CN103555036A - Silver ion anti-bacterial glue and preparation method thereof - Google Patents
Silver ion anti-bacterial glue and preparation method thereof Download PDFInfo
- Publication number
- CN103555036A CN103555036A CN201310471325.3A CN201310471325A CN103555036A CN 103555036 A CN103555036 A CN 103555036A CN 201310471325 A CN201310471325 A CN 201310471325A CN 103555036 A CN103555036 A CN 103555036A
- Authority
- CN
- China
- Prior art keywords
- silver
- glue
- silver ion
- ion antibiotic
- bacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention belongs to the field of chemical technology, and discloses silver ion anti-bacterial glue. The silver ion anti-bacterial glue comprises the following raw materials by weight: 30-50 parts of hydroxypropyl methyl cellulose, 30-60 parts of polyvinyl alcohol, 10-30 parts of redispersible latex powder, 3-5 parts of plant soybean glue, 0.1-0.5 part of a thickener and 0.5-5 parts of a silver ion anti-bacterial additive. A preparation method of the silver ion anti-bacterial glue comprises the following steps of (1) firstly weighing hydroxypropyl methyl cellulose, polyvinyl alcohol, the redispersible latex powder, the plant soybean glue, the thickener and the silver ion anti-bacterial additive according to the above proportions; (2) putting the weighed raw materials successively into a rotary type stirring and mixing pot and mixing for 30-50 min; and (3) mixing uniformly and subpackaging to obtain the silver ion anti-bacterial glue. The silver ion anti-bacterial glue provided by the invention is advantageous in that preparation process is simple; production is convenient and fast; the preparation method is convenient for large-scale production; and raw materials are pollution-free and environment-friendly. Besides, the silver ion anti-bacterial glue has the advantages of strong bactericidal ability and durable bactericidal effect.
Description
Technical field
The present invention relates to chemical technology field, relate in particular to a kind of silver-ion antibiotic glue and preparation method thereof.
Background technology
Silver ions, we can be regarded as a kind of anti-biotic material or material, the anti-microbial effect of material, detrimentally affect and the consequence vitality of microorganism being produced at certain material in general, these detrimentally affects and consequence, the most concentrated performance is exactly to affect microbial growth, breeding so that dead.Namely suppress the effect of microbial growth, breeding or kill microorganisms.Relation between anti-biotic material and microorganism can be regarded the relation of microorganism and environment as, and particularly, to the virose environment of microorganism, the silver ion antimicrobial agent mechanism of action has the following aspects.
1, interference cell wall is synthetic.Bacteria cell wall important component is peptidoglycan, and the interference effect of silver ion antimicrobial agent to cell walls mainly suppresses that polysaccharide chain and tetrapeptide are crosslinked link, thereby makes cell walls lose integrity, lost the provide protection to osmotic pressure, infringement thalline and death.
2, can damaging cells film.Cytolemma is the important integral part of bacterial cell vital movement.Therefore,, as damaged membrane wound, destruction, will cause bacterium dead.
3, arrestin matter is synthetic.The building-up process of protein changes, stops, making bacterium dead.
4, interfere RNA is synthetic.Be in a word to hinder copying of genetic information, comprise the synthetic of DNA, RNA, and DNA profiling transcript mRNA etc.
Because silver has adsorption to the microorganism in liquid, after microorganism is adsorbed by silver, play respiratory enzyme and just lose effect, microorganism will be dead rapidly.The sterilizing ability of silver ions is strong especially, in every premium on currency, as long as contain the silver ions of 2/1sts milligrams, can kill most of bacterium in water.The U.S. one scientist once did overtesting, and he is by 4.5 liters of sewage (every milliliter containing more than 7,000 of intestinal bacteria) after the silver electrodes of 3 hours are processed, and all intestinal bacteria are all dead.Typhoid fever bacterium can only live 18 hours on silver strip, and diphtheria bacterium can only live 3 days on silver strip.
Very strong just because of silver-colored sterilizing ability, again to people and animals without any injury, at present, the airline that surpasses in the world half has been used the water strainer of silvery.The swimming pool of many countries also purifies with silver, and the water after purification can not stimulate swimmer's eyes and skin as the water that uses pharmaceutical chemicals to purify, and silver ion antimicrobial agent is also applied on weaving face fabric.
Silver ions is also widely applied in the paint series products such as emulsion paint at present, reaches the effect of sterilization, mildew-resistant, but mostly antibacterial effect is poor for silver ion glue series products in the market, can only solve sterilization, the mildew-proof function of covering epidermis, surface; Can not solve substantive sterilization, mildew-resistant and permanent sterilization, the anti-mold effect of interior substrate.
