CN100546484C - Semanotus sinoauster attractant and lure core and preparation method thereof - Google Patents

Semanotus sinoauster attractant and lure core and preparation method thereof Download PDF

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Publication number
CN100546484C
CN100546484C CNB2006100780367A CN200610078036A CN100546484C CN 100546484 C CN100546484 C CN 100546484C CN B2006100780367 A CNB2006100780367 A CN B2006100780367A CN 200610078036 A CN200610078036 A CN 200610078036A CN 100546484 C CN100546484 C CN 100546484C
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China
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attractant
semanotus
sinoauster
volume ratio
cedrol
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CN101061808A (en
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张真
孔祥波
苏卫东
杨杰
王鸿斌
卢绪利
张培毅
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Research Institute of Forest Ecology Environment and Protection of Chinese Academy of Forestry
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Research Institute of Forest Ecology Environment and Protection of Chinese Academy of Forestry
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
    • A01N45/02Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/06Coniferophyta [gymnosperms], e.g. cypress

Abstract

The present invention relates to a kind of Semanotus sinoauster attractant, comprising: cedrene, thujopsene, cuparene, cedrol or cedar oil and cedrene, thujopsene, cuparene, cedrol or cedrene, thujopsene, cuparene, cedrol, australene, nopinene, 3-carene, citrene and myrcene; Perhaps cedar oil, australene, nopinene, 3-carene, citrene and myrcene; Perhaps cedar oil, vertofix coeur, epoxycedrane, cedryl acetate, cedrol methyl ether, wherein mix and make Semanotus sinoauster attractant by 1: 1 volume ratio, again it is added drop-wise in the vinyon bottle, makes and lure core, standby in the plastic sack of packing into.That this attractant has is efficient, nontoxic, pollution-free, easy and simple to handle, reuse, save advantage such as forest tree resource.

Description

Semanotus sinoauster attractant and lure core and preparation method thereof
Technical field
The present invention relates to a kind of insect attractant and lure core and preparation method, particularly a kind of semanotus bifasciatus insect attractant and lure core and preparation method thereof.
Background technology
Semanotus bifasciatus (Semanotus bifasciatus (Motschulsky)) belongs to coleoptera (Coleoptera), Cerambycidae (Cerambycidae), longicorn subfamily (Cerambycinae), flat longicorn family (Callidiini), is the important pests of domestic forest plants quarantine.Plants such as main harm arbor-vitae, Sabina, Chamaecyparis Space are the crushing insects of cypress class seeds, cause heavy losses for the forestry of China.In the last few years, the protections of some regional ancient cypresses was constituted a serious threat.Semanotus bifasciatus is distributed widely in ground such as northeast, Beijing, Hebei, Henan, Shanxi, Shandong, Shaanxi, Jiangsu, Zhejiang, Hubei, Jiangxi, Anhui, Guizhou, Sichuan, Fujian, Guangdong, Guangxi, Taiwan at home, and also there are distribution in external Korea, Japan.
This longicorn is in 1 year generation of China, and 2 years generation of minority are survived the winter in the trunk sapwood or in the dead and drying tree with adult, larva or pupa.Next year, early March was to adult eclosion in the first tenday period of a month in May.In 3 months, begin to lay eggs the last ten-days period, larva hatching in the last ten-days period, larva began moth and went into harm in the xylem mid-May, late August pupates in xylem, early September begins to turn into adult and enters the stage of surviving the winter.Need not supplement the nutrients behind the adult eclosion.The power of circling in the air during the fine day activity is stronger, and the longest flying distance can reach 1300m.Adult is many to carry out mating at 14~22 o'clock and lays eggs, and all the other times are drilled in hides motionlessly in the loosening the soil of bark seam, treehole, scar and butt, be difficult for being found.Female male imago can repeatedly carry out mating, and mating limit, limit spawning habit is arranged, and happiness on the sunny side, the new pruning of wind sheltering, trunk, timber and suppressed tree, backlog bark crack and 1~10 on the scar place per unit area yield ovum of just having felled do not wait.Ovum phase 7~14d, natural incubation rate is very high.Moth is gone into cortex behind larva hatching 1~2d, and moth is gone into the back and formed the crooked irregular flat burrow of a rule on the xylem surface, and burrow is circuitous up and down, or cross-section trunk tiltedly stretches, and is full of yellow-white excrement bits in the burrow.The longest 120cm that reaches of burrow, wide 2cm, dark 0.4cm.Mid-May, larva began to eat in the xylem.Bark was easy to peel off after trees were injured.After backlog was killed, top was promptly withered, was injured continuously and just can makes whole strain death.In 8 months, the last ten-days period mature larva in xylem, eat into into dark 0.6cm, the burrow of long 3~5cm, and build 1 oval pupa chamber on the top and pupate interior, pupa time about 10d.Turning into adult successively September survives the winter.What a generation took place in 2 years then is diapause to take place in 1 year, survives the winter in the gallery of xylem sapwood with larva, finishes growth to 1 year autumn, survives the winter with adult, forms 2 years generation.Its polypide is big than 1 year generation generally.
Past is mainly adopted chemical control and felling insect pest strain to the control of this worm, and control efficiency is undesirable; Main prophylactico-therapeutic measures is as follows:
1, the band worm log to allocation and transportation adopts the stifling processing of Celfume, vikane or 56% aluminum phosphide tablet.Dosage is respectively 20~30g/m 3With 12~15g/m 3, stifling 24h and 72h; Or brood tree soaked carry out water logging in the water more than 1 month and handle, or get 20% and kill 20 times of liquid of chrysanthemum fat missible oil or 40% omethoate emulsifiable solution, 10 times of liquid of 2.5% decamethrin dipping in the withe bar after the log barking, insert worm channel and kill insect.
2, be coated with the dried ovum that kills with 1000 times of liquid of 50% parathion emulsion; Or with 50% parathion-methyl missible oil, 500 times of liquid of 40% nuvacron missible oil, 20% fenvalerate missible oil, 20% fenpropathrin milk oil, 1000~1500 times of liquid of 2.5% deltamethrin milk oil spray the young larva that trunk kills newly hatched larvae or invades the food phloem.
3, the first arrival in March utilizes more than the diameter 5cm by the end of April, and the fresh cypress of long 1.5m removes branches and leaves, and per 10 a piles have been placed on the worm area, lure adult to lay eggs, and at last in by the end of May, concentrates to strip off the skin or burn.
Utilize the chemical agent control both to pollute environment, broken the ecological balance of woodland again, the ecosystem is caused very big negative effect.Utilize the trap-tree trapping can obtain certain control efficiency, but the valuable forest tree resource of waste, and waste great amount of manpower and financial resources.In addition, untimely if trap-tree is handled, trap-tree lures the collection point base to take place formation worm source easily, forms artificial propagation harm.Using the swollen leg honeybee control of Guan Shi semanotus bifasciatus also is a good biological control approach, but because the swollen numerous honeybee cost of leg honeybee of Guan Shi is higher, release tech requires high, and bee colony is difficult to set up stable population under natural environmental condition, the effect instability of its control semanotus bifasciatus.
Because the disguise of semanotus bifasciatus larval phase life, be difficult to obtain desirable effect at the prophylactico-therapeutic measures of larval phase.Behind the adult eclosion, in diffusion, seek suitable host, get in the process of food and mating, all be faced with by the threat of parasitic, severe environmental conditions or limited available resources.So the semanotus bifasciatus adult must make full use of chemical composition that host plant discharges or other stimulus signal accurate and effective search out suitable host.According to the behavioral characteristic of adult, the effective way of exploring the improvement of semanotus bifasciatus population large tracts of land is subjected to extensive concern in recent years.For example how tame units such as Beijing Forestry University, forest-science academy, Tai, Shandong Province and Shandong Agricultural University all analyze the arbor-vitae volatile materials and have carried out indoor attractive activity of semanotus bifasciatus and tentaculum electric potential activity test.A few family units all wish to develop the vegetalitas attractant of semanotus bifasciatus and to replace trap-tree this worm are monitored and prevents and treats, but all do not obtain important breakthrough.In a word, adopt medicament to be coated with dried, injection, spray medicine, to lure methods such as collection, the swollen leg honeybee of Guan Shi that semanotus bifasciatus is prevented and treated the present different drawback that all exists.
