good bonding force is just arranged, and sees the following form:
| Base mateiral | Mortar bonding strength (kg/cm 2 | Measuring method | |
| Biological waterproof glue/the cement (weight)=0.1 of biological waterproof glue mortar | The sharp sand slurry | ||
| Mortar | 15.0 | 11.0 | Flexural strength |
| Iron | 7.5 | 0.6 | Tensile strength |
| Rigid polyvinyl chloride | 6.5 | 0.7 | Tensile strength |
| Layer plank | 5.0 | 0.6 | Tensile strength |
| Aluminium | 0.7 | 0 | Tensile strength |
| Glass | 3.0 | 0.2 | Tensile strength |
| Fibre reinforced plastics | 3.5 | 0.2 | Tensile strength |
(4) province dries and covers the maintenance operation
Pure sand-cement slurry should prevent that the too fast ease of moisture from losing in the process of hardening, need spray water when mortar is built the back maintenance usually or with moistening straw bag covering mortar, and biological waterproof glue mortar just can save this procedure.
2. biological waterproof glue is used for the repairing of old concrete layer
On old concrete, cover new concrete or mortar, if old concrete is not carried out unskilled workman's processing, just be difficult to make new-old concrete or mortar to merge well, because the moisture of newly pouring into a mould in the mortar is absorbed in the porous surface of old concrete very soon, produce stress in bending to such an extent as to mortar can't harden, the final generation peeled off.If adopt biological waterproof glue mortar to build the old concrete layer, then effect is made a world of difference, and biological waterproof glue can be penetrated in the concrete surface, and involves in concrete structure formation mechanics.Simultaneously, formed uniform film can prevent the evaporation and the absorption of moisture, and mortar is hardened, thereby impels new-old concrete to merge well.
Biological waterproof glue of the present invention has following outstanding advantage:
1. to dissimilar buildingss,, increase firmness at the biological waterproof glue of external coating, never delamination, the crack is not aging.
2. be used for waterproofing work, only need once construction, lifelong waterproof.
3. have good physicals, shrinking percentage is low and have a waterproof ageing resistance, resistant to chemical media and good heat-resistant etc.
It is strong that biological waterproof glue of the present invention has weathering resistance, anti-water infiltration and resistance to acids and bases excellence, and bonding force is strong, the tensile strength height, elongation at break is big, environmental protection, construction is simple, and the duration is short, and at facade, construction is not trickled on inclined-plane and the end face.Have respiratory function after the film forming, do not play advantages such as drum.
Description of drawings
Fig. 1. the embodiment of the invention 1 is mixed with the shock-resistance graphic representation of the mortar of biological waterproof glue.
Embodiment
Embodiment 1.
40 kilograms in water, 5 kilograms in glutinous rice, 6.5 kilograms of polyvinyl alcohol, 0.5 kilogram of dioctyl phthalate (DOP), 48 kilograms of ethene-vinyl acetate emulsions.
Glutinous rice, water are put into reactor and stirred, after the adding polyvinyl alcohol boils dissolving, stir into paste, add the ethene-vinyl acetate emulsion when cooling to normal temperature, stir, filter at last, obtain biological waterproof glue.
Biological waterproof glue of the present invention can be used for waterproofing wood, protection against the tide, anticorrosion; To anti-corrosion of metal; And be used for the cakingagent of pottery, glass, plastics.
Embodiment 2.
16 kilograms in water, 1.5 kilograms in glutinous rice, 35 kilograms of acrylic acid emulsions, 7 kilograms of dioctyl phthalate (DOP)s, 15 kilograms of light calcium carbonates, 1.3 kilograms of polyvinyl alcohol, 24.2 kilograms of ethene-vinyl acetate emulsions.
Glutinous rice, water are put into reactor and stirred, after the adding polyvinyl alcohol boils dissolving, stir into paste, add ethene-vinyl acetate emulsion, dioctyl phthalate (DOP), acrylic acid emulsion and light calcium carbonate raw material when cooling to normal temperature, high-speed stirring is even, filters at last, obtains biological waterproof glue.