Summary of the invention
For solve existing silver ion glue series products mostly antibacterial effect poor, can not profound sterilization and the shortcoming of persistence sterilization, the present invention proposes a kind of silver-ion antibiotic glue and preparation method thereof.
In order to solve above technical problem, the technical scheme that the present invention takes is:
Silver-ion antibiotic glue of the present invention is comprised of the raw material of following weight part:
Vltra tears 30-50
Polyvinyl alcohol 30-60
Redispersable latex powder 10-30
Plant bean gum 3-5
Thickening material 0.1-0.5
Silver-ion antibiotic additive 0.5-5.
Preferred:
Vltra tears 35-45
Polyvinyl alcohol 35-55
Redispersable latex powder 15-25
Plant bean gum 4-5
Thickening material 0.2-0.5
Silver-ion antibiotic additive 0.8-5.
More preferably:
Vltra tears 40-45
Polyvinyl alcohol 40-50
Redispersable latex powder 20-25
Plant bean gum 4-5
Thickening material 0.2-0.4
Silver-ion antibiotic additive 1-5.
Thickening material is sodium alginate.
Silver-ion antibiotic additive is nano-silver ionic.
The preparation method of silver-ion antibiotic glue of the present invention comprises the following steps:
(1) first by proportioning, take Vltra tears, polyvinyl alcohol, redispersable latex powder, plant bean gum, thickening material and silver-ion antibiotic additive;
(2) then the raw material taking is put into successively to rotary being uniformly mixed in pot, mixed 30-50min;
(3), after mixing, carry out packing and can obtain silver-ion antibiotic glue.
Positively effect of the present invention is as follows:
Silver-ion antibiotic glue of the present invention have preparation technology simple, convenient for production quick, be convenient to scale operation, and raw material is pollution-free, environmental protection, and the silver-ion antibiotic glue prepared of the present invention to have sterilizing ability strong, the advantage that sterilization effect is lasting.
Embodiment
The following examples are to describe in further detail of the present invention.
Embodiment 1
1.1 raw materials form (Kg)
Vltra tears 30
Polyvinyl alcohol 30
Redispersable latex powder 10
Plant bean gum 3
Sodium alginate 0.1
Silver-ion antibiotic additive 0.5.
1.2 preparation method
(1) first by proportioning, take Vltra tears, polyvinyl alcohol, redispersable latex powder, plant bean gum, sodium alginate and silver-ion antibiotic additive;
(2) then the raw material taking is put into successively to rotary being uniformly mixed in pot, mixed 30-50min;
(3), after mixing, carry out packing and can obtain silver-ion antibiotic glue.
Embodiment 2
2.1 raw materials form (Kg)
Vltra tears 50
Polyvinyl alcohol 60
Redispersable latex powder 30
Plant bean gum 5
Sodium alginate 0.5
Silver-ion antibiotic additive 2.
2.2 preparation method
Preparation method is with 1.2 of embodiment 1.
Embodiment 3
3.1 raw materials form (Kg)
Vltra tears 40
Polyvinyl alcohol 45
Redispersable latex powder 20
Plant bean gum 4
Sodium alginate 0.3
Silver-ion antibiotic additive 2.5.
3.2 preparation method
Preparation method is with 1.2 of embodiment 1.
Embodiment 4
4.1 raw materials form (Kg)
Vltra tears 35
Polyvinyl alcohol 35
Redispersable latex powder 15
Plant bean gum 4
Sodium alginate 0.2
Silver-ion antibiotic additive 0.8.
4.2 preparation method
Preparation method is with 1.2 of embodiment 1.
Embodiment 5
5.1 raw materials form (Kg)
Vltra tears 45
Polyvinyl alcohol 55
Redispersable latex powder 25
Plant bean gum 5
Sodium alginate 0.5
Silver-ion antibiotic additive 5.
5.2 preparation method
Preparation method is with 1.2 of embodiment 1.
Embodiment 6
6.1 raw materials form (Kg)
Vltra tears 40
Polyvinyl alcohol 40
Redispersable latex powder 20
Plant bean gum 4
Sodium alginate 0.2
Silver-ion antibiotic additive 1.
6.2 preparation method
Preparation method is with 1.2 of embodiment 1.
Embodiment 7
7.1 raw materials form (Kg)
Vltra tears 45
Polyvinyl alcohol 50
Redispersable latex powder 25
Plant bean gum 5
Sodium alginate 0.4
Silver-ion antibiotic additive 2.
7.2 preparation method
Preparation method is with 1.2 of embodiment 1.
