Colored filter dividing wall and manufacture method thereof, colored filter and manufacture method thereof
[technical field]
The present invention relates to dividing wall and manufacture method thereof, colored filter and manufacture method thereof between a kind of colored filter pixel.
[background technology]
Because LCD (Liquid Crystal Display, LCD) be the element of non-active illuminating, must see through inner backlight light source is provided, the GTG that collocation drive IC and liquid crystal control form black, white dichromatism shows, red (R), green (G), indigo plant (B) three kinds of color layers of seeing through colored filter (Color Filter) again provide form and aspect, form colored display frame, so colored filter is the key part and component of LCD colorize.
At present, the colorful optical filter preparation method of prior art mainly contains: pigment dispersion method (Pigment-dispersed Method) and ink ejecting method (Ink Jet Method).
Pigment dispersion method is that chromatic photoresist (Color Resist) is coated on the substrate in the mode that rotation applies, and is prepared into color lump (Color Area) via the mode of exposure imaging.Chromatic photoresist is that color pigment is dispersed in wherein photoresistance, has the characteristic of irradiation reaction and thermmohardening.The resistance of RGB three color coloured light must form colored filter at last through three road coatings, exposure, developing manufacture process.Pigment dispersion method is replaced by ink ejecting method gradually owing to processing procedure complexity and the high shortcoming of equipment cost.
Ink ejecting method is injected in the black matrix" on the substrate simultaneously for the ink that uses an ink discharge device and will contain the RGB color layers, and the dehydrated back of ink droplet forms painted RGB color layers pattern on this substrate.Use ink ejecting method can once form the RGB color layers, make preparation process simplify in a large number, cost significantly reduces.So ink ejecting method has the plurality of advantages of processing procedure simplification, environmental protection, conservation.
See also Fig. 1, when using ink ejecting method to make colored filter, be the not mutual colour mixture of the ink 140 that makes the RGB color layers, all be provided with the dividing wall 130 higher than conventional thickness between each pixel (Sub-Pixel), wherein dividing wall 130 macromolecular material that increases one deck at least for the black matrix material of individual layer or on black matrix material again is with as buffer action.Yet, the contact angle θ of the dividing wall material that ink 140 is traditional therewith is very little, in addition, the contact angle of ink 140 on glass substrate 110 is also very little, thereby after applying in the evaporating course, pigment is subjected to ink 140 mobile influences and concentrates toward both sides, will cause pigment situation pockety on glass substrate 110, and then influence the quality of colored filter.
In view of this, provide a kind of and colored filter pixel that the ink contact angle is big between dividing wall and manufacture method thereof, and the big colored filter of the dividing wall between a kind of colored filter pixel and ink contact angle and manufacture method thereof real be necessity.
[summary of the invention]
Below will dividing wall and manufacture method thereof between a kind of and colored filter pixel that the ink contact angle is big and dividing wall between a kind of colored filter pixel and big colored filter and the manufacture method thereof of ink contact angle be described with embodiment.
Dividing wall between a kind of colored filter pixel, wherein, the dividing wall material therefor between this colored filter pixel comprises the polysiloxane or derivatives thereof of following general formula:
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, n 〉=1, and n is an integer.
The manufacture method of the dividing wall between a kind of colored filter pixel comprises the following steps: to provide a substrate; The photoresist that will contain the polysiloxane or derivatives thereof of following general formula is coated in and forms a photoresist layer on this substrate:
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, n 〉=1, and n is an integer; The light shield that will have predetermined pattern is arranged between this photoresist layer and the light source, and this photoresist layer is exposed; This photoresist layer that develops makes a plurality of dividing walls.
The manufacture method of the dividing wall between a kind of colored filter pixel comprises the following steps: to provide a substrate; First photoresist is coated on this substrate, forms one first photoresist layer; The light shield that will have predetermined pattern is arranged between this first photoresist layer and the light source, and this first photoresist layer is exposed; Development is also solidified this first photoresist layer, makes a plurality of first dividing walls; The photoresist that will contain the polysiloxane or derivatives thereof of following general formula is coated in and forms one second photoresist layer on this substrate:
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, n 〉=1, and n is an integer; Developing and solidifying this second photoresist layer makes a plurality of second photoresist layers, thereby makes the dividing wall of overlapping combination about a plurality of first dividing walls and second dividing wall.