Biological waterproof glue of the present invention can be used for the waterproof of cement roof, external wall waterproof, toilet warterproof, basement waterproofing protection against the tide within doors; Be used for waterproofing wood, protection against the tide, anticorrosion; Be used for the repairing of ointment, pitch, cement top-crack etc.
Embodiment 3.
40 kilograms in water, 5 kilograms in glutinous rice, 6.5 kilograms of polyvinyl alcohol, 0.5 kilogram of dioctyl phthalate (DOP), 35 kilograms in natural rubber powder, 13 kilograms of ethene-vinyl acetate emulsions.
Glutinous rice, water are put into reactor and stirred, after the adding polyvinyl alcohol boils dissolving, stir and to obtain paste in about 5 hours, add the natural rubber powder when cooling to 30 ℃ of left and right sides, high-speed stirring was disperseed about 30 minutes, added ethene-vinyl acetate emulsion, dioctyl phthalate (DOP) subsequently, and high-speed stirring is even, filter at last, obtain biological waterproof glue.
Biological waterproof glue of the present invention can be used for the waterproof of cement roof, external wall waterproof, toilet warterproof, basement waterproofing protection against the tide within doors etc.
Embodiment 4.
22 kilograms in water, 43 kilograms in glutinous rice, 0.2 kilogram of benzoglyoxaline Urethylane, 6.5 kilograms of tung oil, 11.86 kilograms of 320 order talcum powder, 2.94 kilograms of 320 order light calcium carbonates, 0.5 kilogram of polycarboxylate, 13 kilograms of ethene-vinyl acetate emulsions.
Glutinous rice is put into water soak and to put into reactor after about 8 hours and stir, progressively heat up and boil, subsequent grinding cools to 25 ℃ after becoming paste, add tung oil, the ethene-vinyl acetate emulsion, polycarboxylate stirs, add 320 order talcum powder again, 320 order light calcium carbonates, the benzoglyoxaline Urethylane, high-speed stirring is even, filter at last, obtain biological waterproof glue.
This biological waterproof glue can be used for the waterproof of cement roof, external wall waterproof, toilet warterproof, basement waterproofing protection against the tide within doors; Be used for waterproofing wood, protection against the tide, anticorrosion; Be used for anti-corrosion of metal; Be used for the repairing of ointment, pitch, cement top-crack etc.
22 kilograms in water, 39 kilograms in glutinous rice, 0.2 kilogram of 2-n-octyl-4 isothiazolines-3-ketone, 5 kilograms of tung oil, 5 kilograms of talcum powder, 10 kilograms of light calcium carbonates, 4 kilograms of dry powders, 0.5 kilogram of polyacrylic acid sodium salt, 14.3 kilograms of ethene-vinyl acetate emulsions.
Glutinous rice is put into water soak and to put into reactor after about 10 hours and stir, progressively heat up and boil, cool to 25 ℃ after grinding to form paste with mill subsequently, add 2-n-octyl-4 isothiazolines-3-ketone, tung oil, talcum powder, light calcium carbonate, dry powder, polyacrylic acid sodium salt, the ethene-vinyl acetate emulsion, high-speed stirring is even, grind at last and filter, obtain biological waterproof glue.
This biological waterproof glue can be used for cement roof, bridge than repairing of large fracture etc.
Embodiment 6.
22.4 kilograms in water, 4 kilograms in glutinous rice, 3 kilograms of polyvinyl alcohol, 1 kilogram of dioctyl phthalate (DOP), 0.05 kilogram of 2-n-octyl-4 isothiazolines-3-ketone, 69.55 kilograms of ethene-vinyl acetate emulsions.
Glutinous rice, polyvinyl alcohol are put into the water immersion put into reactor after about 8 hours, after boiling dissolving, adding stirs into paste, add ethene-vinyl acetate emulsion, dioctyl phthalate (DOP), 2-n-octyl-4 isothiazolines-3-ketone when cooling to 30 ℃ while stirring, high-speed stirring is even, filter at last, obtain biological waterproof glue.
The organic silicone oil that can add 0.1 kilogram in biological waterproof glue can be used for the repairing of cement roof, pavement crack etc.
Embodiment 7.
