CN100462492C - Textile with ultraviolet resistant , hygroscopic and perspiratory function, and its preparation method - Google Patents
Textile with ultraviolet resistant , hygroscopic and perspiratory function, and its preparation method Download PDFInfo
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- CN100462492C CN100462492C CNB2006100020034A CN200610002003A CN100462492C CN 100462492 C CN100462492 C CN 100462492C CN B2006100020034 A CNB2006100020034 A CN B2006100020034A CN 200610002003 A CN200610002003 A CN 200610002003A CN 100462492 C CN100462492 C CN 100462492C
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Abstract
The invention discloses a textile with the functions of ultraviolet resistance and moisture absorption and relative producing method. It is formed by the polyester fiber with cross-type section, while the polyester fiber comprises nanometer titanium oxide grains in the weight of 1.0-3.0%, the UPF valve >40, the core absorption height and the dry speed are vertical 80-100mm/min, and horizontal 85-110mm/10min, and the left water amount after 45 minutes is less than 10%. The invention has the advantages of ultraviolet resistance and moisture absorption.
Description
One, technical field
The present invention relates to a kind of textiles and preparation method thereof, more particularly relate to a kind of by prepared textiles of the polyster fibre of cross section and preparation method thereof with uvioresistant and moisture absorption sweat discharging functions with uvioresistant and moisture absorption sweat discharging functions.
Two, background technology
Ultraviolet ray is meant the radiated wave of sun emission wavelength 200-400nm.And according to different wavelength, can be divided into UVA, three kinds of UVB and UVC.Wherein UVC can be absorbed by Atmospheric Carbon Dioxide, and can't arrive ground.But UVA and UVB then can penetrate air by ozone hole, cause melanin to generate, and cause cortex aging, even cause cutaneum carcinoma.Harmful ultraviolet ray has two wave band UVA and UVB, and their wave band divides and is being daylight ultraviolet radiation between 280nm-315nm and the 315nm-400nm, and uvioresistant two important indicators are wave band transmitance and UPF value.Transmitance refers to the transit dose ratio of lining to UVA and two band ultraviolets of UVB, its numerical value is in percentage, more little expression uvioresistant performance is good more, UPF (Ultraviolet protection factor ultraviolet protection index) value then is to utilize transmitance and list datas such as given relative erythema radiance and sunshine spectral radiance, by given formula, calculate the UPF value, its value is big more, and the expression uvioresistant performance is good more.
Moisture absorbing and sweat releasing is to utilize the profiled-cross-section design that capillary effect is applied to textile surface and fabric construction inside, makes its suction fast, water delivery, diffusion and volatilization, thereby keeps the dry and comfortable of human body skin.This is the moisture absorption sweat discharging functions fiber, and the lining that is made into this fiber is a thread water absorben perspiring shell fabric.
The great majority that existing market occurred are single moisture absorbing and sweat releasing or uvioresistant products, and two kinds of functions are combined in being the fiber that utilizes difference in functionality respectively on the lining, form with the interweaving method braiding.
Three, summary of the invention
One of purpose of the present invention provides a kind of textiles with uvioresistant and moisture absorption sweat discharging functions.
Two of purpose of the present invention provides a kind of preparation method with textiles of uvioresistant and moisture absorption sweat discharging functions.
These and other objects of the present invention will further embody and set forth by following detailed description and explanation.
Textiles with uvioresistant and moisture absorption sweat discharging functions of the present invention, this textiles (particularly lining) is made of the polyster fibre of cross section, contains the Nano titanium dioxide particle that accounts for polyster fibre weight 1.0-3.0% in polyster fibre.
Further, in the textiles with uvioresistant and moisture absorption sweat discharging functions of the present invention, in polyster fibre, contain the Nano titanium dioxide particle that accounts for polyster fibre weight 1.5-2.0%.
Textiles with uvioresistant and moisture absorption sweat discharging functions of the present invention, when this textiles is lining, the UPF value of lining〉40, its measure wicking height and rapid-curing cutback speed are respectively vertical 80-100 millimeter/10 minutes, laterally be 85-110 millimeter/10 minute, quantity of residual＜10% after 45 minutes.