Summary of the invention
The objective of the invention is to: the shortcoming of avoiding sex attractant can only lure female worm or only lure male worm, more thorough for semanotus bifasciatus being trapped and killed control, by analyzing the volatile ingredient of semanotus bifasciatus polypide composition and host plant arbor-vitae, juniper, and a kind of plant resource biological control attractant of semanotus bifasciatus is provided and lures core, further by using attractant to lure collection control semanotus bifasciatus adult, cut off its breeding approach, the problem that solve the disguised harm of coleopteran pest, is difficult to prevent and treat.
The objective of the invention is to: a kind of method for preparing the biological attractant of plant resource of semanotus bifasciatus and lure core is provided.
The object of the present invention is achieved like this:
A kind of Semanotus sinoauster attractant provided by the invention comprises: cedrene, thujopsene, cuparene, cedrol and cedar oil; Wherein said 5 kinds of compositions were by 1: 1: 1: 1: 1~3 volume ratio is mixed, and makes Semanotus sinoauster attractant.
In above-mentioned technical scheme, also comprise thujopsene, cedrol, cedrene, cuparene; Wherein said 4 kinds of compositions mix by 1: 1 volume ratio, make Semanotus sinoauster attractant.
In above-mentioned technical scheme, also comprise thujopsene, cedrol, cedrene, cuparene and australene, nopinene, 3-carene, citrene and myrcene; Wherein said 9 kinds of compositions mix by 1: 1 volume ratio, make Semanotus sinoauster attractant.
In above-mentioned technical scheme, also comprise cedar oil, australene, nopinene, 3-carene, citrene and myrcene; Wherein said 6 kinds of compositions are by 1~3: 1: 1: 1: 1: 1 volume ratio is mixed, and makes Semanotus sinoauster attractant.
In above-mentioned technical scheme, also comprise cedar oil, vertofix coeur, epoxycedrane, cedryl acetate, cedrol methyl ether; Wherein these 5 kinds of compositions are by 1~3: 1: 1: 1: 1 volume ratio is mixed, and makes Semanotus sinoauster attractant.
In above-mentioned technical scheme, also comprise above-mentioned Semanotus sinoauster attractant is contained in the vinyon bottle to form and lure core, the bottle wall of this vinyon bottle has release function to the terpene blend that lures core, rate of release approximately is 100-300mg/24hr, the bottle wall only has permeability to the terpene compound that lures core, and the alkane of straight chain is not had permeability; Perhaps directly Semanotus sinoauster attractant is contained in the commercially available general plastic bottle, the bottle wall does not have permeability to terpene component, directly the plastic bottle bottleneck is opened during field studies, discharges attractant.Require the burst size of attractant to be controlled at 50-1000mg/24hr.
Preparation Semanotus sinoauster attractant provided by the invention lure the core method, may further comprise the steps:
1) preparation Semanotus sinoauster attractant:
Press thujopsene, cedrol, cedrene and cuparene; Wherein mix by 1: 1 volume ratio;
Cedrene, thujopsene, cuparene, cedrol and cedar oil; Wherein these 5 kinds of compositions will be by 1: 1: 1: 1: 1~3 volume ratio is mixed;
Thujopsene, cedrol, cedrene, cuparene and australene, nopinene, 3-carene, citrene and myrcene; Wherein these 9 kinds of compositions mix by 1: 1 volume ratio;
Cedar oil, australene, nopinene, 3-carene, citrene and myrcene; Wherein these 6 kinds of compositions will be by 1~3: 1: 1: 1: 1: 1 volume ratio is mixed;
Cedar oil, vertofix coeur, epoxycedrane, cedryl acetate, cedrol methyl ether; Wherein these 5 kinds of compositions are by 1~3: 1: 1: 1: 1 volume ratio is mixed;
2) preparation lures core: lure the terpene blend of core to be contained in the plastic jar step 1) preparation, make and lure core (luring the core carrier to see Fig. 4).