40 kilograms in water, 20 kilograms in glutinous rice, 40 kilograms of ethene-vinyl acetate emulsions.
Glutinous rice, water are put into reactor and stirred, progressively be warming up to 100 ℃ and boil, stir into paste, add the ethene-vinyl acetate emulsion when cooling to 30 ℃, stir, filter at last, obtain biological waterproof glue.
This biological waterproof glue can be used for the waterproof of cement roof, external wall waterproof, toilet warterproof, basement waterproofing protection against the tide within doors etc.
Embodiment 8.
25 kilograms in water, 40 kilograms in glutinous rice, 0.15 kilogram of 2-n-octyl-4 isothiazolines-3-ketone, 5 kilograms of tung oil, 0.05 kilogram of benzoglyoxaline Urethylane, 29.8 kilograms of ethene-vinyl acetate emulsions.
Glutinous rice is put into water to be soaked and to put into reactor after about 10 hours and stir, progressively heat up and boil, cool to 25 ℃ after grinding to form paste with mill subsequently, add 2-n-octyl-4 isothiazolines-3-ketone, benzoglyoxaline Urethylane, tung oil, the ethene-vinyl acetate emulsion, high-speed stirring is even, grinds at last and filters, and obtains biological waterproof glue.
This biological waterproof glue can be painted on timber or metallic surface, is used for waterproofing wood, protection against the tide, anticorrosion; And to anti-corrosion of metal etc.
Claims (6)
1. biological waterproof glue, it is characterized in that: described biological waterproof glue contains following component, in weight part:
Glutinous rice 1.5～43
Water 10～40
Ethene-vinyl acetate emulsion 13～70
Dioctyl phthalate (DOP) 0～8
Polyvinyl alcohol 0～6.5
Tung oil 0～6.5
Acrylic acid emulsion 0～35
Natural rubber powder 0～35.
2. biological waterproof glue according to claim 1 is characterized in that: one or more in the described biological waterproof glue in further adding sanitas, polyethers, filler, the dispersion agent raw material; Wherein:
Add sanitas 0.05～0.2 weight part, add polyethers 0.5～6 weight part, add filler 0～20 weight part, add dispersion agent 0.1.～0.3 weight part.
3. biological waterproof glue according to claim 2 is characterized in that: described sanitas is benzoglyoxaline Urethylane, 2-n-octyl-4 isothiazolines-3-ketone or their mixture.
4. biological waterproof glue according to claim 2 is characterized in that: described filler is selected from one or more in 150～1200 purpose porcelain powder, talcum powder, dry powder, light calcium carbonate, kaolin, cement, the zinc sulfide white.
5. biological waterproof glue according to claim 2 is characterized in that: described dispersion agent is polycarboxylate, polyacrylic acid sodium salt or their mixture.
6. purposes according to each described biological waterproof glue of claim 1～5, it is characterized in that: described biological waterproof glue is used for the waterproof of roofing, external wall waterproof, toilet warterproof, basement waterproofing protection against the tide within doors; Be used for waterproofing wood, protection against the tide, anticorrosion; Be used for anti-corrosion of metal; Be used for the repairing of ointment, pitch, cement top-crack, and be used as the cakingagent of pottery, glass, plastics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410009391 CN1727424A (en) | 2004-07-30 | 2004-07-30 | Biologic waterproof glue and usage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410009391 CN1727424A (en) | 2004-07-30 | 2004-07-30 | Biologic waterproof glue and usage |
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| Publication Number | Publication Date |
|---|---|
| CN1727424A true CN1727424A (en) | 2006-02-01 |
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|---|---|---|---|
