CN100587114C - 不锈钢用阻氢或氢同位素渗透的玻璃质壁垒层及其制备方法 - Google Patents
不锈钢用阻氢或氢同位素渗透的玻璃质壁垒层及其制备方法 Download PDFInfo
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- CN100587114C CN100587114C CN200710191961A CN200710191961A CN100587114C CN 100587114 C CN100587114 C CN 100587114C CN 200710191961 A CN200710191961 A CN 200710191961A CN 200710191961 A CN200710191961 A CN 200710191961A CN 100587114 C CN100587114 C CN 100587114C
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- hydrogen
- stainless steel
- barrier layer
- glassiness
- glass powder
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000001257 hydrogen Substances 0.000 title claims abstract description 55
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 55
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 36
- 239000010935 stainless steel Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 230000008595 infiltration Effects 0.000 title claims abstract description 11
- 238000001764 infiltration Methods 0.000 title claims abstract description 11
- 230000004888 barrier function Effects 0.000 claims abstract description 38
- 239000011521 glass Substances 0.000 claims abstract description 22
- 238000005516 engineering process Methods 0.000 claims abstract description 17
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- 229910021538 borax Inorganic materials 0.000 claims abstract description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 7
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 28
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 19
- 239000011734 sodium Substances 0.000 claims description 16
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 12
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- RCMWGBKVFBTLCW-UHFFFAOYSA-N barium(2+);dioxido(dioxo)molybdenum Chemical compound [Ba+2].[O-][Mo]([O-])(=O)=O RCMWGBKVFBTLCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 6
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 5
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 claims description 4
- 239000010977 jade Substances 0.000 claims description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 3
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 239000012466 permeate Substances 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims 1
- 230000000155 isotopic effect Effects 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000004927 fusion Effects 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 230000006866 deterioration Effects 0.000 abstract 2
- 239000000428 dust Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 229910001610 cryolite Inorganic materials 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 11
- 239000011159 matrix material Substances 0.000 description 10
- 238000007792 addition Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 4
- 239000007769 metal material Substances 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000002320 enamel (paints) Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
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Abstract
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200710191961A CN100587114C (zh) | 2007-12-27 | 2007-12-27 | 不锈钢用阻氢或氢同位素渗透的玻璃质壁垒层及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN200710191961A CN100587114C (zh) | 2007-12-27 | 2007-12-27 | 不锈钢用阻氢或氢同位素渗透的玻璃质壁垒层及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN101215709A CN101215709A (zh) | 2008-07-09 |
CN100587114C true CN100587114C (zh) | 2010-02-03 |
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CN200710191961A Expired - Fee Related CN100587114C (zh) | 2007-12-27 | 2007-12-27 | 不锈钢用阻氢或氢同位素渗透的玻璃质壁垒层及其制备方法 |
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CN (1) | CN100587114C (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2453512C1 (ru) * | 2010-10-28 | 2012-06-20 | Государственное образовательное учреждение высшего профессионального образования "Южно-Российский государственный технический университет (Новочеркасский политехнический институт)" | Защитное стеклокристаллическое покрытие для стали |
CN103802385A (zh) * | 2012-11-12 | 2014-05-21 | 北京有色金属研究总院 | 一种不锈钢基阻氢渗透复合涂层 |
CN103305787B (zh) * | 2013-06-25 | 2015-09-16 | 北京科技大学 | 一种在不锈钢基体上制备阻氢及其同位素渗透层的方法 |
CN103614725B (zh) * | 2013-11-28 | 2015-07-29 | 浙江安吉健丰金属制品有限公司 | 一种搪瓷方法 |
CN104708863A (zh) * | 2013-12-11 | 2015-06-17 | 北京有色金属研究总院 | 氧化铬和氧化铝复合涂层及其制备方法 |
CN105154890B (zh) * | 2015-08-06 | 2019-01-15 | 贵州开磷集团股份有限公司 | 一种被腐蚀的蒸压釜体的防护方法 |
CN110129795A (zh) * | 2019-05-09 | 2019-08-16 | 中国科学院金属研究所 | 一种新型高温阻渗抗氧化梯度涂层材料及其制备方法 |
CN112062469B (zh) * | 2020-08-28 | 2022-06-03 | 浙江开尔新材料股份有限公司 | 一种不锈钢搪瓷板的底釉釉料及其制备方法和应用 |
CN112657815B (zh) * | 2020-12-23 | 2023-08-08 | 合肥工业大学 | 一种316L不锈钢管内壁Al2O3/SiO2复合阻氚涂层的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4847218A (en) * | 1987-03-31 | 1989-07-11 | Bayer Aktiengesellschaft | Enamel frits for sheet steel with improved bonding |
CN1176942A (zh) * | 1995-03-02 | 1998-03-25 | 拜尔公司 | 用于给铝或铝合金上搪瓷的自身不透明的搪瓷玻璃料 |
CN1465745A (zh) * | 2002-06-14 | 2004-01-07 | 中国科学院金属研究所 | 一种高温合金抗高温氧化及热腐蚀的方法 |
WO2006083807A2 (en) * | 2005-02-03 | 2006-08-10 | Corning Incorporated | Low alkali sealing frits, and seals and devices utilizing such frits |
-
2007
- 2007-12-27 CN CN200710191961A patent/CN100587114C/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4847218A (en) * | 1987-03-31 | 1989-07-11 | Bayer Aktiengesellschaft | Enamel frits for sheet steel with improved bonding |
CN1176942A (zh) * | 1995-03-02 | 1998-03-25 | 拜尔公司 | 用于给铝或铝合金上搪瓷的自身不透明的搪瓷玻璃料 |
CN1465745A (zh) * | 2002-06-14 | 2004-01-07 | 中国科学院金属研究所 | 一种高温合金抗高温氧化及热腐蚀的方法 |
WO2006083807A2 (en) * | 2005-02-03 | 2006-08-10 | Corning Incorporated | Low alkali sealing frits, and seals and devices utilizing such frits |
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CN101215709A (zh) | 2008-07-09 |
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EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Zhongxin Energy Equipment Co., Ltd. Assignor: Nanjing University of Aeronautics and Astronautics Contract record no.: 2012320000620 Denomination of invention: Hydrogen or hydrogen isotope infiltration resisting vitreous vallation layer for stainless steel and preparation method thereof Granted publication date: 20100203 License type: Exclusive License Open date: 20080709 Record date: 20120521 |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20100203 Termination date: 20191227 |