The manufacture method of the dividing wall between a kind of colored filter pixel comprises the following steps: to provide a substrate; First photoresist is coated on this substrate, forms one first photoresist layer; The light shield that will have predetermined pattern is arranged between this first photoresist layer and the light source, and this first photoresist layer is exposed; Development is also solidified this first photoresist layer, makes a plurality of first dividing walls; The photoresist that will contain the polysiloxane or derivatives thereof of following general formula is coated in and forms a coating material layer on this substrate and first dividing wall:
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, n 〉=1, and n is an integer; Solidify this coating material layer, thereby make the dividing wall of a plurality of first dividing walls and the combination of coating material layer.
A kind of colored filter, it comprises a plurality of pixels, is provided with dividing wall between each pixel, wherein, this dividing wall material therefor comprises the polysiloxane or derivatives thereof of following general formula:
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, n 〉=1, and n is an integer.
A kind of manufacturing method of color filters comprises the following steps: to provide a substrate; The photoresist that will contain the polysiloxane or derivatives thereof of following general formula is coated in and forms a photoresist layer on this substrate:
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, n 〉=1, and n is an integer; The light shield that will have predetermined pattern is arranged between this photoresist layer and the light source, and this photoresist layer is exposed; This photoresist layer that develops makes a plurality of dividing walls; By ink-jetting style ink is injected between this dividing wall; Solidify this ink.
A kind of manufacturing method of color filters comprises the following steps: to provide a substrate; First photoresist is coated on this substrate, forms one first photoresist layer; The light shield that will have predetermined pattern is arranged between this first photoresist layer and the light source, and this first photoresist layer is exposed; Development is also solidified this first photoresist layer, makes a plurality of first dividing walls; The photoresist that will contain the polysiloxane or derivatives thereof of following general formula is coated in and forms one second photoresist layer on this substrate:
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, n 〉=1, and n is an integer; Developing and solidifying this second photoresist layer makes a plurality of second photoresist layers, thereby makes the dividing wall of overlapping combination about a plurality of first dividing walls and second dividing wall; Ink is injected between the dividing wall of this first dividing wall and the combination of second dividing wall by ink-jetting style; Solidify this ink.
A kind of manufacturing method of color filters comprises the following steps: to provide a substrate; First photoresist is coated on this substrate, forms one first photoresist layer; The light shield that will have predetermined pattern is arranged between this first photoresist layer and the light source, and this first photoresist layer is exposed; Development is also solidified this first photoresist layer, makes a plurality of first dividing walls; The photoresist that will contain the polysiloxane or derivatives thereof of following general formula is coated on this substrate and first dividing wall, forms a coating material layer:
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, n 〉=1, and n is an integer; Solidify this coating material layer, thereby make the dividing wall of a plurality of first dividing walls and the combination of coating material layer; Ink is injected between the dividing wall of this first dividing wall and the combination of coating material layer by ink-jetting style; Solidify this ink.
Compared with prior art, dividing wall between the colored filter pixel that the polysiloxane or derivatives thereof that utilizes above-mentioned general formula to represent is made and the contact angle between the ink are greatly improved, reduced the flow effect of ink when evaporation simultaneously, thereby the distribution of pigment on substrate is also more even, has improved the quality of colored filter.
[description of drawings]
Fig. 1 is the synoptic diagram of pixel cell of the colored filter of prior art.
Fig. 2 (a) to (c) is the manufacture method first embodiment schematic flow sheet of the dividing wall between colored filter pixel of the present invention.
Fig. 3 (a) to (f) is the manufacture method second embodiment schematic flow sheet of the dividing wall between colored filter pixel of the present invention.
Fig. 4 (a) to (d) is manufacture method the 3rd embodiment schematic flow sheet of the dividing wall between colored filter pixel of the present invention.
Fig. 5 (a) to (d) is the manufacturing method of color filters first embodiment schematic flow sheet of the present invention.
Fig. 6 is the synoptic diagram of the pixel cell of the manufacturing method of color filters second embodiment gained colored filter of the present invention.
Fig. 7 is the synoptic diagram of the pixel cell of manufacturing method of color filters the 3rd embodiment gained colored filter of the present invention.
[embodiment]
Dividing wall between a kind of colored filter pixel, wherein, the dividing wall material therefor between this colored filter pixel comprises the polysiloxane or derivatives thereof of following general formula:
Wherein, n 〉=1, and n is integer, R
1, R
2Represent alkyl or phenyl ring base respectively, R
3, R
4Representative comprises the organo-functional group of C, H, O or N respectively, for example: RNH
2, RNHR, ROH, RCOOH, ROR, RCOOR, NH
2, NHR, OH, COOH, OR, COOR, wherein R represents alkyl.