| CN 200410009391 Pending CN1727424A (en) | 2004-07-30 | 2004-07-30 | Biologic waterproof glue and usage |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101058701B (en) * | 2007-05-30 | 2010-05-26 | 陈峰磊 | Water soluble adhesive |
| CN101851475A (en) * | 2010-05-25 | 2010-10-06 | 江苏黑松林粘合剂厂有限公司 | Preparation method of energy-saving, environment-protecting and sag-resistant water-based instant adhesive |
| CN101880512A (en) * | 2010-07-14 | 2010-11-10 | 浙江德尚化工科技有限公司 | Aqueous binding agent and preparation method thereof |
| CN102464951A (en) * | 2010-11-10 | 2012-05-23 | 北京祝邦新技术研究所 | Back coating glue |
| CN102911569A (en) * | 2012-11-07 | 2013-02-06 | 高玉纯 | Waterproof paint |
| CN104130631A (en) * | 2014-07-30 | 2014-11-05 | 开平市日固力涂料有限公司 | Transparent waterproof coating |
| CN105131342A (en) * | 2015-10-27 | 2015-12-09 | 宜昌固德立建材有限公司 | Plant macro-molecule emulsion and waterproof coating |
| CN105175792A (en) * | 2015-10-27 | 2015-12-23 | 宜昌固德立建材有限公司 | Plant macromolecule emulsion and strike-off paint |
| CN105176207A (en) * | 2015-10-27 | 2015-12-23 | 宜昌固德立建材有限公司 | Plant macromolecule emulsion and water paint |
| CN106147649A (en) * | 2016-06-28 | 2016-11-23 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
| CN106978021A (en) * | 2016-01-19 | 2017-07-25 | 上海中海龙高新技术研究院 | A kind of roof water-proof paint |
| CN107903873A (en) * | 2017-12-13 | 2018-04-13 | 陕西省交通建设集团公司 | A kind of environmental-friendly plant cleft weld material and production technology |
| CN108641630A (en) * | 2018-06-11 | 2018-10-12 | 阜南县中信柳木工艺品有限公司 | A kind of wood artwork adhesive of the powder containing Jack-fruit seeds and preparation method thereof |
-
2004
- 2004-07-30 CN CN 200410009391 patent/CN1727424A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101058701B (en) * | 2007-05-30 | 2010-05-26 | 陈峰磊 | Water soluble adhesive |
| CN101851475A (en) * | 2010-05-25 | 2010-10-06 | 江苏黑松林粘合剂厂有限公司 | Preparation method of energy-saving, environment-protecting and sag-resistant water-based instant adhesive |
| CN101851475B (en) * | 2010-05-25 | 2011-09-21 | 江苏黑松林粘合剂厂有限公司 | Preparation method of energy-saving, environment-protecting and sag-resistant water-based instant adhesive |
| CN101880512A (en) * | 2010-07-14 | 2010-11-10 | 浙江德尚化工科技有限公司 | Aqueous binding agent and preparation method thereof |
| CN102464951A (en) * | 2010-11-10 | 2012-05-23 | 北京祝邦新技术研究所 | Back coating glue |
| CN102911569A (en) * | 2012-11-07 | 2013-02-06 | 高玉纯 | Waterproof paint |
| CN102911569B (en) * | 2012-11-07 | 2015-05-06 | 姜晓强 | Waterproof paint |
| CN104130631A (en) * | 2014-07-30 | 2014-11-05 | 开平市日固力涂料有限公司 | Transparent waterproof coating |
| CN105131342A (en) * | 2015-10-27 | 2015-12-09 | 宜昌固德立建材有限公司 | Plant macro-molecule emulsion and waterproof coating |
| CN105175792A (en) * | 2015-10-27 | 2015-12-23 | 宜昌固德立建材有限公司 | Plant macromolecule emulsion and strike-off paint |
| CN105176207A (en) * | 2015-10-27 | 2015-12-23 | 宜昌固德立建材有限公司 | Plant macromolecule emulsion and water paint |
| CN106978021A (en) * | 2016-01-19 | 2017-07-25 | 上海中海龙高新技术研究院 | A kind of roof water-proof paint |
| CN106147649A (en) * | 2016-06-28 | 2016-11-23 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
| CN106147649B (en) * | 2016-06-28 | 2018-06-22 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
| CN107903873A (en) * | 2017-12-13 | 2018-04-13 | 陕西省交通建设集团公司 | A kind of environmental-friendly plant cleft weld material and production technology |
| CN108641630A (en) * | 2018-06-11 | 2018-10-12 | 阜南县中信柳木工艺品有限公司 | A kind of wood artwork adhesive of the powder containing Jack-fruit seeds and preparation method thereof |
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