Preparation method with textiles of uvioresistant and moisture absorption sweat discharging functions of the present invention comprises that grey cloth is scheduled to, deoils, is dyeed and the back is put step in order.Wherein, described grey cloth is predefined for and earlier grey cloth is carried out pre-setting, and the pre-setting temperature is 160-180 ℃, and the time is 6-12 second, the speed of a motor vehicle be 25-35 rice/minute; Described deoiling is to adopt TX series degreaser, single bath process, and at 50-60 ℃, concentration is the 2-4 grams per liter, moves 30-40 minute.In staining procedure, the dyeing heating rate will reduce 0.3-0.5 ℃/minute than normal dyeing, and when 80-90 ℃ and 90-100 ℃ constant temperature 3-6 minute.Single bath process is adopted in dyeing, and dyeing temperature is 125-140 ℃, and the time is 40-50 minute, and after the dyeing, temperature is reduced to 75-85 ℃ of overflow washing 4-6 minute.Back arrangement step comprises fixating shape step, and described setting temperature is 145-160 ℃, and the time is 15-20 second.
Further, in the preparation method of the textiles with uvioresistant and moisture absorption sweat discharging functions of the present invention, described staining procedure is for adding dyestuff and auxiliary agent (dyestuff and the auxiliary agent used during conventional polyester dyeing) in the time of 25-40 ℃, be warming up to 85 ℃ with 0.5 ℃/minute speed then, be incubated 5 minutes, be warming up to 95-110 ℃ with 0.7 ℃/minute speed again, be incubated 5 minutes, and then be warming up to 130-140 ℃ with speed with 0.7 ℃/minute, dyeed 40-50 minute, the dyeing back is cooled to 80 ℃ of overflow washings 4-6 minute with 1 ℃/minute speed.
The present invention adopts cross section, and implants the terylene thread of Nano titanium dioxide particle, is made into the lining with uvioresistant and moisture absorbing and sweat releasing, in institutional framework design and employing coloured differently technology, to guarantee functional and the realization routine techniques parameter.Test then, test two projects, one is the UPF value, and one is measure wicking height and rapid-curing cutback speed, and these two is the important indicator of weighing lining uvioresistant and moisture absorbing and sweat releasing performance.
Realization approach of the present invention at first is to select moisture absorbing and sweat releasing and uvioresistant in conjunction with functional material, and it is that moisture absorbing and sweat releasing combines key with uvioresistant function.We adopt cross section, and implant the terylene thread of Nano titanium dioxide particle, and this fiber had both been had a moisture absorption sweat discharging functions, and uvioresistant performance is arranged again.
In the present invention in institutional framework design, the comfortableness when consideration will be in conjunction with motion and to the ultraviolet protection of human body.So when the design of lining, adopt bilayer or sandwich construction, design suitable grammes per square metre, finish the uvioresistant UPF estimated value of lining, but under the precondition be: this formula is not suitable for eyed structure is used.Specifically calculate as follows according to lining grammes per square metre UPF numerical value:
Make the template that pure raw materials is made earlier, record its UPF value=50, its standard grammes per square metre is 32 (ρ D)
1/2, according to us the lining of a large amount of different grammes per square metres to be tested, its UPF value and grammes per square metre can be regarded as linear, that is:
The numerical value of UPF value=2.5 * G/ (ρ D)
1/2
Grammes per square metre (the g/cm of G---lining
3)
Averag density (the g/m of ρ---the used fiber of lining
2)
D---the DENIER number of the used silk of lining
In dyeing and finishing process, because the special-shaped cross section fibre structure of the height of terylene thread is easy to occur dyeing and differs and characteristics such as COLOR FASTNESS is lower, and influences its moisture absorbing and sweat releasing and uvioresistant performance.For this reason, we mainly carry out from following several steps:
Earlier grey cloth is scheduled to, under the regular situation, the lining that adds spandex just can need to be scheduled to, but because the uvioresistant lining all is institutional framework and the grammes per square metre that designs, for fear of the loosening and grammes per square metre generation deviation of loop construction when dyeing, occurring, so carry out pre-setting, this is one step of key of satisfying exploitation Expected Results lining, also overcomes the unusual shortcoming of knit fabric wrinkle of cross section fiber simultaneously to greatest extent.