At this, dividing wall between the colored filter pixel can be to pile up the sandwich construction of arranging, each layer material therefor comprises in acryl resin, Polyimide, epoxy resin and the polyvinyl alcohol (PVA) one or more, and wherein one deck material therefor contains the polysiloxane or derivatives thereof that above-mentioned general formula is represented at least.
A kind of colored filter, it comprises a plurality of pixels, is provided with dividing wall between each pixel, this dividing wall material therefor comprises the polysiloxane or derivatives thereof that above-mentioned general formula is represented.At this, dividing wall on the colored filter between each pixel can be to pile up the sandwich construction of arranging, each layer material therefor comprises in acryl resin, Polyimide, epoxy resin and the polyvinyl alcohol (PVA) one or more, and wherein one deck material therefor contains the polysiloxane or derivatives thereof that above-mentioned general formula is represented at least.
See also Fig. 2, manufacture method first embodiment of the dividing wall between colored filter pixel of the present invention may further comprise the steps: a substrate 310 is provided, and this substrate 310 can be a glass substrate; The photoresist that will contain the polysiloxane or derivatives thereof that above-mentioned general formula represents is coated on this substrate 310, forms a photoresist layer 300, shown in Fig. 2 (a); The light shield 360 that will have predetermined pattern is arranged between this photoresist layer 300 and the light source, this photoresist layer 300 is exposed, make photoresist layer 300 exposures of not blocked on this photoresist layer 300 by the predetermined pattern on the light shield 360, and avoided the irradiation of light by its photoresist layer that blocks 300, at this, light source can adopt ultraviolet light, shown in Fig. 2 (b); Utilize visualization way that the photoresist layer of predetermined pattern or non-predetermined pattern is removed, this is decided by to adopt the character of photoresist, if the eurymeric photoresistance is just removed the photoresist layer of predetermined pattern, if the minus photoresistance is just removed the photoresist layer of non-predetermined pattern, in the present embodiment photoresist layer 300 of non-predetermined pattern is removed, and solidified this photoresist layer 300, thereby make a plurality of dividing walls 330, form the space between every two adjacent dividing walls 330, shown in Fig. 2 (c).At this, can have black matrix on the substrate 310 that provides, by adopting corresponding light shield 360, dividing wall 330 is formed on this black matrix.Except containing the polysiloxane or derivatives thereof that general formula represents, can also contain in acryl resin, Polyimide, epoxy resin and the polyvinyl alcohol (PVA) one or more mixing in the above-mentioned photoresist.
See also Fig. 3, manufacture method second embodiment of the dividing wall between colored filter pixel of the present invention may further comprise the steps: a substrate 410 is provided, and this substrate 410 can be a glass substrate; First photoresist is coated on this substrate 410, form one first photoresist layer 400 ', shown in Fig. 3 (a), first photoresist can be one or more mixing in photoresist, acryl resin, Polyimide, epoxy resin and the polyvinyl alcohol (PVA) of the polysiloxane or derivatives thereof represented of above-mentioned general formula; The light shield 460 that will have predetermined pattern is arranged between first photoresist layer 400 ' and the light source, first photoresist layer 400 ' is exposed, make first photoresist layer, the 400 ' exposure of not blocked on this first photoresist layer 400 ' by the predetermined pattern on the light shield 460, and avoided the irradiation of light by first photoresist layer 400 ' that it blocks, at this, light source can adopt ultraviolet light, shown in Fig. 3 (b); First photoresist layer 400 ' of non-predetermined pattern is removed, and solidified this first photoresist layer 400 ', thereby make a plurality of first dividing walls 430 ', form the space between every two first adjacent dividing walls 430 ', shown in Fig. 3 (c); The photoresist that will contain the polysiloxane or derivatives thereof that above-mentioned general formula represents is coated on this substrate 410, forms one second photoresist layer 400, shown in Fig. 3 (d); Utilize the photoresist between two first will the be every adjacent dividing walls 430 ' of visualization way to remove, thus form first dividing wall 430 ' and second dividing wall about in the of 430 overlapping combination as required dividing wall, shown in Fig. 3 (e) and Fig. 3 (f).