The rate of release that lures core approximately is 100-300mg/24hr, and rate of release is by plastic bottle, and for example the bottle wall of vinyon bottle slowly evenly discharges, and the bottle wall only has permeability to terpene compound, and the alkane of straight chain is not had permeability.In addition, utilize a bottle wall not have the plastic bottle of permeability to do when luring the core carrier, lure the release plastics of core to require to be controlled at 50-1000mg/24hr, this can guarantee to lure core to semanotus bifasciatus lure the collection effect, have can guarantee the saving attractant.
3) bottleneck is tightened after luring core to make, be contained in the plastic sack sealing and preserve.Directly bottle is suspended on the trapper during field studies.
The invention has the advantages that:
Semanotus bifasciatus plant resource attractant of the present invention, the 1-2 that its attractant effect to semanotus bifasciatus is a trap-tree are doubly.And can simultaneously the female male imago of semanotus bifasciatus be lured, avoid the shortcoming of only luring female worm or only luring male worm, it is more thorough that semanotus bifasciatus is trapped and killed control.That this semanotus bifasciatus plant attractant has is efficient, nontoxic, pollution-free, economical, easy and simple to handle, reuse, be not subjected to the environmental condition restriction, save multiple advantages such as forest tree resource, is to prevent and treat the most effective biologic product of semanotus bifasciatus adult at present.By the trapping of plant resource attractant, can overcome the inconvenience of trap-tree trapping in addition.If for example trap-tree trapping is cleared up untimelyly, lure the collection point can become the diffusion base in worm source, become genuine woodland and support worm, so just more help the propagation of semanotus bifasciatus.Trap-tree trapping cleaning is untimely, the female male imago of semanotus bifasciatus can be on trap-tree mate and oviposit, final trap-tree must be clear clean from woodland, this has increased workload and labour intensity undoubtedly, utilizes to lure the trapping of core trapper then can not have these disadvantageous problems.
Description of drawings
The funnel type trapper that Fig. 1 the present invention uses
The cross plastics trapper that Fig. 2 the present invention uses
The cross tinplate trapper that Fig. 3 the present invention uses
Fig. 4 the present invention uses lures the core carrier.
The drawing explanation:
The cross plastics trapper of 1-funnel type trapper 2-plastic bottle 3-
The cross tinplate trapper of 4-5-funnel type receiver
Concrete embodiment
Below in conjunction with concrete preparation method's embodiment and accompanying drawing to Semanotus sinoauster attractant of the present invention, lure core and application to be described in further detail:
Embodiment 1
1. lure the making of core: weighing thujopsene, cedrol, cedrene and cuparene, and mix by 1: 1 volume ratio, get mixture 30mL the luring (as shown in Figure 4) in the core carrier of vinyon bottle 2 or commercially available general plastic bottle of packing into then, make Semanotus sinoauster attractant and lure core, it approximately is 100~300mg/24hr that this Semanotus sinoauster attractant lures the rate of release of core.
2. the making of trapper: 2 plastic plates are connected into cross plastics trapper 3 (as Fig. 2), fix with a foursquare lid above, connect the receiver 5 of a funnel type below, the lower end of receiver connects a plastic bottle again.
3. the layout of trapper: at the about every 200m of woodland 2A trapper is set, trapper directly is suspended on the high branch of liftoff 1-2m, will lure core to be suspended on the middle and upper part of trapper simultaneously.
4. will lure the adult that collects to collect, dispose in every 1-2 week, can avoid the anthropochory of adult like this, and finally reach and eliminate adult, minimizing egg laying amount, progressively reduce the woodland insect density.
Embodiment 2
1, lures the making of core: with cedrene, thujopsene, cuparene, cedrol and cedar oil, these 5 kinds of compositions are by 1: 1 volume ratio or by 1: 1: 1: 1: 3 volume ratio mixes, make attractant, get the 30mL mixture then and be added drop-wise to and make Semanotus sinoauster attractant in vinyon bottle or the general plastic bottle 2 and lure core.
2, the making of trapper: the plastics device 1 of 6-10 funnel type is chained together as Fig. 1, connects the plastic cup (the cup middle opening covers one deck gauze, to guarantee not deposit rainwater) of a long barrel shape below.
3, lure the suspension of core and the layout of trapper: consistent as layouting of trapper among the embodiment 1, lure core directly to be suspended on the middle and upper part of trapper plant resource.
4, will lure the adult that collects to collect, dispose in every 1-2 week, can avoid the anthropochory of adult like this, and finally reach and eliminate adult, minimizing egg laying amount, progressively reduce the woodland insect density.
Embodiment 3,
The making that lures core of present embodiment lures the composition of core with embodiment 2: with cedrene, thujopsene, cuparene, cedrol and cedar oil, these 5 kinds of compositions are by 1: 1 volume ratio or by 1: 1: 1: 1: 2 volume ratio mixes, and makes attractant.Getting the 30mL mixture then is added drop-wise to and makes Semanotus sinoauster attractant in vinyon bottle or the general plastic bottle 2 and lure core.
Embodiment 4
1. lure the making of core: with thujopsene, cedrol, cedrene, cuparene, australene, nopinene, 3-carene, citrene and myrcene, volume ratio by 1: 1 mixes, make Semanotus sinoauster attractant, get Semanotus sinoauster attractant 30mL then and pack into and make Semanotus sinoauster attractant in vinyon bottle or the general plastic bottle 2 and lure core.
2. the making of trapper: plastic ware such as Fig. 1 of 6-10 funnel type are chained together, connect the plastic cup (the cup middle opening covers one deck gauze, to guarantee not deposit rainwater) of a long barrel shape below.
3. lure the suspension of core and the layout of trapper: consistent as layouting of trapper among the embodiment 1, lure core directly to be suspended on the middle and upper part of trapper plant resource.
4. will lure the adult that collects to collect, dispose in every 1-2 week, can avoid the anthropochory of adult like this, and finally reach and eliminate adult, minimizing egg laying amount, progressively reduce the woodland insect density.
Embodiment 5
1. lure the making of core: with cedar oil, australene, nopinene, 3-carene, citrene and myrcene, by 1: 1 volume ratio or by 1 or 3: 1: 1: 1: 1: 1 volume ratio mixes, make Semanotus sinoauster attractant, make Semanotus sinoauster attractant in then the Semanotus sinoauster attractant 30mL that makes is packed into vinyon bottle or the general plastic bottle and lure core.
2. the making of trapper: the shape of white tinplate such as Fig. 3 is made trapper,, connect a plastics string bag below, be used to collect the adult of traping.
3. lure the suspension of core and the layout of trapper: consistent as layouting of trapper among the embodiment 1, lure core directly to be suspended on the middle and upper part of trapper plant resource.
4. will lure the adult that collects to collect, dispose in every 1-2 week, can avoid the anthropochory of adult like this, and finally reach and eliminate adult, minimizing egg laying amount, progressively reduce the woodland insect density.
Embodiment 6
The making that lures core of present embodiment is with embodiment 5, lure the composition of core: with cedar oil, australene, nopinene, 3-carene, citrene and myrcene, described each component was by 2: 1: 1: 1: 1: 1 volume ratio mixes, make Semanotus sinoauster attractant, make Semanotus sinoauster attractant in then the Semanotus sinoauster attractant 30mL that makes is packed into vinyon bottle or the general plastic bottle and lure core.
Embodiment 7
1. lure core to make: with cedar oil, vertofix coeur, epoxycedrane, cedryl acetate, cedrol methyl ether composition by 1: 1 volume ratio or by 1~3: 1: 1: 1: 1 volume ratio mixed, getting 30mL then is added drop-wise in the vinyon bottle or in the general plastic bottle 2, makes Semanotus sinoauster attractant and lure core.
2. the making of trapper: the extracting waste tinplate cross tinplate trapper 4 as shown in Figure 3 that is made by handwork, these cross tinplate trapper 4 lower ends connect the plastics mesh bag of a green.
3. lure the suspension of core and the layout of trapper: consistent as layouting of trapper among the embodiment 1, lure core directly to be suspended on the middle and upper part of trapper plant resource.
4. will lure the adult that collects to collect, dispose in every 1-2 week, can avoid the anthropochory of adult like this, and finally reach and eliminate adult, minimizing egg laying amount, progressively reduce the woodland insect density.
Adopt above 5 kinds of embodiment to carry out the field trial of semanotus bifasciatus, all obtained good test effect the forest cultivation base of Changping County outlying area arbor-vitae woods.

Claims (8)

1. a Semanotus sinoauster attractant is characterized in that, comprising: cedrene, thujopsene, cuparene, cedrol and cedar oil; Wherein said 5 kinds of compositions were by 1: 1: 1: 1: 1~3 volume ratio is mixed, and makes Semanotus sinoauster attractant.
2. a Semanotus sinoauster attractant is characterized in that, comprises thujopsene, cedrol, cedrene and cuparene; Described each component is mixed by 1: 1 volume ratio, makes Semanotus sinoauster attractant.
3. a Semanotus sinoauster attractant is characterized in that, comprises thujopsene, cedrol, cedrene, cuparene, australene, nopinene, 3-carene, citrene and myrcene; Described each component is mixed by 1: 1 volume ratio, makes Semanotus sinoauster attractant.
4. a Semanotus sinoauster attractant is characterized in that, comprises cedar oil, australene, nopinene, 3-carene, citrene and myrcene; Described each component is by 1~3: 1: 1: 1: 1: 1 volume ratio is mixed, and makes Semanotus sinoauster attractant.
5, a kind of Semanotus sinoauster attractant is characterized in that, comprises cedar oil, vertofix coeur, epoxycedrane, cedryl acetate and cedrol methyl ether; Described each component is by 1~3: 1: 1: 1: 1 volume ratio is mixed, and makes Semanotus sinoauster attractant.
6, by claim 1,2,3,4 or 5 described Semanotus sinoauster attractants, it is characterized in that, also comprise Semanotus sinoauster attractant is added in the vinyon bottle to form luring core, the bottle wall of this vinyon bottle is 100-300mg/24hr to the terpene blend rate of release that lures core.
7. a Semanotus sinoauster attractant lures the preparation method of core, may further comprise the steps:
1) preparation Semanotus sinoauster attractant: this attractant comprises:
Cedrene, thujopsene, cuparene and cedrol; Described each component is mixed by 1: 1 volume ratio; Or
Cedar oil, cedrene, thujopsene, cuparene and cedrol; With described each component by 1: 1: 1: 1: 1~3 volume ratio is mixed; Or
Cedrene, thujopsene, cuparene, cedrol, australene, nopinene, 3-carene, citrene and myrcene; Described each component is mixed by 1: 1 volume ratio; Or
Cedar oil, australene, nopinene, 3-carene, citrene and myrcene; With described each component by 1~3: 1: 1: 1: 1: 1 volume ratio was mixed; Or
Cedar oil, vertofix coeur, epoxycedrane, cedryl acetate and cedrol methyl ether; With described each component by 1~3: 1: 1: 1: 1 volume ratio is mixed, and was standby;
2) preparation lures core: the Semanotus sinoauster attractant of step 1) preparation is loaded in the plastic bottle of vinyon bottle or market selling, makes and lure core;
3) bottleneck is tightened after luring core to make, be contained in the plastic sack sealing and preserve.
8, lure the preparation method of core by the described Semanotus sinoauster attractant of claim 7, it is characterized in that, described vinyon bottle has rate of release 100-300mg/24hr vinyon bottle for its bottle wall to Semanotus sinoauster attractant; The plastic bottle bottle wall that sell in used market is controlled at 50-1000mg/24hr to the rate of release of Semanotus sinoauster attractant.
CNB2006100780367A 2006-04-30 2006-04-30 Semanotus sinoauster attractant and lure core and preparation method thereof Expired - Fee Related CN100546484C (en)

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