CN101011782A - Leadless soft tin solder - Google Patents
Leadless soft tin solder Download PDFInfo
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- CN101011782A CN101011782A CN 200710063012 CN200710063012A CN101011782A CN 101011782 A CN101011782 A CN 101011782A CN 200710063012 CN200710063012 CN 200710063012 CN 200710063012 A CN200710063012 A CN 200710063012A CN 101011782 A CN101011782 A CN 101011782A
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- soft tin
- tin solder
- leadless soft
- alloy
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Abstract
A lead free soft tin features in the composition of Cu 0.1-5.0%,Ni 0.01-2.0%,Ge 0.01-1.0%,In 0.01-1.5 %,Sb O005-2.0% and the rest being Sn with 0.05-1.0%Bi and or 0.001-1.0 %Ti to strengthen the anti oxidation to add 0.01-0.1%P and Ga, with good soldering effect, glaze on the surface, anti fatigue, anti oxidation, low soldering degree, good humidity, and fine crystallization.
Description
Technical field
The present invention relates to a kind of leadless soft tin solder, can be used for hot dipping weldering, the just flat spray soldering of wave-soldering, hot blast, manual welding also can be made scolding tin products such as the solder stick of core band scaling powder and solid tin silk, tin solder, tin cream, sheet tin, belongs to welding material.
Background technology
Oneth century, at the electronics industry welding material based on tin-lead solder since it to have welding performance better; fusing point also compares at the end; use the characteristics of being familiar with, but lead is poisonous and harmful element, to air environmental pollution; harmful to human health; therefore external electronics industry welding material is initiated and must be removed lead element, carries out unleaded tin solder and replaces it, and now for the electronics industry development rapidly; people's environmental protection consciousness all strengthening attention, proposes high-quality requirement to lead-free solder.Existing lead-free solder only has SnCu, SnAgCu, and SnNiCu is extensive use of for three kinds, can not satisfy instructions for use, and the fusing point that has is higher, crystallization is thick, brightness is bad, non-oxidizability is poor, can not meet the demands far away.
Summary of the invention
Purpose of the present invention provides a kind of solderability good for the shortcoming that overcomes above-mentioned prior art existence with deficiency just, the solder joint surface-brightening, energy antifatigue, antioxidizing leadless soft tin solder, thereby for no lead-tin soldering increases new varieties, to satisfy electronics industry development in science and technology requirement.
The objective of the invention is to realize by following technical proposal:
Leadless soft tin solder is characterized in that it is made up of following weight percentages:
Cu 0.1～5.0％、 Ni 0.01～2.0％、 Ge 0.01～1.0％、
In 0.01～1.5%, Sb 0.05～2.0% and surplus Sn,
The preferred weight percent of described raw material is:
Cu 0.4～1.0％、 Ni 0.01～0.5％、Ge 0.01～0.5％、
In 0.01～0.5％、 Sb 0.05～0.8％。
At above-mentioned no-lead soft soldering, also added 0.05～1.0%Bi or/and 0.001～1.0%Ti also can add 0.01～0.1%P and 0.01～1.0%Ga in order to strengthen anti-oxidant dynamics.
The preparation method of leadless soft tin solder, be earlier Sn to be smelted into intermediate alloy with Cu, Ni, Ge, In, Sb, Bi, Ti respectively, wherein SnCu alloy Cu content is 10%, SnNi alloy Ni content is 5%, SnGe alloy Ge content is 2.5%, SnIn alloy In content is 10%, SnSb alloy content Sb is 50%, SnBi alloy B i content is 10%, SnP alloy P content is 5%, then surplus tin fusing back is quantitatively added intermediate alloy and Ga successively under 380～450 ℃ of temperature, be smelted into product.
Lead-free welding material of the present invention has added Ge, sb, In, Bi on traditional SnCuNi basis, it can reduce fusing point, and the fining metal crystallization improves antioxygen property, improves liquidity, and optimizes the rate of spread.
Product of the present invention detects through Ministry of Information Industry proprietary material quality monitoring inspection center, and the result is as follows:
Test piece stretching, test piece are sheared, QFP lead-in wire 45 ° of tension tests, slice component shearing test, the rate of spread and wetting test testing results see Table 1
Table 1 test piece stretching, test piece are sheared, QFP goes between 450 tension tests,
Slice component shearing test, the rate of spread and wetting test testing result
| Test event | Test result | ||||||||
| 10 * 5 test pieces stretchings (KN) | 5.3 | 5.0 | On average: 5.2 | ||||||
| (N) sheared in Φ 5 test pieces | 498 | 535 | On average: 517 | ||||||
| The QFP 45 ° of tension tests (N) that go between | 31.8 | 25.5 | 21.3 | 19.8 | 23.6 | On average: 24.4 | |||
| Slice component shearing test (N) | 17.3 | 23.0 | 26.3 | 27.0 | 35.2 | On average: 25.8 | |||
| The rate of spread (%) | 75.24 | ||||||||
| Wetting test | T between wetting beginning 0(S) | Wetting rise time t 1(S) | Maximum wetting power F max(10 -5N) | Final wetting power F end(10 -5N) | |||||
| 0.9 | 0.2 | 83 | 77 | ||||||
| 0.9 | 0.2 | 73 | 68 | ||||||
| 1.0 | 0.3 | 78 | 69 | ||||||
| 0.9 | 0.3 | 78 | 67 | ||||||
| 0.8 | 0.2 | 76 | 70 | ||||||
| On average: 0.9 | On average: 0.2 | On average: 77 | On average: 70 | ||||||
2, performance relatively sees Table 2
Table 2 rate of spread, fusing point: metallographic comparative result:
| The lead-free solder kind | SnCu | SnCuNiGeInSb |
| Rate of spread % | 71.5 | 75.24 |
| Fusing point (℃) | ＞227 | ＜226.7 |
| Metallographic | Crystal grain is thicker | Grain refinement |
3, chemical composition detects is provided by inspection center of Shanghai Inst. of Materials, and it the results are shown in Table 3
Table 3 testing result
| Detect composition | Cu | Ni | Ge | In | Sb | Bi | Ti |
| % as a result | 0.58 | 0.028 | ＜0.002 | 0.052 | 0.07 | 0.10 | 0.01 |
Be improved from above-mentioned testing result and performance comparison properties of product of the present invention as can be seen.
Owing to take technique scheme, it is good to make the technology of the present invention compared with the prior art have solderability, and the solder joint surface-brightening can antifatigue, and anti-oxidant, fusing point is low, wetability good, the advantage of grain refinement and effect.
The specific embodiment
Embodiment sees Table 4
Each raw material weight proportioning of table 4 embodiment
| Embodiment | Each raw material weight proportioning (kg) | |||||||||
| 1 | Sn | Cu | Ni | Ge | In | Sb | Bi | Ti | P | Ga |
| 2 | 96.34 | 0.1 | 2.0 | 0.01 | 1.5 | 0.05 | ||||
| 3 | 97.55 | 1.0 | 0.5 | 0.05 | 0.8 | 0.1 | ||||
| 4 | 96.70 | 2.0 | 0.4 | 0.2 | 0.2 | 0.5 | ||||
| 5 | 94.70 | 3.0 | 0.1 | 0.6 | 0.10 | 1.5 | ||||
| 6 | 91.98 | 5.0 | 0.01 | 1.0 | 0.01 | 2.0 | ||||
| 7 | 95.80 | 0.4 | 1.5 | 0.02 | 1.2 | 0.08 | 1.0 | |||
| 8 | 96.95 | 1.5 | 0.6 | 0.1 | 0.5 | 0.2 | 0.15 | |||
| 9 | 95.90 | 2.5 | 0.2 | 0.4 | 0.15 | 0.8 | 0.05 | |||
| 10 | 93.599 | 4.0 | 0.05 | 0.8 | 0.05 | 1.5 | 0.001 | |||
| 11 | 97.02 | 0.8 | 1.0 | 0.03 | 1.0 | 0.1 | 0.05 | |||
| 12 | 92.24 | 4.5 | 0.08 | 0.5 | 0.08 | 1.6 | 1.0 | |||
| 13 | 96.748 | 1.0 | 0.5 | 0.05 | 0.8 | 0.1 | 0.8 | 0.002 | ||
| 14 | 95.50 | 3.0 | 0.1 | 0.6 | 0.10 | 0.5 | 0.1 | 0.1 | ||
| 15 | 96.52 | 1.5 | 0.6 | 0.1 | 0 5 | 0.2 | 0.08 | 0.5 | ||
| 16 | 95.69 | 2.0 | 0.4 | 0.2 | 0.2 | 0.5 | 0.01 | 1.0 | ||
| 17 | 96.8 | 1.5 | 0.6 | 0.1 | 0.5 | 0.2 | 0.15 | 0.05 | 0.1 | |
| 18 | 95.5 | 3.0 | 0.1 | 0.6 | 0.10 | 0.5 | 0.05 | 0.1 | 0.05 | |
| 19 | 94.96 | 0.8 | 1.0 | 0.03 | 1.0 | 0.1 | 1.0 | 0.1 | 1.0 | 0.01 |
The preparation method of the leadless soft tin solder of the foregoing description, be earlier Sn to be smelted into intermediate alloy with Cu, Ni, Ge, In, Sb, Bi, Ti respectively, wherein SnCu alloy Cu content is 10%, SnNi alloy Ni content is 5%, SnGe alloy Ge content is 2.5%, SnIn alloy In content is 10%, SnSb alloy Sb content is 50%, SnBi alloy B i content is 10%, SnP alloy P content is 5%, then surplus tin fusing back is quantitatively added intermediate alloy and Ga successively under 380～450 ℃ of temperature, be smelted into product.
Claims (5)
1, a kind of leadless soft tin solder is characterized in that it is made up of following weight percentages:
Cu 0.1～5.0％、Ni 0.01～2.0％、Ge 0.01～1.0％、
In 0.01～1.5%, Sb 0.05～2.0% and surplus Sn.
2. according to the described leadless soft tin solder of claim 1, it is characterized in that the percentage by weight of described raw material is:
Cu 0.4～1.0％、Ni 0.01～0.5％、Ge 0.01～0.5％、
In 0.01～0.5％、Sb 0.05～0.8％。
3. according to claim 1 or 2 described leadless soft tin solders, it is characterized in that described leadless soft tin solder, also added 0.05～1.0%Bi or/and 0.001～1.0%Ti.
4. according to claim 1 or 2 described leadless soft tin solders, it is characterized in that described leadless soft tin solder, also added 0.01～1.0%P and 0.01～1.0%Ga.
5, according to the described leadless soft tin solder of claim 3, it is characterized in that described leadless soft tin solder, also added 0.01～1.0%P and 0.01～1.0%Ga.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2007100630129A CN100439028C (en) | 2007-01-24 | 2007-01-24 | Leadless soft tin solder |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100630129A CN100439028C (en) | 2007-01-24 | 2007-01-24 | Leadless soft tin solder |
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| CN100439028C CN100439028C (en) | 2008-12-03 |
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| CNB2007100630129A Expired - Fee Related CN100439028C (en) | 2007-01-24 | 2007-01-24 | Leadless soft tin solder |
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| CN101804528A (en) * | 2010-04-19 | 2010-08-18 | 北京达博长城锡焊料有限公司 | Lead-free solder for welding high-power transistors and preparation method thereof |
| CN102179642A (en) * | 2011-05-06 | 2011-09-14 | 郴州格瑞特焊业有限公司 | Copper-based brazing filler metal and preparation method thereof |
| CN102554490A (en) * | 2012-01-13 | 2012-07-11 | 广州有色金属研究院 | Copper dissolving resisting stannum-copper lead-free brazing filler metal alloy |
| US8598707B2 (en) | 2008-10-24 | 2013-12-03 | Mitsubishi Electric Corporation | Solder alloy and semiconductor device |
| CN104070302A (en) * | 2013-03-26 | 2014-10-01 | 昆山市天和焊锡制造有限公司 | Leadless solder for photovoltaic solder strips |
| CN104070299A (en) * | 2013-03-26 | 2014-10-01 | 昆山市天和焊锡制造有限公司 | Tin solder of anti-ageing photovoltaic solder strip |
| CN104353840A (en) * | 2014-11-25 | 2015-02-18 | 北京康普锡威科技有限公司 | Low-cost lead-free soldering flux alloy powder for LED (light emitting diode) and preparation method of alloy powder |
| CN104741820A (en) * | 2015-03-24 | 2015-07-01 | 东莞市成飞焊接材料有限公司 | Lead-free brazing filler metal |
| CN105290639A (en) * | 2015-11-30 | 2016-02-03 | 苏州龙腾万里化工科技有限公司 | Manufacturing method for copper-added soldering tin bar |
| CN105339131A (en) * | 2014-04-30 | 2016-02-17 | 日本斯倍利亚股份有限公司 | Lead-free solder alloy |
| CN105463248A (en) * | 2016-01-13 | 2016-04-06 | 云南锡业锡材有限公司 | Tin-based Babbitt alloy material |
| CN105829016A (en) * | 2013-10-31 | 2016-08-03 | 阿尔法金属公司 | Lead-free, silver-free solder alloys |
| CN106514044A (en) * | 2016-11-30 | 2017-03-22 | 安徽华众焊业有限公司 | Copper-based brazing paste |
| CN108135085A (en) * | 2017-12-05 | 2018-06-08 | 张家港市东大工业技术研究院 | A kind of surface spray tin processing method of copper pad |
| CN110170762A (en) * | 2019-06-12 | 2019-08-27 | 烟台博瑞锡业科技有限公司 | A kind of transformer high-temperature-resistant lead-free tin bar and preparation method thereof |
| CN111511494A (en) * | 2017-11-08 | 2020-08-07 | 凯斯特有限责任公司 | Cost-effective lead-free solder alloys for electronic applications |
| CN113727807A (en) * | 2019-06-28 | 2021-11-30 | 千住金属工业株式会社 | Solder alloy, casting, formation and soldered joint |
| CN114055010A (en) * | 2021-11-05 | 2022-02-18 | 安徽工业大学 | Copper-based alloy brazing filler metal containing trace Ge, preparation method and brazing method thereof |
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| US6033488A (en) * | 1996-11-05 | 2000-03-07 | Samsung Electronics Co., Ltd. | Solder alloy |
| TW592872B (en) * | 2001-06-28 | 2004-06-21 | Senju Metal Industry Co | Lead-free solder alloy |
| JP2004188453A (en) * | 2002-12-11 | 2004-07-08 | Harima Chem Inc | Sn-BASED SOLDER ALLOY |
| GB2419137A (en) * | 2004-10-15 | 2006-04-19 | Alpha Fry Ltd | Solder alloy |
| CN1895837B (en) * | 2005-07-12 | 2011-04-20 | 北京有色金属研究总院 | Sn-Cu-Cr lead-free soldering material and its preparation |
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