Embodiment 8
On silver ion glue prepared by embodiment of the present invention 1-7 and market, existing silver ion glue is applied in building surface, and carries out sterilization effect mensuration, and result is as shown in table 1.
The bactericidal property of silver ion glue prepared by table 1 the present invention
| ? | 48h surface disinfection rate (%) | The inner 1m place's sterilizing rate (%) of 48h | 30d surface disinfection rate (%) | The inner 1m place's sterilizing rate (%) of 30d |
| Embodiment 1 sample | 98 | 87 | 90 | 89 |
| Embodiment 2 samples | 98 | 88 | 91 | 87 |
| Embodiment 3 samples | 100 | 97 | 96 | 94 |
| Embodiment 4 samples | 99 | 93 | 90 | 88 |
| Embodiment 5 samples | 99 | 92 | 92 | 92 |
| Embodiment 6 samples | 99 | 94 | 93 | 91 |
| Embodiment 7 samples | 98 | 90 | 92 | 89 |
| Commercially available sample | 98 | 80 | 88 | 50 |
It is strong that the silver ion glue that as can be seen from Table 1 prepared by the present invention has sterilizing ability, the advantage that sterilization effect is lasting.
Although illustrated and described embodiments of the invention, for the ordinary skill in the art, be appreciated that without departing from the principles and spirit of the present invention and can carry out multiple variation, modification, replacement and modification to these embodiment, scope of the present invention is limited by claims and equivalent thereof.
Claims (6)
1. a silver-ion antibiotic glue, is characterized in that: this silver-ion antibiotic glue is comprised of the raw material of following weight part:
Vltra tears 30-50
Polyvinyl alcohol 30-60
Redispersable latex powder 10-30
Plant bean gum 3-5
Thickening material 0.1-0.5
Silver-ion antibiotic additive 0.5-5.
2. silver-ion antibiotic glue as claimed in claim 1, is characterized in that: this silver-ion antibiotic glue is comprised of the raw material of following weight part:
Vltra tears 35-45
Polyvinyl alcohol 35-55
Redispersable latex powder 15-25
Plant bean gum 4-5
Thickening material 0.2-0.5
Silver-ion antibiotic additive 0.8-5.
3. silver-ion antibiotic glue as claimed in claim 1, is characterized in that: this silver-ion antibiotic glue is comprised of the raw material of following weight part:
Vltra tears 40-45
Polyvinyl alcohol 40-50
Redispersable latex powder 20-25
Plant bean gum 4-5
Thickening material 0.2-0.4
Silver-ion antibiotic additive 1-5.
4. the silver-ion antibiotic glue as described in claim 1-3 any one, is characterized in that: thickening material is sodium alginate.
5. the silver-ion antibiotic glue as described in claim 1-3 any one, is characterized in that: silver-ion antibiotic additive is nano-silver ionic.
6. a method of preparing the silver-ion antibiotic glue as described in claim 1-5 any one, is characterized in that: the method comprises the following steps:
(1) first by proportioning, take Vltra tears, polyvinyl alcohol, redispersable latex powder, plant bean gum, thickening material and silver-ion antibiotic additive;
(2) then the raw material taking is put into successively to rotary being uniformly mixed in pot, mixed 30-50min;
(3), after mixing, carry out packing and can obtain silver-ion antibiotic glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310471325.3A CN103555036B (en) | 2013-10-11 | 2013-10-11 | A kind of Silver ion anti-bacterial glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310471325.3A CN103555036B (en) | 2013-10-11 | 2013-10-11 | A kind of Silver ion anti-bacterial glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103555036A true CN103555036A (en) | 2014-02-05 |
| CN103555036B CN103555036B (en) | 2016-03-02 |
Family
ID=50009410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310471325.3A Active CN103555036B (en) | 2013-10-11 | 2013-10-11 | A kind of Silver ion anti-bacterial glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103555036B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105623165A (en) * | 2015-12-24 | 2016-06-01 | 陕西省万安药业有限公司 | Antibacterial silver ion reagent for gynecological medical mat and preparation method of antibacterial silver ion reagent |
| CN108395756A (en) * | 2018-03-07 | 2018-08-14 | 湖州光博生物科技有限公司 | A kind of nanometer silver antimicrobial glue and preparation method thereof |
| CN109432125B (en) * | 2018-12-04 | 2021-08-31 | 吕梁学院 | Nano-silver antibacterial adhesive, preparation method thereof and intelligent detection system |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1616559A (en) * | 2004-09-24 | 2005-05-18 | 深圳清华大学研究院 | Nano metal silver antibiotic paint and its preparing method |
