CN100551854C - 一种玉石纹微晶玻璃制造方法 - Google Patents

一种玉石纹微晶玻璃制造方法 Download PDF

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CN100551854C
CN100551854C CNB2006101407472A CN200610140747A CN100551854C CN 100551854 C CN100551854 C CN 100551854C CN B2006101407472 A CNB2006101407472 A CN B2006101407472A CN 200610140747 A CN200610140747 A CN 200610140747A CN 100551854 C CN100551854 C CN 100551854C
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glass
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crystallization
jade
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CN1919761A (zh
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马国龙
雷恒孚
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/02Compositions for glass with special properties for coloured glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/095Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths

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Abstract

本发明公开了一种玉石纹微晶玻璃制造方法,是将原材料充分混合后,投入到熔炉里熔化,是将熔化的玻璃熔液采用压制的方法制造成粒径为10~50mm的玻璃颗粒,然后再投入到冷水里钢化并形成裂纹,将玻璃颗粒装在模板上进入晶化窑晶化,晶化完成后出窑,经过研磨、抛光和切割成微晶玻璃成品。该方法制造的微晶玻璃象天然玉石一样,纹路自然逼真、色彩柔和、清晰美观、层次分明,而且制造方法简单、成本低廉,可以广泛应用于微晶玻璃制造行业,为建筑材料增加了新的花色品种。

Description

一种玉石纹微晶玻璃制造方法
技术领域
本发明涉及建筑材料技术领域,尤其涉及一种玉石纹微晶玻璃制造方法。
背景技术
烧结微晶玻璃装饰板作为一种新型高档的建筑装饰材料,已经越来越受到国内外建筑师和用户的青睐。现有技术的微晶玻璃主要采用烧结法制备的,是将原料按配方均匀混和后,投入玻璃熔窑中熔化,水淬制成1~4毫米粒度的玻璃渣,然后将玻璃渣放入模具内,在晶化窑中烧结并晶化,最后将晶化好的微晶玻璃板磨、抛、切加工为产品。这种方法制造的微晶玻璃只能产生千篇一律的小颗粒花纹,微晶玻璃装饰板的花色品种少,不能满足装饰材料多样化的市场需求。
发明内容
本发明的目的在于提供一种玉石纹微晶玻璃制造方法,该方法制造的微晶玻璃象天然玉石一样,纹路自然逼真、色彩柔和、清晰美观、层次分明。
本发明的玉石纹微晶玻璃制造方法,是将原材料混合后,投入到熔炉里熔化,制造成玻璃颗粒,将玻璃颗粒装在模板上进入晶化窑晶化,晶化完成后出窑,经过研磨、抛光和切割成微晶玻璃成品,其特征在于:将玻璃熔液在900~950℃的温度下,采用压制的方法制造粒径为10~50mm的玻璃颗粒,玻璃颗粒降温到800~880℃投入到冷水里钢化并形成裂纹。
所述的玻璃颗粒,可以是圆球形、扁圆形、立方体以及其它形状。
制造玉石纹微晶玻璃一般采用CaO-Al2O3-SiO2β-硅灰石系的较多,其配方最好按下列重量份比例配制:SiO2 55~61份、Al2O3 3~9份、CaO5~15份、ZnO 2~7份、BaO 1~6份、Na2O+K2O 3~8份、B2O3 0~5份、MgO 0~5份、SO3 0~1份、Sb2O3 0~1份、着色剂0~5份。
本发明的主要优点在于:1、该方法制造的微晶玻璃象天然玉石一样,纹路自然逼真、色彩柔和、清晰美观、层次分明。2、微晶玻璃表面光滑平整,无烧结气泡,断面结构致密,机械物理强度高,耐磨性、耐腐蚀性、抗风化性好。3、制造方法简单、成本低廉,可以广泛应用于微晶玻璃制造行业,为建筑材料市场增加了新的花色品种。
具体实施方式
下面通过具体实施方案对本发明作进一步描述。
实施例1:按下列重量份比例配制原材料:SiO2 58份、Al2O3 8份、CaO 11.5份、ZnO 2.7份、BaO 4.4份、Na2O 3.5份、K2O 3份、B2O3 2份、SO3 0.5份、Sb2O3 0.4份、着色剂(TiO2+CeO2)TiO2 3.5份、CeO2 2.5份。将原材料配制好后充分混合,投入到熔窑中,在1470℃熔制成玻璃熔液,在930℃温度下将熔融的玻璃熔液压制成粒径为30mm左右的圆球形状,然后将玻璃球降温到850℃投入到冷水里钢化并形成裂纹。干燥后装入模具内,进入梭式窑内晶化,晶化完成经过研磨、切割、抛光得到黄色玉石纹微晶玻璃产品。
实施例2:按下列重量份比例配制原材料:SiO2 54份、Al2O35份、CaO10份、ZnO 6份、BaO 3份、Na2O 3份、K2O 4份、B2O3 3份、MgO 2份、SO3 0.2份、Sb2O3 0.3份、蓝色着色剂(CoO+CuO)CoO 0.05份、CuO 0.15份。将原材料配制好后充分混合,投入到熔窑中,在1470℃熔制成玻璃熔液,在910℃温度下将熔融的玻璃熔液压制成粒径为40mm左右的扁圆形状,然后将扁圆形玻璃颗粒降温到860℃投入到冷水里钢化并形成裂纹。干燥后装入模具内,进入梭式窑内晶化,晶化完成经过研磨、切割、抛光得到蓝色玉石纹微晶玻璃产品。
实施例3:按下列重量份比例配制原材料:SiO2 60份、Al2O3 6份、CaO 12份、ZnO 5份、BaO 5份、Na2O 4份、K2O 3份、B2O3 4份、MgO 3份、SO3 0.5份、Sb2O3 0.2份、米色着色剂NiO 0.025份。将原材料配制好后充分混合,投入到熔窑中,在1470℃熔制成玻璃熔液,在945℃温度下将熔融的玻璃熔液压制成粒径为20mm左右的正方体形状,然后将正方体形状的玻璃颗粒降温到880℃投入到冷水里钢化并形成裂纹。干燥后装入模具内,进入梭式窑内晶化,晶化完成经过研磨、切割、抛光得到米色玉石纹微晶玻璃产品。

Claims (1)

1、一种玉石纹微晶玻璃制造方法,是将原材料混合后,投入到熔炉里熔化,制造成玻璃颗粒,将玻璃颗粒装在模板上进入晶化窑晶化,晶化完成后出窑,经过研磨、抛光和切割成微晶玻璃成品,其特征在于:将玻璃熔液在900~950℃的温度下,采用压制的方法制造粒径为10~50mm的玻璃颗粒,玻璃颗粒降温到800~880℃投入到冷水里钢化并形成裂纹;制造玉石纹微晶玻璃的配方按下列重量份比例配制:SiO2 55~61份、Al2O3 3~9份、CaO 5~15份、ZnO 2~7份、BaO 1~6份、Na2O+K2O 3~8份、B2O3 0~5份、MgO 0~5份、SO3 0~1份、Sb2O3 0~1份、着色剂0~5份。
CNB2006101407472A 2006-10-09 2006-10-09 一种玉石纹微晶玻璃制造方法 Expired - Fee Related CN100551854C (zh)

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