Can the finish that fully slough on the polyster fibre can have very large influence to dyeing homogeneity and COLOR FASTNESS, also can have influence on soft gloss of fabric and elegant style simultaneously.Cross section is because surface area is big, and finish difficulty is removed, so our technology of using degreaser to deoil, and the control temperature of deoiling, and cloth cover is deoiled fully.The degreaser of Shi Yonging can be the mixture of kinds of surface activating agent in the present invention, these degreasers can be made by oneself, also can buy from market, as the TX series degreaser that adopts the Shanghai Gaoqiao petrochemical plant to produce, be preferably the TX-10 degreaser, this degreaser is composited by multiple compositions that deoils such as sulfonic alkyl benzene, sodium hydrogen phosphate and sodium phosphate trimers.And on the technology of deoiling, change the two step method that adopts in the past, and change single bath process into, at 50-60 ℃, concentration is the 2-4 grams per liter, moves 30-40 minute and gets final product.Under the prerequisite of saving the energy, product maniflest function and routine techniques index are carried out.
Because titanium dioxide granule all has extraordinary absorption to each wave band of ultraviolet ray,, make and give fiber extraordinary uvioresistant effect so all fibers are exactly that the Nano titanium dioxide particle is implanted when the spinning in the fiber among the present invention.
Yarn raw material of the present invention is cross terylene thread, the Nano titanium dioxide particle has been added in the fiber the inside, give this fiber moisture absorbing and sweat releasing and uvioresistant function so simultaneously, use fibrage of the same race, can not be subjected to the restriction of material matching, design multiple colored type and structure, satisfy no demand.
The textiles, particularly lining prepared with method of the present invention have excellent uvioresistant and moisture absorption sweat discharging functions.
The all raw material of Shi Yonging etc. all is conventional uses in the present invention, can buy from market.In the present invention, refer in particular to as non-, all amount, percentages are unit of weight.
Below in conjunction with embodiment the present invention is carried out concrete description.As known by the technical knowledge, the present invention can realize by other the embodiment that does not break away from its spiritual essence or essential feature.Therefore, following embodiment with regard to each side, all just illustrates, and is not only.All within the scope of the present invention or the change that is equal in the scope of the present invention all be included in the invention.
Four, the specific embodiment
Embodiment 1 (the deep yellow cloth of honeycomb)
Weaving process: raw material: 75D/36Fcooldry, the lining title: WALF CHECKS, the two-sided machine of type: 34*20G/2160T, density: horizontal close 53/5 centimetres, vertical close 94/5 centimetres, door width of cloth * grammes per square metre: 103 centimetres of * 183 gram/rice
2, the nozzle height: 1.2 millimeters, yarn tension (gram): 2～3, triangle contraposition: eat (2 pieces of pins) after a while.
Earlier grey cloth (fabric that polyster fibre is made into contains the Nano titanium dioxide particle of total fiber weight 1.2 weight %) is carried out pre-setting, the pre-setting temperature is 175 ℃, and the time is 10 seconds, and the speed of a motor vehicle is 30 meters/minute, and washing shrinkage is greater than 3%, less than 5%.
The step of deoiling then, the TX-10 degreaser that adopts the Shanghai Gaoqiao petrochemical plant to produce, single bath process, at 55 ℃, concentration is 2.5 grams per liters, moves 35 minutes and gets final product.
Staining procedure is for adding dyestuff and auxiliary agent (dyestuff and the auxiliary agent used during conventional polyester dyeing) in the time of 40 ℃, be warming up to 85 ℃ with 0.5 ℃/minute speed then, be incubated 5 minutes, be warming up to 110 ℃ with 0.7 ℃/minute speed again, be incubated 5 minutes, and then be warming up to 140 ℃ with 0.7 ℃/minute speed, dyeed 45 minutes, the dyeing back is cooled to 80 ℃ of overflows washings 5 minutes with 1 ℃/minute speed.Finalize the design at last, setting temperature is 145 ℃, and the time is 20 seconds.
This lining is carried out measure wicking height with JIS L 1907 standards and rapid-curing cutback speed is tested, and it vertically is 95 (10 minutes), laterally is 93 (10 minutes), and after 45 minutes, quantity of residual 6% is tested UPF=45 with AS/NZS 4,399 1996 standards.
Embodiment 2 (the light blue cloth of WALF CHECKS)
Weaving process: raw material: 100D/48Fcooldry, the lining title: WALF CHECKS cloth, the two-sided machine of type: 34*24G/2496T, density: horizontal close 72/5 centimetres, vertical close 90/5 centimetres, door width of cloth * grammes per square metre: 180 centimetres of * 220 gram/rice
2, the nozzle height: 1.2 millimeters, yarn tension (gram): 2～3, triangle contraposition: eat (2 pieces of pins) after a while.
Earlier grey cloth (fabric that polyster fibre is made into contains the Nano titanium dioxide particle of total fiber weight 2.5 weight %) is carried out pre-setting, the pre-setting temperature is 165 ℃, and the time is 8 seconds, and the speed of a motor vehicle is 35 meters/minute, and washing shrinkage is greater than 3%, less than 5%.
The step of deoiling then, the TX-10 degreaser that adopts the Shanghai Gaoqiao petrochemical plant to produce, single bath process, at 60 ℃, concentration is 2.2 grams per liters, moves 30 minutes and gets final product.
Staining procedure is for adding dyestuff and auxiliary agent (dyestuff and the auxiliary agent used during conventional polyester dyeing) in the time of 25 ℃, be warming up to 85 ℃ with 0.5 ℃/minute speed then, be incubated 5 minutes, be warming up to 95 ℃ with 0.7 ℃/minute speed again, be incubated 5 minutes, and then be warming up to 130 ℃ with 0.7 ℃/minute speed, dyeed 45 minutes, the dyeing back is cooled to 80 ℃ of overflows washings 5 minutes with 1 ℃/minute speed.Finalize the design at last, setting temperature is 155 ℃, and the time is 15 seconds.
This lining is carried out measure wicking height with JIS L 1907 standards and rapid-curing cutback speed is tested, and it vertically is 98 (10 minutes), laterally is 103 (10 minutes), after 45 minutes, and quantity of residual 6%.Test UPF=50 with AS/NZS 4,399 1996 standards
+
Embodiment 3 (the pale yellow cloth of WALF CHECKS)
Weaving process: raw material: 100D/36Fcooldry, the lining title: WALF CHECKS cloth, the two-sided machine of type: 34*24G/2496T, density: horizontal close 70/5 centimetres, vertical close 92/5 centimetres, door width of cloth * grammes per square metre: 145 centimetres of * 200 gram/rice
2, the nozzle height: 1.2 millimeters, yarn tension (gram): 2～3, triangle contraposition: eat (2 pieces of pins) after a while.
Earlier grey cloth (fabric that polyster fibre is made into contains the Nano titanium dioxide particle of total fiber weight 1.5 weight %) is carried out pre-setting, the pre-setting temperature is 180 ℃, and the time is 6 seconds, and the speed of a motor vehicle is 25 meters/minute, and washing shrinkage is greater than 3%, less than 5%.
The step of deoiling then, the TX-8 degreaser that adopts the Shanghai Gaoqiao petrochemical plant to produce, single bath process, at 50 ℃, concentration is 3.5 grams per liters, moves 40 minutes and gets final product.
Staining procedure is for adding dyestuff and auxiliary agent (dyestuff and the auxiliary agent used during conventional polyester dyeing) in the time of 30 ℃, be warming up to 85 ℃ with 0.5 ℃/minute speed then, be incubated 5 minutes, be warming up to 100 ℃ with 0.7 ℃/minute speed again, be incubated 5 minutes, and then be warming up to 135 ℃ with 0.7 ℃/minute speed, dyeed 45 minutes, the dyeing back is cooled to 80 ℃ of overflows washings 5 minutes with 1 ℃/minute speed.Finalize the design at last, setting temperature is 155 ℃, and the time is 15 seconds.
This lining is carried out measure wicking height with JIS L 1907 standards and rapid-curing cutback speed is tested, and it vertically is 96 (10 minutes), laterally is 100 (10 minutes), after 45 minutes, and quantity of residual 6%.Test UPF=50 with AS/NZS 4,399 1996 standards
+
Claims (2)
1. preparation method with textiles of uvioresistant and moisture absorption sweat discharging functions, it is characterized in that comprising that grey cloth is scheduled to, deoils, is dyeed and the back is put step in order, described grey cloth is predefined for and earlier grey cloth is carried out pre-setting, the pre-setting temperature is 160-180 ℃, time is 6-12 second, the speed of a motor vehicle be 25-35 rice/minute; Described deoiling is to adopt TX series degreaser, single bath process, and at 50-60 ℃, concentration is the 2-4 grams per liter, moves 30-40 minute; In staining procedure, the dyeing heating rate will reduce 0.3-0.5 ℃/minute than normal dyeing, and constant temperature is 3-6 minute when 80-90 ℃ and 90-100 ℃, single bath process is adopted in dyeing, dyeing temperature is 125-140 ℃, time is 40-50 minute, and after the dyeing, temperature is reduced to 75-85 ℃ of overflow washing 4-6 minute; Described back arrangement step comprises fixating shape step, and in fixating shape step, setting temperature is 145-160 ℃, and the time is 15-20 second.
2. the preparation method with textiles of uvioresistant and moisture absorption sweat discharging functions according to claim 1, it is characterized in that described staining procedure is for adding dyestuff and auxiliary agent in the time of 25-40 ℃, be warming up to 85 ℃ with 0.5 ℃/minute speed then, be incubated 5 minutes, be warming up to 95-110 ℃ with 0.7 ℃/minute speed again, be incubated 5 minutes, and then be warming up to 130-140 ℃ with 0.7 ℃/minute speed, dyeed 40-50 minute, the dyeing back is cooled to 80 ℃ of overflow washings 4-6 minute with 1 ℃/minute speed.
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| CN103290699B (en) * | 2013-05-10 | 2015-01-07 | 中华人民共和国南通出入境检验检疫局 | Ultraviolet-prevention, moisture-absorption and quick-drying differentiation type finishing method of polyester fabric |
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| CN110344262B (en) * | 2019-07-03 | 2022-10-25 | 上海驰纺材料科技有限公司 | One-bath one-step processing method for dyeing and waterproof finishing of polyester fabric |
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Effective date of registration: 20080530 Address after: Haitian Industrial Park, Jiangnan Development Zone, Fujian City, Quanzhou Province, China: 362000 Applicant after: Quanzhou Haitian Textile Co., Ltd. Address before: 362000, GUI Tan alley 107, Licheng District, Fujian, Quanzhou Applicant before: Wang Qiming |
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Owner name: QUANZHOU HAITIAN MATERIALS TECHNOLOGY CO.,LTD Free format text: FORMER OWNER: QUANZHOU HAITIAN TEXTILE CO., LTD. Effective date: 20090424 |
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Effective date of registration: 20090424 Address after: The East China Sea City Industrial Park Quanzhou Fengze District in Fujian Province Patentee after: Quanzhou Haitian Material Technology Corporation Address before: Haitian Industrial Park, Jiangnan Development Zone, Quanzhou, Fujian Patentee before: Quanzhou Haitian Textile Co., Ltd. |
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Granted publication date: 20090218 Termination date: 20210120 |
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