CN100492749C - 生产电化学元件用隔膜/电极组件的方法 - Google Patents
生产电化学元件用隔膜/电极组件的方法 Download PDFInfo
- Publication number
- CN100492749C CN100492749C CNB021201943A CN02120194A CN100492749C CN 100492749 C CN100492749 C CN 100492749C CN B021201943 A CNB021201943 A CN B021201943A CN 02120194 A CN02120194 A CN 02120194A CN 100492749 C CN100492749 C CN 100492749C
- Authority
- CN
- China
- Prior art keywords
- electrode
- paste mixture
- paste
- lithium
- separator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004519 manufacturing process Methods 0.000 title abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 15
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 238000009830 intercalation Methods 0.000 claims abstract description 10
- 239000011159 matrix material Substances 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims abstract description 3
- 239000005486 organic electrolyte Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 17
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 14
- 239000002033 PVDF binder Substances 0.000 claims description 12
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 6
- 229920000098 polyolefin Polymers 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000007774 positive electrode material Substances 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000003575 carbonaceous material Substances 0.000 claims description 3
- 239000011262 electrochemically active material Substances 0.000 claims description 3
- 150000002697 manganese compounds Chemical class 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims 2
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 239000007773 negative electrode material Substances 0.000 claims 1
- 239000011149 active material Substances 0.000 abstract description 6
- -1 polyfluoropropylen Polymers 0.000 abstract description 6
- 239000004020 conductor Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000010416 ion conductor Substances 0.000 abstract 1
- 229920000131 polyvinylidene Polymers 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000003475 lamination Methods 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 239000011245 gel electrolyte Substances 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- 229920006370 Kynar Polymers 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 208000003443 Unconsciousness Diseases 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 125000001979 organolithium group Chemical group 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
- H01M4/623—Binders being polymers fluorinated polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Cell Separators (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10125619.1 | 2001-05-25 | ||
| DE10125619A DE10125619A1 (de) | 2001-05-25 | 2001-05-25 | Verfahren zur Herstellung eines Separator/Elektrodenverbundes für galvanische Elemente |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1388606A CN1388606A (zh) | 2003-01-01 |
| CN100492749C true CN100492749C (zh) | 2009-05-27 |
Family
ID=7686189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021201943A Expired - Fee Related CN100492749C (zh) | 2001-05-25 | 2002-05-24 | 生产电化学元件用隔膜/电极组件的方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20020177037A1 (enExample) |
| EP (1) | EP1261046B1 (enExample) |
| JP (1) | JP2003022800A (enExample) |
| KR (1) | KR100870604B1 (enExample) |
| CN (1) | CN100492749C (enExample) |
| DE (1) | DE10125619A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755362A (zh) * | 2007-07-25 | 2010-06-23 | 株式会社Lg化学 | 电化学装置及其制造方法 |
| DE102008015965A1 (de) | 2008-03-20 | 2009-09-24 | Varta Microbattery Gmbh | Galvanisches Element mit Foliendichtung |
| EP2736093B1 (en) * | 2011-07-20 | 2018-01-10 | LG Chem, Ltd. | Separator, manufacturing method thereof, and electrochemical device employing same |
| TWI553945B (zh) * | 2011-10-21 | 2016-10-11 | 帝人股份有限公司 | 非水系蓄電池用分隔器及非水系蓄電池 |
| US10096811B2 (en) * | 2011-10-21 | 2018-10-09 | Teijin Limited | Separator for a non-aqueous secondary battery and non-aqueous secondary battery |
| CN111403183A (zh) * | 2020-03-26 | 2020-07-10 | 浙江浙能技术研究院有限公司 | 一种由石墨烯薄膜-绝缘滤膜构成的电极-隔膜结构 |
| CN115513602B (zh) * | 2022-10-21 | 2024-01-26 | 武汉中金泰富新能源科技有限公司 | 一种含界面管理层结构电极的动力电池制造工艺 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2674685B1 (fr) * | 1991-03-29 | 1996-12-13 | Alsthom Cge Alcatel | Generateur electrochimique secondaire au lithium et a electrolyte organique liquide. |
| US5894656A (en) * | 1997-04-11 | 1999-04-20 | Valence Technology, Inc. | Methods of fabricating electrochemical cells |
| FR2766296B1 (fr) * | 1997-07-17 | 1999-08-20 | Alsthom Cge Alcatel | Procede de fabrication d'un generateur electrochimique de structure unitaire |
| JP4075259B2 (ja) * | 1999-05-26 | 2008-04-16 | ソニー株式会社 | 固体電解質二次電池 |
| AU7496200A (en) * | 1999-11-23 | 2001-06-04 | Valence Technology (Nevada), Inc. | Multi-layer electrochemical cell devices |
| US6488721B1 (en) * | 2000-06-09 | 2002-12-03 | Moltech Corporation | Methods of preparing electrochemical cells |
-
2001
- 2001-05-25 DE DE10125619A patent/DE10125619A1/de not_active Withdrawn
-
2002
- 2002-05-02 EP EP02009822A patent/EP1261046B1/de not_active Expired - Lifetime
- 2002-05-09 KR KR1020020025433A patent/KR100870604B1/ko not_active Expired - Fee Related
- 2002-05-21 US US10/152,954 patent/US20020177037A1/en not_active Abandoned
- 2002-05-24 JP JP2002150999A patent/JP2003022800A/ja active Pending
- 2002-05-24 CN CNB021201943A patent/CN100492749C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003022800A (ja) | 2003-01-24 |
| KR20020090117A (ko) | 2002-11-30 |
| EP1261046A1 (de) | 2002-11-27 |
| DE10125619A1 (de) | 2002-12-05 |
| KR100870604B1 (ko) | 2008-11-25 |
| US20020177037A1 (en) | 2002-11-28 |
| EP1261046B1 (de) | 2012-11-28 |
| CN1388606A (zh) | 2003-01-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: VALDAS MICRO-BATTERY CO., LTD. Free format text: FORMER NAME: MICRO-BATTERY CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: Hannover Patentee after: Verta Microbattery GmbH Address before: Hannover, Federal Republic of Germany Patentee before: Microcell GmbH |
|
| ASS | Succession or assignment of patent right |
Owner name: VOLKSWAGEN VARTA MICROBATTERY FORSCHUNGSGESSELLSCH Effective date: 20120116 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20120116 Address after: Hannover Co-patentee after: Varta Microbattery GmbH Patentee after: Verta Microbattery GmbH Address before: Hannover Patentee before: Verta Microbattery GmbH |
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| C56 | Change in the name or address of the patentee | ||
| CP02 | Change in the address of a patent holder |
Address after: German El Wongan Co-patentee after: Varta Microbattery GmbH Patentee after: Verta Microbattery GmbH Address before: Hannover Co-patentee before: Varta Microbattery GmbH Patentee before: Verta Microbattery GmbH |
|
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: German El Wongan Patentee after: Verta Microbattery GmbH Patentee after: Volkswagen Varta Microbattery Forschungsgesellschaft mbH & Co. KG Address before: German El Wongan Patentee before: Verta Microbattery GmbH Patentee before: Varta Microbattery GmbH |
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| TR01 | Transfer of patent right |
Effective date of registration: 20190515 Address after: German El Wongan Co-patentee after: Volkswagen Power Plant Co., Ltd. Patentee after: Verta Microbattery GmbH Address before: German El Wongan Co-patentee before: Volkswagen Varta Microbattery Forschungsgesellschaft mbH & Co. KG Patentee before: Verta Microbattery GmbH |
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| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090527 Termination date: 20200524 |
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| CF01 | Termination of patent right due to non-payment of annual fee |