| CN1632027A (en) * | 2004-11-16 | 2005-06-29 | 张国栋 | Aldehyde-free water soluble adhesive |
| CN101058701A (en) * | 2007-05-30 | 2007-10-24 | 陈峰磊 | Water soluble adhesive |
| JP2008063439A (en) * | 2006-09-07 | 2008-03-21 | Sk Kaken Co Ltd | Coating composition |
| CN102698313A (en) * | 2012-01-11 | 2012-10-03 | 北京大学 | Nano-silver antibacterial hydrogel and preparation method thereof |
-
2013
- 2013-10-11 CN CN201310471325.3A patent/CN103555036B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1616559A (en) * | 2004-09-24 | 2005-05-18 | 深圳清华大学研究院 | Nano metal silver antibiotic paint and its preparing method |
| CN1632027A (en) * | 2004-11-16 | 2005-06-29 | 张国栋 | Aldehyde-free water soluble adhesive |
| JP2008063439A (en) * | 2006-09-07 | 2008-03-21 | Sk Kaken Co Ltd | Coating composition |
| CN101058701A (en) * | 2007-05-30 | 2007-10-24 | 陈峰磊 | Water soluble adhesive |
| CN102698313A (en) * | 2012-01-11 | 2012-10-03 | 北京大学 | Nano-silver antibacterial hydrogel and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 刘登良主编: "《涂料工艺（第四版）》", 31 December 2009, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105623165A (en) * | 2015-12-24 | 2016-06-01 | 陕西省万安药业有限公司 | Antibacterial silver ion reagent for gynecological medical mat and preparation method of antibacterial silver ion reagent |
| CN108395756A (en) * | 2018-03-07 | 2018-08-14 | 湖州光博生物科技有限公司 | A kind of nanometer silver antimicrobial glue and preparation method thereof |
| CN108395756B (en) * | 2018-03-07 | 2020-08-18 | 济南豪瑞生物技术有限公司 | Nano-silver antibacterial adhesive and preparation method thereof |
| CN109432125B (en) * | 2018-12-04 | 2021-08-31 | 吕梁学院 | Nano-silver antibacterial adhesive, preparation method thereof and intelligent detection system |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103555036B (en) | 2016-03-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100360036C (en) | Preparation method of chitin/metal copper composite antibactericidal agent | |
| CN100360035C (en) | Preparation method of chitin/zinc compound bactericide | |
| KR101114185B1 (en) | Deodorant composition and manufacturing method thereof | |
| CN103555225B (en) | A kind of preparation method of Silver ion anti-bacterial glue | |
| CN110951303A (en) | Plant antibacterial water paint capable of decomposing formaldehyde and releasing negative ions | |
| CN110624127A (en) | Dual-bacteriostatic healing-promoting liquid dressing and preparation method thereof | |
| CN103555036B (en) | A kind of Silver ion anti-bacterial glue and preparation method thereof | |
| CN107582459A (en) | A kind of preservative containing the capsule of weeping forsythia and preparation method thereof | |
| CN101402792B (en) | Polyamide composite material with function of generating negative ion, far-infrared ray or antimicrobial mildew resistant function | |
| CN104840401A (en) | Plant preservative for skincare product | |
| WO2021196111A1 (en) | Broad-spectrum antiviral bactericidal plastic and application thereof | |
| CN103145225B (en) | Botanic water purifying agent | |
| CN105010398A (en) | Preparation method of negative ion, far-infrared, and composite functional antibacterial disinfectant | |
| CN104164127A (en) | Putty cream for long-acting antibacterial negative-ion building interior wall | |
| CN107535540A (en) | A kind of antiseptic and preparation method thereof | |
| CN111820240A (en) | Antibacterial and disinfectant additive based on nano metal wires and preparation method thereof | |
| CN111567519A (en) | Preparation method of biological disinfectant containing silver ion water | |
| CN101503527B (en) | Anti-bacteria agent added to plastic water supply pipe raw material | |
| KR101934878B1 (en) | Cosmetic pack composition containing natural mineral and manufacturing method thereof | |
| CN105418799A (en) | Chitosan oligosaccharide-iodine complex as well as preparation method and application thereof | |
| CN106174814B (en) | A kind of antibacterial gloves and preparation method thereof | |
| CN104904753A (en) | Efficient disinfectant and preparation method thereof | |
| CN104351180A (en) | Microcapsule suspension for preventing and controlling rice false smut | |
| CN111226946A (en) | Bactericidal disinfectant and preparation method thereof | |
| CN105623165A (en) | Antibacterial silver ion reagent for gynecological medical mat and preparation method of antibacterial silver ion reagent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |