CN1006414B - 分析测定有机物质的方法 - Google Patents
分析测定有机物质的方法Info
- Publication number
- CN1006414B CN1006414B CN86102624A CN86102624A CN1006414B CN 1006414 B CN1006414 B CN 1006414B CN 86102624 A CN86102624 A CN 86102624A CN 86102624 A CN86102624 A CN 86102624A CN 1006414 B CN1006414 B CN 1006414B
- Authority
- CN
- China
- Prior art keywords
- concentration
- organic substance
- organic substances
- mentioned
- mass spectrometer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000126 substance Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title abstract description 14
- 230000035945 sensitivity Effects 0.000 claims abstract description 7
- 238000003860 storage Methods 0.000 claims abstract description 4
- 238000003556 assay Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 13
- 238000004458 analytical method Methods 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 239000012855 volatile organic compound Substances 0.000 abstract description 2
- 239000003256 environmental substance Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 15
- 238000001514 detection method Methods 0.000 description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005070 sampling Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000013043 chemical agent Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- 230000001473 noxious effect Effects 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000010574 gas phase reaction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 210000000577 adipose tissue Anatomy 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 231100000037 inhalation toxicity test Toxicity 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/0022—Portable spectrometers, e.g. devices comprising independent power supply, constructional details relating to portability
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/02—Details
- H01J49/24—Vacuum systems, e.g. maintaining desired pressures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/26—Mass spectrometers or separator tubes
- H01J49/34—Dynamic spectrometers
- H01J49/42—Stability-of-path spectrometers, e.g. monopole, quadrupole, multipole, farvitrons
- H01J49/4205—Device types
- H01J49/421—Mass filters, i.e. deviating unwanted ions without trapping
- H01J49/4215—Quadrupole mass filters
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Electron Tubes For Measurement (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853510378 DE3510378A1 (de) | 1985-03-22 | 1985-03-22 | Verfahren zur analytischen bestimmung von organischen stoffen |
| DEP3510378.7 | 1985-03-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86102624A CN86102624A (zh) | 1987-04-08 |
| CN1006414B true CN1006414B (zh) | 1990-01-10 |
Family
ID=6266006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN86102624A Expired CN1006414B (zh) | 1985-03-22 | 1986-03-20 | 分析测定有机物质的方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4757198A (https=) |
| EP (1) | EP0195296A3 (https=) |
| JP (1) | JPS61269844A (https=) |
| CN (1) | CN1006414B (https=) |
| AU (1) | AU5489486A (https=) |
| CA (1) | CA1249380A (https=) |
| DE (1) | DE3510378A1 (https=) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3631862A1 (de) * | 1986-09-19 | 1988-03-31 | Strahlen Umweltforsch Gmbh | Einrichtung zur analytischen bestimmung von organischen stoffen |
| JPH0466862A (ja) * | 1990-07-06 | 1992-03-03 | Hitachi Ltd | 高感度元素分析法及び装置 |
| DE4133300C2 (de) * | 1991-10-08 | 1996-07-11 | Fraunhofer Ges Forschung | Verfahren und Vorrichtung zum Bestimmen strippbarer Substanzen aus Flüssigkeiten |
| US5261793A (en) * | 1992-08-05 | 1993-11-16 | The United States Of America As Represented By The Secretary Of The Department Of Health And Human Services | Miniature mechanical vacuum pump |
| US5670378A (en) * | 1995-02-23 | 1997-09-23 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Method for trace oxygen detection |
| US20070258894A1 (en) * | 2000-11-08 | 2007-11-08 | Melker Richard J | System and Method for Real-Time Diagnosis, Treatment, and Therapeutic Drug Monitoring |
| US6605176B2 (en) * | 2001-07-13 | 2003-08-12 | Taiwan Semiconductor Manufacturing Co., Ltd. | Aperture for linear control of vacuum chamber pressure |
| US6982413B2 (en) * | 2003-09-05 | 2006-01-03 | Griffin Analytical Technologies, Inc. | Method of automatically calibrating electronic controls in a mass spectrometer |
| WO2005031287A2 (en) * | 2003-09-25 | 2005-04-07 | Oi Corporation | Method and apparatus employing turbo pump-foreline pump configuration, for example, in mass spectrometer |
| GB0327241D0 (en) * | 2003-11-21 | 2003-12-24 | Gv Instr | Ion detector |
| EP1721330A2 (en) * | 2004-03-05 | 2006-11-15 | Oi Corporation | Focal plane detector assembly of a mass spectrometer |
| US7023003B2 (en) * | 2004-03-18 | 2006-04-04 | Taiwan Semiconductor Manufacturing Co., Ltd. | Ion implanter and method of preventing undesirable ions from implanting a target wafer |
| WO2006002027A2 (en) * | 2004-06-15 | 2006-01-05 | Griffin Analytical Technologies, Inc. | Portable mass spectrometer configured to perform multidimensional mass analysis |
| CN101317246A (zh) | 2005-04-25 | 2008-12-03 | 格里芬分析技术有限责任公司 | 分析仪器、装置和方法 |
| US20070131860A1 (en) * | 2005-12-12 | 2007-06-14 | Freeouf John L | Quadrupole mass spectrometry chemical sensor technology |
| US7992424B1 (en) | 2006-09-14 | 2011-08-09 | Griffin Analytical Technologies, L.L.C. | Analytical instrumentation and sample analysis methods |
| US8859956B2 (en) | 2009-04-30 | 2014-10-14 | Purdue Research Foundation | Ion generation using wetted porous material |
| US8704167B2 (en) * | 2009-04-30 | 2014-04-22 | Purdue Research Foundation | Mass spectrometry analysis of microorganisms in samples |
| US9500572B2 (en) | 2009-04-30 | 2016-11-22 | Purdue Research Foundation | Sample dispenser including an internal standard and methods of use thereof |
| JP6039580B2 (ja) * | 2011-01-12 | 2016-12-07 | ファースト ディテクト コーポレイション | サンプルチャンバの真空引き |
| US9546979B2 (en) | 2011-05-18 | 2017-01-17 | Purdue Research Foundation | Analyzing a metabolite level in a tissue sample using DESI |
| US9157921B2 (en) | 2011-05-18 | 2015-10-13 | Purdue Research Foundation | Method for diagnosing abnormality in tissue samples by combination of mass spectral and optical imaging |
| US8895918B2 (en) | 2011-06-03 | 2014-11-25 | Purdue Research Foundation | Ion generation using modified wetted porous materials |
| CN102288643B (zh) * | 2011-08-01 | 2013-01-09 | 山东省科学院海洋仪器仪表研究所 | 土壤中有机质的测量方法及装置 |
| JP5861775B2 (ja) * | 2012-05-08 | 2016-02-16 | 株式会社島津製作所 | 質量分析装置 |
| US9733228B2 (en) | 2013-01-31 | 2017-08-15 | Purdue Research Foundation | Methods of analyzing crude oil |
| WO2014120411A1 (en) | 2013-01-31 | 2014-08-07 | Purdue Research Foundation | Systems and methods for analyzing an extracted sample |
| WO2014209474A1 (en) | 2013-06-25 | 2014-12-31 | Purdue Research Foundation | Mass spectrometry analysis of microorganisms in samples |
| US9786478B2 (en) | 2014-12-05 | 2017-10-10 | Purdue Research Foundation | Zero voltage mass spectrometry probes and systems |
| CN107960130A (zh) | 2015-02-06 | 2018-04-24 | 普度研究基金会 | 探针、系统、盒及其使用方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2400557A (en) * | 1942-07-31 | 1946-05-21 | Cons Eng Corp | Analytical system |
| US2610300A (en) * | 1951-08-07 | 1952-09-09 | Wilson W Walton | Flow control |
| US2714164A (en) * | 1954-02-23 | 1955-07-26 | John W Riggie | Mass spectrometer sampling system |
| GB960237A (en) * | 1961-09-04 | 1964-06-10 | Ass Elect Ind | Improvements relating to mass spectrometer ion sources |
| US3700893A (en) * | 1971-02-12 | 1972-10-24 | Nasa | Method and apparatus for determining the contents of contained gas samples |
| JPS5036393A (https=) * | 1973-08-04 | 1975-04-05 | ||
| US3955084A (en) * | 1974-09-09 | 1976-05-04 | California Institute Of Technology | Electro-optical detector for use in a wide mass range mass spectrometer |
| US4016421A (en) * | 1975-02-13 | 1977-04-05 | E. I. Du Pont De Nemours And Company | Analytical apparatus with variable energy ion beam source |
| JPS583589B2 (ja) * | 1977-03-30 | 1983-01-21 | 株式会社日立製作所 | 質量分析計の直接試料導入装置 |
| JPS54104585A (en) * | 1978-02-03 | 1979-08-16 | Hitachi Ltd | Three-phase group bus |
| US4261698A (en) * | 1980-01-23 | 1981-04-14 | International Business Machines Corporation | Trace oxygen detector |
| FR2485201A1 (fr) * | 1980-06-20 | 1981-12-24 | Rech Geolog Miniere | Procede de mesure de grande precision des concentrations de gaz et produits volatils en situ et en continu et appareil in situ en oeuvre |
| US4672203A (en) * | 1983-05-20 | 1987-06-09 | Inficon Leybold-Heraeus, Inc. | Two stage valve for use in pressure converter |
-
1985
- 1985-03-22 DE DE19853510378 patent/DE3510378A1/de active Granted
-
1986
- 1986-03-01 EP EP86102699A patent/EP0195296A3/de not_active Ceased
- 1986-03-19 AU AU54894/86A patent/AU5489486A/en not_active Abandoned
- 1986-03-20 CN CN86102624A patent/CN1006414B/zh not_active Expired
- 1986-03-21 CA CA000504735A patent/CA1249380A/en not_active Expired
- 1986-03-22 JP JP61064647A patent/JPS61269844A/ja active Pending
- 1986-09-22 US US06/910,371 patent/US4757198A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA1249380A (en) | 1989-01-24 |
| DE3510378C2 (https=) | 1988-07-07 |
| AU5489486A (en) | 1986-09-25 |
| DE3510378A1 (de) | 1986-10-02 |
| EP0195296A2 (de) | 1986-09-24 |
| CN86102624A (zh) | 1987-04-08 |
| JPS61269844A (ja) | 1986-11-29 |
| US4757198A (en) | 1988-07-12 |
| EP0195296A3 (de) | 1987-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |