CN100569690C - A kind of Weather resistance permeable material and uses thereof - Google Patents
A kind of Weather resistance permeable material and uses thereof Download PDFInfo
- Publication number
- CN100569690C CN100569690C CNB2005101327365A CN200510132736A CN100569690C CN 100569690 C CN100569690 C CN 100569690C CN B2005101327365 A CNB2005101327365 A CN B2005101327365A CN 200510132736 A CN200510132736 A CN 200510132736A CN 100569690 C CN100569690 C CN 100569690C
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- China
- Prior art keywords
- weather resistance
- resin
- permeable material
- resistance permeable
- epoxy
- Prior art date
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- 239000000463 material Substances 0.000 title claims abstract description 65
- 239000011347 resin Substances 0.000 claims abstract description 47
- 229920005989 resin Polymers 0.000 claims abstract description 47
- 239000004593 Epoxy Substances 0.000 claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000006004 Quartz sand Substances 0.000 claims abstract description 10
- 239000011230 binding agent Substances 0.000 claims abstract description 9
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 9
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 7
- 239000011147 inorganic material Substances 0.000 claims abstract description 7
- 238000009736 wetting Methods 0.000 claims abstract description 7
- 239000004576 sand Substances 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 5
- 239000002699 waste material Substances 0.000 claims abstract description 5
- 239000010881 fly ash Substances 0.000 claims abstract description 3
- 238000002844 melting Methods 0.000 claims abstract description 3
- 230000008018 melting Effects 0.000 claims abstract description 3
- 239000002893 slag Substances 0.000 claims abstract description 3
- 230000003647 oxidation Effects 0.000 claims description 23
- 238000007254 oxidation reaction Methods 0.000 claims description 23
- 239000003112 inhibitor Substances 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 16
- -1 aliphatic polyol Chemical class 0.000 claims description 14
- 239000011449 brick Substances 0.000 claims description 12
- 239000007822 coupling agent Substances 0.000 claims description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 8
- 229920000768 polyamine Polymers 0.000 claims description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004970 Chain extender Substances 0.000 claims description 5
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 5
- 125000002723 alicyclic group Chemical group 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 5
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 5
- 239000007809 chemical reaction catalyst Substances 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 4
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000005056 polyisocyanate Substances 0.000 claims description 4
- 229920001228 polyisocyanate Polymers 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 150000003254 radicals Chemical class 0.000 claims description 4
- HBGPNLPABVUVKZ-POTXQNELSA-N (1r,3as,4s,5ar,5br,7r,7ar,11ar,11br,13as,13br)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1h-cyclopenta[a]chrysen-9-one Chemical compound C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 claims description 3
- PFRGGOIBYLYVKM-UHFFFAOYSA-N 15alpha-hydroxylup-20(29)-en-3-one Natural products CC(=C)C1CCC2(C)CC(O)C3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 PFRGGOIBYLYVKM-UHFFFAOYSA-N 0.000 claims description 3
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 claims description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical group [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 claims description 3
- 239000010451 perlite Substances 0.000 claims description 3
- 235000019362 perlite Nutrition 0.000 claims description 3
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 claims description 2
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 125000005442 diisocyanate group Chemical group 0.000 claims description 2
- 230000001804 emulsifying effect Effects 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229920002050 silicone resin Polymers 0.000 claims description 2
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 claims description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000013638 trimer Substances 0.000 claims description 2
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 229920005749 polyurethane resin Polymers 0.000 claims 2
- CJVKAEYGNINWLI-UHFFFAOYSA-N 1,2-diisocyanatoethane 1,2,3,4-tetramethylbenzene Chemical compound C(CN=C=O)N=C=O.CC1=C(C(=C(C=C1)C)C)C CJVKAEYGNINWLI-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 7
- 230000035699 permeability Effects 0.000 abstract description 6
- 239000003963 antioxidant agent Substances 0.000 abstract description 2
- 230000003078 antioxidant effect Effects 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000000428 dust Substances 0.000 description 5
- 239000000975 dye Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000004566 building material Substances 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 239000003673 groundwater Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- NNOZGCICXAYKLW-UHFFFAOYSA-N 1,2-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC=C1C(C)(C)N=C=O NNOZGCICXAYKLW-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- MBVGJZDLUQNERS-UHFFFAOYSA-N 2-(trifluoromethyl)-1h-imidazole-4,5-dicarbonitrile Chemical compound FC(F)(F)C1=NC(C#N)=C(C#N)N1 MBVGJZDLUQNERS-UHFFFAOYSA-N 0.000 description 1
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001112258 Moca Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000011456 concrete brick Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000004643 material aging Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 230000003351 photoxidation Effects 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Road Paving Structures (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of Weather resistance permeable material, include aggregate, binding agent; Described aggregate is one of natural siliceous sand, flyash, melting waste slag, synthetic quartz sand or its arbitrary combination, and its particle diameter is: 0.07 millimeter～1.6 millimeters; Described binding agent is one of Resins, epoxy, urethane resin, acrylic resin of good weatherability or its arbitrary combination; By selecting the binding agent of good weatherability for use, and add photostabilizer, antioxidant has effectively improved weathering resistance; But by selecting the wetting ability reacting resin of good water permeability for use, and in aggregate, add hydrophilic inorganic material, effectively improved the water-permeable of material, the purposes of described Weather resistance permeable material is: above-mentioned raw materials can be mixed and made into and be used for that road surfacing or rainwater are collected, the permeable prefabricated component of water filtration, also can directly be layed in the road surface and form porous pavement, promote making full use of of rainwater resource, improve the municipal water circulation.
Description
Technical field
The present invention relates to a kind of seepy material, particularly the permeable effective seepy material of using in fields such as building materials, rainwater collection, water filtration purifications of good weatherability.
Background technology
At present, global energy, water resources shortage, the frequent generation of the enlarged areas that desertifies simultaneously and dust storm makes the environment of human survival abominable day by day.The place of city resident's inhabitation is at present mainly surrounded by the ground in the city square of laying with fluid-tight material such as grouan, marble, ornamental brick, cement and pitch, commercial street, walkway, community activity ground, parking lot etc., and hardened ground is very big to the harm of urban environment.When raining, hardened ground has stoped rainwater directly to infiltrate through ground fully, and completely ponding makes people's trip become very inconvenient; Precious water resource flows away along with drainage pipeline at last, has increased the weight of the burden of municipal drainage facility; A large amount of losses of rainwater cause ground water table to be difficult to go up, and directly have influence on the health of urban vegetation, make that the ground flora in the city is difficult to normal growth, increase the weight of municipal administration greening burden; A large amount of losses of rainwater further increase the weight of arid, the water shortage problem in city, form " artificial desert " on the ecology.
And when not raining, hardened ground is very dry again, piles up dust easily, the situation that causes dust to fly upward everywhere; The exchange that ground and air carry out heat, moisture is relatively more difficult, the ability of urban surface temperature, humidity of regulating is also followed step-down, the radiant heat of the sun also can be reflected, keeps and be discharged in ground in a large number, greatly increased the tropical island effect in city, and the The Surroundings in Cities comfort level is significantly reduced.Enter the 21 century people environment of being lived is paid close attention to more, but day by day to worsen be undisputable fact to the human ecotope that is faced that the environmental-friendly construction material of development of new improves and to beautify environment for human survival imperative.
The dank material main raw material of the permeable brick of some of building materials field, porous pavement etc. adopts pottery or concrete in the market, adopt a large amount of ore deposit soil resource and cement, and the exploitation of raw material causes environment damage; The permeable brick complex manufacturing of ceramic mould, and the ceramic base brick need expend a large amount of energy when forming and sintering, the cost height, production efficiency is low, and environmental protection has high input, and the one-time investment scale is big; Concrete brick also uses a large amount of cement, also can consume a large amount of resources; The material that some permeable bricks are also arranged is that natural gravel and waste and old plastics are raw material, and its shortcoming is that the weathering resistance official post is short with the life-span;
Above-described permeable brick or porous pavement all are to improve permeability rate by increasing brick body space, and voidage is stopped up the space problem more than 20% owing to can not solve dust, therefore can not continue to keep the high water-permeability energy; And because the space is bigger, it is also relatively poor that it is used for the water filtration effect.
About dank material field and environment-friendly type to be developed, energy conservation type, good weatherability, product that permeability rate is high.
Summary of the invention
The objective of the invention is to overcome the above-mentioned deficiency of seepy material in the prior art, a kind of environmental protection, save energy, good weatherability, seepy material that permeability rate is high are provided.
In order to realize purpose of the present invention, the present invention is achieved through the following technical solutions:
A kind of Weather resistance permeable material includes aggregate, binding agent; Wherein:
Described aggregate is one of natural siliceous sand, flyash, melting waste slag, synthetic quartz sand or its arbitrary combination, and its particle diameter is: 0.07 millimeter～1.6 millimeters;
Described binding agent is one of Resins, epoxy, urethane resin, acrylic resin of good weatherability or its arbitrary combination; And the mass percent that used resin accounts for aggregate is: 1～20%;
Wherein also be added with aliphatic polyamine or alicyclic polyamine class solidifying agent in the Resins, epoxy of good weatherability, the mass percent that its consumption accounts for Resins, epoxy is: 5～60%;
Wherein also be added with the Polyurethane curing reaction catalyst in the good weatherability urethane resin.
In order to increase the water-permeable of this seepy material, but be added with the wetting ability reacting resin in the described tackiness agent; Wherein but this wetting ability reacting resin accounts for resin: 1～60%; Described wetting ability Resins, epoxy is to introduce hydrophilic radical by chemical reaction in the Resins, epoxy molecule, and introduces epoxy group(ing) or hydroxyl, but makes it become the reacting resin with certain automatic emulsifying performance.
For the weathering resistance of tackiness agent is good, wherein be added with aliphatic polyamine or alicyclic polyamine class solidifying agent in the Resins, epoxy of good weatherability, the mass percent that its consumption accounts for Resins, epoxy is: 10～60%;
The Resins, epoxy of described good weatherability is one or more in alicyclic type Resins, epoxy, bisphenol-A epoxy resin, organic-silicon-modified bisphenol A type epoxy resin, saturated glycidyl ester type epoxy resin, heterocyclic type and the mixed type Resins, epoxy.
Described Polyurethane curing reaction catalyst is one of organic tin, plumbous class catalyzer or its combination; Described organic tin catalyzer is dibutyl tin laurate, stannous octoate, stannous iso caprylate; Described plumbous class catalyzer is lead naphthenate or isocaprylic acid lead.
The urethane resin of described good weatherability is the aliphatic polyol and the polyisocyanate mixtures of good weatherability.Described polyisocyanates is one or more in hexamethylene diisocyanate HDI, isophorone diisocyanate IPDI, xylylene diisocyanate XDI, Methylcyclohexyl diisocyanate HTDI, dicyclohexyl methane diisocyanate HMDI, tetramethylxylylene diisocyanate TMXDI, HDI biuret, HDI tripolymer, IPDI tripolymer, TDI-HDI mixed trimer or the performed polymer; To be polyester polyol, tetrahydrofuran (THF) be the acrylic resin of the polyether glycol of base, hydroxyl or in the silicone resin one or more to described aliphatic polyol.
In order to improve the water-permeable of seepage material, be added with hydrophilic inorganic material in the described aggregate, the mass percent that its consumption accounts for aggregate is: 1～20%.Described hydrophilic inorganic material is one or more in diatomite, wilkinite, the perlite.
Also can be added with ammonia ester level solvent in the described urethane resin; This ammonia ester level solvent is preferably one or more in vinyl acetic monomer, methylethylketone, acetone, toluene, dimethyl formamide, the tetrahydrofuran (THF).Described urethane resin also can add chainextender and linking agent, this chainextender and linking agent are preferably alcohols and amine, described alcohols and amine are 1, the 4-butyleneglycol, 1,6-hexylene glycol, TriMethylolPropane(TMP), 3,3 '-two chloro-4,4 '-among diamino-ditan MOCA one or more.
Described Weather resistance permeable material also is added with coupling agent, the mass percent that its consumption accounts for resin is: 0-10%, the mass percent that described coupling agent consumption accounts for resin is: best results during 0.5-5%, described coupling agent are preferably the coupling agent of elements such as siliceous, titanium, phosphorus.
Cause in the factors of macromolecule material aging, the ultraviolet ray in the sunlight is extremely important one.Photostabilizer is the light stability auxiliary agent that is used to improve macromolecular material, its energy shielding ultraviolet rays, or absorb ultraviolet ray and it is converted into harmless heat energy, or cancellation is by the excited state of ultraviolet ray excited molecule or group, make it be returned to ground state, perhaps catch the free radical that produces because of photoxidation, avoid photooxidation reaction to go on, thereby make macromolecular material exempt from ultraviolet destruction, in order to increase weathering resistance, described Weather resistance permeable material also adds photostabilizer, the mass percent that the consumption of described photostabilizer accounts for resin is 0.1-5%, and described photostabilizer is a benzophenone, the salicylate class, benzotriazole category, hindered amines, among photostabilizer HPT and the photostabilizer EPU any or several; Specifically, the photostabilizer of suitable above-mentioned binding agent has benzophenone (UV-207, UV-9, UV-531, UV-A, MA, D49 and photostabilizer-50 etc.), salicylate (photostabilizer TBS, photostabilizer BAD etc.), benzotriazole (UV-P, UV-320, UV-326, UV-327, UV-328 and UV-5411 etc.), hindered amine (photostabilizer 744, photostabilizer 144, hindered amine 770, photostabilizer 292 etc.), photostabilizer HPT and photostabilizer EPU etc.
Macromolecular material is being stored, in processing and the use, under the effect of oneself factor and environmental factors, can be subjected to oxidation, thereby cause the decline or the loss of macromolecular material and product properties thereof, in order to strengthen the oxidation-resistance of this seepy material, and then strengthen its weathering resistance, described Weather resistance permeable material is added with oxidation inhibitor, effect was preferable when the mass percent that the consumption of described oxidation inhibitor accounts for resin was 0.1-4%, and described oxidation inhibitor is oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, in the antioxidant 1010 one or more.
In order to improve flame retardant resistance, can add fire retarding epoxide resin (as: brominated Resins, epoxy, chloride Resins, epoxy and phosphorous and azo-cycle epoxy resins) and fire retardant.
Described quartz sand can be dyed shades of colour as required.
The purposes of described Weather resistance permeable material is: above-mentioned raw materials can be mixed and made into and be used for that road surfacing or rainwater are collected, the permeable prefabricated component of water filtration, as permeable brick, permeable Artificial lawn, permeable tree pond, porous disc etc.; Also can directly be layed in the road surface and form porous pavement.
The present invention is owing to adopt such scheme to have following beneficial effect:
(1) environmental protection, energy-saving seepy material: nontoxic, tasteless, pollution-free, renewable recycle; Directly adopting the sand in the desert is raw material, and changing waste into valuable is opened up science sand control new way---progressively " eat " and fall the desert.
(2) good weatherability: select the binding agent of good weatherability for use, add antioxidant, photostabilizer; Improve the ability of oxidation-resistance and antiultraviolet, improved the weathering resistance of this seepy material greatly.
(3) good water permeability: by selecting the hydrophilic resin of good water permeability for use, and in aggregate, add hydrophilic inorganic material, effectively improved the water-permeable of material.
(4) Application Areas is extensive: make permeable building materials, but large-area applications in gardens, street, building construction; Attractive and durable, optimize urban environment, both can heat insulating, save the energy; Can also be used for rain water collecting system, collect, filter, purify rainwater, promote making full use of of rainwater resource, and dust suction fixes the sand, improve Air quality; The seepy material that is used for road surfacing improves the municipal water circulation, replenishes groundwater resource; Can lay permeable, infiltration road surface, natural precipitation and artificial rainmaking all can be infiltrated the face of land rapidly, and rainfall resource is fully used, and effectively replenish urban groundwater resource, improve water cycle.
Embodiment
For further checking effective effect of the present invention, the contriver has carried out repeatedly experiment, now is listed below preferable embodiment beneficial effect of the present invention is described;
Example 1:
Get the 0.4～0.2mm order quartz sand 100g that dyes cyan, bisphenol-A epoxy resin 4.6g, aliphatic polyamine solidifying agent 1.4g, coupling agent are glycidoxy-propyltrimethoxy silane 5600.12g, photostabilizer UV-320:0.012g and antioxidant 1010: 0.006g; Mix the back and make permeable brick, test the contrast situation of its performance index and common permeable brick by mould molding:
Example 2:
Get and dye green 0.07～0.2mm order quartz sand 10Kg, tackiness agent is the acrylic resin 600g of hydroxyl and 75% HDI biuret 200g, silane coupling agent 550:3g, photostabilizer UV-3260.6g and antioxidant 1010 0.9g, lead naphthenate solution 0.5g, the dibutyl tin laurate 0.9g of curing reaction catalyst 0.5%; Mix the back and make permeable brick, survey its ultimate compression strength and reach 38MPa by mould molding.
Example 3:
Get the 0.2～0.4mm quartz sand 10Kg that dyes black, tackiness agent is the biuret solution 560g of the HDI of 70% 650 polyester liquid 600g and 75%, adds silane coupling agent 550:5g, photostabilizer UV-327:0.6g; Oxidation inhibitor 1222:0.9g, zinc naphthenate 1.8g; Chainextender and linking agent are TriMethylolPropane(TMP) 20g; Get methylethylketone 15g as ammonia ester level solvent; The sample piece of making after the mixing is surveyed its ultimate compression strength and is reached 40.3MPa.
Example 4:
Get and dye red 1.2～1.6mm quartz sand 10Kg, diatomite 100g; Tackiness agent is bisphenol-A epoxy resin 1.8Kg and the bisphenol-A epoxy resin 0.18Kg that introduces hydrophilic radical; Aliphatic polyamine solidifying agent 189g, photostabilizer EPU:1.98g, oxidation inhibitor 1035:1.98g; Select one 1 square metre road surface, on the road surface, lay 20 centimetres stone basic unit and compacting, will be laid on the pervious bed that compacting levelling on the stone roadbed forms 15 cm thicks behind the above-mentioned seepy material thorough mixing of selecting for use, record after 5 days:
Example 5: get 0.07～0.4mm quartz sand 10Kg, perlite powder 2Kg; Tackiness agent is good weatherability acrylic resin 1.2Kg; Photostabilizer HPT:6g, oxidation inhibitor 1035:6g; Siliceous coupling agent 12g; With the above-mentioned raw materials thorough mixing, make the dmp filter layer of 20 cm thicks; Do not have solid impurity, limpid in the water that obtains behind the dmp filter, can be used for carwash.
According to above embodiment as can be known:, significantly improved the water-permeable and the weathering resistance of permeable product by using the application of dank material of the present invention.
Claims (29)
1, a kind of Weather resistance permeable material includes aggregate and binding agent; It is characterized in that:
1) described aggregate is one of natural siliceous sand, flyash, melting waste slag, synthetic quartz sand or its arbitrary combination, and its grain diameter is: 0.07 millimeter-1.6 millimeters;
2) described binding agent is Resins, epoxy, acrylic resin, urethane resin one of them or its arbitrary combination, and the mass percent that used resin accounts for aggregate is: 1-20%, and, but be added with the wetting ability reacting resin in the described tackiness agent; Wherein but this wetting ability reacting resin accounts for the mass percent of resin and is: 1-60%;
Wherein also be added with aliphatic polyamine or alicyclic polyamine class solidifying agent in the Resins, epoxy, the mass percent that its consumption accounts for Resins, epoxy is: 5-60%;
Wherein also be added with the Polyurethane curing reaction catalyst in the urethane resin.
2, Weather resistance permeable material as claimed in claim 1, it is characterized in that: but described wetting ability reacting resin is to introduce hydrophilic radical by chemical reaction in the Resins, epoxy molecule, and introduce epoxy group(ing) or hydroxyl, but make it become reacting resin with certain automatic emulsifying performance.
3, Weather resistance permeable material as claimed in claim 1 is characterized in that: described Resins, epoxy is a kind of or its arbitrary combination in alicyclic type Resins, epoxy, bisphenol-A epoxy resin, organic-silicon-modified bisphenol A type epoxy resin, saturated Racemic glycidol fat type Resins, epoxy, heterocyclic type and the mixed type Resins, epoxy.
4, Weather resistance permeable material as claimed in claim 1 is characterized in that: described polyurethane resin is aliphatic polyol and polyisocyanate mixtures.
5, Weather resistance permeable material as claimed in claim 4, it is characterized in that: described polyisocyanates is 1, one or more in the own diisocyanate resin of 6-, isophorone diisocyanate resin, phenylenedimethylidyne diisocyanate resin, Methylcyclohexyl diisocyanate, dicyclohexyl methyl hydride diisocyanate resin, tetramethyl-benzene dimethylene diisocyanate resin, HDI biuret, HDI tripolymer, IPDI tripolymer, TDI-HDI mixed trimer or the performed polymer; To be polyester polyvalent alcohol, tetrahydrofuran (THF) be the acrylic resin of the polyether glycol of base, hydroxyl or in the silicone resin one or more to described aliphatic polyol.
6, as claim 1 or 4 or 5 described Weather resistance permeable materials, it is characterized in that: described Polyurethane curing reaction catalyst is one of organic tin, plumbous class catalyzer or its arbitrary combination.
7, Weather resistance permeable material as claimed in claim 6 is characterized in that: described organic tin catalyzer is dibutyl tin laurate, stannous octoate, stannous iso caprylate; Described plumbous class catalyzer is lead naphthenate or isocaprylic acid lead.
8, as claim 1 or 7 described Weather resistance permeable materials, it is characterized in that: also be added with ammonia ester level solvent in the described polyurethane resin.
9, Weather resistance permeable material as claimed in claim 8 is characterized in that: described ammonia ester level solvent is one or more in vinyl acetic monomer, methylethylketone, acetone, toluene, dimethyl formamide, the tetrahydrofuran (THF).
10, Weather resistance permeable material as claimed in claim 1 is characterized in that: described urethane resin also adds chainextender and linking agent.
11, Weather resistance permeable material as claimed in claim 10 is characterized in that: described chainextender and linking agent are alcohols and amine.
12, Weather resistance permeable material as claimed in claim 11 is characterized in that: described alcohols and amine are 1,4-butyleneglycol, 1,6-hexylene glycol, TriMethylolPropane(TMP), 3,3 '-two chloro-4, one or more in 4 '-diamino-ditan.
13, Weather resistance permeable material as claimed in claim 1 is characterized in that: be added with hydrophilic inorganic material in the described aggregate, the mass percent that its consumption accounts for aggregate is: 1～20%.
14, Weather resistance permeable material as claimed in claim 13 is characterized in that: described hydrophilic inorganic material is one or more in diatomite, wilkinite, the perlite.
15, as claim 1 or 13 or 14 described Weather resistance permeable materials, it is characterized in that: described Weather resistance permeable material also is added with coupling agent, and the mass percent that its consumption accounts for resin is: 0-10%.
16, Weather resistance permeable material as claimed in claim 15 is characterized in that: the mass percent that described coupling agent consumption accounts for resin is: 0.5-5%.
17, as claim 15 or 16 described Weather resistance permeable materials, it is characterized in that: described coupling agent is the coupling agent of siliceous, titanium, phosphoric.
18, Weather resistance permeable material as claimed in claim 1 is characterized in that: described Weather resistance permeable material also adds photostabilizer.
19, Weather resistance permeable material as claimed in claim 18 is characterized in that: the mass percent that the consumption of described photostabilizer accounts for resin is 0.1-5%.
20, Weather resistance permeable material as claimed in claim 18 is characterized in that described photostabilizer is any or its arbitrary combination among benzophenone, Whitfield's ointment lipid, benzotriazole category, hindered amines, photostabilizer HPT and the photostabilizer EPU.
21, as claim 18 or 19 or 20 described Weather resistance permeable materials, it is characterized in that: be added with hydrophilic inorganic material in the described aggregate, the mass percent that its consumption accounts for aggregate is: 1-20%.
22, Weather resistance permeable material as claimed in claim 21 is characterized in that: described Weather resistance permeable material is added with oxidation inhibitor.
23, as claim 1 or 13 or 14 or 18 described Weather resistance permeable materials, it is characterized in that: described Weather resistance permeable material is added with oxidation inhibitor.
24, Weather resistance permeable material as claimed in claim 23 is characterized in that: the consumption of described oxidation inhibitor accounts for the 0.1-4% of resin quality.
25, Weather resistance permeable material as claimed in claim 23 is characterized in that: described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, the antioxidant 1010.
26, Weather resistance permeable material as claimed in claim 1 is characterized in that: described Weather resistance permeable material is added with fire retardant.
27, as claim 1 or 18 or 22 described Weather resistance permeable materials, it is characterized in that: described quartz sand is dyed shades of colour.
28, the purposes of Weather resistance permeable material as claimed in claim 1 is: 1) make the permeable prefabricated component that is used for road surfacing or rainwater collection or water filtration; 2) directly be layed in the road surface and form porous pavement.
29, the purposes of Weather resistance permeable material as claimed in claim 28 is characterized in that: described permeable prefabricated component is permeable brick or porous disc or permeable tree pond.
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