See also Fig. 4, manufacture method the 3rd embodiment of the dividing wall between colored filter pixel of the present invention may further comprise the steps: a substrate 510 is provided, and this substrate 510 can be a glass substrate; First photoresist is coated on this substrate 510, form one first photoresist layer 500 ', shown in Fig. 4 (a), first photoresist can be one or more mixing in photoresist, acryl resin, Polyimide, epoxy resin and the polyvinyl alcohol (PVA) of the polysiloxane or derivatives thereof represented of above-mentioned general formula; The light shield 560 that will have predetermined pattern is arranged between first photoresist layer 500 ' and the light source, first photoresist layer 500 ' is exposed, make first photoresist layer, the 500 ' exposure of not blocked on this first photoresist layer 500 ' by the predetermined pattern on the light shield 560, and avoided the irradiation of light by first photoresist layer 500 ' that it blocks, at this, light source can adopt ultraviolet light, shown in Fig. 4 (b); First photoresist layer 500 ' of non-predetermined pattern is removed, and solidified this first photoresist layer 500 ', thereby make a plurality of first dividing walls 530 ', form the space between every two first adjacent dividing walls 530 ', shown in Fig. 4 (c); The photoresist that will contain the polysiloxane or derivatives thereof that above-mentioned general formula represents is coated on this substrate 510, forms a coating material layer 530; Solidify this coating material layer 530, thus each first dividing wall 530 ' and on the photoresist that contains the polysiloxane or derivatives thereof that above-mentioned general formula represents form required dividing wall, shown in Fig. 4 (d).
See also Fig. 5, manufacturing method of color filters first embodiment of the present invention may further comprise the steps: at first, the described step of manufacture method first embodiment according to the dividing wall between above-mentioned colored filter pixel forms a plurality of dividing walls 630 on substrate 610, shown in Fig. 5 (a) and (b), (c); Utilize ink discharge device, for example Thermal Bubble Ink-jet Printer device or piezoelectric ink jet device, in the space that the ink 640 of the color of needs is injected between the dividing walls 630, and utilize solidification equipment, for example heating arrangement or light-emitting device, have these ink 640 oven dry or commissure or the two concurrently it, with the uniform color layers of formation pigment distribution, and ink 640 is big with the contact angle of dividing wall 630, at this, ink 640 can reach more than 40 degree, shown in Fig. 5 (d) with the contact angle of dividing wall 630.
See also Fig. 6, manufacturing method of color filters second embodiment of the present invention may further comprise the steps: at first, form the overlapping combination about in the of 730 of a plurality of first dividing walls 730 ' and second dividing wall according to the described step of manufacture method second embodiment of the dividing wall between above-mentioned colored filter pixel on substrate 710; Utilize ink discharge device, for example Thermal Bubble Ink-jet Printer device or piezoelectric ink jet device, the ink 740 of the color of needs is injected in the space between the combination of first dividing walls 730 ' and second dividing wall 730, and utilize solidification equipment, for example heating arrangement or light-emitting device, have these ink 740 oven dry or commissure or the two concurrently it, to form the uniform color layers of pigment distribution, and the contact angle of the combination of the ink 740 and first dividing wall 730 ' and second dividing wall 730 is big, at this, the contact angle of the combination of the ink 740 and first dividing wall 730 ' and second dividing wall 730 also can reach more than 40 degree.
See also Fig. 7, manufacturing method of color filters the 3rd embodiment of the present invention may further comprise the steps: at first, form the combination of a plurality of first dividing walls 830 ' and coating material layer 830 according to the described step of manufacture method the 3rd embodiment of the dividing wall between above-mentioned colored filter pixel on substrate 810; Utilize ink discharge device, for example Thermal Bubble Ink-jet Printer device or piezoelectric ink jet device, the ink 840 of the color of needs is injected in the space between the combination of first dividing walls 830 ' and coating material layer 830, and utilize solidification equipment, for example heating arrangement or light-emitting device, have these ink 840 oven dry or commissure or the two concurrently it, to form the uniform color layers of pigment distribution, and the contact angle of the combination of the ink 840 and first dividing wall 830 ' and coating material layer 830 is big, at this, the contact angle of the combination of the ink 840 and first dividing wall 830 ' and coating material layer 830 also can reach more than 40 degree.
The above derivant that contains the polysiloxane that above-mentioned general formula represents comprises that also wherein having a repetitive at least is the structure of polysiloxane, that is: with the formed copolymer of different repeat units, ternary polymerization zoarium or multi-component copolymer zoarium etc.
Wherein, R
1, R
2Represent alkyl or phenyl ring base respectively.
In addition, those skilled in the art also can do other variation in spirit of the present invention.So the variation that these are done according to spirit of the present invention all should be included within the present invention's scope required for protection.